the production of thymoquinone from thymol and carvacrol
the production of thymoquinone from thymol and carvacrol
the production of thymoquinone from thymol and carvacrol
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LIST OF TABLES<br />
Table Page<br />
Table 2.1. Catalytic zeolites ……………..................................................................... 6<br />
Table 3.1. Electronic configuration <strong>of</strong> <strong>the</strong> free atoms <strong>of</strong> <strong>the</strong> first row transition<br />
elements…………………………………………………………………... 13<br />
Table 3.2. Known oxidation numbers <strong>of</strong> first row transition elements ……………… 14<br />
Table 4.1. Data on heterogeneous catalysts used in oxidation reactions...................... 22<br />
Table 5.1. Chemical composition <strong>of</strong> <strong>the</strong> essential oils (% total peak area)………...... 26<br />
Table 5.2. Data on heterogeneous <strong>and</strong> homogeneous catalysts used in monoterpene<br />
<strong>and</strong> essential oil oxidation reaction……………………………………….. 28<br />
Table 7.1 Metal content <strong>of</strong> encapsulated catalysts ……………………………..…… 38<br />
Table 7.2. IR spectral data <strong>of</strong> lig<strong>and</strong>, its neat <strong>and</strong> encapsulated complexes…………. 46<br />
Table 7.3. Surface area <strong>and</strong> micropore volume analysis …………………………….. 47<br />
Table 7.4. Total amount <strong>of</strong> weight loss up to 800 o C for NaY, CrNaY, Cr(salpn)-<br />
NaY ............................................................................................................. 48<br />
Table 7.5. Percentage decomposition <strong>of</strong> hydrogen peroxide after 1 <strong>and</strong> 2 h <strong>of</strong><br />
contact time at ambient temperature……………………………………… 50<br />
Table 7.6. Conversion <strong>and</strong> yield in <strong>the</strong> oxidation <strong>of</strong> <strong>carvacrol</strong> reactions…. ……........ 53<br />
Table 7.7. Values <strong>of</strong> parameters …………………………………………………....... 61<br />
Table 7.8. Oxidation <strong>of</strong> <strong>carvacrol</strong> by Cr (salpn)- NaY catalyst under different<br />
reaction conditions....................................................................................... 63<br />
xi