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Polymerisation Processes Polymerisation Processes Polyethylene ...

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Polyoxymethylene – anionic polymerization of CH 2 O<br />

CH 2 O<br />

Purification, drying<br />

CH 2 O<br />

R Hexane<br />

Suspensions polymerization<br />

Formaldehyde<br />

(water solution.)<br />

Formaldehyde<br />

(Gas)<br />

R O CH2 O CH2O n<br />

Acetic anhydride<br />

End group stabilization by chemical modification<br />

R O CH2 O CH2O O CH<br />

n<br />

3<br />

Dr. Klaus-Dieter Hungenberg, BASF AG Ludwigshafen Vorlesung <strong>Polymerisation</strong>stechnik, Universität Paderborn, WS 07/08 Polymer processes<br />

Polyoxymethylene – end group stabilization<br />

Dr. Klaus-Dieter Hungenberg, BASF AG Ludwigshafen Vorlesung <strong>Polymerisation</strong>stechnik, Universität Paderborn, WS 07/08 Polymer processes<br />

O<br />

89<br />

91<br />

Polyoxymethylene – anionic polymerization of CH 2 O<br />

Dr. Klaus-Dieter Hungenberg, BASF AG Ludwigshafen Vorlesung <strong>Polymerisation</strong>stechnik, Universität Paderborn, WS 07/08 Polymer processes<br />

Polyoxymethylene – cationic bulk process –<br />

‘Schalenkreis’<br />

Milling<br />

Vacuum<br />

Heat Stabilizier<br />

Antioxidant<br />

Polymerized<br />

Material<br />

Additives<br />

Dr. Klaus-Dieter Hungenberg, BASF AG Ludwigshafen Vorlesung <strong>Polymerisation</strong>stechnik, Universität Paderborn, WS 07/08 Polymer processes<br />

90<br />

92

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