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1"'1 National Library of Canada Bib
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y thcnnally dc
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Gregory for his kindness and making
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LIST OF TABLES Table 1.1 Corrosion
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single crystals ofquartz (Nacken, 1
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phosphate control in the 19&Os was
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the standard Gibbs energies and ent
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consist ofortnophospllatcs. The bou
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2 FcIlFc[[J204(S) + 26 Na+(aq) + 12
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solubility and phase relations ofpr
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where 11 equals the ionic state ofh
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'", g :£ 30
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1.10 Project Objectives The objecti
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II - "7 /'7"7L 41 J n
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2.3.2 Single Crystal X-Ray Dif'frac
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2.4 Synthesis and Characterization
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Several solid starting materials we
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FeUlNTA(aq) + HPOl(aq) + NH/(aq) __
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All runs lasted up to to days at a
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0.0 l--l_-L_l-....J.._-L_l-....J..-
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dissolution orSNHP and allowed the
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(a) (b) Figure 3.1a and b: Scanning
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and the equilibrium constant for ma
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groups. Oxidizing agents were previ
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and reacted with aqueous sodium pho
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(al (b) Figure 3.5a and b: Scanning
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Figure 3.7: Scanning electron micro
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Table 3.1: Positional parameters fo
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Figure 3.10: Scanning electron micr
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pattern is listed in Table A.LI3. E
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4.0 SOLUBILITY AND REACTION KINETIC
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Table 4.1 Experimental C
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Table 4.3 Standard slale properties
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Table 4.6 HKF equation ofstate coef
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Equilibrium constants are listed in
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Table 4.9 Equilbrium constants for
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Table 4.10 Standard state propertie
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- Page 144: Broadbent D., Lewis G.G., and Wetto
- Page 147 and 148: Marshall W.L. (1982) Two-liquid-pha
- Page 150 and 151: Welton E.A.M. (1981) Phase equilibr
- Page 152 and 153: APPENDIX I: Powder X-ray Diffractio
- Page 154 and 155: TABLE A.l.l: X-Ray Diffraction Resu
- Page 157 and 158: TABLE A,I.3 (continued) Quinlan JCP
- Page 159 and 160: TABLE A.1.4 (continued) Quinlan (19
- Page 162 and 163: TABLE A.l.S (continued) JCPDS Quinl
- Page 164 and 165: TABLE A.1.6 (continued) Quinlan (19
- Page 168 and 169: TABLE A.L8 (continued) Boudin JCPDS
- Page 170 and 171: TABLE A.I.9 (continued) Product RGH
- Page 172 and 173: TABLE A.I.IO (continued) Ziemniak a
- Page 174: TABLE AJ.11 (continued) Zicmniak an
- Page 177 and 178: TABLE A.T.I2 (continued) Zicmniak a
- Page 180: TABLE A.I.13 (continued) Ziemniak a
- Page 183: Experimental A colorless irrcg.plal
- Page 188 and 189: Slfuc!ure Solution Refinemenl Funct
- Page 192 and 193: TABLE A.1II.1: Summary of ICP ES Re
- Page 194 and 195: TABLE A.lll.2: KinclicData Time m(N
- Page 196 and 197: TABLE A.III.2 (continued) Time m(Na
- Page 198 and 199: TABLE A.lll.2 (continued) Time m(Na
- Page 200 and 201: TABLE A.lIl.l (continued) Time m(Na
- Page 202: TABLE A.III.3 (continued) t "C m(p0