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Production of BHD (Bio Hydrofined Diesel) with Improved Cold Flow ...

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isomerization, we should select a reaction system which has moderate isomerization and minimal<br />

cracking.<br />

Compositions, mass%<br />

100<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

Feed <strong>BHD</strong> 300℃ 320℃<br />

Gas+Nap<br />

C11-C14<br />

isoC15<br />

isoC16<br />

isoC17<br />

isoC18<br />

nC15<br />

nC16<br />

nC17<br />

nC18<br />

Fig. 5<br />

Catalyst : Zeolite Type<br />

Compositions <strong>of</strong> Isomerization Products<br />

We compared the reactivity <strong>of</strong> two catalysts, one being zeolitic and the other amorphous. The<br />

activity <strong>of</strong> the zeolitic catalyst was higher than that <strong>of</strong> the amorphous type (Fig. 6).<br />

Feed Conversion, mass%<br />

100<br />

80 Zeolite Type<br />

60<br />

40<br />

20<br />

Amorphous Type<br />

0<br />

290 300 310 320 330 340 350<br />

Reaction Temperature, ℃<br />

Fig. 6<br />

Activity <strong>of</strong> two kinds <strong>of</strong> catalyst<br />

Focusing on the relation between isomerization and cracking, we compared cracking ratios at the<br />

same isomerization ratio (Fig. 7). The amorphous catalyst had a lower cracking ratio in the low<br />

conversion region, but the zeolitic catalyst had a lower cracking ratio in the high conversion region.

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