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Erik Lindahl

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Free Energy<br />

• Introduce the available volume V A<br />

• Number of states proportional to volume<br />

• Thus, probability is proportional to volume<br />

• Consider probabilities of finding particles<br />

somewhere in volumes A vs. B:<br />

pVA/pVB = (VA exp{-EA/kT}) / (VB exp{-EB/kT})

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