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Kouli_etal_2008_Groundwater modelling_BOOK.pdf - Pantelis ...

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246<br />

Franco Cucchi, Giuliana Franceschini and Luca Zini<br />

mg/l (mean of 62.5 mg/l) in shallow confined groundwater and from 30.9 mg/l to 67.6 mg/l<br />

(mean of 49.5 mg/l) in the deep confined aquifers. In contrast to the elements discussed<br />

above, the distribution of SO 4 is very different. Sulphate concentration decreases with the<br />

distance to the Tagliamento River that has 130 mg/l of sulphate when its waters enter in the<br />

Friuli Plain due to gypsum formations outcropping in the Carnic Alps.<br />

Figure 8. SO 4 , Piper diagram of the unconfined and confined groundwater samples.<br />

Environmental Isotopes<br />

The δ 18 O of groundwater (Figure 9) fall in the range -6.25‰ to -8.90‰ with a mean value of<br />

-7.59‰ in the unconfined aquifer, from -6.83‰ to -9.14‰ with a mean value of -8.05‰ in<br />

the shallow confined aquifer and from -7.01‰ to -10.35‰ with a mean value of -8.74‰ in<br />

the deeper confined aquifer (Tables 1 and 3). The most depleted groundwater samples are<br />

located in the Carnic Alps (Table 1). The rainfall samples show a great variation in isotopic<br />

composition (calculated over a two year monitoring period), the δ 18 O weighted mean values<br />

range from -7.09‰ to -10.39‰ with an average value of -9.04‰ in the mountainous areas<br />

and from -7.45‰ to -7.78‰ for δ 18 O in the Friuli Venezia Giulia Plain with a mean of -<br />

7.62‰ (Table 3).

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