Vol.1 part 4-5 - Department of Invertebrate Zoology

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TABLE 1 . Instrument parameters - AAS Instrument Sample Type Parameters Cd Cr Cu Fe Ni P6 Zn Surficial Sediment wavelength (nm) 228.8 357 .9 324.7 248 .3 232 .0 283 .3 213.9 (partial & total) slit (nm) 0.7 0.7 0.7 OZ 0.2 0.7 0.7 Downcores atomization HGA air/HZCZ air/HZCZ air/HZCZ air/HZCZ air/1-12c, air/H2C2 00 wavelength (nm) 228.8 357.9 324.7 248.3 232.0 283.3 213.9 Paint Chips slit (nm) 0.7 0.7 0.7 0.2 0.2 0.7 0.7 atomization' air/HZCZ air/HZCZ air/HZCZ air/HZCZ air/HZCZ air/HZCZ air/HZCZ Pelagic & Demersal wavelength (nm) 228.8 357.9 324.7 248.3 232.0 283.3 213.9 Fish and Macro- slit (nm) 0.7 0.7 0.7 0.2 0.2 0.7 0.7 crustacea Flesh atomization HGA HGA HGA air/HZCZ HGA HGA air/HZCZ Pelagic Fish : wavelength (nm) 228 .8 357.9 324.7 248 .3 232.0 283 .3 213 .9 gills, gonads slit (run) 0.7 0.7 0.7 0.2 0.2 0.7 0.7 and liver atomization HGA HGA HGA air/HZCZ HGA HGA air/HZCZ 1 . Type of atomication: HGA = graphite furnace (flameless) air/HZCZ = air/acetylene (flame)
analyses . The standard reference sample used in this program was the National Bureau of Standards (NBS), Standard Reference Material 1645, River Sediments . Table 2 gives the results of our analyses of this reference material using the partial digestion procedure previously described . Replicate analyses (7) of an actual surficial sediment sample gave the following variabilities (coefficient of variation in percent) : Ba, 22% ; Cd, 17% ; Cr, 13% ; Cu, 18% ; Fe, 9% ; Ni, 7% ; Pb, 18% ; Zn, 5% ; and V, 6% . For many of the metals the variability is greater than expected due to analytical precision and probably results from sample inhomogeneity . 2. Biota Digested biota samples were analyzed by both AAS and NAA as described above for sediments . More flameless AAS analyses were required for the biota samples because of the low concentrations of analyte metals in the samples . Verification of the methodologies and quality assurance for the biota samples involved the analysis of spiked, homogeneous tissues (shrimp muscle) and standard reference samples . National Bureau of Standards, Standard Reference Material 1577, Bovine Liver samples were routinely analyzed . Table 3 gives the results of analysis of this NBS reference material . TABLE 2 . Trace concentrations and percent recovery in NBS SRM 1645 River Sedimentl(;Ag/g dry wt) Be Cd Crt Cu Fe' P6 Ni V Zn Reported -- 10 .2t1 .5 2.9610.28 109119 11 .311 .2 714128 45.812.9 -- 17201169 Concentration Determined 20 .2 7 .23 2 .26 84 .2 3 .94 710 23 .6 ND' 1519 Concentration % Recovery -- 71 76 77 35 99 52 -- 88 i . by partial digestion procedure 2 . weight % 3 . value not certified 4 . not determined TABLE 3. Trace concentrations and percent recovery in NBS SRM 1577 Bovine Liver (mg/g dry wt) Ba Cd Cry Gti Fe Pb Nip V Za Reported -- 0.2710 .04 -- 193110 270120 0.34±0 .08 -- -- 130110 Concentration Determined 4 .78 0 .43 1 .19 188 252 0 .31 0 .19 0 .90 138 Concentration % Recovery -- 119 -- 97 93 91 -- -- 106 1 . by partial digestion procedure
Page 1 and 2: 1981 - 13 ECOLOGICAL INVESTIGATIONS
Page 3 and 4: ECOLOGICAL INVESTIGATIONS OF PETROL
Page 5 and 6: VOLUME I-POLLUTANT FATE AND EFFECTS
Page 7 and 8: TABLE OF CONTENTS (cont'd) 3. Task
Page 9 and 10: ABSTRACT In 1978 and 1979, a multid
Page 11 and 12: wells had been drilled and also sho
Page 13 and 14: II . MATERIALS AND METHODS A. Sampl
Page 15: approximately the same size and dev
Page 19 and 20: TABLE S . Biota samples collected f
Page 21 and 22: TABLE 7. Comparison of trace metal
Page 23 and 24: TABLE 9 . Comparison of average tra
Page 25 and 26: TABLE 11 . Comparison of average tr
Page 27 and 28: IV . DISCUSSION A. Sediments l . Su
Page 29 and 30: whether or not sediment contaminati
Page 31 and 32: Cu, and Zn concentrations are simil
Page 33 and 34: number of species being collected f
Page 35 and 36: l x 10-6 TABLE 17 OIL Probable Poss
Page 37 and 38: V. CONCLUSIONS No strong evidence e
Page 39 and 40: VII. LITERATURE CITED Anderson, J .
Page 41 and 42: VIII . PERSONAL COMMUNICATIONS John
Page 43 and 44: APPENDIX A Abbreviations used in th
Page 45 and 46: APPENDIX B Metal Concentrations in
Page 47 and 48: Summary for CD in Surficial Sedimen
Page 49 and 50: Summary for CU in SurfiCial Sedimen
Page 51 and 52: Summary for NJ in Surficial Sedimen
Page 53 and 54: Summary for V in Surficial Sediment
Page 55 and 56: Trace Metals in Surficial Sediments
Page 57 and 58: APPENDIX Cl Graph of Metal Concentr
Page 59 and 60: Ca VERSUS Fe FOR bLMZB1CX +I t+t+tt
Page 61 and 62: . i t -- - * - . _ p5 .5~- Cu VERSU
Page 63 and 64: Ni VERSUS Ft FOR BLM2B1Cx tl*+t+ *t
Page 65 and 66: zn VERSUS F. FOR aLMZetcx - 210:0 t
Page 67 and 68:
Summary for CD/FE in Surfieial Sedi
Page 69 and 70:
I I Summary for CU/FE in Surfieiat
Page 71 and 72:
Summary for PB/FE in 3urfieisl Sedi
Page 73 and 74:
Trace Metals/FE in 3urfieisl Sedime
Page 75 and 76:
APPENDIX D Metal Concentrations vs
Page 77 and 78:
Summary for CR/CLAY in Surtieial Se
Page 79 and 80:
~ Summary for FE/CLAY in Surtieiel
Page 81 and 82:
. Summary for PB/CLAY in Surficial
Page 83 and 84:
. (Trace Metals/CLAY in Surficial S
Page 85 and 86:
APPENDIX E Metal Concentration vs H
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Summary Ior tR/MC in Surfitiat Sedi
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Summary for FE/HC in Surficial Sedi
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Summary for PB/MC in Surticisl Sedi
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Trace Metals/Ht Station OS in Surfi
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APPENDIX Fl Concentration of Trace
Page 97 and 98:
APPENDIX F2 Concentration of Trace
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10 20 30 CM 40 50 0 0 .2 0 .4 0,6 0
Page 101 and 102:
10 20 30 CM 40 50 FIG. 4 . 5 10 15
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0 _- to 20 30 CM O ~+ 40 t~ O 50 O
Page 105 and 106:
10 20 30 CM 40 50 0 5 10 15 20 V (
Page 107 and 108:
APPENDIX G Downcore Sediment Pb-210
Page 109 and 110:
Sample Moisture Total Weight of pCi
Page 111 and 112:
TABLE OF CONTENTS Page I . INTRODUC
Page 113 and 114:
LIST OF FIGURES Figure Page 1 . Map
Page 115 and 116:
LIST OF TABLES (coat'd) Page 36. 37
Page 117 and 118:
I . INTRODUCTION Microorganisms are
Page 119 and 120:
II . METHODS AND MATERIALS A. Study
Page 121 and 122:
Secondary Platform 13-1967 spill of
Page 123 and 124:
TABLE 3 . Composition of synthetic
Page 125 and 126:
ecording integrator . Total oil was
Page 127 and 128:
with 1 % finely ground chitin for 3
Page 129 and 130:
n,., T f+ C 41 N G d d r x .` d V U
Page 131 and 132:
300 41 200 m E as H I-25X m a X U F
Page 133 and 134:
T 0 ,o 20 30 O r X .` V m 40 W m 50
Page 135 and 136:
C m E E X OD N O C O t0 .y d U v O
Page 137 and 138:
s° O Q 0 18 * 24 0 14 e o ~o O° 0
Page 139 and 140:
100 80 J=257 60 40 20 i 0 1 N 1 E 1
Page 141 and 142:
TABLE 16 . Total number of yeast an
Page 143 and 144:
triplicate tubes of Rosenfeld's Sul
Page 145 and 146:
O V ~ ~J o v n -- 0 `'' e g 21 ~ 5
Page 147 and 148:
TABLE 29 . Concentrations of inorga
Page 149 and 150:
TABLE 33 . Oxygen consumption (z t
Page 151 and 152:
TABLE 37 . Oxygen consumption (z f
Page 153 and 154:
6.02 /x 15C 5.16 ~x27x x ~x-x ~x -x
Page 155 and 156:
10 VIL FLASKS 8 02 CONSUMED N W H J
Page 157 and 158:
2.0 FE O H Q ac 1 .0 0 50 100 150 2
Page 159 and 160:
FIG . 17 . Gas chromatography traci
Page 161 and 162:
8000 6000 W J 4000 Q i i 2000 i 0 2
Page 163 and 164:
TABLE 40 . Respiration rate for pur
Page 165 and 166:
4DOO sN N m r "O V 1000 500 50 100
Page 167 and 168:
TABLE 41 . Concentrations of NH4-N,
Page 169 and 170:
TABLE 45 . Concentrations of insolu
Page 171 and 172:
TABLE 47 . COZ produced from glucos
Page 173 and 174:
TABLE 49 . COZ produced from glucos
Page 175 and 176:
IS. Phosphorus Uptake Forty composi
Page 177 and 178:
TABLE 52 . COZ produced from tripal
Page 179 and 180:
TABLE 54 . Quantity of COZ produced
Page 181 and 182:
TABLE 56 . Quantity of COZ produced
Page 183 and 184:
TABLE 57 . COZ produced from cellul
Page 185 and 186:
TABLE 59 . COZ produced from cellul
Page 187 and 188:
TABLE 61 . COZ produced from bovine
Page 189 and 190:
TABLE 63 . Impact of oil on metabol
Page 191 and 192:
2500 0 W U D O a O U CM i 2000 1500
Page 193 and 194:
500 400 O W U O 0 X a N 0 U i 300 Z
Page 195 and 196:
IV . DISCUSSION A . Analysis of Mic
Page 197 and 198:
aerobic heterotrophs after sediment
Page 199 and 200:
grab samples (e .g. fungal counts f
Page 201 and 202:
p0 O° y °~, ,y 0 ' 2 c~ oa Ct_ c3
Page 203 and 204:
een discussed for each of the micro
Page 205 and 206:
maximum of 269 pg/day (see Tables 5
Page 207 and 208:
VI . ACKNOWLEDGEMENTS We express ou
Page 209 and 210:
Coler, R.A ., and H .B . Gunner . 1
Page 211 and 212:
VIII . PUBLICATIONS RESULTING FROM
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