29.01.2014 Views

COMMISSION GEOLOGIOUE - Arkisto.gsf.fi

COMMISSION GEOLOGIOUE - Arkisto.gsf.fi

COMMISSION GEOLOGIOUE - Arkisto.gsf.fi

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

72 Bulletin de la Commission geologique de Finlande :0 212.<br />

Actually, in Table 10, only the following occurrences of orthoclase are<br />

those not belonging to the areas either described above or already earlier<br />

known to contain orthoclase (rapakivi): Suvasvesi, Heinävesi, Kuusjärvi,<br />

Ilomantsi, Kuopio, Kaavi. They all are situated in eastern Finland. Thus,<br />

such an »orthoclase areal) may weIl be expected to exist there.<br />

OPTICAL STUDY<br />

A REVIEW ON THE OPTICAL PROPERTIES OF POTASH FELDSPAR<br />

The optical properties of potash feldspars are dependent on the composition,<br />

submicroscopically exsolved phases, submicroscopic twinning, and the<br />

degree of the Al/Si order.<br />

The influence of chemical composition on optical properties has been<br />

treated by Winche1l1925 (K-Na feldspars and K-Ba feldspars), Spencer 1937<br />

and Tuttle 1952 (K-Na feldspars), and Oftedahl 1948 (K-Na-Ca feldspars).<br />

Hewlett (1959) studied the influence of Ca, Ba, Sr, and Fe on the optical<br />

properties of potash feldspar , emphasizing that the substitution of Na for<br />

K causes such a small change in the index of refraction in the range Or100<br />

to Or 60 that its effects normally are masked by the larger change caused<br />

by the substitution of minor amounts of Ca, Sr, Ba and Fe. Microclinemicroperthite<br />

usually contains in natural occurrences less than 5 wt. %<br />

NaAISi 3<br />

0 s in solid solution in the potash feldspar phase (Goldsmith and<br />

Laves 1961). The influence of this substitution on 2V of microcline can be<br />

omitted. In orthoclase-microperthites the corresponding NaAISi 3<br />

0 s content<br />

is of the magnitude of 8-10 wt. % (Goldsmith and Laves, op. cit.).<br />

Tuttle's diagram (1952) shows the axial angle to change a few degrees over<br />

the composition range Or100-0rgo'<br />

In the light of present knowledge, the influence of the cryptoperthitic<br />

exsolutions on tbe optical properties of potash feldspar is small. During<br />

homogenization of cryptoperthites there occur very small changes in the<br />

indices of refraction, and the changes in 2V are almost negligible, occasionally<br />

possibly some few degrees.<br />

Marfunin (1961, 1962) has shown that submicroscopically twinned triclinic<br />

potash feldspar has an axial angle smaller by 2 to 3 degrees than the<br />

single crystal potash feldspar with the same degree of order in Al/Si. If the<br />

twinning is balanced, the average structure has the axial plane perpendicular<br />

to (010), and the optical orientation is monoclinic. Depending upon the

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!