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Sodium methanolate - ipcs inchem

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OECD SIDS<br />

POTASSIUM METHANOLATE<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 865-33-8<br />

DATE: 28.06.2006<br />

Half-life in air: 464 hours<br />

Emission rate:<br />

Scenario 1:<br />

3000 kg/h into air, 0 kg/h into water and soil<br />

Scenario 2:<br />

3000 kg/h into water, 0 kg/h into air and soil<br />

Scenario 3:<br />

3000 kg/h into soil, 0 kg/h into water and air<br />

Reliability : (2) valid with restrictions<br />

Calculated data, internationally accepted method.<br />

12.01.2006 (18)<br />

3.4 MODE OF DEGRADATION IN ACTUAL USE<br />

3.5 BIODEGRADATION<br />

Type :<br />

Inoculum : other<br />

Remark : As potassium methylate rapidly hydrolyzes in water to methanol and<br />

potassium hydroxide, the data of the hydrolysis products are relevant for<br />

this substance as well. SIDS dossiers, SIARs and SIAPs are available for<br />

the degradation products.<br />

Methanol is readily biodegradable (BOD5 is 76-82%).<br />

Biodegradability is not applicable to potassium hydroxide.<br />

04.12.2005 (23) (25)<br />

3.6 BOD5, COD OR BOD5/COD RATIO<br />

3.7 BIOACCUMULATION<br />

Species : other: expert judgement<br />

Exposure period : at °C<br />

Concentration :<br />

Remark : As sodium and potassium <strong>methanolate</strong> react with water under formation of<br />

sodium and potassium hydroxide and methanol, an octanol-water partition<br />

coefficient cannot be experimentally established and bioaccumulation of<br />

the substances themselves is unlikely.<br />

02.12.2005<br />

3.8 ADDITIONAL REMARKS<br />

86<br />

UNEP PUBLICATIONS

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