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04 | 2010

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Bottle Applications<br />

PHA Bioplastics<br />

for Caps and<br />

Closures<br />

By Kristin Taylor, Business Development Manager,<br />

Telles, Lowell, Massachussetts, USA<br />

In today’s increasingly green marketplace, bioplastics can<br />

provide a strategic market advantage to brand owners by<br />

combining the environmental benefits of bioplastics (in<br />

this case, PHA) with the physical properties of conventional<br />

polymers. In this example, Mirel bioplastics were used to<br />

replace polypropylene in a cosmetic jar application, offering<br />

consumers identical product performance with the potential<br />

for reducing waste sent to landfills by providing composting<br />

alternatives.<br />

When making the transition from a traditional petroleumbased<br />

plastic to an innovative new material such as<br />

bioplastic, there is a learning curve that converters must go<br />

through to ensure proper material processing. Biopolymers<br />

can be processed on traditional process equipment with<br />

good results. It is important that processors understand<br />

the differences between biopolymers and petroleum-based<br />

polymers.<br />

The Telles technical team recently conducted trials<br />

with Cosmetic Specialties International (CSI), a Southern<br />

California-based plastic injection-molding manufacturer,<br />

utilizing their existing molds for jars and caps. The primary<br />

objective of the first trial was to successfully mold caps for<br />

cosmetic jars using Mirel P1003 injection molding grade<br />

material on the customer’s existing production tooling and<br />

machinery. The existing tooling was multi-cavity with hotrunners.<br />

Because the tool was designed for PP, slight<br />

flashing could not be avoided due to the vent geometry.<br />

Proper thread design, equipment and tooling set-up<br />

facilitated effective stripping of the Mirel P1003 caps from<br />

the mold without thread damage or the use of a collapsible<br />

core.<br />

The second trial conducted at CSI involved molding caps<br />

for shampoo bottles using existing PP tooling with collapsible<br />

cores. In this case, the male part of the tool (inside of the<br />

cap) collapses inward thus allowing the part to be removed<br />

without damage to the threads. Molds with collapsible cores<br />

are more expensive to manufacture due to their increased<br />

complexity. Parts were produced on this tooling with minimal<br />

flash and at cycle times comparable to the current PP resin.<br />

Telles (the joint venture between Metabolix and ADM)<br />

has made significant strides this year in providing injection<br />

molding grades that can be processed on existing equipment<br />

and tooling. However, as with any material change, tweaking<br />

of the processing conditions and some minor tooling<br />

modifications are generally required to provide the most<br />

robust and repeatable process. Parts made with Mirel P1003<br />

not only look, feel and perform just like their traditional<br />

petroleum-based plastic counterparts, but also offer brand<br />

owners significant environmental benefits to distinguish<br />

themselves in this increasingly competitive, green market.<br />

Mirel P1003 is a semi-crystalline polyester specifically<br />

engineered for injection molding applications with properties<br />

comparable to traditional polymers, such as heat resistance,<br />

moisture resistance, high modulus and outstanding shelf<br />

stability. The P1003 resin can be easily colored using a<br />

Mirel-based masterbatch color without affecting its physical<br />

properties or biodegradability.<br />

“Jars, double-wall containers, and closures made from this<br />

material are ideal for a family of cosmetics, skincare, hair<br />

care, styling products, and body scrubs. These containers<br />

are easy to silk screen and to decorate,” explained Hiram<br />

Santana, Director of Marketing & Business Development at<br />

CSI. “With the combination of material performance and the<br />

environmental benefits, this is an excellent material for brand<br />

owners with corporate sustainability goals who want to bring<br />

an environmentally responsible product line to market.”<br />

Mirel is biobased and biodegradable in natural soil and<br />

water environments, home composting systems, and<br />

industrial composting facilities, where these facilities are<br />

available. The rate and extent of Mirel’s biodegradability will<br />

depend on the size and shape of the articles made from it.<br />

However, like nearly all bioplastics and organic matter, Mirel<br />

is not designed to biodegrade in conventional landfills.<br />

www.mirelplastics.com<br />

18 bioplastics MAGAZINE [<strong>04</strong>/10] Vol. 5

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