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Earth Science Frontiers, Vol. 17, Special Issue, Aug. 2010 ISSN 1005-2321<br />

Evidences of Widespread Wildfires <strong>in</strong> Laurasia <strong>and</strong> Gondwana Dur<strong>in</strong>g<br />

the Middle <strong>Jurassic</strong><br />

376<br />

L. Marynowski 1 , M. Zatoń 1<br />

1. University of Silesia, Faculty of Earth Sciences, Będzińska 60 Street, PL-41-200 Sosnowiec, Pol<strong>and</strong><br />

(E-mail: leszek.marynowski@us.edu.pl)<br />

Wildfires play a key role <strong>in</strong> Recent <strong>and</strong> ancient<br />

terrestrial ecosystem model<strong>in</strong>g but their geological<br />

history after higher plants colonization is still not<br />

well-recorded. We used the charcoals (Fig.1) <strong>and</strong><br />

pyrolytic polycyclic aromatic hydrocarbons (PAHs)<br />

co-occurrence as proxies of Middle <strong>Jurassic</strong> wildfires<br />

on both the Laurasia <strong>and</strong> Gondwana cont<strong>in</strong>ents. The<br />

Laurasian evidence comes from the Lower Callovian<br />

terrigenous deposits of the eastern part of the Central<br />

European Bas<strong>in</strong>. We have detected the charcoal frag-<br />

ments co-occurr<strong>in</strong>g with unsubstituted polycyclic<br />

aromatic hydrocarbons <strong>in</strong> the Lower Callovian, Papilė<br />

Formation of Lithuania, <strong>in</strong>dicat<strong>in</strong>g that forest fires took<br />

place at this time. The sum of concentrations of the<br />

pyrolytic polycyclic aromatic hydrocarbons, <strong>in</strong>clud<strong>in</strong>g<br />

fluoranthene, pyrene, benzofluoranthenes, benzo[e]<br />

pyrene, benzo[ghi]perylene <strong>and</strong> coronene (F<strong>in</strong>kelste<strong>in</strong><br />

et al., 2005) ranged from 4.66 <strong>and</strong> 6.57 μg/g TOC for<br />

charcoal-bear<strong>in</strong>g clay <strong>and</strong> s<strong>and</strong> samples, respectively,<br />

while for the rest of the samples, the obta<strong>in</strong>ed values are<br />

below 0.5 μg/g TOC. Concentrations of PAHs are<br />

significantly lower than those from the Hettangian<br />

samples of Sołtyków <strong>and</strong> similar to those from the<br />

Podole <strong>and</strong> Lower Gromadzice localities <strong>in</strong> central<br />

Pol<strong>and</strong> (Marynowski <strong>and</strong> Simoneit, 2009). Besides of<br />

pyrogenic PAHs, the charcoal-bear<strong>in</strong>g horizons are<br />

characterized by the occurrence of oxygen-conta<strong>in</strong><strong>in</strong>g<br />

aromatic compounds. The most common are benzo[b]<br />

naphthofurans, d<strong>in</strong>aphthofurans, <strong>and</strong> benzobisben-<br />

zofurans. As far as we know, this is the first evidence of<br />

wildfires dur<strong>in</strong>g Callovian, as based on multi-proxy<br />

documentation (Marynowski <strong>and</strong> Zatoń, 2010). The<br />

Gondwanan record of wildfires comes from the<br />

Neuquén prov<strong>in</strong>ce <strong>in</strong> Argent<strong>in</strong>a, where the Upper<br />

Aalenian/Lower Bajocian to Bathonian terrigenous<br />

sequences are characterized by the occurrence of<br />

charcoal <strong>and</strong> PAHs, a distribution of which suggests<br />

their pyrolytic orig<strong>in</strong>. This is the first multi-proxy<br />

evidence of <strong>Jurassic</strong> wildfires from the Gondwana<br />

cont<strong>in</strong>ent <strong>and</strong> generally one of a very few records of<br />

wildfires <strong>in</strong> Gondwana dur<strong>in</strong>g the Mesozoic.<br />

Fig.1 Scann<strong>in</strong>g electron photomicrographs of: (a) relatively well preserved small charcoal fragment from the Lower Callovian<br />

clays of the Karpenai exposure, Lituania. (b) tangential section of excellently preserved charcoal from the Upper Aalenian-Lower<br />

Bajocian of the R<strong>in</strong>cón del Águila exposure, Argent<strong>in</strong>a.<br />

Temperature <strong>in</strong>terpretations, derived from <strong>in</strong>er-<br />

t<strong>in</strong>ite reflectance data, show that <strong>in</strong> all cases the Middle<br />

<strong>Jurassic</strong> charcoals formed at low temperature surface<br />

fires that, <strong>in</strong> the case of Aalenian/Bajocian wildfires,<br />

sporadically reached the higher temperature crown fires.<br />

The occurrence of charcoals <strong>in</strong> the <strong>in</strong>vestigated deposits<br />

of the both cont<strong>in</strong>ents confirms the recent results that<br />

the atmospheric oxygen level reached at least 15%<br />

dur<strong>in</strong>g the Middle <strong>Jurassic</strong> times (Belcher <strong>and</strong><br />

McElwa<strong>in</strong> 2008; Berner, 2009).<br />

Acknowledgements: This work has been<br />

supported by the MNISW grant: N N307 2379 33 (for<br />

LM).<br />

Key words: Wildfires; Charcoal; PAHs; Middle<br />

<strong>Jurassic</strong><br />

References:<br />

Belcher C.M., McElwa<strong>in</strong> J.C. Limits for combustion <strong>in</strong><br />

low O2 redef<strong>in</strong>e paleoatmospheric predictions for

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