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Sodium methanolate - ipcs inchem

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OECD SIDS<br />

SODIUM METHANOLATE<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 124-41-4<br />

DATE: 28.06.2006<br />

Air : % (Fugacity Model Level I)<br />

Water : % (Fugacity Model Level I)<br />

Soil : % (Fugacity Model Level I)<br />

Biota : % (Fugacity Model Level II/III)<br />

Soil : % (Fugacity Model Level II/III)<br />

Method : other: (calculation): PCKOCWIN<br />

Year : 2003<br />

Method : PC-KOC (c) Program, Version 1.66 Syracuse Research Corporation, Merril<br />

Lane, Syracuse, New York, 13210, U.S.A., 2000, GLP: no<br />

Result : The soil or sediment adsorption coefficient (Koc) of <strong>Sodium</strong> methoxide was<br />

calculated as Koc = 1.<br />

Reliability : (3) invalid<br />

Value uncertain, because of the ionic nature of the substance.<br />

06.12.2005 (20)<br />

Type : other<br />

Media :<br />

Air : % (Fugacity Model Level I)<br />

Water : % (Fugacity Model Level I)<br />

Soil : % (Fugacity Model Level I)<br />

Biota : % (Fugacity Model Level II/III)<br />

Soil : % (Fugacity Model Level II/III)<br />

Method :<br />

Year :<br />

Remark : Due to the rapid hydrolysis in water, yielding methanol and sodium<br />

hydroxide, the data for methanol are relevant.<br />

04.12.2005 (33) (35)<br />

3.3.2 DISTRIBUTION<br />

Media : air - biota - sediment(s) - soil - water<br />

Method : Calculation according Mackay, Level III<br />

Year : 2005<br />

Method : Mackay et al.: Chemosphere, 24, 695-717 (1992) and earlier publications.<br />

Remark : Level III Program, Mackay, D., 2002, Version 2.70, Trent University<br />

The distribution of sodium <strong>methanolate</strong> is of limited relevance for the<br />

assement of the environmental behaviour as due to the rapid hydrolysis in<br />

water, the relevant species subject to environmental distribution are the<br />

degradation products sodium hydroxide and methanol.<br />

Result : Scenario 1 Scenario 2 Scenario 3 100 % Release<br />

100 % Release 100 % Release<br />

into air into water into soil<br />

[%] [%] [%]<br />

Compartment<br />

Air 18.0 0 0<br />

Water 3.50 100 0<br />

Soil 78.5 0 100<br />

Sediment 0 0 0<br />

Test condition : The calculation was conducted with the following user entered parameters:<br />

Molar mass: 54.02 g/mol<br />

Ambient temperature: 25 °C<br />

Log Kow: -0.74<br />

Vapour pressure: 1.00E-05 Pa [20 °C]<br />

Melting point: 127 °C<br />

Half-life in air: 464 hours<br />

UNEP PUBLICATIONS 51

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