13.01.2015 Views

Chem 55 Exam 2 Solutions

Chem 55 Exam 2 Solutions

Chem 55 Exam 2 Solutions

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

CHEM <strong>55</strong> Fall 2007 <strong>Exam</strong> 1 Copy # 1<br />

Name: Au,Hai Nguyen<br />

7. How many milliliters of 0.100 M KI are needed to react with 40.0 mL of 0.0400 M<br />

Hg 2 (NO 3 ) 2 if the reaction is Hg 2 2+ + 2I - Hg 2 I 2 (s)<br />

5<br />

40.0⋅<br />

10 − 3<br />

mol⋅<br />

Hg2NO32 2KI ⋅ 1L ⋅ ⋅KI<br />

⋅L⋅ Hg2NO32⋅<br />

0.0400⋅<br />

⋅ ⋅<br />

=<br />

L⋅<br />

Hg2NO32 Hg2NO32 0.100⋅<br />

mol⋅<br />

KI<br />

0.0320L⋅<br />

KI<br />

8.<br />

a. Find the activity coefficient of H + in a solution containing 0.010 M HCl plus 0.040 M<br />

KClO 4 . (H + = 900 pm)<br />

5<br />

0.010⋅ 1 2 + 0.010⋅( −1) 2 + 0.040⋅<br />

1 2 + 0.040⋅( −1) 2<br />

μ := μ = 0.050<br />

2<br />

− 0.51⋅z 2 ⋅<br />

1+<br />

α⋅<br />

μ<br />

305<br />

z:= 1 α := 900<br />

γH:= 10<br />

γH = 0.85<br />

μ<br />

b. What is the pH of this solution<br />

5<br />

( )<br />

pH := −log 0.010⋅<br />

γH pH = 2.069

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!