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Wale Aboyade's thesis - lumes

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Akinwale Aboyade, LUMES Thesis, 2003/2004<br />

third of total anthropogenic emissions of CH 4 in the region. A separate US study also reveals that<br />

landfills are the largest anthropogenic source of methane-CH 4 in the US. Globally waste is estimated to<br />

be responsible for anywhere up to 20% of global methane emissions with MSW representing about<br />

90% of it (Bingemer and Crutzen, 1987; IPCC, 1992; Thorneloe el al, 2002).<br />

Hence the potential for reducing CH4 emissions in the waste sector lies primarily with landfills and<br />

dumpsites. Mitigating climate change therefore implies increased efforts in the proper operation of<br />

landfills in such a way as to make them more ‘climate friendly’. This is basically done by collecting<br />

emitted LFG from the disposal sites and either flaring it, or utilizing it as an energy resource for heating<br />

or for electricity production, a process referred to as Landfill Gas to Energy (LFGTE) which would be<br />

described in the next section.<br />

It is worthy to mention the fact that according to some studies, when properly maintained will actually<br />

have a positive impact on the carbon balance. Unlike incineration for instance which results in the rapid<br />

oxidation of organic matter, landfills serves as sinks for the long term accumulation of such materials,<br />

much like natural peatlands (Bramryd, 1997).<br />

2.4.1 The LFGTE process<br />

2.4.2 LFG Generation<br />

Methane (CH 4 ) emissions from disposed MSW are as a result of anaerobic biodegradation of organic<br />

waste. When large amounts of waste are dumped on the same spot, oxygen availability declines<br />

creating favourable conditions for anaerobic bacteria to act on the waste, decomposing it to produce<br />

compounds like amino acids, sugars and fatty acids which are further broken down to H 2 , CO 2 , COOH,<br />

HCOOH and CH3OH. These substances form the substrate which methanogenic bacteria works on to<br />

produce what is known as biogas or landfill gas(LFG) - a combustible gas which consists mainly of<br />

CH 4 (Bingemer and<br />

Crutzen 1987).<br />

Various conditions govern<br />

the rate of LFG generation<br />

from any site. The most<br />

important are waste<br />

composition, operation and<br />

management of the disposal<br />

site and physical conditions<br />

of location of the site.<br />

Waste composition is<br />

regarded as the most<br />

important factor affecting<br />

LFG production in any site;<br />

LFG generation is a<br />

microbial process<br />

Figure 2.2 Fate of LFG Production over time (Source: M E Fernandez et al 1995)<br />

dependent on the organic<br />

content of the waste. Studies show that the methane generation potential of waste ranges from 0 for<br />

17

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