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Mineralogical and Chemical Compositions of<br />

Silicate Inclusions in the El Taco,<br />

Campo del Cielo, Iron Meteorite<br />

ABSTRACT<br />

The silicate minerals in these inclusions (olivine,<br />

orthopyroxene, diopside and a sodic plagioclase)<br />

have the same composition as silicates in chondrites<br />

except for a lower FeO-content of the mafic<br />

minerals and a lower K-content of the feldspar.<br />

Small grains of K-feldspar occur with the plagioclase.<br />

Olivine contains 3.5% to 4.5% FeO, orthopyroxene<br />

3.8% to 4.6% FeO. The range of compositions<br />

within one inclusion is smaller, however, and<br />

distinct differences in mean FeO-content occur<br />

between different inclusions; the fayalite to ferrosilite<br />

ratio varies from inclusion to inclusion.<br />

The outer zone of olivine and pyroxene grains is<br />

depleted in iron oxide compared to the central part.<br />

Thus three types of disequilibria occur: (1) disequilibrium<br />

between different inclusions, (2)<br />

disequilibrium between olivine and pyroxene in a<br />

given inclusion, and (3) disequilibrium within<br />

single olivine and pyroxene grains. Both the mineral<br />

composition and the bulk chemistry of the<br />

silicate part of the inclusions are close to normal<br />

chondrites, if compared on an iron-free basis.<br />

Variations that do not seem to be caused by<br />

nonrepresentative sampling are found between different<br />

inclusions. The variations affect mainly the<br />

elements Ca, Al, and the alkalies. They can be<br />

explained by the removal of diopside and/or feldspar<br />

from a chondritic material, perhaps through<br />

partial melting. Other features suggest that the<br />

lower iron content of the mafic minerals was produced<br />

by reduction of chondritic silicates.<br />

Frank Wlotzka, Max-Planck-Institut fur Chemie, Mainz,<br />

Germany. Eugene Jarosewich, Department of Mineral<br />

Sciences, National Museum of Natural <strong>Hi</strong>story, <strong>Smithsonian</strong><br />

<strong>Institution</strong>, Washington, D.C. 20560.<br />

Frank Wlotzka and Eugene Jarosewich<br />

104<br />

Introduction<br />

The El Taco meteorite is one of the Campo del<br />

Cielo, Argentina, irons. It was recovered by an<br />

expedition described by Cassidy, et al. (1965). The<br />

El Taco specimen, which weighed 2000 kg, was cut<br />

at the Max-Planck-lnstitut fur Chemie at Mainz,<br />

Germany (<strong>Hi</strong>ntenberger, Schultz, and Weber, 1969).<br />

Three cuts were made parallel to the longest axis<br />

of the meteorite, so that two slices of about 2 cm<br />

thickness and two end pieces resulted. One of the<br />

slices (slice A, Figure 1) is on exhibit in the<br />

Meteorite Hall of the National Museum of Natural<br />

<strong>Hi</strong>story, and the other (slice B) was made<br />

available for research by the Max-Planck-Institut<br />

fiir Chemie, Mainz.<br />

Slice A revealed a large number of silicate inclusions<br />

(Figure 1). One inclusion of this kind had<br />

already been found in the El Toba specimen of<br />

Campo del Cielo and described by Park, Bunch,<br />

and Massalski (1966). Silicate inclusions are known<br />

from other iron meteorites, for instance, Linwood<br />

(Henderson and Perry, 1949), Woodbine (Mason,<br />

1967), Netschaevo (Olsen and Jarosewich, 1971),<br />

and Odessa (Marshall and Keil, 1965). A thorough<br />

description of the mineral compositions of the<br />

silicate inclusions from most of the iron meteorites<br />

known to contain them was given by Bunch, Keil,<br />

and Olsen (1970). All these iron meteorites (except<br />

Netchaevo) belong to the same chemical group IAB<br />

ofWasson(1970).<br />

In continuation of earlier work (Wlotzka and<br />

Jarosewich, 1969), this paper describes the mineralogy<br />

and the bulk chemical composition of a

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