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Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />

bioplastics MAGAZINE VOL 18<br />

Cover Story<br />

30 Years of European Bioplastics | 14<br />

Highlights<br />

Fibres / Textiles | 18<br />

Polyurethane / Elastomers | 38<br />

ISSN 1862-5258 Sep / Oct <strong>05</strong> / <strong>2023</strong>


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FKuR works every day to support our customers to meet their product sustain -<br />

ability objectives by creating sustainable resins. Discover our „Plastics care for<br />

Future“-portfolio with FKuR’s bioplastics, high-quality recyclates, mass-balanceresins<br />

or bio-recyclate hybrids. Are you ready to power up your product?<br />

We make circular plastic products work!<br />

Visit us!<br />

Booth B4-44<strong>05</strong>, hall B4<br />

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dear<br />

Editorial<br />

readers<br />

In your hands, or on your screens, you see the official<br />

2 nd issue of Renewable Carbon Plastics. After the previous<br />

issue had a flashier black and gold look, we are returning<br />

to our old and faithful look. But we were not the only<br />

ones who had things to celebrate with our 100 th issue<br />

and simultaneous rebranding. FKuR turned 20 (or 30<br />

depending on how you count) and EUPB also celebrated<br />

their 30-year anniversary. Bioplastics are getting old y’all,<br />

but we – as an industry – won’t slow down. There is still a<br />

need for trailblazers and innovators that risk challenging<br />

the status quo, rising to new heights.<br />

We are no different as this year we will be hosting our<br />

very first conference across the pond with the 3 rd PHA<br />

World Congress, which will be held on the 10 th and 11 th<br />

of October in Atlanta. It is a very exciting time and the<br />

whole team seems to be buzzing with energy. And we<br />

hope to see many familiar and also many new faces. And<br />

in case you cannot make it to Atlanta shortly after the<br />

Fakuma (Friedrichshafen, Germany) will offer another<br />

opportunity connect or reconnect.<br />

And while many things are changing and evolving<br />

(hopefully for the better) some things remain the same,<br />

like our commitment to bring you the best and most<br />

interesting stories and news. This issue will focus on<br />

Fibres / Textiles as well as Polyurethane / Elastomers.<br />

I will now finish the last round of proofreading before<br />

trying to catch some late summer sun before autumn<br />

claims its place with more windy and rainy weather. Yet,<br />

rainy and windy days are also the perfect atmosphere to stay<br />

inside and read – Renewable Carbon Plastics for example.<br />

@BIOPLASTICSMAG<br />

In any case, I hope you will enjoy the weather, be it bright or<br />

gloomy – just like I will try to do.<br />

Yours sincerely<br />

@RENEWABLECARBONPLASTICS<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

3


Imprint<br />

Content<br />

Sep / Oct <strong>05</strong>|<strong>2023</strong><br />

Renewable Carbon Initiative<br />

10 RCI Manifesto<br />

Events<br />

12 PLAST review<br />

13 8 th PLA World Congress<br />

Cover Story<br />

14 30 Years of driving the<br />

evolution of bioplastics<br />

On-Site<br />

16 Bioplastics expert: FKuR<br />

Fibres, Textiles<br />

20 Biobased Nylon<br />

20 Mushroom fibres for textiles<br />

22 Algae-based textiles<br />

24 Infinitely recycled Nylon<br />

25 Depolymerization of PA66<br />

using microwaves<br />

26 Sustainable leather<br />

27 Cellulose fibres – a smooth additive<br />

27 Textile yarns for biopolyesters<br />

Advanced Recycling<br />

30 Use biodegradation to recycle conventional<br />

plastics into new biobased materials<br />

From Science & Research<br />

34 Catalysis for a multidimensional circular<br />

economy<br />

Materials<br />

36 Seawead based resins<br />

Polyurethane / Elastomers<br />

38 Polyurethane upcycling approach<br />

39 Sustainable polyurethane<br />

mattress recycling<br />

40 New sustainable materials<br />

Applications<br />

41 Industrially compostable stretch<br />

wrap technology<br />

Opinion<br />

44 Solving the plastics challenge together<br />

FIBRES<br />

ELASTOMERS<br />

ON-SITE<br />

3 Editorial<br />

5 News<br />

32 10 years ago<br />

42 Application News<br />

46 Suppliers Guide<br />

49 Event calendar<br />

50 Companies in this issue<br />

Publisher / Editorial<br />

Alex Thielen, Editor-in-Chief (AT)<br />

Dr Michael Thielen,<br />

Senior Consulting Editor, Publisher (MT)<br />

Samuel Brangenberg, Reporter (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Hackesstr. 99<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 664864<br />

fax: +49 (0)2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161-6884468<br />

sb@bioplasticsmagazine.com<br />

Michael Thielen (English Language)<br />

(see head office)<br />

Layout/Production<br />

Philipp Thielen<br />

Photography<br />

Philipp Thielen, Michael Thielen<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Renewable Carbon Plastics<br />

(bioplastics MAGAZINE)<br />

Volume 18 – <strong>2023</strong><br />

ISSN 1862-5258<br />

RCP / bM is published 6 times a year.<br />

This publication is sent to qualified<br />

subscribers (179 Euro for 6 issues).<br />

Renewable Carbon Plastics (bioplastics<br />

MAGAZINE) is read in 100 countries.<br />

Every effort is made to verify all information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

Renewable Carbon Plastics<br />

(bioplastics MAGAZINE), or on the websites<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not<br />

necessarily reflect those of Polymedia<br />

Publisher.<br />

Renewable Carbon Plastics (bioplastics<br />

MAGAZINE) welcomes contributions for<br />

publication. Submissions are accepted on<br />

the basis of full assignment of copyright<br />

to Polymedia Publisher GmbH unless<br />

otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity, or legality.<br />

The fact that product names may not be<br />

identified in our editorial as trademarks is<br />

not an indication that such names are not<br />

registered trademarks.<br />

Renewable Carbon Plastics (bioplastics<br />

MAGAZINE) uses British spelling.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped bioplastic envelopes<br />

sponsored by Sidaplax/Plastic Suppliers<br />

Belgium/USA).Cover<br />

Cover<br />

Denise Valdix, European Bioplastics<br />

(Photo: Michael Thielen)<br />

@BIOPLASTICSMAG @BIOPLASTICSMAGAZINE @RENEWABLECARBONPLASTICS


Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of the past two months.<br />

The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />

tinyurl.com/news-<strong>2023</strong>0829<br />

News<br />

From CO 2<br />

to polyolefins<br />

(29 August <strong>2023</strong>)<br />

Braskem (São Paulo, Brazil) and the University of São Paulo (USP)<br />

have announced a partnership to develop lines of research for converting<br />

CO 2<br />

into chemical products such as olefins and alcohols, thus mitigating<br />

its emissions into the environment and using it as a raw material for the<br />

production of polyolefins.<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

PET bottles produced with bio-attributed<br />

materials in Japan<br />

Neste (Espoo, Finland) has entered a cooperation with<br />

Suntory (Osaka, Japan), ENEOS (Tokyo, Japan), and Mitsubishi<br />

Corporation (Tokyo, Japan) to enable the production of PET<br />

made with renewable Neste RE on a commercial scale.<br />

Neste RE is Neste’s feedstock for polymer production,<br />

made 100 % from biobased raw materials such as waste and<br />

residues, e.g. used cooking oil, to replace fossil feedstock<br />

in the value chain. Japanese beverage company Suntory<br />

will utilize the renewable PET resin to produce bottles for<br />

its products in 2024.<br />

A new partner for Neste in Japan, ENEOS will use biointermediates<br />

based on Neste RE to produce bio-PX (bioparaxylene)<br />

at its Mizushima Refinery in Okayama, Japan.<br />

The bio-PX will then be converted to PTA (purified terephthalic<br />

acid) and subsequently to PET resin for Suntory to use to<br />

manufacture their PET bottles. Mitsubishi Corporation<br />

will be coordinating the collaboration between the<br />

value chain partners.<br />

“In order to tackle the imminent climate crisis and its<br />

consequences, companies are required to take responsibility<br />

now. Through partnering along the value chain, Neste can<br />

contribute to reducing the polymers and chemicals industry’s<br />

dependence on fossil resources as well as to manufacturing<br />

of products that have a lower carbon footprint”, says Lilyana<br />

Budyanto, Head of Sustainable Partnerships APAC at Neste<br />

Renewable Polymers and Chemicals business unit.<br />

A mass balancing approach will be applied to allocate the<br />

biobased materials to the PET bottles. AT MT<br />

www.neste.com | www.suntory.com<br />

www.eneos.co.jp | www.mitsubishicorp.com<br />

Our frame colours<br />

Topics related to the<br />

Renewable Carbon Initiative...<br />

Bioplastics related topics, i.e.<br />

all topics around biobased<br />

and biodegradable plastics,<br />

come in the familiar<br />

green frame.<br />

All topics related to<br />

Advanced Recycling, such<br />

as chemical recycling<br />

or enzymatic degradation<br />

of mixed waste into<br />

building blocks for<br />

new plastics have this<br />

turquoise coloured frame.<br />

When it comes to plastics<br />

made of any kind of carbon<br />

source associated with<br />

Carbon Capture & Utilisation<br />

we use this frame colour.<br />

The familiar blue<br />

frame stands for rather<br />

administrative sections,<br />

such as the table of<br />

contents or the<br />

“Dear readers” on page 3.<br />

If a topic belongs to more<br />

than one group, we use<br />

crosshatched frames.<br />

Ochre/green stands for<br />

Carbon Capture &<br />

Bioplastics, e. g.<br />

PHA made from methane.<br />

Articles covering<br />

Recycling and Bioplastics ...<br />

Recycling & Carbon Capture<br />

We’re sure, you got it!<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

5


News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

A new era of<br />

renewable carbon<br />

materials<br />

Conagen (Bedford, MA USA), and Sumitomo<br />

Chemical (Tokyo, Japan) have announced to jointly<br />

develop p-hydroxystyrene (HS) and its polymer, poly<br />

p-hydroxystyrene (PHS), using a combination of<br />

biosynthesis, chemosynthesis, and polymerization.<br />

The monomer and the polymer are made of<br />

100 % renewable carbon, marking a new era of<br />

sustainable production.<br />

Developing PHS using a combination of biosynthesis,<br />

chemosynthesis, and polymerization represents a<br />

significant breakthrough in the field of sustainable material<br />

production. Efforts to reduce reliance on petroleum and<br />

transition towards renewable and sustainable alternatives<br />

have gained momentum in recent years.<br />

With renewable biomass as the starting material, this<br />

joint development between Conagen and Sumitomo<br />

Chemical creates an environmentally friendly and<br />

cost-effective product.<br />

This partnership represents a significant milestone in the<br />

development of sustainable materials, and this approach<br />

to PHS production is expected to reduce the carbon<br />

footprint associated with traditional chemical synthesis<br />

methods. It is a crucial step towards more sustainable<br />

manufacturing processes with a positive impact.<br />

The Conagen-Sumitomo partnership leverages<br />

Conagen’s expertise in microbial strain design and<br />

development with Sumitomo Chemical’s proficiency<br />

in chemical production and commercialization.<br />

The collaboration aims to create a platform that enables<br />

the production of sustainable chemicals to replace<br />

petrochemicals in an extended range of many applications.<br />

PHS is used to produce polymers, resins, and other<br />

chemicals. The monomer HS can also be used as an<br />

input for the synthesis of other chemicals, such as<br />

pharmaceuticals and fragrances. The applications of HS<br />

and PHS are limitless and can span uses from electronics<br />

to personal care and other consumer products.<br />

The monomer HS, with the chemical formula C 8<br />

H 8<br />

O, is<br />

a derivative of styrene in which a hydroxyl group (-OH) is<br />

attached to the aromatic ring’s para position (carbon atom<br />

4). The HS and PHS are examples of green chemistry for<br />

minimizing waste, reducing hazardous chemicals, and<br />

using catalysts that can be easily separated and reused.<br />

This joint development project promises to potentially<br />

pave the way for developing novel renewable and<br />

sustainable materials. “Similar technology can be used to<br />

produce other key chemical ingredients by fermentation<br />

at industrial scale, such as cinnamic acid, monohydroxybenzoic<br />

acid, and dihydroxy-benzoic acid”, said J.<br />

McNamara, V.P. of chemical applications at Conagen. AT<br />

www.conagen.com | www.sumitomo-chem.co.jp<br />

From CO 2<br />

to<br />

polyolefins<br />

Braskem (São Paulo, Brazil) and the University of São<br />

Paulo (USP) have announced a partnership to develop lines<br />

of research for converting CO 2<br />

into chemical products such<br />

as olefins and alcohols, thus mitigating its emissions into<br />

the environment and using it as a raw material for the<br />

production of polyolefins.<br />

The partnership with USP, through the Research Center<br />

for Greenhouse Gas Innovation (RCGI), which also includes<br />

the participation of the Federal University of São Carlos<br />

(UFSCar), focuses on studying innovative routes for CO 2<br />

conversion through both catalytic and electrocatalytic<br />

processes. While in conventional processes in the chemical<br />

industry, catalysts (materials that trigger chemical<br />

reactions) are thermally activated, electrocatalysis uses<br />

electricity to activate them. As such, renewable energy can<br />

be used partially or fully for CO 2<br />

conversion. AT<br />

www.braskem.com | www5.usp.br<br />

Chemical recycling<br />

from old plastic to new<br />

adhesives<br />

A recently launched research project by the Fraunhofer<br />

Institute for Manufacturing Technology and Advanced<br />

Materials IFAM in Bremen (Germany) and the German<br />

Plastics Center SKZ in Würzburg aims to add thermally<br />

damaged plastics to the recycling economy through<br />

chemical recycling. The material of choice is PET, which<br />

is already well-established in mechanical recycling.<br />

Thanks to the well-known bottles and the deposit system<br />

in Germany, the material is mostly sorted by type and most<br />

of it is already efficiently recycled. The RezyBond project is<br />

dedicated to PET fractions that have been recycled several<br />

times and are too old, or that do not end up in this (bottle)<br />

cycle at all, such as other PET packaging.<br />

The process is unique in that the chemical recycling is<br />

performed on a standard twin-screw extruder. "Our goal<br />

is to develop a continuous, reactive recycling process for<br />

PET recyclates into polyester polyols. These can then be<br />

used as chemical feedstock", explains Hatice Malatyali,<br />

Group Manager Extrusion and Compounding at SKZ.<br />

The polyols obtained can be used as raw materials for<br />

a wide range of technological applications, such as<br />

adhesives and coatings. In the project, they will be used<br />

as starting materials for adhesive formulations and thus<br />

transferred directly to an application. A demonstration<br />

plant is also planned at the SKZ to make the process<br />

accessible to interested medium-sized companies. AT<br />

www.skz.de | www.ifam.fraunhofer.de<br />

6 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Novel hybrid PET/F bottle<br />

Origin Materials (West Sacramento, CA, USA) and Husky Technologies (Bolton, ON, Canada) announced a milestone in the<br />

commercialization of PET (polyethylene terephthalate) incorporating the sustainable chemical FDCA (furandicarboxylic acid) for<br />

advanced packaging and other applications.<br />

Origin successfully polymerized the biobased sustainable chemical FDCA into the common recyclable plastic, PET, and Husky<br />

moulded the resulting PET/F hybrid polymer into preforms that were then blown into bottles. The companies used Husky’s injection<br />

moulding technologies and manufacturing equipment, a commercial manufacturing-scale level of processing demonstrating the<br />

ability of PET/F, a polymer made with FDCA, to be integrated into existing PET production systems.<br />

Origin expects to develop and sell a family of 100 % biobased, low-carbon PET/F polymers offering full recyclability and<br />

superior performance compared with traditional 100 % petroleum-derived PET. Origin anticipates that PET/F will offer tuneable<br />

performance, with properties like enhanced mechanical performance and superior barrier properties enabling longer shelf life<br />

controlled by adjusting manufacturing conditions and the quantity of FDCA copolymer.<br />

This innovation demonstrates a pathway for the drop-in market adoption of FDCA to produce superior polymers cost-effectively<br />

from biomass using Origin technology. Origin expects to enable the production of FDCA, PEF (polyethylene furanoate), and PET/F<br />

at commercial scale using its patented technology platform, which turns the carbon found in sustainable wood residues into<br />

useful materials, while capturing carbon in the process.<br />

FDCA is a chemical building block with diverse applications including polyesters,<br />

polyamides, polyurethanes, coating resins, and plasticizers. FDCA is also the<br />

precursor for the next-generation sustainable polymer PEF (polyethylene<br />

furanoate). By combining FDCA with PET, Origin has produced PET/F, a tuneable<br />

hybrid polymer offering performance enhancements and full recyclability.<br />

PEF, another product derived from FDCA, offers an attractive combination of<br />

sustainability and performance benefits for packaging. Origin’s PEF is expected<br />

to be 100 % biobased, fully recyclable, have attractive unit economics, and<br />

offer a significantly reduced carbon footprint, with superior strength, thermal<br />

properties, and barrier properties compared to today’s widely used petroleumbased<br />

materials. AT/MT<br />

News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

www.originmaterials.com | www.husky.co<br />

Textiles aiming to go greener<br />

There’s a growing demand for sustainable products in the<br />

textile sector, meaning the development, production, and<br />

use of biopolymers for such use introduces an alternative<br />

with a very high investment potential.<br />

Within this context, the synergies between<br />

textile and natural resin areas are highly<br />

innovative for the textile and clothing<br />

sector. The RN21 project– Innovation<br />

in the natural resin sector to<br />

strengthen the national bioeconomy<br />

– has received European funding.<br />

The goal of this RN21 project, R&D<br />

line II2.M3A – Application of natural<br />

resin in textiles – is the development<br />

of new and innovative textile structures<br />

produced from rosin-based biopolymers.<br />

The consortium is formed of five partners – Tintex,<br />

United Resins, United Biopolymers, CITEVE, and CeNTI<br />

– promoting the collaboration between the textile sector<br />

and rosin derivatives producers, ultimately increasing the<br />

sustainability and applicability of rosin derivatives in the<br />

textile sector. To achieve such an ambitious goal, and ensure<br />

the promotion and the exploitation of natural resin, distinct<br />

approaches were outlined with a strong focus on<br />

the valorization of the rosin derivatives<br />

on the development of<br />

• biopolymer fibres<br />

and textile structures,<br />

• rosin-derived systems as a<br />

colouring/dyeing auxiliary for<br />

textile structures, and<br />

• films and coatings based<br />

exclusively on biodegradable<br />

biopolymers and rosin derivatives.<br />

The vision is to encourage and<br />

purpose the use of sustainable<br />

biobased materials, such as rosin<br />

derivatives, to decrease the carbon<br />

footprint heading towards green carbon,<br />

within high-added value textile products. MT<br />

www.forestwise.pt/en/projects/rn21<br />

www.unitedbiopolymers.com<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

7


New PHA collaboration<br />

Danimer Scientific (Bainbridge, GA, USA), a leading next-generation bioplastics company focused on the development and<br />

production of biodegradable materials, recently announced it is expanding its collaboration with Chevron Phillips Chemical (The<br />

Woodlands, TX, USA) to explore development and commercialization of cast extrusion films, blown extrusion films, injection<br />

moulded parts, and rotational moulded parts using Rinnovo polymers produced in a loop slurry reactor process.<br />

Rinnovo is a type of PHA synthesized from lactones produced using Danimer’s proprietary Novo22 catalyst technology, which<br />

can be used in the production of biodegradable alternatives to traditional plastics. The collaboration expands on Danimer and<br />

CPChem’s previously announced agreement, in which Danimer is evaluating the use of CPChem’s loop slurry reactor design to<br />

develop a continuous reactor system in the manufacturing process for Rinnovo.<br />

Danimer CEO Stephen E. Croskrey said, “Our business relationship with CPChem continues to yield results, and we’re excited<br />

about the further opportunities that lie ahead. CPChem’s Research and Technology lab in Bartlesville, Oklahoma, is a premier<br />

facility staffed with world-class talent that, we believe, will accelerate the path toward adoption of Rinnovo materials in highvolume<br />

applications that will assist in lowering the cost to serve key markets”.<br />

Opened in 1950 by Phillips 66, CPChem’s Bartlesville facility contains first-class research equipment allowing for rapid testing<br />

of products across various processing conditions. Additionally, the facility’s testing and analytical capabilities provide a more rapid<br />

feedback loop, accelerating the development and optimization of resin formulations.<br />

“We continue to be excited about the potential of our MarTECH ® process technology and related collaborations to advance<br />

Danimer’s Rinnovo, another CPChem initiative that can help accelerate change for a more sustainable future”, said Venki<br />

Chandrashekar, CPChem VP of research and technology. AT<br />

www.danimerscientific.com | www.cpchem.com<br />

New cellulosebased<br />

packaging<br />

films<br />

LUT University (Lappeenranta, Finland) and the<br />

VTT Technical Research Centre of Finland (Espoo,<br />

Finland) are developing new environmentally friendly<br />

packaging solutions with 34 industrial partners. In the<br />

Films for Future (F3) research project, a cellulosebased<br />

alternative will replace the plastic films of<br />

cardboard packages. The program is funded by the<br />

European Regional Development Fund.<br />

Packages with biobased and biodegradable<br />

films will make recycling easier because they can<br />

be put straight into the cardboard recycling pile.<br />

Recyclability will also minimize the amount of waste<br />

and tackle littering.<br />

The new film material will also meet the demands<br />

of the EU’s Packaging and Packaging Waste Directive,<br />

which deals with the shift to a circular economy and<br />

improving the quality of the environment.<br />

In the F3 project, VTT researches and develops<br />

the properties of the cellulose film. LUT University,<br />

in turn, verifies packaging performance, tailors the<br />

converting process, equipment, and tooling, and<br />

examines the value chain of the new product. AT<br />

www.lut.fi | www.vttresearch.com<br />

Joint venture for<br />

bio-ethylene<br />

Braskem (São Paulo, Brazil) and SCG Chemicals (Bangkok,<br />

Thailand) have signed a joint venture agreement to create Braskem<br />

Siam Company Limited.<br />

Subject to clearance from the relevant anti-trust authorities<br />

and final investment decision by the partners, this joint venture<br />

aims to produce bio-ethylene from bioethanol dehydration and<br />

to commercialize I’m green biobased polyethylene (PE), using<br />

the EtE EverGreen technology. The technology results from the<br />

partnership agreement between Lummus Technology (Houston,<br />

TX, USA) and Braskem to develop and license this technology.<br />

The bio-ethylene plant, that will enable the production of the<br />

I’m green biobased polyethylene, is the first of its kind outside of<br />

Brazil. The new plant in Thailand will almost double the existing<br />

capacity of I’m green biobased polyethylene to meet the growing<br />

demand for biopolymers globally, with a focus on the fast-growing<br />

demand for sustainable products in Asia.<br />

The combination of Braskem’s biobased plastics know-how with<br />

SCG Chemicals’ position in the Asian market and expertise in PE<br />

production provides a solid business basis for the joint venture.<br />

Braskem will contribute with proven technology through its<br />

partnership with Lummus Technology, operational experience in<br />

the ethanol dehydration process and the I´m green brand strength<br />

in key global markets. SCG Chemicals will provide expertise in<br />

high-quality polyethylene grades for different applications,<br />

operational excellence in polyethylene manufacturing and market<br />

reach in Southeast Asia.<br />

The project will be located in Map Ta Phut, Rayong, Thailand. AT<br />

www.braskem.com | www.scgchemicals.com<br />

8 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Transforming flies into degradable plastics<br />

Imagine using insects as a source of chemicals<br />

to make plastics that can biodegrade later –<br />

with the help of that very same type of bug.<br />

That concept is closer to reality than you might<br />

expect. Recently, researchers described their<br />

progress, including isolation and purification of<br />

insect-derived chemicals and their conversion<br />

into functional bioplastics.<br />

The researchers presented their results at the<br />

fall meeting of the American Chemical Society<br />

(ACS). ACS Fall <strong>2023</strong> was a hybrid meeting held<br />

virtually and in-person featuring about 12,000<br />

presentations on a wide range of science topics.<br />

“For 20 years, my group has been developing<br />

methods to transform natural products — such as glucose<br />

obtained from sugar cane or trees – into degradable,<br />

digestible polymers that don’t persist in the environment”,<br />

says Karen Wooley, the project’s principal investigator. “But<br />

those natural products are harvested from resources that are<br />

also used for food, fuel, construction, and transportation”.<br />

So Wooley began searching for alternative sources that<br />

wouldn’t have these competing applications. Her colleague<br />

Jeffery Tomberlin suggested she could use waste products<br />

left over from farming black soldier flies, an expanding<br />

industry he had been helping to develop.<br />

The larvae of these flies contain many proteins and<br />

other nutritious compounds, so the immature insects are<br />

increasingly being raised for animal feed and to consume<br />

waste. However, the adults have a short life span after their<br />

breeding days are over and are then discarded. At Tomberlin’s<br />

suggestion, those adult carcasses became the new starting<br />

material for Wooley’s team. “We’re taking something that’s<br />

quite literally garbage and making something useful out of<br />

it”, says Cassidy Tibbetts, a graduate student working on the<br />

project in Wooley’s lab at Texas A&M University.<br />

When Tibbetts examined the dead flies, she determined that<br />

chitin is a major component. This nontoxic, biodegradable,<br />

sugar-based polymer strengthens the shell, or exoskeleton,<br />

of insects and crustaceans. Manufacturers already extract<br />

chitin from shrimp and crab shells for various applications, and<br />

Tibbetts has been applying similar techniques using ethanol<br />

rinses, acidic demineralization, basic deproteinization, and<br />

bleach decolourization to extract and purify it from the insect<br />

carcasses. She says her fly-sourced chitin powder is probably<br />

purer since it lacks the yellowish colour and clumpy texture<br />

of the traditional product. She also notes that obtaining chitin<br />

from flies could avoid possible concerns over some seafood<br />

allergies. Some other researchers isolate chitin or proteins<br />

from fly larvae, but Wooley says her team is the first that she<br />

knows of to use chitin from discarded adult flies, which –<br />

unlike the larvae – aren’t used for feed.<br />

While Tibbetts continues to refine her extraction<br />

techniques, Hongming Guo, another graduate student<br />

in Wooley’s lab, has been converting the purified fly chitin<br />

into a similar polymer known as chitosan. He does this by<br />

stripping off chitin’s acetyl groups. That exposes chemically<br />

reactive amino groups that can be functionalized and then<br />

Photo: Sander Freitas Shutterstock<br />

cross-linked. These steps transform chitosan into useful<br />

bioplastics such as superabsorbent hydrogels, which are 3D<br />

polymer networks that absorb water.<br />

Guo has produced a hydrogel that can absorb 47 times<br />

its weight in water in just one minute. This product could<br />

potentially be used in cropland soil to capture floodwater<br />

and then slowly release moisture during subsequent<br />

droughts, Wooley says. “Here in Texas, we’re constantly<br />

either in a flood or drought situation”, she explains, “so I've<br />

been trying to think of how we can make a superabsorbent<br />

hydrogel that could address this”. And because the hydrogel<br />

is biodegradable, she says it should gradually release its<br />

molecular components as nutrients for crops.<br />

This summer, the team is starting a project to break down<br />

chitin into its monomeric glucosamines. These small sugar<br />

molecules will then be used to make bioplastics, such as<br />

polycarbonates or polyurethanes, which are traditionally<br />

made from petrochemicals. Black soldier flies also contain<br />

many other useful compounds that the group plans to use<br />

as starting materials, including proteins, DNA, fatty acids,<br />

lipids, and vitamins.<br />

The products made from these chemical building blocks<br />

are intended to degrade or digest when they’re discarded,<br />

so they won’t contribute to the current plastic pollution<br />

problem. Wooley’s vision for that process would align with<br />

the sustainable, circular economy concept: “Ultimately,<br />

we'd like the insects to eat the waste plastic as their food<br />

source, and then we would harvest them again and collect<br />

their components to make new plastics”, she says. “So the<br />

insects would not only be the source, but they would also then<br />

consume the discarded plastics”.<br />

The researchers acknowledge support and funding from<br />

the Welch Foundation and a private donation. AT<br />

www.acs.org<br />

Info<br />

See a video-clip at:<br />

https://youtu.be/AhzqzPCvneI<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

9


INITIATIVE<br />

RCI’s Manifesto for the next<br />

European Commission<br />

RENEWABLE<br />

CARBON<br />

Dependence on fossil fuels such as crude oil and gas –<br />

the main cause of climate change – must end! Political<br />

support is essential to successfully implement this shift<br />

to renewable carbon use. The RCI Manifesto outlines seven<br />

key recommendations for the next European Commission to<br />

turn this vision into reality.<br />

The Renewable Carbon Initiative (RCI) has published a<br />

Manifesto for the next European Commission (2024 – 2029),<br />

highlighting key issues as policymakers’ awareness<br />

and support is crucial for the much-needed transition<br />

to renewable carbon.<br />

Defossilisation is essential for the chemicals and<br />

materials industry to meet both climate change targets<br />

and the continuing demand for embedded carbon – the<br />

carbon bound within molecules. This can only be achieved<br />

by using renewable carbon sources from biomass, direct use<br />

of CO 2<br />

, or recycling.<br />

The manifesto outlines seven key messages to<br />

policymakers to make this transformation a reality:<br />

1. Ensure renewable carbon is a guiding<br />

principle for policies and targets<br />

Product-related policies do not sufficiently consider the<br />

feedstock base or the carbon source of products. If they<br />

do, they only consider recycled content, as seen in recent<br />

developments around the Packaging and Packaging Waste<br />

Regulation (PPWR) and the Ecodesign for Sustainable<br />

Products Regulation (ESPR). This oversight is detrimental<br />

to climate objectives, as the material and chemical sectors<br />

will then continue to rely on fossil carbon feedstock from<br />

below the ground for their products. The embedded fossil<br />

carbon in these products will eventually be released into<br />

the atmosphere at their end of life through degradation or<br />

incineration – if the products are not collected and recycled.<br />

This embedded carbon needs more political attention as an<br />

important factor for material-related emissions (Scope 3).<br />

2. Stepwise phaseout of fossil carbon by 2<strong>05</strong>0<br />

In order to achieve independence from fossil carbon<br />

from the ground, three sources of renewable carbon are<br />

available: biobased, CO 2<br />

-based, and recycling, including<br />

advanced recycling technologies that complement<br />

mechanical recycling when it falls short (i.e., accumulation<br />

of toxic substances, quality loss, recycled packaging for food<br />

contact). The concept of circular carbon cycles – in which<br />

carbon is emitted, re-captured, recycled, emitted, and recaptured<br />

again through the use of CCU (from point sources<br />

and direct air capture (DAC)), and biomass used as feedstock<br />

– must be an integral part of political thinking. RCI believes<br />

that virgin fossil-based chemicals and materials should not<br />

have a future beyond 2<strong>05</strong>0, and the European Commission<br />

must make this an explicit objective.<br />

3. Enshrine the Sustainable Carbon Cycles<br />

Communication’s 20 % target of non-fossil<br />

carbon in binding legislation<br />

The Sustainable Carbon Cycles Communication has<br />

a visionary target: “At least 20 % of the carbon used in<br />

chemical and plastic products should be from sustainable<br />

non-fossil resources by 2030”. While the RCI agrees with<br />

this target, there is no definition for “sustainable non-fossil<br />

resources”. Therefore, we urge the Commission to adopt<br />

a precise definition that includes all three carbon sources<br />

(biobased, CO 2<br />

-based, and recycling), enshrine the target<br />

in binding legislation, and follow up with concrete political<br />

action for implementation.<br />

4. Establish a Carbon Management Regulation<br />

Establishing a comprehensive legal framework that<br />

promotes the management of sustainable carbon supply<br />

and demand, and that facilitates renewable carbon uptake,<br />

would be a significant step towards a climate-neutral and<br />

circular chemical and material sector. It should be possible<br />

to set targets for Member States or companies to increase<br />

the minimum percentage of renewable carbon in products,<br />

similar to renewable energy targets. In particular, such targets<br />

could be achieved through blending mechanisms and the<br />

trade of renewable carbon credits. Updated methodologies<br />

are needed to accurately account for carbon, including<br />

biogenic carbon, in European production and imported goods.<br />

5. Promote bio – and CO 2<br />

-based content<br />

in addition to recycled content in<br />

product-related legislation<br />

All three renewable carbon sources should be recognised<br />

as preferable alternatives to fossil carbon from the ground.<br />

Product-related regulation (both for short – and long-lived<br />

products) should provide incentives for bio – and CO 2<br />

-based<br />

or – attributed content in parallel to recycled content.<br />

Sustainable primary biomass should be equivalently accepted<br />

as a feedstock for meeting these political ambitions. Such an<br />

approach in regulation also ensures industry competitiveness<br />

and avoids carbon leakage.<br />

6. Enable the deployment of CCU as a key<br />

strategic net-zero technology to supply<br />

sustainable and circular carbon<br />

CCU is an indispensable technology for supplying carbon to<br />

the chemical and material industries without further tapping<br />

into fossil carbon resources from below the ground, making<br />

it an important CO 2<br />

abatement tool. CCU with biogenic or<br />

atmospheric carbon also leads to carbon removals when<br />

used for long-term applications or in combination with<br />

high recycling rates. This should be accounted for in carbon<br />

removal legislation.<br />

10<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Bio-based CO2-based Recycling<br />

INITIATIVE<br />

Renewable Carbon Initiative (RCI) Manifesto for the next European Commission (2024-2029)<br />

2<br />

Renewable Carbon Initiative (RCI) Manifesto for the next European Commission (2024-2029)<br />

3<br />

RENEWABLE<br />

CARBON<br />

INITIATIVE<br />

Renewable Carbon Initiative (RCI)<br />

Manifesto for the next European<br />

Commission (2024-2029)<br />

Key messages<br />

Circular Economy<br />

1. Ensure renewable carbon is a guiding principle for policies and targets<br />

Product-related policies do not sufficiently consider the feedstock base or the carbon source of products.<br />

If they do, they only consider recycled content as seen in recent developments around the Packaging and<br />

Packaging Waste Regulation (PPWR) and the Ecodesign for Sustainable Products Regulation (ESPR). This<br />

oversight is detrimental to climate objectives as the material and chemical sectors will then continue to<br />

rely on fossil carbon feedstock from below the ground for their products. The embedded fossil carbon in<br />

these products will eventually be released into the atmosphere at their end of life through degradation or<br />

incineration – if the products are not collected and recycled. This embedded carbon needs more political<br />

attention as an important factor for material-related emissions (Scope 3).<br />

2. Stepwise phaseout of fossil carbon by 2<strong>05</strong>0<br />

In order to achieve independence from fossil carbon from the ground, three sources of renewable carbon are<br />

available: bio-based, CO₂-based and recycling, including advanced recycling technologies that complement<br />

mechanical recycling when it falls short (i.e., accumulation of toxic substances, quality loss, recycled<br />

packaging for food contact). The concept of circular carbon cycles – in which carbon is emitted, re-captured,<br />

recycled, emitted and re-captured again through the use of CCU (from point sources and direct air capture<br />

6. Enable the deployment of CCU as a key strategic net-zero technology to supply<br />

sustainable and circular carbon<br />

CCU is an indispensable technology for supplying carbon to the chemical and material industries without<br />

further tapping into fossil carbon resources from below the ground, making it an important CO 2 abatement<br />

tool. CCU with biogenic or atmospheric carbon also leads to carbon removals when used for long-term<br />

applications or in combination with high recycling rates. This should be accounted for in carbon removal<br />

legislation.<br />

7. Support the transformation of existing chemical infrastructure from fossil to<br />

renewable carbon and support the transformation of biofuels plants<br />

The demand for carbon-containing fuels in road transport is expected to decrease in Europe in the coming<br />

decades. In contrast, the share of chemicals derived from refineries will increase heavily compared to fuels.<br />

This will free up existing biofuel infrastructure which should not be left behind. Instead, the biofuel sector<br />

could grab the opportunity to become one source of raw materials supply for a chemical industry based on<br />

renewable carbon. Investments in production changes are already taking place; this is a unique opportunity<br />

for policymakers to steer these changes in a sustainable direction and support the shift to renewable<br />

RENEWABLE<br />

CARBON<br />

(DAC)), and biomass used as feedstock – must be an integral part of political thinking. RCI believes that<br />

carbon without discriminating against existing production from renewable feedstock.<br />

1. Ensure that carbon embedded in chemicals and materials is given more political attention as an<br />

virgin fossil-based chemicals and materials should not have a future beyond 2<strong>05</strong>0, and the European<br />

important factor for material-related emissions. Renewable carbon derived from biomass, direct CO 2<br />

utilisation, and recycling must become a guiding principle for policies and targets regulating chemicals<br />

Commission must make this an explicit objective.<br />

and materials.<br />

2. Make a stepwise phaseout of fossil carbon from below the ground for chemicals and materials by<br />

2<strong>05</strong>0 an explicit objective.<br />

3. Enshrine the Sustainable Carbon Cycles Communication’s 20% target of non-fossil<br />

carbon in binding legislation<br />

The Sustainable Carbon Cycles Communication has a visionary target: “at least 20% of the carbon used<br />

in chemical and plastic products should be from sustainable non-fossil resources by 2030”. While the RCI<br />

3. Enshrine the 20% target of non-fossil carbon in chemicals and plastics by 2030 from the Sustainable<br />

agrees with this target, there is no definition for “sustainable non-fossil resources”. Therefore, we urge the<br />

Carbon Cycles Communication in binding legislation and ensure implementation through concrete<br />

Commission to adopt a precise definition that includes all three carbon sources (bio-based, CO₂-based<br />

political action.<br />

and recycling), enshrine the target in binding legislation, and follow up with concrete political action for<br />

4. Establish a ‘Carbon Management Regulation’ to incentivise companies to replace fossil carbon from<br />

implementation.<br />

below the ground with renewable alternatives.<br />

4. Establish a ‘Carbon Management Regulation’<br />

5. Promote bio- and CO 2-based 1 or -attributed content in parallel to recycled content in product-related<br />

Establishing a comprehensive legal framework that promotes the management of sustainable carbon supply<br />

regulation.<br />

and demand and that facilitates renewable carbon uptake would be a significant step towards a climate-<br />

6. Deploy carbon capture and utilisation (CCU) as a key strategic net-zero technology to supply sustainable<br />

neutral and circular chemical and material sector. It should be possible to set targets for Member States<br />

and circular carbon.<br />

or companies to increase the minimum percentage of renewable carbon in products, similar to renewable<br />

7. Support the transformation of existing chemical infrastructure from fossil to renewable carbon and<br />

support the transformation of biofuels plants into chemical suppliers without discriminating against<br />

existing production from renewable feedstock (including primary biomass).<br />

energy targets. In particular, such targets could be achieved through blending mechanisms and the trade of<br />

renewable carbon credits. Updated methodologies are needed to accurately account for carbon, including<br />

biogenic carbon, in European production and imported goods.<br />

5. Promote bio- and CO 2-based content in addition to recycled content in productrelated<br />

legislation<br />

All three renewable carbon sources should be recognised as preferable alternatives to fossil carbon from<br />

the ground. Product-related regulation (both for short- and long-lived products) should provide incentives<br />

1 The use of the term CCU generally refers to the utilisation of carbon dioxide (CO2), but can also include industrial carbon monoxide<br />

(CO) sources prior to flaring or other conversions to CO2 before release to the atmosphere. In the US, CO2 and CO are grouped<br />

together as “carbon oxides” for purposes of Section 45Q CCUS tax credits. In this report, “CO2 utilisation” is meant to also include<br />

for bio- and CO 2-based or -attributed content in parallel to recycled content. Sustainable primary biomass<br />

should be equivalently accepted as a feedstock for meeting these political ambitions. Such an approach in<br />

other carbon oxides.<br />

regulation also ensures industry competitiveness and avoids carbon leakage.<br />

renewable-carbon.eu August <strong>2023</strong><br />

renewable-carbon.eu<br />

August <strong>2023</strong><br />

renewable-carbon.eu<br />

August <strong>2023</strong><br />

Full Manifesto<br />

7. Support the transformation of existing chemical<br />

infrastructure from fossil to renewable carbon and<br />

support the transformation of biofuel plants<br />

The demand for carbon-containing fuels in road transport<br />

is expected to decrease in Europe in the coming decades.<br />

In contrast, the share of chemicals derived from refineries will<br />

increase heavily compared to fuels. This will free up existing<br />

biofuel infrastructure, which should not be left behind. Instead,<br />

the biofuel sector could grab the opportunity to become one<br />

source of raw materials supply for a chemical industry based<br />

on renewable carbon. Investments in production changes are<br />

already taking place; this is a unique opportunity for policymakers<br />

to steer these changes in a sustainable direction and support the<br />

shift to renewable carbon without discriminating against existing<br />

production from renewable feedstock.<br />

You can support the efforts of the RCI<br />

by adding your name to the manifesto.<br />

https://renewable-carbon-initiative.com/call-for-signature-rci-manifesto<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

11


Events<br />

PLAST <strong>2023</strong>: the green economy<br />

involves plastics and rubber<br />

Carbon footprints of exhibitors and green innovation among the<br />

novelties at the exhibition<br />

Circularity, sustainability, and energy savings were some<br />

of the guiding themes at the international trade fair<br />

PLAST <strong>2023</strong> (5 – 8 September, Milan, Italy). The green<br />

economy is a hot topic for the entire plastics and rubber<br />

industry and generates a strong push toward innovation and<br />

the search for new production paradigms with a central focus<br />

on emission reduction and environmental protection.<br />

Plast <strong>2023</strong>, with its satellite shows Rubber (rubber industry),<br />

3D Plast (3D printing and related), PlastMat (innovative<br />

materials) and a wide range of cutting-edge technological<br />

solutions on the key subjects of industrial production such<br />

as digitalisation and sustainability, was attended by 1,323<br />

exhibitors, 47 % of whom were foreigners, a figure that once<br />

again confirms the international nature of the event.<br />

The 38,000 visitors who filled the halls were characterised<br />

by a considerable international presence, with 26 % of the<br />

visitors coming from 109 countries.<br />

An exclusive service for exhibitors:<br />

assessment of carbon footprint<br />

As part of its effort to promote sustainability – a theme<br />

guiding the entire industry – and with the consolidated<br />

tradition of Fiera Milano behind it, PLAST provides<br />

exhibitors a service for calculating the carbon footprint of<br />

their organization. Fiera Milano has long been committed<br />

to reducing its environmental impact and CO 2<br />

emissions<br />

generated by events in its facilities by optimizing logistical<br />

operations, properly managing waste, and adopting<br />

sustainable food-service practices in keeping with the PLAST<br />

philosophy, which is shared with all exhibitors.<br />

Working in collaboration with the specialized company<br />

Ambiente Consulenza & Ingegneria, Amaplast supports<br />

and guides exhibiting companies wishing to calculate their<br />

carbon footprint according to standards developed by the<br />

Intergovernmental Panel on Climate Change (IPCC), which<br />

operates under the aegis of the United Nations, applying<br />

internationally recognized protocols (GHG Protocol and ISO<br />

14064). Assessment of the Carbon Footprint of Organization is<br />

one of the most immediate and generally accepted methods<br />

for representing and communicating the environmental<br />

impact of an enterprise. Amaplast has also undertaken this<br />

process for its own internal operations and will share the<br />

initial results during PLAST <strong>2023</strong>.<br />

Sustainability at the fair: the French collective<br />

Making its first appearance at PLAST this year, the French<br />

collective, composed of 24 businesses, boasted a significant<br />

number of projects directly related to sustainability with a<br />

particular focus on new, biobased, compostable, or recycled<br />

materials. Sponsored by French Fab, which brings together<br />

the industrial ecosystem across France, the group presented,<br />

among the many novelties, Cabamix by the JM Polymers<br />

Group, which proposes its new Carbomax ® Phoenix range<br />

of 100 % biobased, compostable, or recycled plastics;<br />

Natureplast with new bioplastics obtained from food industry<br />

scrap or by-products (cereals, shellfish, algae, etc.); the<br />

two start-ups Polytopoly, specialized in research, analysis,<br />

and sales of recycled plastics via a digital platform, and<br />

Holimaker, which exhibited a French-made manual injection<br />

press for plastics that is unlike any other in Europe. Known as<br />

the HoliPress, it offers injection moulding of nearly industrial<br />

quality at reduced costs using 3D moulds and offering<br />

options for recycling.<br />

Other companies presenting solutions and materials<br />

from the Renewable Carbon Plastics sector included Biotec,<br />

Cossa Polimeri, Esun, Futerro, Gema Polimer, Gianeco,<br />

Planet Bioplastics, Ruian Applied Biotechnology, Sirmax,<br />

Sunar NP and a few more. MT<br />

www.plastonline.org<br />

Photo: Fiera Milano)<br />

12 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


8 th PLA World Congress<br />

28 + 29 MAY 2024 › MUNICH › GERMANY<br />

HYBRID EVENT<br />

organized by<br />

aka<br />

Call for Papers<br />

Save the Date<br />

www.pla-world-congress.com<br />

PLA is a versatile bioplastics raw material from<br />

renewable resources. It is being used for films and rigid<br />

packaging, for fibres in woven and non-woven applications,<br />

injection moulded toys, automotive applications, consumer<br />

electronics and in many other industries. Innovative<br />

methods of polymerizing, compounding or blending PLA<br />

have broadened the range of properties and thus the range<br />

of possible applications. That‘s why Renewable Carbon<br />

Plastics (also known as bioplastics MAGAZINE) is now<br />

organizing the PLA World Congress in its 8 th edition:<br />

28 + 29 May 2024 in Munich / Germany<br />

Experts from all involved fields will share their knowledge<br />

and contribute to a comprehensive overview of today‘s<br />

opportunities and challenges and discuss the possibilities,<br />

limitations and future prospects of PLA for all kinds of<br />

applications. Like the seven previous congresses the<br />

8 th PLA World Congress will also offer excellent networking<br />

opportunities for all delegates and speakers as well as<br />

exhibitors of the tabletop exhibition. Based on our good<br />

experiences the conference will again be a hybrid event.<br />

Participation is possible on-site in Munich as well as<br />

online via live streaming or a recording of all presentations<br />

after the event.<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

13


Cover Story<br />

30 Years of driving the<br />

evolution of bioplastics<br />

European Bioplastics celebrates anniversary<br />

According to legend, it all started in 1993 with the<br />

Interessengemeinschaft Biologisch Abbaubare<br />

Werkstoffe e.V. (IBAW: Interest Group Biodegradable<br />

Materials). Based initially in Rosenheim, Germany,<br />

the association moved to Berlin and opened its first<br />

official office in 2000.<br />

In 2006, the association took a big turn and broadened<br />

its scope to also include durable biobased plastics next to<br />

biodegradable plastics. This transformation is reflected in the<br />

name change: European Bioplastics e.V. (EUBP). “We will now<br />

concentrate on assisting the market introduction of bioplastics<br />

in Europe”, explained Harald Kaeb, Chairman of the association<br />

at the time. An important part of the new activities was to build<br />

a network of stakeholders from the bioplastics industry in<br />

European Union member states. To fulfil its aspirations, in the<br />

same year, European Bioplastics created CEBON, a network<br />

of bioplastics organisations across Europe. To accompany this<br />

shift, the association organised for the first time the European<br />

Bioplastics Conference, in Brussels, which eventually became<br />

the annual leading business and discussion forum for the whole<br />

bioplastics industry. “We are looking forward to welcoming the<br />

readers of Renewable Carbon Plastics at the upcoming edition<br />

of the EBC this December in Berlin”, says Denise Valdix, Head<br />

of Events at European Bioplastics. (See box).<br />

In 2010, the association published the very first annual<br />

Bioplastics Market Data report, a report that would soon become<br />

a reference for the bioplastics industry. From EU policymakers<br />

and other stakeholders, to researchers and media, there is little<br />

literature on bioplastics that doesn’t refer to this data.<br />

Shortly after, the association celebrated its 20-year<br />

anniversary, in 2013. That same year, François de Bie became<br />

Chair of the Board, and the main focus was put on intensifying<br />

advocacy efforts in Brussels. To achieve these goals, EUBP<br />

created the Regulatory Affairs Working Group in 2016, which is<br />

now counting more than 100 participants.<br />

The last decade has certainly been the decade of change.<br />

In 2017, EUBP became a member of EUBA, the European<br />

Bioeconomy Alliance, to strengthen its position in the EU<br />

Institutions and build synergies with the various stakeholders<br />

of the bioeconomy. It is also that same year that EUBP started<br />

its engagement in several EU-funded research projects, where<br />

the association mainly provides support with communication,<br />

dissemination, and production of deliverables.<br />

Coming back to the present year. Earlier in <strong>2023</strong>, EUBP opened<br />

its second office, marking the beginning of a new adventure.<br />

The association now has a physical foot in the Brussels Bubble,<br />

with the second office located a mere 10-minute walk away<br />

from the EU Institutions.<br />

In the last 30 years, EUBP’s work has been instrumental in the<br />

growth of the bioplastics market. The association has a strong<br />

membership base of 90 companies from across the bioplastics<br />

value chain. This gives EUBP a unique voice and allows it to<br />

represent the interests of the industry effectively. Its dedicated<br />

team of experts enables the association to provide its members<br />

with valuable insights and support.<br />

In addition to the milestones listed above, EUBP<br />

has also been active over the years in a number<br />

of other areas, including:<br />

• Developing standards for bioplastics<br />

and most notably EN 13432<br />

• Owning and protecting the correct use<br />

of the Seedling ® logo<br />

• Promoting research and development in<br />

the bioplastics sector<br />

• Working with policymakers to create a supportive<br />

regulatory environment for bioplastics<br />

• Raising awareness of the benefits of bioplastics<br />

among consumers and businesses<br />

Renewable Carbon Plastics wishes a happy birthday. AT/MT<br />

www.european-bioplastics.org<br />

Info:<br />

If you are interested in learning more about EUBP<br />

or bioplastics in general, get your tickets for<br />

EBC 23, 12-13 December in Berlin. More info at:<br />

www.european-bioplastics.org/events/ebc<br />

Francois de Bie (Chairman of the Board 2013-2022)<br />

and Denise Valdix<br />

14 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


available at www.renewable-carbon.eu/graphics<br />

O<br />

OH<br />

HO<br />

OH<br />

HO<br />

OH<br />

O<br />

OH<br />

HO<br />

OH<br />

O<br />

OH<br />

O<br />

OH<br />

© -Institute.eu | 2021<br />

Natural rubber<br />

Cellulose-based<br />

polymers<br />

Lignin-based polymers<br />

PFA<br />

Casein polymers<br />

Starch-containing<br />

polymer compounds<br />

Unsaturated polyester resins<br />

Polyurethanes<br />

Furfuryl alcohol<br />

ECH<br />

MPG<br />

Fatty acids<br />

11-AA<br />

All figures available at www.renewable-carbon.eu/graphics<br />

fossil<br />

available at www.renewable-carbon.eu/graphics<br />

All figures available at www.bio-based.eu/markets<br />

PE<br />

Epoxy resins<br />

Furfural<br />

NOPs<br />

PP<br />

Building blocks<br />

for UPR<br />

Glycerol<br />

Sebacic<br />

acid<br />

Castor oil<br />

DDDA<br />

PHA<br />

renewable<br />

Hemicellulose<br />

HMDA<br />

EPDM<br />

Building blocks<br />

for polyurethanes<br />

Casein<br />

Caprolactame<br />

PA<br />

Propylene<br />

DN5<br />

APC<br />

Aniline<br />

Naphthta<br />

Natural rubber<br />

Non-edible milk<br />

Plant oils<br />

Lysine<br />

Isosorbide<br />

Waste oils<br />

Lignocellulose<br />

Sorbitol<br />

Ethylene<br />

Starch<br />

Vinyl chloride<br />

Saccharose<br />

Glucose<br />

Lactic<br />

acid<br />

Lactide<br />

Methyl methacrylate<br />

Ethanol<br />

PVC<br />

Isobutanol<br />

Itaconic<br />

acid<br />

PLA<br />

Fructose<br />

Succinic<br />

acid<br />

Adipic<br />

acid<br />

3-HP<br />

MEG<br />

2,5-FDCA<br />

5-HMF/5-CMF<br />

Acrylic<br />

acid<br />

allocated<br />

PMMA<br />

ABS<br />

1,3 Propanediol<br />

p-Xylene<br />

Terephthalic<br />

acid<br />

THF<br />

Levulinic<br />

acid<br />

1,4-Butanediol<br />

FDME<br />

PEF<br />

PBS(x)<br />

Superabsorbent polymers<br />

PBAT<br />

PET<br />

PBT<br />

PTF<br />

PTT<br />

SBR<br />

© -Institute.eu | <strong>2023</strong><br />

conventional<br />

© -Institute.eu | 2021<br />

Adipic acid (AA)<br />

11-Aminoundecanoic acid (11-AA)<br />

1,4-Butanediol (1,4-BDO)<br />

Dodecanedioic acid (DDDA)<br />

Epichlorohydrin (ECH)<br />

Ethylene<br />

Furan derivatives<br />

D-lactic acid (D-LA)<br />

L-lactic acid (L-LA)<br />

Lactide<br />

Monoethylene glycol (MEG)<br />

Monopropylene glycol (MPG)<br />

Naphtha<br />

1,5-Pentametylenediamine (DN5)<br />

1,3-Propanediol (1,3-PDO)<br />

Sebacic acid<br />

Succinic acid (SA)<br />

© -Institute.eu | 2020<br />

Mechanical<br />

Recycling<br />

Extrusion<br />

Physical-Chemical<br />

Recycling<br />

available at www.renewable-carbon.eu/graphics<br />

Refining<br />

Dissolution<br />

Physical<br />

Recycling<br />

Polymerisation<br />

Formulation<br />

Processing<br />

Use<br />

Enzymolysis<br />

Biochemical<br />

Recycling<br />

Depolymerisation<br />

Solvolysis<br />

Thermal depolymerisation<br />

Enzymolysis<br />

Purification<br />

Dissolution<br />

Plastic Product<br />

End of Life<br />

Plastic Waste<br />

Collection<br />

Separation<br />

Different Waste<br />

Qualities<br />

Solvolysis<br />

Chemical<br />

Recycling<br />

Monomers<br />

Recycling<br />

Conversion<br />

Pyrolysis<br />

Gasification<br />

Depolymerisation<br />

Thermochemical<br />

Recycling<br />

Pyrolysis<br />

Thermochemical<br />

Recycling<br />

Incineration<br />

CO2 Utilisation<br />

(CCU)<br />

Gasification<br />

Thermochemical<br />

Recycling<br />

Recovery<br />

Recovery<br />

Recovery<br />

CO2<br />

© -Institute.eu | 2022<br />

© -Institute.eu | 2020<br />

nova Market and Trend Reports<br />

on Renewable Carbon<br />

The Best Available on Bio- and CO2-based Polymers<br />

& Building Blocks and Chemical Recycling<br />

Summer<br />

Special<br />

Category<br />

20 % Discount<br />

Code: Summer<strong>2023</strong><br />

( 01.06 – 31.08.23 )<br />

Carbon Dioxide (CO 2)<br />

as Feedstock for Chemicals,<br />

Advanced Fuels, Polymers,<br />

Proteins and Minerals<br />

Technologies and Market, Status and<br />

Outlook, Company Profiles<br />

Bio-based Building Blocks<br />

and Polymers<br />

Global Capacities, Production and Trends 2022–2027<br />

Mapping of advanced recycling<br />

technologies for plastics waste<br />

Providers, technologies, and partnerships<br />

Polymers<br />

Building Blocks<br />

Diversity of<br />

Advanced Recycling<br />

Intermediates<br />

Feedstocks<br />

Plastics<br />

Composites<br />

Plastics/<br />

Polymers<br />

Monomers<br />

Monomers<br />

Naphtha<br />

Syngas<br />

Authors: Pauline Ruiz, Pia Skoczinski, Achim Raschka, Nicolas Hark, Michael Carus.<br />

With the support of: Aylin Özgen, Jasper Kern, Nico Plum<br />

April <strong>2023</strong><br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Authors: Pia Skoczinski, Michael Carus, Gillian Tweddle, Pauline Ruiz, Doris de Guzman,<br />

Jan Ravenstijn, Harald Käb, Nicolas Hark, Lara Dammer and Achim Raschka<br />

February <strong>2023</strong><br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Authors: Lars Krause, Michael Carus, Achim Raschka<br />

and Nico Plum (all nova-Institute)<br />

June 2022<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Mimicking Nature –<br />

The PHA Industry Landscape<br />

Latest trends and 28 producer profiles<br />

Bio-based Naphtha<br />

and Mass Balance Approach<br />

Status & Outlook, Standards &<br />

Certification Schemes<br />

Chemical recycling – Status, Trends<br />

and Challenges<br />

Technologies, Sustainability, Policy and Key Players<br />

Plastic recycling and recovery routes<br />

Principle of Mass Balance Approach<br />

Virgin Feedstock<br />

Renewable Feedstock<br />

Feedstock<br />

Process<br />

Products<br />

Monomer<br />

Secondary<br />

valuable<br />

materials<br />

Chemicals<br />

Fuels<br />

Others<br />

Polymer<br />

Use of renewable feedstock<br />

in very first steps of<br />

chemical production<br />

(e.g. steam cracker)<br />

Utilisation of existing<br />

integrated production for<br />

all production steps<br />

Allocation of the<br />

renewable share to<br />

selected products<br />

Primary recycling<br />

(mechanical)<br />

Plastic<br />

Product<br />

Secondary recycling<br />

(mechanical)<br />

Tertiary recycling<br />

(chemical)<br />

CO 2 capture<br />

Product (end-of-use)<br />

Quaternary recycling<br />

(energy recovery)<br />

Energy<br />

Landfill<br />

Author: Jan Ravenstijn<br />

March 2022<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Authors: Michael Carus, Doris de Guzman and Harald Käb<br />

March 2021<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Author: Lars Krause, Florian Dietrich, Pia Skoczinski,<br />

Michael Carus, Pauline Ruiz, Lara Dammer, Achim Raschka,<br />

nova-Institut GmbH, Germany<br />

November 2020<br />

This and other reports on the bio- and CO 2-based economy are<br />

available at www.renewable-carbon.eu/publications<br />

Genetic engineering<br />

Production of Cannabinoids via<br />

Extraction, Chemical Synthesis<br />

and Especially Biotechnology<br />

Current Technologies, Potential & Drawbacks and<br />

Future Development<br />

Plant extraction<br />

Plant extraction<br />

Cannabinoids<br />

Chemical synthesis<br />

Biotechnological production<br />

Production capacities (million tonnes)<br />

Commercialisation updates on<br />

bio-based building blocks<br />

Bio-based building blocks<br />

Evolution of worldwide production capacities from 2011 to 2024<br />

4<br />

3<br />

2<br />

1<br />

2011 2012 2013 2014 2015 2016 2017 2018 2019 2024<br />

Levulinic acid – A versatile platform<br />

chemical for a variety of market applications<br />

Global market dynamics, demand/supply, trends and<br />

market potential<br />

HO<br />

OH<br />

diphenolic acid<br />

H 2N<br />

O<br />

OH<br />

O<br />

O<br />

OH<br />

5-aminolevulinic acid<br />

O<br />

O<br />

levulinic acid<br />

O<br />

O<br />

ɣ-valerolactone<br />

OH<br />

HO<br />

O<br />

O<br />

succinic acid<br />

OH<br />

O<br />

O OH<br />

O O<br />

levulinate ketal<br />

O<br />

H<br />

N<br />

O<br />

5-methyl-2-pyrrolidone<br />

OR<br />

O<br />

levulinic ester<br />

Authors: Pia Skoczinski, Franjo Grotenhermen, Bernhard Beitzke,<br />

Michael Carus and Achim Raschka<br />

January 2021<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Author:<br />

Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />

Updated Executive Summary and Market Review May 2020 –<br />

Originally published February 2020<br />

This and other reports on the bio- and CO 2-based economy are<br />

available at www.bio-based.eu/reports<br />

Authors: Achim Raschka, Pia Skoczinski, Raj Chinthapalli,<br />

Ángel Puente and Michael Carus, nova-Institut GmbH, Germany<br />

October 2019<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

renewable-carbon.eu/publications<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

15


On-site<br />

Bioplastics experts<br />

Renewable Carbon Plastics visited FKuR in Willich, Germany<br />

Two friends who studied plastics engineering at<br />

RWTH University Aachen (Germany) and earned their<br />

doctorates in the 1980s met a few years later at a<br />

trade show in Germany. It was in those days that plastics<br />

recycling became kind of a hot topic for the first time. But it<br />

seemed that nobody really felt responsible to take the lead<br />

here. So, Heinz Breuer and Edmund Dolfen had the idea,<br />

that a kind of recycling institute was needed. Heinz Breuer,<br />

who was a professor at the University for Applied Sciences<br />

in Krefeld (Germany) at that time, suggested to simply<br />

found such an institute connected to the university. And so,<br />

in 1992, they did it.<br />

Research Institute<br />

With a start-up funding from the German Federal State<br />

of North Rhine-Westphalia, the institute started with a<br />

name that today will certainly ring in many ears: FKuR.<br />

This abbreviation stands for the German words for Research<br />

Institute for Plastics and Recycling. Almost at the same time,<br />

a support association was founded to determine the destiny<br />

and research goals, along with additional industrial funding.<br />

The total number of about 60 members included machine<br />

manufacturers, recycling companies, and others, but also<br />

the DKR (German Society for Circular Economy and Raw<br />

Materials, creator of the Green Dot). First research topics<br />

included the recycling of rubber tyres or plastic pallets.<br />

Services like consulting and certification rounded off the<br />

FKuR portfolio. Our Michael Thielen remembers very well his<br />

visit to the first Recycling Colloquium in Krefeld, a conference<br />

with 40 exhibitors. And finally, the FKuR also founded the<br />

first Quality Association for Recycled Standard Polymers<br />

to prove and certify that plastic recyclates can indeed offer<br />

reproducible qualities.<br />

Plastics – made by nature!<br />

End of the 1990s, plastics recycling had outgrown its infancy<br />

in Germany. At the time, Edmund Dolfen was convinced that<br />

nature itself is the best recycler. That was the time when<br />

FKuR focused on the development of biodegradable plastics.<br />

“Not many in the market believed in bioplastics end of the<br />

nineties”, says Patrick Zimmermann, today one of the three<br />

managing directors of FKuR, “bioplastics were a child treated<br />

stepmotherly and not given much chance for the future”.<br />

“As a matter of fact, in the context of the circular economy<br />

and the waste management legislation different endof-life<br />

options were discussed”, adds Carmen Michels,<br />

Managing Director of FKuR, “and organic recycling is<br />

definitely a solution”.<br />

Already experienced in the field of conventional recycling,<br />

including the technologies of sorting, cleaning, preparation,<br />

and compounding, it was just a logical step to investigate<br />

biodegradable plastics, Carmen explains. And soon it became<br />

a specialty of FKuR to develop tailor-made compounds for<br />

certain applications. A first example was a biodegradable<br />

packaging for poultry meat with certain water vapour barrier<br />

and flexibility properties. The result was a special compound<br />

based on PLA, a biodegradable copolyester, and certain<br />

fillers to laminate already existing starch-based trays. “The<br />

challenge was to create a compound that would offer all: the<br />

biodegradability, water vapour barrier, flexibility (not too stiff<br />

and not too soft) that could be processed on a film blowing<br />

line and subsequently be laminated onto a tray in a kind of<br />

thermoforming process”, Patrick explains.<br />

The first range of products included different PLA/<br />

copolyester compounds branded as Bioflex ® , soon to be<br />

followed by the Biograde ® cellulose acetate-based materials.<br />

For Biograde Patrick describes the challenges with the<br />

need for a biodegradable heat-resistant material that can<br />

be injection moulded in short cycletimes, and transparent,<br />

if desired. The experience and know-how in the area of<br />

compounding, finding the secret recipe to build on the<br />

strengths of the individual ingredients while offsetting their<br />

weaknesses, would become a core competence of FKuR.<br />

In 1998, FKuR started its cooperation with the Fraunhofer<br />

Institute UMSICHT (Oberhausen, Germany), which soon<br />

proved to be a fruitful symbiosis.<br />

A new company<br />

As the scope of material developments took on an everincreasing<br />

scale, and the need to commercially produce<br />

larger amounts of resins increased, the decision was made<br />

in 2003 to found a separate company. FKuR the research<br />

institute became FKuR Kunststoff GmbH, the company, which<br />

is now celebrating its 20 th anniversary.<br />

In the course of time, the Bioflex and Biograde range was<br />

complemented by more and more products, such as Fibrolon ®<br />

natural fibre filled compounds, or Ceroflex ® biobased and<br />

compostable starch compounds for fast degrading films –<br />

their development was often initiated by customer requests.<br />

Milestones<br />

A significant milestone and highlight for Carmen was the<br />

installation and commissioning of their first large turnkey<br />

compounding line in 2012 in addition to the lines they had<br />

engineered and built themselves over the years.<br />

Patrick likes to remember the start of their US facility and<br />

company FKuR Plastics Corp. in Texas, USA in 2009 and SKYi<br />

FKuR Biopolymers Pvt Ltd. In India in 2019.<br />

Another milestone is definitely the cooperation with<br />

Braskem that started in 2011.<br />

Increasing the portfolio<br />

In addition to different special, and – if desired – tailor-made<br />

biobased and/or biodegradable compounds, FKuR started<br />

to act as a sales organization for other biobased plastics.<br />

These materials are for example Eastlon 30 % biobased PET<br />

for transparent packaging and recyclable bottles. As a drop-<br />

16 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


with roots in recycling<br />

On-site<br />

By: Alex and Michael Thielen<br />

in bioplastic, bio-PET has the same mechanical and thermal<br />

product properties as fossil PET and is 100 % recyclable.<br />

Braskem’s I’m green polyethylene, distributed in Europe by<br />

FKuR, can upon request, also be compounded for special<br />

properties. Such special compounds are marketed under<br />

FKuR’s trade name Terralene ® . Other Braskem products<br />

include I’m green EVA biobased ethylene vinyl acetate.<br />

Terraprene ® biobased TPE compounds for extrusion and<br />

injection moulding with individually adjustable hardness<br />

grades from 40 Shore A to 40 Shore D and Terrasol ®<br />

biodegradable and water-soluble plastics made from PVOH<br />

(polyvinyl alcohol) for packaging round off the portfolio of<br />

FKuR’s bioplastic materials.<br />

Back to the roots<br />

Just recently, in kind of a back to the roots, FKuR started<br />

re-strengthening its focus on recycling. So, the company is<br />

now also offering EuCertPlast-certified PE and PP plastic<br />

recyclates from post-consumer or pre-consumer sources<br />

and Terralene ® rPP – Hybrid compounds based on recycled<br />

polypropylene (PP) and renewable raw materials.<br />

Outlook<br />

The clear focus of FKuR is on three main pillars, all of<br />

them aiming at sustainable plastic products. In addition to<br />

their self-developed products and the trade products, the<br />

third is the recent focus on recycled products. “We are no<br />

longer the bioplastics specialists that we were”, as Daniel<br />

Peltzer, Managing Direcor of FKuR points out, “we are<br />

now a sustainability specialist. And often, there is not one<br />

single solution. Often a dovetailing of different approaches<br />

is necessary to find the technically, economically, and<br />

environmentally best solution”. And finally, Carmen tells us<br />

about their next steps: new properties they just purchased in<br />

the vicinity to further increase their capacities.<br />

FKuR is a mere 20-minute ride from our Renewable<br />

Carbon Plastics offices, so rest assured that we’ll keep you<br />

updated about all developments of this bioplastics pioneer<br />

with a promising future.<br />

Left to right: Daniel Pelzer, Patrick Zimmermann, Carmen<br />

Michels (Mananging Directors of FKuR), Alex Thielen<br />

Melanie Schreurs and Niklas Voß explain some details on<br />

biodegradable products<br />

(Photos: Philipp Thielen)<br />

www.fkur.com<br />

Edmund Dolfen (Photo: FKuR)<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

17


Fibres / Textiles<br />

Biobased nylon<br />

A combination of electrons and microbes<br />

T-shirts, stockings, shirts, and ropes – or as a component<br />

of parachutes and car tyres – just a few examples,<br />

thatpolyamides are used everywhere as synthetic fibres.<br />

At the end of the 1930s, the name Nylon was coined for<br />

such synthetic polyamides. Nylon-6 and Nylon-6.6 are two<br />

polyamides that account for around 95 % of the global nylon<br />

market. Until now, they have been produced from fossilbased<br />

raw materials. However, this petrochemical process is<br />

harmful to the environment because it emits around 10 % of<br />

the climate-damaging nitrous oxide (laughing gas) worldwide<br />

and requires a great deal of energy. “Our goal is to make the<br />

entire nylon production chain environmentally friendly. This is<br />

possible if we access biobased waste as feedstock and make<br />

the synthesis process sustainable”, says Falk Harnisch, head<br />

of the Electrobiotechnology working group at the Helmholtz<br />

Centre for Environmental Research – UFZ (Leipzig, Germany).<br />

The Leipzig researchers led by Falk Harnisch and Rohan<br />

Karande (University of Leipzig/Research and Transfer Centre<br />

for bioactive Matter b-ACTmatter) have described how this<br />

can be achieved in an article published in Green Chemistry.<br />

For example, nylon consists of about 50 % adipic acid, which<br />

has so far been industrially extracted from petroleum. In<br />

the first step, phenol is converted to cyclohexanol, which is<br />

then converted to adipic acid. This energy-intensive process<br />

requires high temperatures, high gas pressure, and a large<br />

amount of organic solvents. It also releases a lot of nitrous<br />

oxide and carbon dioxide. The researchers have now developed<br />

a process in which they can convert phenol into cyclohexanol<br />

using an electrochemical process. “The chemical<br />

transformation behind it is the same as in the established<br />

processes. However, electrochemical synthesis replaces the<br />

hydrogen gas with electric energy which takes place in an<br />

aqueous solution and requires only ambient pressure and<br />

temperature”, explains Harnisch. For this reaction to run<br />

as quickly and efficiently as possible, a suitable catalyst is<br />

needed. This would maximise the yield of electrons needed<br />

for the reaction and the efficiency of the conversion of phenol<br />

to cyclohexanol. In laboratory experiments, the best yields<br />

(almost 70 % electrons and just over 70 % cyclohexanol) were<br />

shown with a carbon-based rhodium catalyst. “The relatively<br />

short reaction time, the efficient yield, and the effective use<br />

of energy as well as synergies with the biological system<br />

make this process attractive for a combined production<br />

of adipic acid”, says Micjel Chávez Morejón, UFZ-chemist<br />

and first author of the study. In earlier research, two other<br />

UFZ working groups led by Katja Bühler and Bruno Bühler<br />

discovered how the bacterium Pseudomonas taiwanensis<br />

can convert cyclohexanol into adipic acid in a second step.<br />

“Until now, it had not been possible to microbially convert<br />

phenol to cyclohexanol. We have closed this gap with the<br />

electrochemical reaction”, says Rohan Karande, who is<br />

now continuing this work in cooperation with the UFZ at the<br />

University of Leipzig.<br />

The Leipzig researchers were able to close yet another gap<br />

in environmentally friendly nylon production by developing<br />

an alternative for phenol produced from fossil-based raw<br />

materials. To achieve this, they used monomers such as<br />

syringol, catechol, and guaiacol, all of which are produced as<br />

a degradation product of lignin – a waste product of the wood<br />

industry. “For these model substances, we have been able to<br />

show that together we can go all the way to adipic acid”, says<br />

Harnisch. Rohan Karande adds, “Around 4.5 million tonnes of<br />

adipic acid are produced worldwide. If we were to use waste<br />

products from the wood industry for this, it would have a<br />

considerable effect on the world market”.<br />

However, there is still a long way to go before lignin-based<br />

nylon is ready for the market. For example, the scientists<br />

have so far achieved a yield of 57 % for the 22-hour overall<br />

process (i.e. from the monomers from lignin residues utilizing<br />

microbial and electrochemical reaction steps to adipic acid).<br />

“This is a very good yield”, says Micjel Chávez Morejón. The<br />

results are still based on laboratory tests on a millilitre<br />

scale. The prerequisites for scaling up the process are to<br />

be created in the next two years. This technology transfer<br />

requires not only a better understanding of the entire process<br />

but also, among other things, the use of real lignin mixtures<br />

instead of model mixtures (as has been the case so far) and<br />

the improvement of the electrochemical reactors. Harnisch<br />

and Karande agree: “The process for the lignin-based<br />

nylon exemplifies the great potential of electrochemicalmicrobial<br />

processes because an optimal process chain<br />

can be set up through the intelligent way in which various<br />

components are combined”.<br />

The process for developing biobased nylon is funded by the<br />

UFZ’s “transfun” innovation programme, which supports the<br />

translation of ideas into applications at the UFZ. The project<br />

funding of EUR 250,000 is supplemented by the University of<br />

Leipzig’s own contributions. AT<br />

www.ufz.de<br />

Publication:<br />

Micjel Chávez Morejón, Alexander Franz, Rohan Karande, and<br />

Falk Harnisch: Integrated electrosynthesis and biosynthesis for<br />

the production of adipic acid from lignin-derived phenols. Green<br />

Chemistry, https://doi.org/10.1039/D3GC011<strong>05</strong>D<br />

18 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Category<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

19


Fibres / Textiles<br />

Mushroom fibres for textiles<br />

Chitosan for the textile industry obtained from fungal biomass<br />

The textile sector is facing a turning point: It is<br />

already clear that one of the most important market<br />

drivers of the future will be the growing demand for<br />

environmentally friendly textiles. This is shown by a look at<br />

neighbouring sectors such as the food industry, which is<br />

increasingly relying on organic products. However, the share<br />

of biobased fibres in the textile industry does not yet reflect<br />

this trend. Quite the opposite: for decades, the worldwide<br />

consumption of synthetic fibres has been rising continuously.<br />

On the one hand, this is due to the increased functionality<br />

of polyester fibres in recent years and on the other hand, due<br />

to the low production costs. The raw material for these fibres<br />

is crude oil, the price of which has remained at a constantly<br />

low level for years and ensures that cheap synthetic fibres<br />

flood the textile market.<br />

The environmental impact is huge: greenhouse gas<br />

emissions during production, growing mountains of textile<br />

waste for disposal, and microplastic pollution of the oceans,<br />

to name but a few. Cotton, as a widespread alternative, is<br />

hardly less harmful to the environment: from the use of<br />

toxic pesticides during production to the immensely high<br />

water and energy consumption during processing, the<br />

environmental balance sheet of this textile raw material<br />

source hardly looks any better.<br />

Environmentally friendly alternatives are therefore urgently<br />

needed. Of all the natural fibre base materials, cellulose as a<br />

plant fibre has seen the fastest increase in all textile substrates<br />

in recent years, as it is the most abundant biopolymer on<br />

earth. The second most naturally occurring polymer is chitin.<br />

While cellulose is a polymer of glucose, chitin is a polymer of<br />

the closely related molecule N-acetylglucosamine. It is the<br />

main component of the cell walls of fungi and is also found in<br />

nature in caterpillar skins, butterfly wings, the exoskeleton<br />

of insects or in a strong mixture with calcium carbonate in<br />

crab and crustacean shells. Chitosan can be obtained by the<br />

deacetylation of chitin.<br />

In the past 20 years, several chitin extraction plants have<br />

been built, mainly in the Asia-Pacific region and in Japan,<br />

using a raw material obtained from transformed shrimp<br />

and crab shells. In Europe, there is practically no production<br />

of chitin or chitosan today. The remarkable properties of<br />

chitosan such as biodegradability, antibioticity (inhibition of<br />

bacterial growth), and compatibility with cotton and cellulose<br />

make it a promising bioplastic for the production of synthetic<br />

fibres for textile applications.<br />

The production volume of chitin and chitosan is mainly<br />

limited by the availability of the biological feedstock.<br />

Worldwide demand for chitin in 2015 was above 60,000<br />

tonnes, worldwide production of chitin the same year was<br />

Mould<br />

(Aspergillus Niger)<br />

Gene modification,<br />

cultivation and<br />

fermentation<br />

Extraction and<br />

deacetylation<br />

Solvent<br />

spinning<br />

Yarn development Fabric development Product prototyping<br />

20 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


around 28,000 tonnes. It is expected that the worldwide<br />

market for chitin derivatives (including chitosan) should<br />

reach USD 63 billion by 2024, following a report from<br />

Global Industry Analysts (chitin and chitosan derivatives<br />

market report – 2015).<br />

To overcome feedstock dependency and other<br />

disadvantages of the current chitin supply chain (such as,<br />

low traceability, a lack of reproducible and standardised<br />

processes, and a lack of quality control) an alternative,<br />

reliable, reproducible, and highly scalable production<br />

process is needed. Recent studies have shown that chitosan<br />

can be extracted and processed from fungal biomass.For<br />

example, as a byproduct of biotechnological processes in<br />

which filamentous fungi are already used on a large scale<br />

as natural cell factories for the production of platform<br />

chemicals, organic acids, proteins, enzymes, antibiotics,<br />

pharmaceuticals, dyes, and fuels at particularly low costs.<br />

The aim of current research projects is to produce chitosan<br />

from the fungus Aspergillus niger, which is one of the most<br />

important fungal cell factories used in biotechnology.<br />

The fungus achieves enormous throughput in a short<br />

time, with reproducible high quality and purity for gentle<br />

extraction and multiple refining and conversion options with<br />

fully verifiable and tailor-made specifications that meet the<br />

requirements of the relevant markets. In addition to its high<br />

growth and multiplication rate, its acceptance of a broad<br />

food spectrum, including starch, pectins and lignocellulosic<br />

waste from agriculture and forestry, is an advantage. Up to<br />

30 % of its cell walls consist of chitin, which can be further<br />

increased by gene modification and the addition of stressors<br />

in the culture environment.<br />

Chitosan production from fungal biomass can draw on<br />

both primary feedstock streams (direct industrial fungal<br />

cultivation for polymer production) and secondary feedstock<br />

streams (waste streams from established industrial fungal<br />

cultivation for chemical and active ingredient production).<br />

In particular, the use of secondary raw material streams,<br />

i.e. a coupled production of polymer and other substances,<br />

represents a cost advantage that other biopolymers do not<br />

have, which means that chitosan has higher chances of<br />

being truly competitive compared to conventional petroleumbased<br />

polymers. For this reason, the development of a<br />

chitosan industry in Europe is also conceivable, which<br />

serves numerous current demands for regional, sustainable<br />

production, the limitation of water and land requirements as<br />

well as spatially short and traceable supply chains. As the<br />

infrastructure of industrial fungi cultivation is already an<br />

established industrial standard, and chitosan can be spun on<br />

conventional spinning lines used for cellulose and processed<br />

on available textile machines, only the chitin to chitosan<br />

conversion has to be created.<br />

For use in clothing, the fungus-based polymers are very<br />

suitable. Their performance and quality do not have to fear<br />

comparison with cotton or cellulose fibres. Some properties<br />

By:<br />

Simon Kammler, Scientific Assistant<br />

Department of Chemical Technologies for Textile and Fibre Innovations<br />

Institut für Textiltechnik of RWTH Aachen University<br />

Aachen, Germany<br />

are even superior to those of petroleum-based polymers,<br />

the material offers a very pleasant natural feel and high<br />

wearing comfort. The odour-inhibiting effect is just as much<br />

in favour of the mushroom fibres as the temperature – and<br />

climate-balancing function, as the material is characterised<br />

by high moisture absorption and good moisture retention.<br />

The material is visually appealing with its light, silky sheen.<br />

The antibiotic properties of chitosan fibres make them<br />

particularly suitable for medical applications such as hospital<br />

garments and wound dressings, sportswear and footwear,<br />

and clothing where the chitosan can inhibit bacterial growth,<br />

improve hygiene, and prevent odour. The biobased origin and<br />

biodegradability of chitosan fibres contribute to the ongoing<br />

transition of the textile market to more environmentally<br />

friendly products, and are also suitable for use in disposable<br />

textiles. The fact that chitosan is non-toxic and does not<br />

form toxic degradation products makes it additionally<br />

attractive as a raw material, as there are no disposal or<br />

environmental problems.<br />

The low use of resources speaks in favour of the chitosan<br />

polymers, as the production can take place with a closed<br />

water cycle. In addition, the mushrooms can be used<br />

completely within the framework of a coupled production.<br />

In addition, no entire production facilities have to be built,<br />

neither in the raw material production nor in the yarn<br />

production. Antimicrobial treatment with problematic<br />

chemicals is not necessary, nor is the use of pesticides,<br />

herbicides, and artificial fertilisers. In addition, the chitosan<br />

is biodegradable. Currently, the focus is on the fungal strain<br />

Aspergillus niger, but the use of other fungal species is<br />

conceivable in the future.<br />

The research described in this article is part of the project<br />

“Fungal Fibers”, funded by the German Federal Ministry<br />

for Economic Affairs and Climate Protection within the<br />

BioTexFuture Innovation Space.<br />

www.ita.rwth-aachen.de<br />

www.biotexfuture.info/projects/fungalfibers<br />

Fibres / Textiles<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

21


Fibres / Textiles<br />

Algae-based textiles<br />

Qualifying PA 6.9 for sporting goods and technical yarns<br />

BIOTEXFUTURE is one of four innovation spaces<br />

which are funded by the German Federal Ministry of<br />

Education and Research (BMBF) in the course of the<br />

National Research Strategy BioEconomy 2030 [1]. The vision<br />

of BIOTEXFUTURE is the conversion of the textile value<br />

chain from petroleum-based to biobased. In order to fulfil<br />

this vision, in the AlgaeTex subproject, the development of<br />

microalgae as a raw material basis for plastic filaments to<br />

produce sustainable textile products is being researched.<br />

In particular, the AlgaeTex project aims to demonstrate the<br />

applicability of algae-based multifilament fibres for textiles in<br />

the sports industry, such as knitted shoe uppers or T-shirts.<br />

The crimp contraction, modulus, and stability were<br />

determined to be about 16/6/93 % (DIN 53841-1), which<br />

needs some more improvement with a better false-twist<br />

texturing process. Microscopy images of sample PA 6.9 DTY<br />

are shown in Fig. 3.<br />

In order to approve and qualify the new material for the<br />

sporting industry, polyamide 6.9 has to be investigated and<br />

qualified for the intended usage.<br />

Therefore, in AlgaeTex, the first Adidas shoe was produced<br />

a short while ago at a lab scale from flatbed-knitted<br />

non-algae biobased PA 6.9 yarns which were<br />

melt-spun and textured at ITA (Fig. 1).<br />

Fig. 3: Microscopy images of PA 6.9 DTY in a loose state (top) and<br />

under tension (bottom<br />

Fig. 1: Adidas shoe<br />

made from non-algae<br />

biobased PA 6.9 yarns<br />

spun at ITA<br />

Additionally, the first finer textured yarns for apparel were<br />

produced at ITA at lab scale from the same commercially<br />

sourced PA 6.9, and they will soon be processed into<br />

sportswear at Adidas. Thus, further proving the selection of<br />

PA 6.9 as a suitable choice for the textile industry.<br />

Furthermore, very fine and strong fully-drawn yarns (FDY)<br />

for technical applications like car interiors in automotive<br />

use were successfully developed, in order to explore<br />

further application scenarios. During tensile testing (DIN<br />

EN ISO 2060 and 2062), a tenacity with up to 42,7 cN/dtex<br />

and an elongation at max. force between 31 and 46 % was<br />

determined (Fig. 4).<br />

The measured tenacity reaches up to 44,3 cN/dtex and the<br />

elongation at max. force lies between 18 and 30 % (Fig. 2).<br />

These values are well-comparable to commercial DTY.<br />

Tenacity [cN/tex]<br />

45<br />

40<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

V9<br />

V15<br />

V16<br />

V17<br />

V18<br />

V20<br />

V26<br />

V27<br />

V28<br />

V29<br />

V31<br />

V32<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

Elongation [%]<br />

Tenacity [cN/tex]<br />

45<br />

40<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

FDY 1<br />

FDY 2 FDY 3<br />

120<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

Elongation [%]<br />

Tenacity<br />

Elongation<br />

Tenacity<br />

Elongation<br />

Fig. 2: Tenacity and elongation at max. force of the PA 6.9 DTY<br />

for apparel<br />

Fig. 4: Tenacity and elongation at max. force of the PA 6.9 FDY<br />

22 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Fibres<br />

FDY production was possible at a pilot scale with up<br />

to 37 dtex and 24 filaments in the yarn, which results in<br />

1,54 dtex/filament. The production was merely limited<br />

by the current machine parameters, and the polymer<br />

can most likely withstand even higher stresses while<br />

spinning it, resulting in even finer yarns that are suitable<br />

for technical applications.<br />

COMPEO<br />

Leading compounding technology<br />

for heat- and shear-sensitive plastics<br />

To further validate the usability of the spun yarns for<br />

textile applications, the yarns were processed on different<br />

knitting machines. In the knitting trials, the unwinding<br />

properties and the general loop formation were comparable<br />

with industrial yarns.<br />

Fig. 5: Knitted PA 6.9 – DTY (left) and FDY (right)<br />

Following on from the current evidence that PA 6.9 is<br />

generally suitable, in the next months, the first algae-based<br />

polymers will be produced and processed at ITA to create<br />

an algae-based shoe demonstrator for the project. Next,<br />

algae-based apparel and technical yarns are to be produced<br />

to showcase the versatile suitability of biobased PA 6.9.<br />

www.ita.rwth-aachen.de<br />

By:<br />

H. Löcken, M. Ortega, T. Gries<br />

ITA Institut für Textiltechnik of RWTH Aachen University,<br />

Aachen, Germany<br />

Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />

With its new COMPEO Kneader series, BUSS continues<br />

to offer continuous compounding solutions that set the<br />

standard for heat- and shear-sensitive applications, in all<br />

industries, including for biopolymers.<br />

Acknowledgements<br />

The authors want to thank the Federal Ministry<br />

of Education and Research (BMBF) for funding<br />

the innovation space BIOTEXFUTURE and<br />

this research project.<br />

• Moderate, uniform shear rates<br />

• Extremely low temperature profile<br />

• Efficient injection of liquid components<br />

• Precise temperature control<br />

• High filler loadings<br />

www.busscorp.com<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

23


Fibres / Textiles<br />

Infinitely recycled Nylon<br />

The athletic apparel brand lululemon (Vancouver,<br />

Canada) recently formed a partnership with Australian<br />

biotech start-up Samsara Eco (Sydney, Australia)<br />

in form of a multi-year collaboration. The goal is to scale<br />

circular textile-to-textile recycling of Nylon 66 and polyester,<br />

which they call infinite recycling.<br />

Samsara is still a rather young company and was founded<br />

in late 2021 at the Australian National University (ANU).<br />

The enzymatic recycling technology is based on two PhD<br />

students, Matthew Spence and Vanessa Vongsouthi, who are<br />

two of the four founders of the company.<br />

Samsara Eco’s enzymatic library can already break down<br />

plastics back into their monomers that are difficult to recycle<br />

mechanically. But the company also claims that it is better<br />

than other advanced recycling technologies as it can recover<br />

and reuse many of its chemicals and consumables, water,<br />

and energy. Its infinite recycling does not generate any toxic<br />

or harmful by-products.<br />

“Unlike our competitors, these differences make our<br />

technology carbon-neutral and affordable, with minimal<br />

environmental impact”, it says on Samsara’s website. CEO<br />

and Founder of Samsara Eco Paul Riley said, “Plastic is one<br />

of the greatest inventions of the 20 th century and provides<br />

enormous utility because of its durability, flexibility, and<br />

strength. Yet, it’s also an environmental disaster, with<br />

almost every piece of the nine billion tonnes ever made<br />

still on the planet”.<br />

While still relatively young, the cooperation with lululemon<br />

is already a significant milestone for the ambitious start-up<br />

and shows the need for innovative recycling technologies.<br />

Paul Riley, CEO and Founder (l.) with Vanessa Vongsouthi, Head of<br />

Protein Engineering & Research and Founder (r.)<br />

Currently, Samsara Eco’s enzymatic library can break<br />

down challenging plastics including coloured, multi-layered,<br />

mixed plastics and textiles like polyester and nylon 6,6. Riley<br />

said: “You can’t solve the climate crisis unless you solve the<br />

plastics crisis”. Samsara’s objective is to deliver climate<br />

repair through infinite recycling. Its technology maturity<br />

roadmap involves developing proprietary libraries of enzymes<br />

addressing multiple plastics and textiles over the next six<br />

months to two years.<br />

And Samsara doesn’t shy away from big goals. “Our 2030<br />

ambition is to recycle 1.5M+ tonnes of plastic and textile<br />

waste per annum, saving 2.5M tonnes of CO 2<br />

emissions”,<br />

said Riley. “If the Samsara technology is applied across the<br />

plastic and chemical manufacturing industries, it could<br />

save us around five per cent of global annual CO 2<br />

emissions<br />

(2.5 Gt of CO 2<br />

)”. AT<br />

corporate.lululemon.com | www.samsaraeco.com<br />

“Nylon remains our biggest opportunity to achieve our 2030<br />

sustainable product goals. This partnership demonstrates<br />

what’s possible through collective innovation to solve unmet<br />

needs. Through Samsara Eco’s patented enzymatic process,<br />

we’re advancing transforming apparel waste into highquality<br />

nylon and polyester, which will help us live into our<br />

end-to-end vision of circularity”, said Yogendra Dandapure,<br />

Vice President, Raw Materials Innovation at lululemon.<br />

There is a need for these technologies and a need for<br />

trailblazers like Samsara that will soon open a new Research<br />

& Development facility at Queanbeyan (Australia), which is<br />

expected to be operational by late 2024.<br />

“We’ve had fantastic growth out of our ANU lab so far, but<br />

the plastic problem is growing fast”, Riley comments. “As we<br />

gear up towards commercialisation, access to our first R&D<br />

facility will enable us to accelerate the capabilities of infinite<br />

recycling and scale our solution which breaks down plastics<br />

in minutes, not centuries”.<br />

24 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Depolymerization of PA66<br />

using microwaves<br />

Asahi Kasei (Tokyo, Japan) produces fossil fuel–derived<br />

hexamethylenediamine (HMD) and adipic acid (ADA)<br />

as intermediates to manufacture Leona PA66, an<br />

engineering plastic featuring outstanding heat resistance<br />

and rigidity. PA66 is used in various applications, including<br />

plastic parts for automotive and electronic products,<br />

and yarn for airbag fabric, and its demand is expected<br />

to increase worldwide.<br />

As the world moves toward carbon neutrality, attention<br />

is increasingly focused on manufacturing processes for<br />

reducing greenhouse gas (GHG) emissions from chemical<br />

products derived from fossil fuels. One such approach is<br />

recycling, and recently chemical recycling has become<br />

a more viable solution. There are many approaches to<br />

advanced or chemical recycling, ranging from using<br />

enzymes to microwaves. Microwave Chemical, as the name<br />

suggests, focuses on the latter. They developed a process<br />

which can directly and selectively heat target substances<br />

with high energy efficiency with, you guessed it, microwaves.<br />

Their proprietary technology platform for decomposing<br />

plastic using microwaves is called PlaWave .<br />

Microwave Chemical is promoting technological and<br />

business development to achieve carbon neutrality in<br />

the industrial sector, focused on process development<br />

using microwaves, which can directly and selectively<br />

heat target substances with high energy efficiency.<br />

For chemical recycling, Microwave Chemical is advancing its<br />

proprietary PlaWave technology platform for decomposing<br />

plastic using microwaves.<br />

Laboratory-scale studies that began in fiscal 2021 have<br />

confirmed the high-yield depolymerization of PA66 using<br />

microwaves, as well as the principle of the separation and<br />

purification process after depolymerization. Bench-scale<br />

equipment will now be assembled at Microwave Chemical’s<br />

Osaka Factory (Japan) by the end of fiscal <strong>2023</strong>, and a<br />

small-scale demonstration trial using this equipment will<br />

be performed in fiscal 2024 to collect basic process data<br />

for commercialization.<br />

The manufacturing process for PA66 using HMD and ADA<br />

obtained by depolymerization using PlaWave is expected to<br />

reduce GHG emissions compared to the conventional PA66<br />

manufacturing process, while further reduction of GHG<br />

emissions may be achieved utilizing renewable energy for<br />

the power required to generate the microwaves.<br />

The small-scale demonstration trial will be analysed in<br />

detail to decide whether commercialization of the process<br />

makes sense, Asahi Kasei plans to come to a decision by<br />

fiscal 2025. Concurrently with the small-scale demonstration<br />

trial, construction of a business model that involves the<br />

entire value chain in the chemical recycling of PA66 will be<br />

advanced, aiming to achieve a circular economy together with<br />

stakeholders in the PA66 value chain.<br />

Asahi Kasei aims to be a global partner for its PA66<br />

customers by providing optimal solutions for their carbon<br />

neutrality initiatives through studies of the practical<br />

application of material recycling and chemical recycling, as<br />

well as trials for the commercialization of PA66 made using<br />

biomass-derived intermediates.<br />

Microwave Chemical is working to increase the scale of<br />

equipment and to make PlaWave more generally applicable<br />

in order to achieve the practical application of the chemical<br />

recycling of polymethyl methacrylate (PMMA, also called<br />

acrylic resin), automotive shredder residue (ASR), plastic<br />

containers and packaging, flexible polyurethane foam, etc. AT<br />

www.asahi-kasei.com<br />

Fibres / Textiles<br />

Expected effect of<br />

microwave process<br />

- Atmospheric<br />

pressure and low<br />

temperature<br />

- Shorter processing time<br />

- Lower energy<br />

consumption<br />

Heating plastics in solvent<br />

microwave<br />

Adipic acid (ADA)<br />

Hexamethylenediamine (HMD)<br />

Conventional<br />

Process<br />

- High temperature<br />

- Longer processing<br />

time<br />

- Higher energy<br />

consumption<br />

Heating plastics in solvent<br />

Adipic acid<br />

(ADA)<br />

Hexamethylene<br />

diamine<br />

(HMD)<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

25


Fibres / Textiles<br />

Sustainable leather<br />

alternatives for fashion<br />

Lenzing (Lenzing, Austria) has teamed up with NFW<br />

(Natural Fiber Welding, Peoria, IL, USA) to offer<br />

TENCEL branded fibres as another backer option for<br />

NFW’s patented plant-based technology, MIRUM ® .<br />

are compostable and biodegradable, enabling complete<br />

circularity of finished products. The collaboration creates a<br />

uniquely sustainable alternative for leather applications, as<br />

both Tencel fibres and Mirum are versatile enough to be used<br />

in multiple applications.<br />

“At NFW, we believe that plant matter is the only material<br />

that can scale to replace conventional plastic. Since its<br />

inception, Mirum has been engineered to benefit our planet.<br />

By adding fabrics made of Tencel to Mirum, we can enhance<br />

material transparency and traceability, while guaranteeing<br />

comfort and great hand feel on the skin. We are thrilled to join<br />

hands with the Tencel brand, and we will continue creating<br />

greener alternatives for the fashion industry”, said Oihana<br />

Elizalde, Vice President and General Manager of Mirum at<br />

NFW. One of the best examples of the collaboration is the<br />

Allbirds Plant Pacer, which was released last fall. The shoe’s<br />

upper is made with Mirum lined with Tencel.<br />

Mirum is an ideal option for designers and brands looking<br />

to reduce their environmental footprint and expand their<br />

creative palettes. Tencel fibres are soft and pleasant on the<br />

skin, with outstanding moisture management. Adding backer<br />

material made of Tencel fibres to Mirum not only creates a<br />

truly sustainable option but also one that enhances the<br />

comfort level of products made from leather alternatives.<br />

Mirum is a categorically unique material class, perfect<br />

for luxury accessories, fashion, footwear, automotive, and<br />

home goods. Tencel Lyocell and Modal fibres are derived<br />

from sustainable wood sources and produced using<br />

environmentally responsible processes. The fibres are<br />

identifiable, verifiable, and traceable through Lenzing’s<br />

Fiber Identification technology which enables a physical<br />

identification of fibre origin at different stages of production.<br />

This enables full traceability of the fibre materials used during<br />

the production process, be it on a piece of fabric or finished<br />

product, like garments or footwear. Mirum is made from<br />

natural rubber, plant and mineral pigments, plant-based oils<br />

and waxes, and an all-natural fabric backing. Each Mirum<br />

recipe is unique, but the commitment to using only natural<br />

ingredients is unchanging. Instead of relying on PU binders,<br />

a characteristic of most leather alternatives, Mirum uses<br />

natural rubber and plant oils for binding.<br />

“This partnership is a perfect example of how the<br />

combination of our sustainable Tencel fibres and innovative<br />

materials like Mirum can go beyond traditional textiles.<br />

With innovation at heart, there are infinite possibilities for<br />

application of the new material. Tencel fibres used as backer<br />

not only increase the level of transparency and traceability of<br />

Mirum, but also enhance comfort – and with a very low carbon<br />

footprint. We are confident that the versatile material will be<br />

loved by supply chain partners and brands across footwear,<br />

fashion apparel, accessories, furniture, and even automotive<br />

industries”, said Birgit Schnetzlinger, Head of Business<br />

Development Functional Wear and Footwear, Global Textiles<br />

Business at Lenzing. AT<br />

www.nfw.earth | www.lenzing.com<br />

NFW’s unique approach incorporates a diversity of natural<br />

ingredients like biobased charcoal, clay, cork powder, rice<br />

hulls, coconut fibres, recycled denim or seaweed to develop<br />

colour or add visual interest. At the end of its life cycle,<br />

products made with Mirum can be recycled into new Mirum<br />

or ground up and returned to the earth, while Tencel fibres<br />

26 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Cellulose nano fibres –<br />

a smooth additive<br />

The next big event, the FAKUMA (Friedrichshafen,<br />

Germany) is just around the corner and Asahi Kasei<br />

(Tokyo, Japan) will present, among other things, their<br />

cellulose nano fibre (CNF). Renewable Carbon Plastics talked<br />

to Tomofumi Maekawa, General Manager XRP Development<br />

Project at Asahi Kasei’s Sustainable Polymers Laboratory,<br />

about the material. “The material is derived from cotton linter,<br />

a by-product of the cotton yield, which is usually considered<br />

as a waste material. We only use cotton linter which is already<br />

GRS-certified or in the process of acquiring the certification”,<br />

said Maekawa. “CNF is generated from fibrillated pulp.<br />

Going down to the nanoscopic scale makes our fibre boast<br />

high strength and elasticity, in addition to its lightweight”.<br />

One field of application is to replace glass fibre, as the<br />

material shows a reinforcing effect when used in small<br />

amounts while being lighter than glass fibre. “Naturally,<br />

we aim for glass fibre replacement in plastic compounds.<br />

Since our CNF is a very soft material, it is suitable for sliding<br />

part applications as a filler that does not damage the mating<br />

material. It also shows less material degradation in the<br />

recycling process than glass fibres, which is another added<br />

value”, comments Maekawa. “There is a broad range of<br />

possible applications. One is, for example, in gears and other<br />

moving parts, which can benefit from CNF’s outstanding<br />

sliding properties. Due to its thixotropic behaviour, it also<br />

features a unique viscosity, making it suitable for 3D printing<br />

applications. Compared to other additives, CNF contributes<br />

to a smoother surface appearance after the printing process”.<br />

In Table 1 you can see some of the technical data for<br />

CNF when used with PA6. The table shows reinforced PA6<br />

with 10 % CNF content, as well as reinforced PA6 with<br />

15 % GF content. PA6/CNF10 % shows a high stiffness and<br />

low specific gravity. Compared to PA6/GF15 % the specific<br />

flexural modulus is 7 % higher.<br />

Tensile modulus retention rate / %<br />

Another potentially added value is its biodegradability,<br />

which makes it a great additive for biodegradable applications.<br />

The biodegradability is not certified yet, but Asahi Kasei is<br />

currently considering the certification of their CNF material.<br />

“CNF is a great material, not only does it offer a broader<br />

range of outstanding properties, compared to standard filler<br />

materials, but it also shows a superior recyclability with less<br />

material degradation”, Maekawa concludes.<br />

You can find Asahi Kasei at booth 5319, in Hall B5 during<br />

the Fakuma <strong>2023</strong> (from 17 to 21 October). AT<br />

120<br />

100<br />

www.asahi-kasei.com<br />

80<br />

60<br />

40<br />

20<br />

0<br />

Properties of 100% recycled material<br />

★Tensile modulus retention rate of PA6/CNF10%<br />

materials after 5 times 100% recycle is 92%.<br />

PA/GF15%<br />

Tensile modulus retention after using<br />

100 % regrind (5 cycles).<br />

PA/CNF10%<br />

0 1 2 3 4 5<br />

Times of using 100% regrind<br />

Fibres / Textiles<br />

Items Method Condition unit PA6_CNF10% PA6_GF15%<br />

Specific gravity (ρ) ISO 1183 23°C ― g/cm 3 1.16 1.25<br />

Equilibrium water<br />

absorption<br />

ISO 1110<br />

similar<br />

Table 1: PA/CNF10 % Datasheet. Current development data may change without<br />

notification. The data stated are measured values, not guaranteed values.<br />

23°C / 50%RH % 2.6 2.4<br />

Tensile Strength (TS) ISO 527 23°C<br />

DRY<br />

95 110<br />

MPa<br />

WET 63<br />

70<br />

Tensile Modulus (TM) ISO 527 23°C DRY MPa 5,800 5,300<br />

Tensile Elongation (TE) ISO 527 23°C<br />

DRY<br />

3 3<br />

%<br />

WET 15 15<br />

Flexural Strength (FS) ISO 178 23°C<br />

DRY<br />

135 190<br />

MPa<br />

WET 60 100<br />

Flexural Modulus (FM)<br />

ISO 178 23°C DRY<br />

5,000 5,000<br />

MPa<br />

ISO 178 23°C WET 2,500 2,800<br />

ISO 178 80°C DRY MPa 1,700 1,950<br />

Specific Flexural Modulus ( 3 √FM/ρ) 23°C DRY MPa 14.7 13.7<br />

Molding Condition: Compliant with ISO 294<br />

Test piece: ISO 20753 type A1<br />

Mold temp.=80<br />

WET condition : 23°C, 50%RH<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

27


Fibres / Textiles<br />

Textile yarns from<br />

biopolyesters<br />

KORTEKS (Bursa/Türkiye) is one of the largest suppliers<br />

of polyester yarn. In addition, a new plant for processing<br />

recycled polymer has been commissioned with a daily<br />

capacity of 20 tonnes. Korteks is also active in the development<br />

of yarns from various biopolymers. The experimental design<br />

of all yarn developments is carried out on a pilot scale<br />

melt spinning machine with a 5-zone extruder, spinnerets,<br />

quenching line, drawing godets and winder.<br />

In 2017 and 2020, respectively, Korteks started to develop<br />

filament yarns from PLA, PHA, and PBS. After the first<br />

results and observations, industrial trials were carried out<br />

for the three biopolymers.<br />

PLA<br />

PLA has inherent properties such as flame retardancy,<br />

UV resistance, low density, and low-emperature dyeability.<br />

However, the production of PLA fibre/yarn is challenging due<br />

to its hydrolytic degradation and brittle structure.<br />

In an initial research programme, PLA Pre Oriented<br />

Yarn (POY) was spun and then texturised to give volume,<br />

elasticity, and crimp properties like natural fibres. 100, 150,<br />

300 denier PLA filament yarns have been developed on an<br />

industrial scale. In addition, dope dyed coloured texturised<br />

PLA yarns could be produced. PLA filament yarns have<br />

sufficient strength and elongation properties for weaving<br />

and knitting processes. As PLA is sensitive to alkaline<br />

conditions and high temperatures, PLA yarns and fabrics<br />

require some modifications in dyeing. In addition, finishing<br />

processes of PLA fabrics show close processes with PET<br />

fabrics, but considering the chemical properties of PLA,<br />

some modifications should be made with R&D studies.<br />

PBS<br />

Polybutylene succinate (PBS) is an aliphatic polyester that<br />

can be synthesised from both fossil fuels and monomers<br />

derived from biobased feedstocks. Biodegradability and<br />

excellent melt processability make PBS suitable for<br />

sustainable textiles [1]. The fact that its production costs are<br />

lower than PHAs and that it is more ductile than PLA puts<br />

PBS at the forefront. In addition, PBS has a wide processing<br />

temperature range and good thermal stability compared<br />

to other biopolymers.<br />

Due to the high elongation properties of PBS, the<br />

problem of tight winding is often encountered during the<br />

process. Furthermore, in order to eliminate the melt flow<br />

problems, PBS trials are carried out with different ranges of<br />

melt flow rate polymers.<br />

PHA<br />

The production of biodegradable fibres from P3HB has<br />

been investigated by previous researchers on a laboratory<br />

or pilot scale. The common problem was the formation of<br />

irregular, large crystallites with low density, resulting in<br />

inadequate mechanical properties. Various solutions have<br />

been proposed to improve the structure development.<br />

However, none of these studies were suitable for largescale<br />

production. In studies investigating the thermal<br />

behaviour of PHB, it was found that the molecular weight<br />

starts to decrease just above the melting point around 185°C,<br />

and weight loss and chain breaks occur in the polymer<br />

above 200°C. Initial experiments conducted above 180°C<br />

resulted in degraded, discontinuous melt flow. Extruder<br />

temperatures, residence time, and spinneret exit pressure<br />

Figure 1. Samples of PHA and PBS filament yarns<br />

(from left to right respectively, raw POY, air texturized<br />

PHB, and raw POY and texturized PBS)<br />

Figure 2. Samples of PLA filament yarns (from left to<br />

right respectively, raw white POY, FDY, and dope dyed<br />

green POY and DTY bobbins)<br />

28 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


By:<br />

H. Aybige Akdag Ozkan, R&D Center/Chief of Int.Projects and Fundings<br />

Onur Celen, R&D Center deputy manager<br />

Cansu Uludogan, R&D Center/ Chief of Project and Test Analysis<br />

Korteks Mensucat<br />

Bursa/Türkiye<br />

Category<br />

should be investigated and the quenching line modified<br />

to prevent thermal degradation and the formation of<br />

heterogeneous large crystallites prior to drawing to<br />

provide chain orientation.<br />

On the other hand, the biodegradability of PHAs is<br />

much more advanced. The reasons for this are the<br />

influence of crystallinity, crystal structure, molecular<br />

orientation, melting temperature (Tm) and glass<br />

transition temperature (Tg), as well as the percentage<br />

of degrading microorganisms for each polyester [2].<br />

Despite the fact that PLA and PBS are texturised on<br />

an industrial scale, the PHA yarn experiment is still at<br />

the melt-spinning stage and only a few air texturisation<br />

trials have been carried out. The results showed that the<br />

mechanical properties (tensile strength, elongation) of<br />

PHB yarns can be improved by high draw rates rather<br />

than by increasing the speed. Therefore, the stressstrain<br />

relationship should be investigated.<br />

Conclusions<br />

To conclude, biopolyesters have a tolerable and<br />

improvable processability for making textiles. Thermal<br />

degradation is an important parameter that needs<br />

to be carefully controlled during the process. The<br />

development of PLA and PBS products is moving<br />

faster than PHB due to their relatively coherent thermal<br />

properties with PET.<br />

Considering that synthetic fibres have the highest<br />

market share with 64 %, of which 54 % is fossil-derived<br />

PET, switching to biopolymers from conventional<br />

thermoplastics and using them in the textile industry<br />

can be an alternative to reduce the processing<br />

of fossil fuels. However, materials and designed<br />

products should be well assessed for environmental<br />

impact. Government regulations and changes in<br />

consumer behaviour will also be very important<br />

to enable this change.<br />

REGISTER<br />

NOW!<br />

For your registration scan this QR code<br />

or go to www.european-bioplastics.org/<br />

events/ebc/registration<br />

12 – 13 Dec <strong>2023</strong><br />

Titanic Hotel, Berlin, Germany<br />

www.korteks.com.tr<br />

References<br />

[1] Rudnik, E. (2013). Plastic films in food packaging (pp. 217-248).<br />

William Andrew Publishing.<br />

[2] Tokiwa, Y., & Calabia, B. P. (2007) Journal of Polymers and the<br />

Environment, 15, 259-267.<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

29


Advanced Recycling<br />

Use biodegradation to recycle<br />

conventional plastics into new<br />

biobased materials<br />

AIMPLAS (Valencia, Spain), the Plastics Technology<br />

Centre, forms part of the BioICEP project (Bio<br />

Innovation of a Circular Economy for Plastics), which<br />

started in February 2020 and is funded by the Horizon 2020<br />

programme. The goal of the project is to develop sustainable<br />

and environmentally friendly alternatives to traditional<br />

petroleum-based plastics.<br />

The project used an innovative cascade process by<br />

applying and combining chemical and biological methods<br />

to turn fossil-based plastic waste into natural, biologically<br />

degradable substitutes to be used in the packaging<br />

and pharma industries.<br />

The role of Aimplas in the project involved the pretreatment<br />

of plastics using microwave-assisted thermochemical<br />

degradation. This new technology provided promising<br />

results by turning non-biodegradable plastic waste<br />

(such as low-density polyethylene) into easily biologically<br />

degradable materials. Another technique used was the<br />

depolymerization of polyamides to obtain the monomers of<br />

these polymers. Microorganisms are then able to degrade<br />

these monomers, so they can be turned into products<br />

as building blocks (monomers, or low molecular weight<br />

molecules – oligomers and derivatives) for new bioplastics,<br />

e.g. PHB or nanocellulose.<br />

Likewise, Aimplas used reactive extrusion technologies<br />

that made changes to the structure of the polymeric chains to<br />

improve the biological degradation of these plastics. Aimplas<br />

is also the coordinator in charge of dissemination and<br />

exploitation of results, as well as communication activities.<br />

Reducing the amount of<br />

plastic in the environment<br />

The solution proposed by the BioICEP project focused<br />

on the use of three technologies that enhance, accelerate,<br />

and increase the degradation of plastics to levels far beyond<br />

what is currently possible. A triple-action depolymerization<br />

system broke down plastic waste through three consecutive<br />

processes. The first consisted of chemical disintegration<br />

processes, including a new microwave-based technology that<br />

reduces the molecular weight of base polymers to improve<br />

biological degradation. The second process was biocatalytic<br />

digestion with improved enzymes using different innovative<br />

techniques, including screening with fluorescent sensors<br />

and directed evolution. Finally, in the third process, microbial<br />

consortia developed from best-in-class single microbial<br />

strains were used in combination to produce the highly<br />

efficient degradation of mixed plastic waste streams. The<br />

products of this degradation process will be used as building<br />

blocks for the synthesis of new polymers and bioproducts to<br />

enable a new plastic waste-based circular economy.<br />

To avoid misunderstanding<br />

It should be clear, that this kind of biological degradation<br />

is a completely different process that does not aim at a<br />

biodegradation in the meaning of an alternative disposal<br />

option comparable to composting (complete assimilation by<br />

microorganisms and conversion into CO 2<br />

, water, and biomass).<br />

The consortium and funding<br />

The BioICEP project is funded by the European Union<br />

within the framework of the H2020 programme, topic<br />

CE-BIOTEC-<strong>05</strong>-2019 “Microorganism communities for<br />

plastics bio-degradation”, agreement number 870292.<br />

Besides Aimplas, thirteen partners from nine European<br />

and Asian countries are participating: Acteco (Spain),<br />

Avecom (Belgium), Technische Universität Clausthal<br />

(Germany), Institut za molekularnu genetiku i genetičko<br />

inženjerstvo (Serbia), Instituto de Biologia Experimental e<br />

Tecnológica and Logoplaste Innovation LAB LDA (Portugal),<br />

Technological University of the Shannon and The Provost,<br />

Fellows, Foundation Scholars and other Members of Board<br />

of the College of the Holy and Undivided Trinity of Queen<br />

Elizabeth near Dublin (Ireland), Microlife Solutions (the<br />

Netherlands), National Technical University of Athens –<br />

NTUA (Greece) and Beijing Institute of Technology, Institute of<br />

Microbiology – Chinese Academy of Sciences and Shandong<br />

University (China). MT<br />

www.aimplas.es<br />

www.bioicep.eu<br />

Mixed Plastic Waste<br />

Triple Action Depolymerisation<br />

Fermentation<br />

BioICEP Diagram<br />

1) Physical/Green<br />

Chemical<br />

2) Biocatalysis<br />

3) Microbial Consortia<br />

Monomer<br />

Recovery<br />

Bioproducts<br />

30 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


BOOK STORE<br />

Category<br />

3 rd<br />

Edition<br />

NEW<br />

NEW<br />

NEW<br />

NEW<br />

This book, created and published by Polymedia Publisher<br />

– maker of bioplastics MAGAZINE, is available in English<br />

and German (now in the third, revised edition), and<br />

brand new also in Chinese, French, Spanish and Polish.<br />

Intended to offer a rapid and uncomplicated introduction<br />

to the subject of bioplastics, this book is aimed at all<br />

interested readers, in particular those who have not yet<br />

had the opportunity to dig deeply into the subject, such<br />

as students or those just joining this industry, as well<br />

as lay readers. It gives an introduction to plastics and<br />

bioplastics, explains which renewable resources can be<br />

used to produce bioplastics, what types of bioplastics<br />

exist, and which ones are already on the market. Further<br />

aspects, such as market development, the agricultural<br />

land required, and waste disposal, are also examined.<br />

The book is complemented by a comprehensive<br />

literature list and a guide to sources of additional<br />

information on the Internet.<br />

The author Michael Thielen is the publisher of<br />

bioplastics MAGAZINE.<br />

He is a qualified mechanical design engineer<br />

with a PhD degree in plastics technology from<br />

the RWTH University in Aachen, Germany. He<br />

has written several books on the subject of<br />

bioplastics and blow-moulding technology<br />

and disseminated his knowledge of plastics<br />

in numerous presentations, seminars, guest<br />

lectures, and teaching assignments.<br />

3 rd<br />

Edition<br />

ORDER<br />

NOW<br />

www.bioplasticsmagazine.com/en/books<br />

email: books@bioplasticsmagazine.com<br />

phone: +49 2161 6884463 31<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Automotive<br />

Casein is a protein that makes up to 80% of milk protein and<br />

Category<br />

10<br />

Years ago<br />

Published in<br />

bioplastics MAGAZINE<br />

Fibers & Textiles<br />

What is casein?<br />

Fibers & Textiles<br />

is thus one of the major proteins in milk. Casein is employed<br />

as a binder and excipient. In milk the casein consists of 18 out<br />

of the known 22 amino acids. Casein has an extremely high<br />

content of glutamine and calcium. With approximately 20% of<br />

glutamine no other protein contains as much glutamine as<br />

casein.<br />

Qmilk is particularly suitable for underwear, as this kind<br />

of apparel is worn directly in contact with the skin. Thus skin<br />

kindness and hygiene are of utmost importance. In addition<br />

to the antibacterial and moisture regulating properties the<br />

Qmilk fibres feel very smooth and, thanks to their smooth<br />

surface, skin irritations and itching are effectively avoided<br />

Asked whether she feels she has been dressed in a<br />

Treehugger-Shop when wearing apparel from Qmilk, Tanja<br />

says: “Absolutely not. That kind of fashion in the 70s and 80s<br />

wanted to differentiate itself from the conventional fashion of<br />

those days. Fashion from Qmilk is not only sustainable, but<br />

also beautiful, fashionable and sexy.”<br />

Other typical fibre applications are pillow cases, bed sheets<br />

and mattress covers. Niten Trasy, purchasing manager<br />

of Sunham Home Fashion in New York, is convinced that<br />

sleeping in a Qmilk-bed is healthier than in any other textile<br />

[2]. Potential applications apart from fibres and textiles can<br />

be found for example in toys or in dashboard components<br />

for automobiles. Since Qmilk features a natural resistance to<br />

diesel, ethanol, E10, polyethylene glycol, acetic acid, sodium<br />

hydroxide, and oleic acid, it fulfils many requirements that<br />

could be applied in the automotive industry.<br />

Qmilk collect<br />

Qmilk are working to build the first logistics system for the<br />

collection of unused, and so far technically, unmarketable<br />

milk.<br />

www.en.qmilk.eu<br />

www.qmilk-collect.com<br />

References<br />

[1] www.en.qmilk.eu (Website of Qmilch Deutschland GmbH, last<br />

accessed Sep. 18, 2013<br />

[2] Qmilk, natural fibre, Brochure of Qmilch Deutschland GmbH<br />

[3] Polymerization: From Milk to Plastic - University of Manitoba,<br />

[4] Food wastage footprint: Impacts on natural ressources, FAOreport,<br />

Sept. 2013<br />

Technical Specifications:<br />

Fineness 1.6 dtex<br />

fibre cross section* round<br />

colour milky white<br />

specific weight 1.17 g/cm 3<br />

cutting length 30-60 mm<br />

number of filaments 1400<br />

thermal shrinkage (150°C} 0.4 (ow Fest)<br />

decomposition temperature 200 °C<br />

loop strength 72%<br />

moisture absorption 13.6- 16.3 %<br />

*Special cross-sections and titers upon request<br />

Fibers & Textiles<br />

The fibres<br />

In a first step the casein powder is mixed with water and<br />

melted in an extruder to become a biopolymer-precursor.<br />

Already now the material can be dyed. This avoids the<br />

additional need for water in a later dyeing step, as is required<br />

for example with cotton fibres. Now the biopolymer mass is<br />

pressed into a specially shaped spinneret in a continuous<br />

process to form the fibres. Since the process temperature is<br />

below 100°C the special properties of the milk-casein can be<br />

maintained. Water is used as a plasticizer.<br />

Qmilk offers a wide range of cross-sections and versatilities<br />

in clothing, home textiles and technical textiles. The Qmilk<br />

fibre can be obtained as a staple fibre and filament.<br />

Because of its smooth surface it is ideal for sensitive skin<br />

and gives the feeling of wearing something rather silky.<br />

26 bioplastics MAGAZINE [<strong>05</strong>/13] Vol. 8<br />

Special Features of the fibres are:<br />

• antibacterial<br />

• pleasant to touch<br />

“Sustainability is an integral part of our corporate culture<br />

and we are committed to our corporate values i.e. to work<br />

sustainably and in a socially responsible manner”, says<br />

Anastasia Bresler, PR Manager of Qmilk.”In the focus of<br />

our sustainable policy are our products, innovations and<br />

technologies. We set new standards in the field of man-made<br />

fibre.”<br />

• temperature regulating<br />

• controlled shrinkage<br />

• natural UV filter<br />

• B2 flammability in accordance with DIN 41021<br />

and DIN 75200<br />

• heat resistant up to 200°C<br />

The raw material: No food<br />

• washable up to 60°C<br />

To develop sustainable innovations and processes and to<br />

take advantage of natural materials, are the cornerstones of<br />

the Qmilk company‘s philosophy.<br />

• lower density than cotton and silk<br />

• non allergic<br />

The casein, which is the main resource of Qmilk’s products,<br />

is made from raw milk that is no Ionger suitable for sale<br />

and, under the current legislation cannot be used as food.<br />

ln Germany alone every year 1.9 million tonnes of milk must<br />

be disposed of. Globally more than 100 million tonnes of milk<br />

are wasted every year [4]. Reasons for this are, for example,<br />

heat, cellular problems, or germs. This kind of milk must be<br />

be disposed of at the expense of the farmer. In many cases<br />

this milk ends up – albeit prohibited – in the sewerage. But<br />

not only milk that does not fulfill the hygiene requirements<br />

of the dairy industry is abuntantly available. There are also<br />

waste products e.g. from cheese making etc. that need to be<br />

disposed.<br />

• good moisture absorbance<br />

• good colouring performance<br />

Antibacterial Activity<br />

Qmilk is naturally antibacterial. There is no need to use<br />

anti-bacterial treatment. It is another advantage of crosslinked<br />

polymers (see above) that textiles made with such<br />

fibres cannot mildew and will behave absolutely neutral<br />

in terms of their odour. Qmilk also has an antibacterial<br />

action against E. coli and even Staphyllococcus aureus. The<br />

bacteria cannot multiply in the Qmilk fibre and thus it gives a<br />

However, this milk still contains valuable ingredients and<br />

offers great potential for technical purposes. “We use a raw<br />

smoothing freshness throughout the day.<br />

Moisture absorption<br />

The Qmilk fibre easily absorbs moisture and is therefore<br />

particularly suitable for applications in underwear, functional<br />

sports clothing, and the home textiles sector, but also for<br />

technical textiles.<br />

Fire protection class<br />

The Qmilk fibre reaches fire protection class B2 according<br />

to DIN 4102-1 and DIN 75200 and can therefore be used in<br />

home decoration, but also in the automotive industry.<br />

The textiles<br />

The smooth surface of the Qmilk fibre avoids skin irritation<br />

and promotes an optimum skin feeling. Qmilk fibre can<br />

be modified in its visual aspects and properties for textile<br />

surfaces.<br />

“The fibres are very smooth and on my skin it feels like<br />

silk,” says Tanja Berthold, fashion tailoress at Qmilk. “I love it<br />

for my pyjamas”, she adds. “I don’t want to sleep in anything<br />

else – ever!” At night she never feels cold, or sweats, thanks<br />

to the excellent moisture properties of Qmilk.<br />

bioplastics MAGAZINE [<strong>05</strong>/13] Vol. 8 27<br />

material which inevitably becomes available and thus we only<br />

extend its product life cycle”, says Anastasia. “Additionally,<br />

we pay attention to sustainable animal husbandry by our<br />

suppliers.”<br />

The bioplastic<br />

Fibers & Textiles<br />

N<br />

The principle of converting milk into a biopolymer and<br />

eventually into fibre products is based on the concept of<br />

white biotechnology, one of today’s key technologies. The<br />

biotechnological advances allow many new industrial<br />

processes which are cheaper and more ecological. In<br />

addition, the use of renewable resources was brought to the<br />

fore, and we all strive to reduce the use of raw material and<br />

energy.<br />

The advantage of the new manufacturing process is the<br />

ability to produce a biopolymer comprised of 100% natural<br />

and renewable raw materials - milk. “The production of 1kg<br />

of the biopolymer needs only 5 minutes and a maximum of<br />

2 liters of water”, explains Ines Klinger, head of technical<br />

development at Qmilch. “This implies a particular level of<br />

cost efficiency and ensures a minimum of CO 2 emissions.”<br />

There are lots of options for modification of the polymer<br />

which offers the potential for numerous applications.<br />

However, one has to keep in mind the fact that Qmilk is a<br />

cross-linked, thermoset material. The cross-linking of<br />

the molecules makes the material (including the fibres)<br />

water resistant, as opposed to approaches in the past when<br />

chemicals had to be added to achieve water resistant caseinbased<br />

fibres.<br />

The material can be made flexible or rigid. It absorbs colour<br />

very easily and has good colour brilliance. It is antibacterial<br />

and therefore complements a wide range of applications<br />

even outside the fibre and textile industry.<br />

Qmilk is resistant to water, ethanol, acetone, methanol,<br />

fuels, and oils, weak acids, alkalis and minerals. Its<br />

temperature stability is above 200°C and the density is at<br />

1.17 g/cm³. The Qmilk biopolymer is compostable in a few<br />

weeks.<br />

ature produces a versatile resource, namely milk. Incredible<br />

amounts of milk have to be disposed of every<br />

day because it is longer marketable and legislation<br />

says that it should not be used as food. Qmilch Deutschland<br />

GmbH (Hanover, Germany) have developed an innovative and<br />

unique technology for the production of textile fibres made<br />

from the milk protein, casein. Qmilk ® produces textile fibres<br />

for various applications including clothing, home textiles,<br />

industrial applications, medical equipment and automotive<br />

equipment. And the company is working continuously to advance<br />

the unique biopolymer with an excellent product quality<br />

and an outstanding performance in the field of man-made<br />

fibres.<br />

The company<br />

Bioplastic fibres from m<br />

Founder of the company is Dipl.-Biologist Anke Domaske<br />

who originally was searching for chemically untreated<br />

clothing for her stepfather who had cancer, and eventually for<br />

bioplastics MAGAZINE [<strong>05</strong>/13] Vol. 8 25<br />

By M<br />

other people who were suffering from allergies,<br />

Then she had the idea of creating a product th<br />

only help people, but is also good for the environm<br />

Eventually milk proteins came to her notice. Suc<br />

had already been processed into textiles in the 1930<br />

fibres were treated with various chemicals and produ<br />

complex process.<br />

Qmilk began as a classic start-up – however, not in a g<br />

but in a kitchen. Since the company and its developm<br />

not a university spin-off, there was initially no laborato<br />

work in, just the idea of developing a fibre that is chemic<br />

untreated. The necessary equipment was bought in a groc<br />

store and built into a laboratory for about € 200.<br />

In April 2011 the Qmilch GmbH was founded. There is now<br />

a group of companies – Qmilch IP GmbH, Qmilch Holding<br />

GmbH and Qmilch Deutschland GmbH – engaged in the<br />

production and development of biopolymers, based on milk<br />

proteins and other natural and renewable raw materials.<br />

24 bioplastics MAGAZINE [<strong>05</strong>/13] Vol. 8<br />

tinyurl.com/qmilk2013<br />

32 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Automotive<br />

Stay informed<br />

the fastest way!<br />

Categroy<br />

for example.<br />

at can not<br />

ent itself.<br />

h proteins<br />

s, but the<br />

ced in a<br />

arage,<br />

ent is<br />

ry to<br />

ally<br />

ery<br />

ilk<br />

ichael Thielen<br />

In September <strong>2023</strong>, Anke Domaske<br />

(now Anke Nagler),<br />

founder of Qmilk, said:<br />

Even if the development of biopolymers and<br />

fibres from milk-based protein was a great<br />

success, our main focus today is on dental care<br />

products for dogs and cats. This<br />

may sound strange, but<br />

our extensive research<br />

about 10 years ago<br />

also revealed a very<br />

positive influence of milk<br />

protein-based products<br />

on the oral flora. So, we<br />

not only put our emphasis<br />

on polymers and fibres, as<br />

described in the article, but<br />

also on other applications.<br />

After a couple of really<br />

successful years, however,<br />

for different reasons, the<br />

pandemic and its influence on<br />

the textile market on the one<br />

hand, but also changing personel<br />

and shifting priorities in our<br />

partner companies made it difficult<br />

recently to successfully market<br />

our initial products.<br />

Our current main focus on pet oral care<br />

showed very good market opportunities,<br />

and the success in Germany as well as in<br />

many other countries proves us right. You<br />

may want to check our website.<br />

But even if our focus today is on such<br />

kinds of products, we are still active in some<br />

segments of the initial applications and we are<br />

still interested to partner with companies that<br />

want to bring milk protein-based polymers and<br />

fibres to successful products into the market.<br />

Oh, and it‘s<br />

for FREE...<br />

Subscribe to our<br />

Newsletter<br />

https://www.bioplasticsmagazine.com/en/newsletter/<br />

NEWS<br />

www.qchefsdental.de<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

33


From Science& Research Category<br />

Catalysis for a multidimensional<br />

circular economy<br />

The chemical industry supplies indispensable substances<br />

for our health, nutrition, and current standard of living.<br />

However, many of the chemical products accumulate as<br />

waste at the end of their product life. Due to their chemical<br />

complexity and diversity of substance mixtures, no viable<br />

recycling concepts exist for most waste streams to date; they<br />

are therefore often used thermally, landfilled, or introduced<br />

into natural ecosystems, thus leading to environmental<br />

pollution. The resulting ecological challenges are particularly<br />

evident in the case of plastic waste, e.g. microplastics are now<br />

found in the most remote areas of the world. The politically<br />

and socially demanded resource and energy transition<br />

therefore requires transforming the traditionally linear<br />

structure of production and use in the chemical industry<br />

into a holistic circular economy in which economic growth is<br />

decoupled from primary resource consumption and waste is<br />

understood as a valuable resource. This requires viable new<br />

recycling concepts for chemical products.<br />

Regina Palkovits and Jürgen Klankermayer of RWTH<br />

Aachen University (Aachen, Germany), together with an<br />

interdisciplinary team of researchers in “catalaix – Catalysis<br />

for a Circular Economy”, want to ensure chemical products<br />

become valuable resources of an integrated circular economy<br />

according to the open-loop principle at the end of their product<br />

life. The chemical building blocks created in open-loop<br />

recycling will be tailored and flexibly fed into a wide variety<br />

of value chains and material cycles in line with demand.<br />

The aim is to create a flexible, multidimensional circular<br />

economy that supports the sustainable transformation of<br />

the chemical industry. This will be achieved by developing<br />

customized chemo-, bio – and electro-catalyst systems and<br />

integrating renewable raw materials and energy sources into<br />

the recycling process.<br />

Using the example of plastics recycling, the researchers<br />

have already demonstrated the technical feasibility of this<br />

concept for diverse classes of plastics. As one example, the<br />

PalkovitsLab was able to transform the biobased plastics<br />

polyhydroxybutyrate (PHB) and polylactic acid (PLA) with<br />

easily separable solid catalysts back into the monomers.<br />

This was possible for both pure polymer streams and<br />

mixtures of the two bioplastics. The strategy could even<br />

be extended to PET as a non-biopolymer. Here, PHB and<br />

PLA were converted with similar yields as in the previous<br />

mixed recycling approach of the bioplastics, whereas PET<br />

remained largely intact in solid form and could therefore be<br />

easily separated from the reaction solution. Furthermore,<br />

the Klankermayer group demonstrated the effective<br />

and selective catalytic depolymerization of polyester/<br />

polycarbonate wastes into various diols using a tailormade<br />

molecular catalyst that tolerates polymer additives.<br />

Investigations on the integration of biobased diols in the<br />

chemical recycling of POM (polyoxymethylene) polymers<br />

enabled the selective production of chemical building blocks<br />

from the plastics mainly used in automotive construction.<br />

These flexible building blocks can then serve as solvents,<br />

fuel additives, pharmaceutical intermediates, and even<br />

as monomer materials for polymerization reactions. The<br />

showcases exemplify the potential and capability of chemical<br />

recycling of real mixed waste streams, with the possibility<br />

of avoiding extensive sorting and purification steps prior<br />

to depolymerization.<br />

“Catalaix – Catalysis for a Circular Economy” is one of six<br />

finalists in the competition for a new WSS research centre<br />

for the sustainable use of the planet’s resources that have<br />

each already received a WSS research prize of 1 million<br />

Swiss francs (~ EUR 1 million). A total of 123 proposals were<br />

submitted in the competition for the “project of the century”<br />

of the Werner Siemens Foundation (WSS). Based on their<br />

ideas, the finalists will develop their detailed concepts by the<br />

end of October <strong>2023</strong>. The final competitive decision will be<br />

announced in January 2024. The WSS research centre will<br />

be funded with 100 million Swiss francs (~EUR 1<strong>05</strong> million)<br />

over a funding period of ten years. The Werner Siemens<br />

Foundation initiated the competition on the occasion of its<br />

100 th anniversary. MT/AT<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

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• Current Market Prices<br />

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• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

34 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Category<br />

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bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

35


Materials<br />

Seaweed based resins<br />

come to Europe<br />

An innovative seaweed resin that replaces single-use<br />

plastic at scale and disappears into compost and soil<br />

after it’s used is now available to European plastics<br />

manufacturers and processors globally.<br />

Loliware, the first of-its-kind seaweed resin technology<br />

firm based in San Francisco (CA, USA), announced its<br />

partnership with Florida-based distributor Montachem<br />

International in September. Loliware seaweed resins<br />

are the only biomaterials available through Montachem,<br />

which has historically offered polyethylene, polypropylene,<br />

polystyrene, PVC, and PET. Loliware’s SEA Tech resins can be<br />

processed on existing manufacturing equipment and require<br />

no new infrastructure.<br />

“Our ocean-safe resin is a 1-to-1 replacement for<br />

fossil-fuel-based polymers”, Loliware Founder and CEO<br />

Sea Briganti says. “We’re fulfilling consumer demand for<br />

products needed in daily life, while at the same time creating<br />

an opportunity to end the plastic pollution that is destroying<br />

the ocean and significantly contributing to climate change”.<br />

Loliware is the first company worldwide to scale seaweed<br />

as a high-performance, cost-effective replacement for<br />

conventional plastics. A full agreement with Montachem<br />

will be signed by the end of <strong>2023</strong>, leading to a multiyear<br />

program to distribute the extrusion and injection<br />

moulding grade resins.<br />

The global plastics market is projected to reach USD 753<br />

billion by 2026, with increasing demand for plastic products,<br />

according to KPMG estimates. “Plastic alternatives are<br />

flooding the market, but many use fossil fuel-based<br />

components. Loliware’s seaweed resin is accepted under<br />

even the strictest regulations because its inputs are modified<br />

in nature”, Briganti says.<br />

Loliware produces, via a partnership with manufacturer<br />

Sinclair & Rush based in Missouri, a straw to showcase the<br />

function of the resin. The straw behaves identically to its<br />

plastic counterpart until a few hours after use when it begins<br />

to break down. Once added to a compost pile or into soil, it<br />

disappears within weeks.<br />

“The straw was our proof of concept”, Briganti says.<br />

“It shows that there is a regenerative, ocean-safe way to<br />

replace single-use plastics”.<br />

One hundred million straws are being produced each<br />

year. They are used at restaurants owned by the Jose<br />

Andres Group, as well as by eco-luxury hotel chain 1Hotels<br />

and other major brands. A new line of utensils will be<br />

available later this year. MT<br />

www.loliware.com<br />

“We aim to be fully engaged with environmentally-friendly<br />

materials that contribute to our ESG mission (Environmental,<br />

Social, Governance), and Loliware was the clear<br />

standout”,says Montachem President and CEO Jerry Murcia.<br />

Loliware is 100 % USDA BIOBASED certified and home<br />

compostable. Additionally, it is plastic-free verified and<br />

100 % marine safe (ISO 19679). “Loliware’s SEA Tech resins<br />

break down within about 50 days via aerobic degradation”,<br />

says Victoria Puinova, Loliware’s Chief Technology Officer.<br />

There are just four resin inputs – seaweed, water, limestone<br />

and mineral colour – but can be processed on conventional<br />

plastics equipment through injection moulding, extrusion,<br />

and thermoforming to create a wide range of replacements<br />

for single-use plastics.<br />

“Our resins make it easy for processors to transition<br />

from petroleum-based commodity resins”, Puinova says.<br />

Only subtle changes are needed, such as melt temperature<br />

adjustment and post-processing, she adds. A wide range of<br />

single-use plastic replacements is possible with the resins.<br />

Loliware partners with ocean-farmed seaweed producers<br />

around the world, including Atlantic Sea Farms based in<br />

Maine (USA). Seaweed captures five to 20 times more carbon<br />

than land-based forests per unit area, including permanently<br />

storing some of it at depth/the seafloor.<br />

36 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


ADVANCED<br />

RECYCLING<br />

Conference <strong>2023</strong><br />

28–29 November<br />

Cologne (Germany)<br />

Hybrid Event<br />

advanced-recycling.eu<br />

Category<br />

Diversity of<br />

Advanced Recycling<br />

of Plastic Waste<br />

All you want to know about advanced recycling technologies<br />

and renewable chemicals, building blocks, monomers, and polymers<br />

based on recycling<br />

Organiser<br />

Contact<br />

Dominik Vogt<br />

Conference Manager<br />

dominik.vogt@nova-institut.de<br />

Sponsor<br />

Sessions – Day 1<br />

• Policy, Markets & Strategy<br />

• Pyrolysis<br />

• Dissolution<br />

• Versatility of Extruders &<br />

Advanced Mechanical Recycling<br />

Sessions – Day 2<br />

• Depolymerisation<br />

• Gasification<br />

• Pre- / Post-treatment & Upgrading<br />

• LCA & Environmental Aspects<br />

• Pyrolysis & Other Thermochemical Approaches<br />

Program online<br />

advanced-recycling.eu/program<br />

The Unique Conference Focused<br />

on Cellulose Fibres – in Textiles, Hygiene<br />

and Packaging<br />

The conference will give deep insights into the promising future of cellulose fibres,<br />

which perfectly fits the current trends of circular economy, recycling and sustainable<br />

carbon cycles.<br />

1<br />

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I N S T I T U T E<br />

I O N<br />

A W A R D<br />

• Strategies, Policy Framework<br />

of Textiles and Market Trends<br />

• Cellulose Fibres at the<br />

Forefront of the Race to Replace<br />

Single-Use Plastic Products<br />

• Sustainability and<br />

Environmental Impacts<br />

• Circular Economy<br />

and Recyclability of Fibres<br />

• Alternative Feedstocks<br />

and Supply Chains<br />

• Ionic Liquids and<br />

New Technologies for Pulps,<br />

Fibres and Yarns<br />

• New Technologies<br />

and Applications beyond<br />

Textiles<br />

• Cellulose Fibre Based<br />

Hygiene and Packaging<br />

Products<br />

Submit your Applications:<br />

Call for Abstracts until<br />

15 October <strong>2023</strong><br />

Call for Innovation until<br />

15 December <strong>2023</strong><br />

Organiser<br />

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Sponsor<br />

Sponsors<br />

cellulose-fibres.eu<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

37


Polyurethane / Elastomers<br />

Polyurethane upcycling approach<br />

Groundbreaking upcycling approach for the manufacture of<br />

customized polymer aerogels<br />

The RAMPF Group (Grafenberg, Germany) has developed<br />

a pioneering upcycling approach for the manufacture<br />

of customized polymer aerogels. In contrast to<br />

conventional methods that involve costly sorting processes,<br />

Rampf’s new technology enables the processing of mixed<br />

polyurethane-based production scraps into eco-friendly<br />

and ultralight materials for use in thermal insulation,<br />

lightweight fillers, rheology additives, and oil binding<br />

agents, amongst others.<br />

The chemical recycling of plastics is increasingly becoming<br />

the focus of attention for its role in reducing the dependence<br />

on fossil fuels and mitigating the global plastic pollution<br />

crisis. It essentially involves breaking down plastic waste<br />

into its chemical components so that it can be reused as<br />

feedstock to produce new products instead of being landfilled<br />

or exploited in incineration plants.<br />

as biobased precursors, could significantly accelerate the<br />

development of holistic circular economies. We are convinced<br />

that it has the potential to pave the way for a new generation<br />

of sustainable value-added polymers and can effectively<br />

contribute to the reduction of plastic waste in our ecosystem”.<br />

The project has received funding from the German Federal<br />

Ministry for Economic Affairs and Climate Action and is part<br />

of the German cluster “Aerogels for Energy Efficiency” led by<br />

Irina Smirnova, Head of the Institute of Thermal Separation<br />

Processes and Vice President Research of the Hamburg<br />

University of Technology. “This unique combination of aerogel<br />

and recycling technology is a very promising candidate for the<br />

industrialization of aerogels. Furthermore, the work being<br />

done by Rampf demonstrates that implementing robust<br />

circular economy value chains can sometimes demand outof-the-box<br />

thinking”, she says.<br />

Whilst conventional chemical recycling methods usually<br />

involve costly sorting and separating processes for different<br />

plastics into single-origin material flows or demand a<br />

high energy input, Rampf has developed a groundbreaking<br />

chemical solution for the direct upcycling of unsorted<br />

polyurethane scraps into customized polymer aerogels.<br />

This comprises the<br />

1. Glycolysis of mixed polyurethane scraps to<br />

obtain a recycled polyol.<br />

2. Synthesis of a polyurethane-based gel.<br />

3. Supercritical drying of the wet gel to obtain an aerogel.<br />

Gerd-Sebastian Beyerlein, Director of New Business<br />

Development at Rampf and Technology Lead says: “During<br />

the course of this development, we found that the technical<br />

properties of the aerogels are highly dependent on their<br />

physical microstructure, while the purity of the feedstock<br />

plays a less significant role. The aerogels we synthesized<br />

from different batches of mixed production scraps possess<br />

a well-defined and adjustable mesoporous microstructure,<br />

as well as very low thermal conductivity in the range of<br />

comparable high-performance insulation materials.<br />

This demonstrates the robustness of this novel upcycling<br />

approach, which was developed completely in-house with<br />

regard to the materials used”.<br />

Potential for upcycling diverse types of polymers<br />

For the development of a first proof of concept, mixed<br />

polyurethane production scraps from Rampf Tooling<br />

Solutions RAKU ® Tool modelling boards were used. However,<br />

preliminary tests indicate that the valorization approach is<br />

not limited to a certain type of polymer. This could open a path<br />

of cutting-edge research that will propose solutions for the<br />

treatment of complex plastic waste.<br />

Michael Rampf, CEO of the Rampf Group, concludes:<br />

“With this new approach we have again demonstrated that<br />

we are a true chemical recycling pioneer. Whilst our company<br />

Rampf Eco Solutions has been developing and optimizing the<br />

processing of sorted production scraps for more than two<br />

decades, we have now found a revolutionary solution that<br />

could signal the end of unsorted residues being incinerated<br />

or thrown in landfills”. MT<br />

www.rampf-group.com<br />

mixed PUR<br />

scraps<br />

Info:<br />

glycol +<br />

catalyst<br />

recycled<br />

polyol<br />

solvent +<br />

isocyanate +<br />

catalyst<br />

PUR based<br />

wet gel<br />

supercritical<br />

drying<br />

PUR based<br />

aerogel<br />

Detailed information on this technological development can be<br />

found in the recently published open-access manuscript “Novel<br />

robust upcycling approach for the manufacture of value-added<br />

polymers based on mixed (poly)urethane scraps”. It can be<br />

downloaded from https://tinyurl.com/PU-recycling-23<strong>05</strong><br />

Beyerlein, who has been involved in the development of<br />

aerogel technology for over a decade, explains: “The transfer<br />

of this newly developed approach to other polymers, as well<br />

38 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Sustainable polyurethane<br />

mattress recycling<br />

Evonik (Essen, Germany) is one step closer to its goal of<br />

closing the material cycle in the polyurethane industry:<br />

The company has joined forces with the REMONDIS<br />

Group (Lünen, Germany), one of the world’s leading recycling<br />

companies, to secure the supply of end-of-life mattress<br />

foams. The cooperation will support Evonik as it develops its<br />

chemical recycling process to the next level.<br />

Evonik’s innovative hydrolysis process makes it possible<br />

to recover the main components of polyurethane foam and<br />

reuse them as high-quality building blocks in the production<br />

of new mattresses. The result of this hydrolysis process is a<br />

dark brown liquid containing pure polyol and an amine (TDA).<br />

This amine can be converted into the isocyanate TDI in a<br />

subsequent reaction. These substances, which are needed<br />

for the production of polyurethane, are recovered. In order for<br />

the molecules to be building blocks for new foam, they have<br />

to be cleanly separated from each other.<br />

This process is currently being tested in a pilot plant in<br />

Hanau (Germany), and in a next step, the recycling process<br />

will be tested in a larger demonstration plant.<br />

The Remondis Group contributes its expertise in sorting<br />

PU flexible foams from waste and feeding them into the<br />

cycle in constant quality so that they can be converted into<br />

chemical recyclates using Evonik’s hydrolysis process. “By<br />

working together with Remondis, we can evolve from the<br />

current linear value chains to functioning circular loops.<br />

True circularity only works in networks, that’s why we are<br />

actively expanding our collaborations”, said Patrick Glöckner,<br />

Head of Evonik’s Global Circular Economy Program.<br />

The cooperation with the flexible foam producer The<br />

Vita Group (Manchester, UK), started in 2021, has already<br />

successfully demonstrated that Evonik’s hydrolysis process<br />

recovers raw materials of significantly higher quality, and<br />

thus improved usability compared with previous recycling<br />

technologies. Increased use of recycled materials lowers<br />

the dependence on fossil raw materials and reduces the<br />

ecological footprint of the PU industry. According to findings<br />

so far, Evonik’s process significantly reduces the CO 2<br />

footprint compared with mattress production using fossil raw<br />

materials. The demonstration plant intends to prove that this<br />

also applies on a larger scale.<br />

Polyurethane / Elastomers<br />

According to estimations, more than 250,000 tonnes of PU<br />

foam from old mattresses are incinerated or landfilled in<br />

Europe every year. Evonik and Remondis want to help reduce<br />

this with the goal of ensuring fewer fossil raw materials are<br />

used in the PU value chain by returning valuable materials<br />

to the raw material cycle. “Circularity in the field of<br />

flexible polyurethane foams is very important both for the<br />

environment, and for the future viability of our business. It gives<br />

us the opportunity to act in the interests of the environment,<br />

the industry, and consumers”, said Thomas Wessel,<br />

the member of Evonik’s Executive Board<br />

responsible for sustainability.<br />

“For us, closing material life cycles is not only a business<br />

objective but also an expression of our responsibility<br />

towards society as a whole. Conserving raw materials<br />

around the world and processing them again and again is<br />

a fundamental prerequisite for sustainable environmental<br />

and climate protection”, said Jürgen Ephan, Managing<br />

Director of Remondis Recycling. “Remondis reintegrates<br />

enormous quantities of materials back into the production<br />

cycle. Every year, we collect more than 30 million tonnes<br />

of recyclable materials, process them and make them<br />

available to the industry as raw materials, with the numbers<br />

continuing to increase. What drives us is the constant<br />

development of new processes to close or optimize material<br />

cycles. Therefore, we are very pleased to be working<br />

with Evonik to tackle the challenge of finding<br />

an efficient solution for the raw material<br />

recovery of foam mattresses”.<br />

The initial focus of the project is on<br />

the region of North Rhine-Westphalia,<br />

Germany. However, the goal is to<br />

develop a scalable technology<br />

and a business model that can be<br />

expanded internationally. MT<br />

www.evonik.com<br />

www.remondis.com<br />

Strengthening the cycle<br />

How hydrolysis can be used to<br />

recycle PU foam<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

39


Polyurethane / Elastomers<br />

New sustainable materials<br />

Adhesives and inks for packaging, polyurethanes for shoe soles and<br />

plasticisers for PVC<br />

C.O.I.M., headquartered in Buccinasco, Italy, is a<br />

multinational company that has manufactured<br />

chemical products since 1962 and that operates all<br />

over the world through nineteen manufacturing and trading<br />

companies. Recently, at the PLAST trade fair (Milan, Italy,<br />

4 – 8 September) the company presented a wide range of<br />

innovations inspired by maximum efficiency and sustainability.<br />

“COIM’s approach to sustainability is both integrated –<br />

environment, economy, and society – and, on the product<br />

development front, open. In fact, it takes account of the<br />

various opportunities with which sustainable policies may<br />

develop: raw materials from biological sources, recyclable<br />

raw materials, biodegradable and compostable systems, and<br />

Low VOC systems, control and abatement of CO 2<br />

emissions<br />

along the entire supply line and recovery downstream of<br />

finished products for polyurethane recycling. The innovations<br />

that we propose are of the drop in type, sustainable also<br />

from the operational point of view: they can be used by our<br />

customers without modifying their production processes<br />

or purchasing new machines. Our customers can also<br />

obtain integrated and personalized solutions from COIM,<br />

thus reaching maximum efficiency in supply, use and<br />

performance. Plast <strong>2023</strong> will be an important opportunity<br />

to present the results of our commitment to innovation<br />

and sustainability to the entire sector”, explained Giuseppe<br />

Librandi, President and CEO of COIM.<br />

Sustainable solutions for flexible packaging<br />

With its Novacote and Coiminks ranges, COIM offers flexible<br />

packaging manufacturers a 3-in-1 solution: the proposal of<br />

adhesives, coatings, and inks by a single supplier represents<br />

a peculiar feature that makes COIM one of the most complete<br />

players on the world scene in this sector.<br />

Environmental sustainability, a top priority for<br />

COIM, is realized in this sector according to which are<br />

four main directives:<br />

Compostable solution offer: COIM presents the new<br />

solvent-based adhesive NOVACOTE ® NE 810 S + CE 510,<br />

tested in accordance with the EN 13432 standard and OK<br />

Compost Industrial certified, in accordance with the TÜV<br />

Austria, Seedling, and BPI standards.<br />

The CoLam FX series of inks of COIMINKS has recently<br />

obtained and renewed its TÜV Austria OK Compost Industrial<br />

certificate that enables converters who use substrates and<br />

components certified as compostable, with ink within the<br />

maximum limit of application indicated on its certificate, to<br />

produce compostable packaging materials.<br />

Transition from fossil to renewable sources in<br />

the shoe material sector<br />

Urexter RS and Laripur RS are used to produce soles for<br />

fashion shoes also in the sectors of luxury, casual, sports<br />

and safety shoes, they are the fruit of accurate development<br />

towards maximum sustainability due to their formulation<br />

with a percentage of raw materials from renewable<br />

sources of over 70 %.<br />

For the shoe sector, the substitution of materials from fossil<br />

sources with materials from renewable sources represents a<br />

real breakthrough towards environmentally friendly solutions<br />

on a large scale: the biobased materials developed by COIM<br />

using renewable vegetable sources ensure a better CO 2<br />

footprint, without altering the durability of the products and<br />

allowing the manufacturers to avoid making changes to their<br />

machinery and consolidated production techniques.<br />

New series of polymeric plasticizers with<br />

a content of raw materials from renewable<br />

sources of up to 50 %<br />

COIM has been operating on the market of polymeric<br />

plasticizers for PVC-based compounds for decades.<br />

The evolution of the range towards sustainable solutions<br />

began several years ago with the Plaxter P-L products,<br />

which offer innovative solutions using in part raw materials<br />

from renewable sources. The products in the Plaxter P-L<br />

series are present on the market with large volumes in all<br />

the applications that involve plasticized PVC products, such<br />

as transparent stretch film for food, faux leathers for the<br />

fashion and waterproof fabric sectors, the coating of special<br />

electrical cables, technical liquid or gas conveying pipes,<br />

special seals for food packaging and specific applications.<br />

With the new Plaxter E-LB series of products, COIM meets<br />

the growing market need for more sustainable plasticizers<br />

and offers products with a content of raw materials from<br />

renewable sources of up to 50 %, responding at the same<br />

time to the higher technical market needs. The Plaxter E-LB<br />

products can be industrialized through drop-in substitutions,<br />

in which the fossil source materials are replaced without<br />

making any changes to the process.<br />

The solutions in the new Plaxter E-LB series have been<br />

compared to the standard products also from the point of view<br />

of their potential CO 2<br />

emissions, by conducting a comparative<br />

life cycle analysis (LCA) so as to be able to provide the user<br />

also with a documental estimate of emission reductions. MT<br />

www.coimgroup.com<br />

40 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Industrially compostable<br />

stretch wrap technology<br />

Now protected by US patent<br />

Applications<br />

Cortec Corporation (St. Paul, MN, USA) has been<br />

awarded a US patent for its commercially compostable<br />

industrial strength stretch film technology, also known<br />

as Eco Wrap ® film. This patent is a significant milestone<br />

in Cortec’s ongoing quest to develop environmentally<br />

responsible products and distinguishes Cortec ® as a leader<br />

in green packaging technology.<br />

Eco Wrap is a specialty wrapping film that meets the EN<br />

13432/ASTM D6400 standards for commercial composting<br />

and was certified industrially compostable by TÜV Austria<br />

(#TA8012106218) in 2021. It is extremely elastic and suited<br />

for general machine stretch wrapping applications. It can be<br />

used to replace conventional plastic stretch wrap with the goal<br />

of improving the user’s environmental image and reducing<br />

conventional plastic waste when the material is properly<br />

disposedof in a commercial composting environment,<br />

operated in accordance with best management practices.<br />

Eco Wrap can be used on most existing automated machines<br />

and is easily applied by adjusting (typically increasing) the<br />

tension on standard stretch wrapping equipment. It has<br />

also been tested on an orbital wrapping machine without<br />

breaking, showing greater strength than another film that<br />

did not successfully pass the trial. In another case, a coffee<br />

distributor who tried Eco Wrap for stretch wrapping pallets<br />

of coffee bags was pleased with the results.<br />

Due to the extensive use of stretch film in today’s world,<br />

Eco Wrap has many exciting possible uses across multiple<br />

industries wherever palletization is needed.<br />

• Manufacturing: Countless raw materials and finished<br />

goods need to be placed on pallets and wrapped before<br />

storage or shipping. Items may include raw material<br />

drums, auto parts, computers, tools, wires, cables,<br />

carpets, and much more.<br />

• Online retail: Online shopping represents a growing<br />

market share of retail and is a natural consumer of<br />

stretch wrap for palletizing boxed goods. Companies can<br />

use Eco Wrap in an effort to reverse their negative<br />

image of contributing heavily to plastic packaging waste.<br />

By using Eco Wrap within their own supply chain, they<br />

will also have better oversight of making sure the film is<br />

disposed of in the proper waste stream after use.<br />

• Agriculture: Firewood, lumber, hay bales, and<br />

other agriculture materials can be bundled and<br />

wrapped with Eco Wrap.<br />

• Baggage and furniture handling: Eco Wrap can be used<br />

to corral luggage at the airport or securely wrap furniture<br />

before loading it onto the moving van. These are two<br />

more applications where users have better oversight of<br />

disposal due to internal use.<br />

• Food industry: The food industry presents a major<br />

opportunity for palletizing cans, crates, bottles, cartons,<br />

and bags. Eco Wrap can be used for stretch-wrapping in<br />

these countless bulk packaging applications where there<br />

is no direct contact with food.<br />

While today’s society is placing increasing pressure on<br />

industries to conform to new environmental goals, Cortec<br />

has long been on its own mission to use biodegradable or<br />

biobased materials where possible. The new Eco Wrap patent<br />

is an excellent example of how that motivation has turned<br />

Cortec into a leader in “green” packaging development. MT<br />

www.cortecvci.com<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

41


Application News<br />

PHA/PLA-blend for<br />

premium skincare<br />

products<br />

RIMAN to blend CJ Biomaterials’ patented PHA<br />

technology with PLA in packaging for premium skincare<br />

INCELLDERM products<br />

CJ Biomaterials (Woburn, MA, USA), a global leader in<br />

the manufacture of PHAs, announced on August 23, <strong>2023</strong>,<br />

that it is working with RIMAN Korea to blend its patented<br />

PHA technology with polylactic acid (PLA) to create<br />

packaging for Riman’s premium line of INCELLDERM<br />

products. The new packaging is more environmentally<br />

friendly and helps reduce Riman’s usage of fossil-fuel<br />

based packaging for its skin care products in line with<br />

Riman’s sustainable packaging initiatives.<br />

PHAs work well as modifiers to other polymers or<br />

biopolymers and can be used to increase biobased<br />

content, accelerate biodegradation and improve the<br />

functional properties of resins and finished products.<br />

The company produces its PHA under the brand name<br />

PHACT , which stands for PHA + Action, demonstrating<br />

CJ Biomaterials’ commitment to help preserve the planet.<br />

The combined PLA-PHA material will be used to<br />

package Incellderm Active Cream EX, Dermatology<br />

First Package Booster EX and Vieton Oil Mist, all offered<br />

through Riman Incellderm brand. These three products<br />

alone account for more than 5.4 million unit-sales each<br />

year, and the company plans to gradually expand use of<br />

CJ Biomaterials’ PHA across more of its product line.<br />

Riman and CJ Biomaterials also intend to broaden their<br />

collaboration to develop 100 % PHA solutions for injection<br />

moulding applications.<br />

This is another in a series of collaborations CJ<br />

Biomaterials has entered to develop products based on<br />

its PHA technology. Over the past year, the company has<br />

also announced agreements with NatureWorks, Dongil<br />

Platech, Banila Co., CJ Olive Young, and others. AT/MT<br />

www.cjbiomaterials.com<br />

Compostable singleuse<br />

packaging for<br />

extra virgin olive oil<br />

ADBioplastics (Valencia, Spain) and the oils and dressings<br />

producer and marketer, Capricho Andaluz (Córdoba, Spain),<br />

have developed a compostable single-use packaging for extra<br />

virgin olive oil together.<br />

The material used for this single-use packaging is “PLA-<br />

Premium”, which has been developed by ADBioplastics.<br />

It is an industrial compostable bioplastic and is able to be<br />

disposed of in the organic bin (where permitted). These<br />

single-use products will be marketed in the coming months,<br />

initially under the Capricho Andaluz and Borges brands.<br />

According to ADBioplastics, PLA-Premium improves<br />

elongation at break by up to 70 % compared to conventional<br />

virgin PLA, making it less brittle and more elastic. The<br />

material has further improvements such as better toughness<br />

and impact resistance, cycle times and density that are<br />

comparable to PET, improved barrier properties (water<br />

vapour and oxygen), and transparency levels similar to PET.<br />

This important innovation adds to the already consolidated<br />

sustainability strategy of the Borges group, which works<br />

daily to reduce its environmental impact, through the<br />

TecnoBi product line, which consists of grades specifically<br />

designed for processing by cast extrusion and blow moulding<br />

technologies. These grades are OK Compost certified by TÜV<br />

Austria, which guarantees that, under industrial conditions,<br />

the material reaches the disintegration stage within a<br />

maximum of 3 months.<br />

In addition, this material is suitable for food contact in<br />

accordance with the applicable European legislation (FCM),<br />

allowing its use in packaging applications for food, beverages,<br />

cosmetics, pharmaceuticals, and other products. AT<br />

www.adbioplastics.com<br />

42 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Biobased and biodegradable eyewear<br />

Wingram (Hong Kong) is a leading sustainable materials<br />

producer, most commonly known for its material of<br />

BioAcetate S70. BioAcetate S70 has an excellent ecoprofile<br />

as it’s a material derived from<br />

plants and is biodegradable as well.<br />

Furthermore, it is made with no harsh<br />

chemicals and is tested to be nonskin-irritant<br />

and non-skin sensitizing.<br />

BioAcetate S70 has its primary<br />

applications within the eyewear<br />

industry (alternative applications<br />

include: household appliances,<br />

e-cigarette parts, and smartphone<br />

accessories) and is typically produced<br />

into 3 types of frames:<br />

1. Traditional Injection Frames<br />

BioAcetate S70 injection frames are made from BioAcetate<br />

S70 injection pellets/granules. These frames are made<br />

traditionally, like with CP or Nylon frames, where a frame’s<br />

colour/design are colour sprayed and varnishing is required.<br />

These frames have much flexibility in colours/designs and<br />

offer great scalability due to the frames being injected.<br />

2. Injection Acetate Frames – BioAcetate S70 injection<br />

acetate frames are made from BioAcetate S70 pellets/<br />

granules. Injection acetate frames are unique to BioAcetate<br />

S70 injection frames, which feel and<br />

look like handmade frames. Since<br />

no varnishing or colour spraying for<br />

colours/designs are required, these<br />

frames offer the superior quality and<br />

touch of handmade frames but at the<br />

scalability of injection frames.<br />

3. Handmade Acetate Frames –<br />

BioAcetate S70 Handmade Frames are<br />

made from BioAcetate S70 sheets/slabs.<br />

Handmade frames have a superior<br />

quality and touch when compared<br />

to injection frames. BioAcetate S70<br />

handmade frames have extra durability,<br />

longevity, and flexibility in designs due to its Hardness<br />

Enhanced CA (HECA) characteristics.<br />

Since the launch of BioAcetate S70, many companies and<br />

brands have been using the sustainable material BioAcetate<br />

S70 and have found that the material is a perfect balance of<br />

high-performance and sustainable friendliness. MT<br />

Application News<br />

www.bioacetate.com<br />

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bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

43


Opinion<br />

Solving the<br />

plastics challenge together<br />

We have to solve what’s wrong with plastics: their<br />

dependence on fossil resources and too little of<br />

plastic waste being recycled.<br />

What may sound easy is a mammoth task. The demand<br />

for plastic is set to grow, alternative feedstocks need to be<br />

extended many times over and plastic waste management<br />

systems are not yet existing in many regions of the world.<br />

And yet, it’s an inevitable task if we want to continue to reap the<br />

benefits of plastics in a climate-neutral and environmentally<br />

conscious future society.<br />

A new White Paper by Neste (Espoo, Finland) takes a look<br />

at what’s wrong with plastics and what is required to change<br />

it. It considers challenges and opportunities – and it picks up<br />

on the need to cooperate if we are to overcome the barriers<br />

to make the change happen.<br />

Neste invites companies along the plastics value<br />

chain to collaborate and join them on this journey.<br />

The complete White Paper can be downloaded (link below).<br />

A circular and renewable plastics economy is possible<br />

Plastics are versatile materials that make things better<br />

in many ways. They are part of the complex value chains<br />

that underpin our lives – and behind most of the life-saving<br />

advances of modern medicine. At the same time, poorly<br />

managed plastic waste is choking the world’s oceans,<br />

piling up in landfill, polluting the planet, and putting people<br />

and wildlife at risk.<br />

Plastic also contributes to climate change. Most of it is made<br />

from fossil resources and around 20 % is incinerated at end<br />

of life, which releases the carbon back into the atmosphere.<br />

From fossil-based to renewable and recycled<br />

Technologies exist that can replace the fossil resources<br />

in plastic with renewable and recycled materials.<br />

Through new recycling technologies, more material could<br />

be kept circulating in the loop, reducing the need for virgin<br />

plastic production, fossil resources, landfill and incineration,<br />

as well as turning waste plastic into a valuable resource – all<br />

while also drastically reducing the carbon impact.<br />

Along with a more environmentally-conscious approach to<br />

how to use and reuse plastic, these changes, if adopted, could<br />

be transformative on a global scale. But progress towards<br />

this transition is still too slow and tentative.<br />

The need for concerted action<br />

This white paper from Neste looks at the problems with<br />

plastic, the potential solutions, the business opportunities<br />

in a circular and renewable future, and how to overcome the<br />

barriers to change. As one company among many, Neste<br />

understands that real change is hard to achieve alone. That is<br />

why they are inviting companies, consumers, and regulators<br />

to join them on this endeavour – to move the dial on the<br />

chemicals and polymers industry from being seen as part of<br />

the problem to integral to the solution.<br />

The white paper includes 4 sections and a conclusion.<br />

1) The challenge<br />

The goalposts are moving: we need to act now<br />

Despite ongoing efforts to recycle plastic and reduce its<br />

fossil content, it is still not happening at scale. Less than<br />

10 % of all plastic waste is currently recycled, with the<br />

majority going to incineration or landfill. The vast majority of<br />

production is still virgin plastic, made from fossil resources<br />

that contribute to carbon emissions.<br />

That volume can be expected to multiply as global demand<br />

for plastic is projected to increase dramatically in future<br />

decades (they are currently estimated to triple by 2<strong>05</strong>0<br />

compared to current demand).<br />

Here regulators, consumers and major brands<br />

are called to action:<br />

Increasing evidence of the impact of plastic waste on<br />

oceans, ecosystems, food chains, and climate change<br />

are ringing alarm bells. Environmental campaigners,<br />

governments and policymakers are looking for ways to<br />

limit the impact, while consumers and brands are also<br />

taking more of a stand.<br />

2) The solutions<br />

The solutions exist, but they need to be adopted at scale<br />

Reducing our use of plastics, particularly in packaging<br />

and single-use items, is essential – as is moving away from<br />

our throwaway culture to one that is focused on reuse and<br />

recycling. That means increasing the volumes of plastic<br />

waste recycled by current methods and curbing the growth<br />

of single-use plastic applications.<br />

But those changes will not be enough to solve the problems<br />

caused by plastics on their own. There are still significant<br />

barriers – for example, many of the plastic products made<br />

today are not recyclable in practice. Existing recycling<br />

technologies also result in a loss in material quality, which<br />

restricts the number of times materials can be recycled.<br />

To achieve change at the scale that is needed, the industry<br />

needs to embrace a wider range of solutions and technologies.<br />

What are the solutions?<br />

Of course, everyone will agree to the buzzwords: reduce,<br />

reuse, refurbish, repair, and of course recycle using existing<br />

methods. But there are more solutions:<br />

Rethink recycling to close the materials loop.<br />

Chemical recycling: break down existing plastics into<br />

hydrocarbons at a molecular level, so they can be reused to<br />

make virgin quality plastic time and time again.<br />

Make plastics from renewable sources, such as waste and<br />

residue oils and fats, biomass or plant-based feedstocks<br />

such as corn and sugar cane.<br />

44 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


A new White Paper by Neste asks to join forces<br />

to make plastic more sustainable<br />

summarized by Michael Thielen<br />

Opinion<br />

3) The opportunities<br />

Seizing the opportunity through early adoption<br />

To solve the plastic challenge on a global scale, everyone<br />

needs to play their part. Governments and regulators need<br />

to create a level playing field, incentivise the shift away from<br />

virgin fossil resources. Brand owners need to be open to<br />

change and new technologies. Consumers need to vote with<br />

their wallets and embrace sustainable solutions.<br />

The chemicals and polymers industry is in a unique position.<br />

It can lead the change that is needed by showing what is<br />

possible. The sector has the solutions and technologies in its<br />

hands today that can accelerate innovation and develop new<br />

greener business models.<br />

By acting now, the industry can:<br />

• seize an enormous business opportunity by developing<br />

the plastics that everyone will want in the future<br />

• shift supplies of raw materials and feedstocks away<br />

from fossil sources, which are declining and may be<br />

restricted over time<br />

• increase traceability of raw materials throughout the<br />

product life cycle and across the value chain – helping<br />

to reinforce sustainability claims and get ahead of<br />

regulations coming down the road<br />

• reduce the carbon in plastics and their<br />

overall climate impact<br />

Early adopter companies that invest in innovative<br />

technologies today will stand to gain the greatest advantage<br />

as they become the industry norm.<br />

Research suggests consumers are more likely to support<br />

businesses that show environmental responsibility.<br />

Change will also bring opportunities and benefits<br />

throughout the value chain, from creating a stable market<br />

for renewable feedstock crops to supporting reuse and repair<br />

business models and sorting and recycling infrastructure.<br />

The cost of not acting<br />

As time goes on, chemicals and polymers companies will<br />

come under increasing pressure to defossilise and take<br />

responsibility for how they source raw materials through the<br />

supply chain and for what happens to products at their end<br />

of life. These longer-term and hidden costs are not captured<br />

in short-term price calculations.<br />

4) Collaboration<br />

What is needed: more collaboration across the value chain<br />

Making change at the scale that is needed requires more<br />

exchange, trust, and transparency. Competition remains<br />

important as a driver of innovation and transformation. But it<br />

can also hold back development at an industry and global<br />

level. Collaboration and co-creation are essential.<br />

For a very long time, the mantra of the polymers and<br />

chemicals industry has been every person for himself – and<br />

it worked quite well. However, going forward and to meet<br />

corporate and societal targets, this won’t be enough anymore.<br />

It will take a joint effort to accelerate the transformation.<br />

Through collaboration, risks can be shared and reduced.<br />

Best practices can be shared, and everyone can learn from<br />

each other. This will not only help us move towards a circular<br />

plastics economy and reduce climate impacts – it can bring<br />

real and lasting benefits for all the businesses involved,<br />

creating win-win situations.<br />

Thinking more circular, less linear<br />

The industry needs to go beyond linear supplier-companycustomer<br />

relationships and consider a wider range of<br />

stakeholders and longer-term life cycle impacts. To gain<br />

the deepest benefits from collaboration, businesses must<br />

engage more with companies and industries with which they<br />

do not have direct business relationships, but which are part<br />

of the same circular economy.<br />

That means being open to new things: for example, taking<br />

a step toward waste management so that waste materials<br />

can be recovered, moving closer to genuinely closed material<br />

cycles. It is important to understand all parties who are part of<br />

the value chain, from polymerisation to cracking, from waste<br />

managers to brand owners. What are their goals and needs?<br />

And how can barriers to collaboration be broken down?<br />

Conclusions<br />

In the conclusions, Neste’s White Paper invites: let’s work<br />

together to make it happen.<br />

For all their amazing properties and uses, plastics have<br />

become a bad news story. And on current trajectories, with<br />

production, waste, and carbon impacts continuing to rise,<br />

the public perception of plastics is only going to get worse.<br />

The chemicals and polymers industry has solutions at hand<br />

that could make plastics more sustainable and change some<br />

of those negative stories into positive ones.<br />

It can be part of the transition to a circular economy by<br />

producing plastics from renewable and recycled materials<br />

and making it possible to recycle them more often, creating<br />

a closed materials loop with less plastic waste.<br />

Neste is committed to making this transition. They are<br />

open to partnering and working with anyone who shares their<br />

aim to create a sustainable future for plastic. “We would love<br />

to welcome you on the journey”, the paper ends.<br />

www.neste.com<br />

Download the full<br />

White Paper<br />

tinyurl.com/neste-white-paper-23<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

45


Suppliers Guide<br />

1. Raw materials<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

bioplastics.starch@agrana.com<br />

www.agrana.com<br />

Mixcycling Srl<br />

Via dell‘Innovazione, 2<br />

36042 Breganze (VI), Italy<br />

Tel.: +39 04451911890<br />

info@mixcycling.it<br />

www.mixcycling.it<br />

Biofibre GmbH<br />

Member of Steinl Group<br />

Sonnenring 35<br />

D-84032 Altdorf<br />

Tel.: +49 (0)871 308 – 0<br />

Fax: +49 (0)871 308 – 83<br />

info@biofibre.de<br />

www.biofibre.de<br />

39 mm<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be listed among top suppliers in the<br />

field of bioplastics.<br />

For Example:<br />

Polymedia Publisher GmbH<br />

Hackesstr. 99<br />

41066 Mönchengladbach<br />

Germany<br />

Tel.: +49 2161 664864<br />

Fax: +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 € = 234,00 €<br />

per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide<br />

is bookable for one year (6 issues)<br />

and extends automatically if it’s not<br />

cancelled three months before expiry.<br />

Arkema<br />

Advanced Bio-Circular polymers<br />

Rilsan ® PA11 & Pebax ® Rnew ® TPE<br />

WW HQ: Colombes, France<br />

bio-circular.com<br />

hpp.arkema.com<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel.: +49 621 60 – 6692<br />

joerg.auffermann@basf.com<br />

www.ecovio.com<br />

Gianeco S.r.l.<br />

Via Magenta 57 10128 Torino - Italy<br />

Tel.: +390119370420<br />

info@gianeco.com<br />

www.gianeco.com<br />

Tel.: +86 351 – 689356<br />

Fax: +86 351 – 689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

Bioplastics – PLA, PBAT<br />

www.lgchem.com<br />

youtu.be/p8CIXaOuv1A<br />

bioplastics@lgchem.com<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel.: +66(0) 2 140 – 563<br />

MCPP Germany GmbH<br />

+49 (0) 211 520 54 662<br />

Julian.Schmeling@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0)2 51 65 71 43<br />

fabien.resweber@mcpp-europe.com<br />

Xiamen Changsu Industrial Co., Ltd<br />

Tel.: +86 – 92-6899303<br />

Mobile: +86 185 5920 1506<br />

Email: andy@chang-su.com.cn<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 2716195<br />

Mob.: +86 186 99400676<br />

maxirong@lanshantunhe.com<br />

www.lanshantunhe.com<br />

PBAT, PBS, PBSA, PBST supplier<br />

Zhejiang Huafon Environmental<br />

Protection Material Co.,Ltd.<br />

No.1688 Kaifaqu Road,Ruian<br />

Economic Development<br />

Zone,Zhejiang,China.<br />

Tel.: +86 577 6689 01<strong>05</strong><br />

Mobile: +86 139 5881 3517<br />

ding.yeguan@huafeng.com<br />

www.huafeng.com<br />

Professional manufacturer for<br />

PBAT /CO 2<br />

-based biodegradable materials<br />

1.1 Biobased monomers<br />

1.2 Compounds<br />

Earth Renewable Technologies BR<br />

Estr. Velha do Barigui 1<strong>05</strong>11, Brazil<br />

kfabri@ertbio.com<br />

www.ertbio.com<br />

eli<br />

bio<br />

Elixance<br />

Tel.: +33 (0) 2 23 10 16 17<br />

Tel PA du +33 Gohélis, (0)2 56250 23 Elven, 10 16 France 17 - elixb<br />

elixbio@elixbio.com/ www.elixbio.com<br />

www.elixance.com - www.elixb<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47877 Willich<br />

Tel.: +49 2154 9251-0<br />

Tel.: +49 2154 9251 – 51<br />

sales@fkur.com<br />

www.fkur.com<br />

P O L i M E R<br />

GEMA POLIMER A.S.<br />

Ege Serbest Bolgesi, Koru Sk.,<br />

No.12, Gaziemir, Izmir 35410,<br />

Turkey<br />

+90 (232) 251 5041<br />

info@gemapolimer.com<br />

http://www.gemabio.com<br />

Global Biopolymers Co., Ltd.<br />

Bioplastics compounds<br />

(PLA+starch, PLA+rubber)<br />

194 Lardproa 80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel.: +66 81 9150446<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 041 5190621<br />

Fax: +39 041 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

BIO-FED<br />

Member of the Feddersen Group<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94 – 00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel.: +49 36459 45 0<br />

www.grafe.com<br />

46 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


Green Dot Bioplastics Inc.<br />

527 Commercial St Suite 310<br />

Emporia, KS 66801<br />

Tel.: +1 620 – 73-8919<br />

info@greendotbioplastics.com<br />

www.greendotbioplastics.com<br />

a brand of<br />

Helian Polymers BV<br />

Bremweg 7<br />

5951 DK Belfeld<br />

The Netherlands<br />

Tel.: +31 77 398 09 09<br />

sales@helianpolymers.com<br />

https://pharadox.com<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. w<br />

Tel.: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.kingfa.com<br />

Natureplast – Biopolynov<br />

6 Rue Ada Lovelace<br />

14120 Mondeville – France<br />

Tel.: +33 (0)2 31 83 50 87<br />

www.natureplast.eu<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel.: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

Plásticos Compuestos S.A.<br />

C/ Basters 15<br />

08184 Palau Solità i Plegamans<br />

Barcelona, Spain<br />

Tel.: +34 93 863 96 70<br />

info@kompuestos.com<br />

www.kompuestos.com<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel.: +41 44 787 57 77<br />

Fax: +41 44 787 57 78<br />

www.sukano.com<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel.: +49 (0)7062/97687-0<br />

www.tecnaro.de<br />

Trinseo<br />

1000 Chesterbrook Blvd. Suite 300<br />

Berwyn, PA 19312<br />

+1 855 8746736<br />

www.trinseo.com<br />

1.3 PLA<br />

Shenzhen Esun Industrial Co., Ltd.<br />

www.brightcn.net<br />

bright@brightcn.net<br />

Tel.: +86 – 55-26031978<br />

TotalEnergies Corbion bv<br />

Stadhuisplein 70<br />

4203 NS Gorinchem<br />

The Netherlands<br />

Tel.: +31 183 695 695<br />

www.totalenergies-corbion.com<br />

PLA@totalenergies-corbion.com<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel.: +86 – 76-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

1.4 Starch-based bioplastics<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Plásticos Compuestos S.A.<br />

C/ Basters 15<br />

08184 Palau Solità i Plegamans<br />

Barcelona, Spain<br />

Tel.: +34 93 863 96 70<br />

info@kompuestos.com<br />

www.kompuestos.com<br />

Sunar NP Biopolymers<br />

Turhan Cemat Beriker Bulvarı<br />

Yolgecen Mah. No: 565 01355<br />

Seyhan /Adana,TÜRKIYE<br />

info@sunarnp.com<br />

burc.oker@sunarnp.com.tr<br />

www.sunarnp.com<br />

Tel.: +90 (322) 441 01 65<br />

UNITED BIOPOLYMERS S.A.<br />

Parque Industrial e Empresarial<br />

da Figueira da Foz<br />

Praça das Oliveiras, Lote 126<br />

3090 – 51 Figueira da Foz – Portugal<br />

Tel.: +351 233 403 420<br />

info@unitedbiopolymers.com<br />

www.unitedbiopolymers.com<br />

1.5 PHA<br />

Bluepha PHA<br />

A Phabulous Blend With Nature<br />

contact@bluepha.com<br />

www.bluepha.bio<br />

CJ Biomaterials<br />

www.cjbio.net<br />

cjphact.us@cj.net<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel.: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel.: +86 – 57 48 68 62 50 2<br />

Fax: +86 – 57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

1.6 Masterbatches<br />

Albrecht Dinkelaker<br />

Polymer- and Product Development<br />

Talstrasse 83<br />

60437 Frankfurt am Main, Germany<br />

Tel.: +49 (0)69 76 89 39 10<br />

info@polyfea2.de<br />

www.caprowax-p.eu<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel.: +49 36459 45 0<br />

www.grafe.com<br />

Treffert GmbH & Co. KG<br />

In der Weide 17<br />

55411 Bingen am Rhein; Germany<br />

+49 6721 403 0<br />

www.treffert.eu<br />

Treffert S.A.S.<br />

Rue de la Jontière<br />

57255 Sainte-Marie-aux-Chênes,<br />

France<br />

+33 3 87 31 84 84<br />

www.treffert.fr<br />

1.7 Composites<br />

Sustainable Composites<br />

Tel.: +1 604 – 372-4200<br />

www.ctkbio.com<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel.: +49 36459 45 0<br />

www.grafe.com<br />

3. Semi-finished products<br />

3.1 Sheets<br />

Customised Sheet Xtrusion<br />

James Wattstraat 5<br />

7442 DC Nijverdal<br />

The Netherlands<br />

+31 (548) 626 111<br />

info@csx-nijverdal.nl<br />

www.csx-nijverdal.nl<br />

4. Bioplastics products<br />

Bio4Pack GmbH<br />

Marie-Curie-Straße 5<br />

48529 Nordhorn, Germany<br />

Tel.: +49 (0)5921 818 37 00<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

Suppliers Guide<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

47


Suppliers Guide<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, Vice president<br />

Yunlin, Taiwan (R.O.C)<br />

Mobile: (886) 0 – 82 829988<br />

Email: esmy@minima-tech.com<br />

Website: www.minima.com<br />

w OEM/ODM (B2B)<br />

w Direct Supply Branding (B2C)<br />

w Total Solution/Turnkey Project<br />

7. Plant engineering<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4<strong>05</strong>2 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190 – 23<br />

erema@erema.at<br />

www.erema.at<br />

9. Services<br />

10.2 Universities<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 – 22 69<br />

Fax: +49 5 11 / 92 96 – 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

Naturabiomat<br />

AT: office@naturabiomat.at<br />

DE: office@naturabiomat.de<br />

NO: post@naturabiomat.no<br />

FI: info@naturabiomat.fi<br />

www.naturabiomat.com<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Pfaffenwaldring 32<br />

7<strong>05</strong>69 Stuttgart<br />

Tel.: +49 711/685 – 62801<br />

info@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel.: +1 763.404.8700<br />

Fax: +1 763.225.6645<br />

info@naturtec.com<br />

www.naturtec.com<br />

Innovation Consulting Harald Kaeb<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30 – 8096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel.: +1 517 719 7163<br />

narayan@msu.edu<br />

10.3 Other institutions<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax: +39.0321.699.601<br />

Tel.: +39.0321.699.611<br />

www.novamont.com<br />

6. Equipment<br />

6.1 Machinery & moulds<br />

nova-Institut GmbH<br />

Tel.: +49(0)2233 – 60 14 00<br />

contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel.: +49 2161 664864<br />

info@polymediaconsult.com<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6 – 4216733<br />

www.greenseredipity.nl<br />

10. Institutions<br />

10.3 Other institutions<br />

10.1 Associations<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

info@busscorp.com<br />

www.busscorp.com<br />

6.2 Degradability Analyzer<br />

BPI – The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel.: +1 – 88-274 – 646<br />

info@bpiworld.org<br />

GO!PHA<br />

Rick Passenier<br />

Oudebrugsteeg 9<br />

1012JN Amsterdam<br />

The Netherlands<br />

info@gopha.org<br />

www.gopha.org<br />

MODA: Biodegradability Analyzer<br />

Based on ISO 14855-2, ISO 13975<br />

SAIDA FDS INC.<br />

143 – 10 Isshiki, Yaizu,<br />

Shizuoka, Japan<br />

Tel.: +81 – 54-624 – 6260<br />

info_fds@saidagroup.jp<br />

www.saidagroup.jp/fds_en<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel.: +49 30 284 82 350<br />

Fax: +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

48 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


You can meet us<br />

3 rd PHA platform World Congress – <strong>2023</strong> USA<br />

10.10. – 11.10.<strong>2023</strong>, Atlanta, USA<br />

by bioplastics MAGAZINE<br />

www.pha-world-congress.com<br />

The Greener Manufacturing Show North America<br />

11.10. – 12.10.<strong>2023</strong>, Atlanta, USA<br />

www.greener-manufacturing.com/usa<br />

Fakuma<br />

17.10. – 21.10.<strong>2023</strong>, Friedrichshafen, Germany<br />

www.fakuma-messe.de<br />

15 th Bioplastics Market<br />

18.10. – 19.10.<strong>2023</strong>, Bangkok, Thailand<br />

www.cmtevents.com/aboutevent.aspx?ev=231021<br />

The Greener Manufacturing Show Europe<br />

08.11. – 09.11.<strong>2023</strong>, Cologne, Germany<br />

www.greener-manufacturing.com<br />

European Congress on Biopolymers and Bioplastics<br />

16.11. – 17.11.<strong>2023</strong>, Rome, Italy<br />

https://scisynopsisconferences.com/biopolymers<br />

Upcoming Events<br />

Diversity of Advanced Recycling of Plastic Waste<br />

28.11. – 29.11.<strong>2023</strong>, Cologne, Germany<br />

https://advanced-recycling.eu<br />

European Sustainable Plastics Summit <strong>2023</strong><br />

21.11. – 22.11.<strong>2023</strong>, Frankfurt/M, Germany<br />

https://www.ecvinternational.com/EuropeanSustainablePlastics/index.html<br />

European Bioplastics Conference <strong>2023</strong><br />

12.12. – 13.12.<strong>2023</strong>, Berlin, Germany<br />

www.european-bioplastics.org/events/ebc<br />

ArabPlast<br />

13.12. – 15.12.<strong>2023</strong>, Dubai, UAE<br />

https://arabplast.info<br />

2 nd Annual World Biopolymers and Bioplastics Innovation Forum<br />

28.02. – 29.02.2024, Amsterdam, The Netherlands<br />

www.leadventgrp.com/events/2nd-annual-world-biopolymers-and-bioplasticsinnovation-forum/details<br />

Subject to changes.<br />

For up to date event-info visit https://www.bioplasticsmagazine.com/en/event-calendar/<br />

Suppliers Calendar Guide<br />

daily updated eventcalendar at<br />

www.bioplasticsmagazine.com<br />

Next issues<br />

<strong>Issue</strong><br />

Month<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

Edit. Focus 1 Edit. Focus 2 Trade Fair Specials<br />

06/<strong>2023</strong> Nov/Dec 04.12.<strong>2023</strong> 03.11.<strong>2023</strong> Films / Flexibles / Bags Barrier materials<br />

01/2024 Jan/Feb <strong>05</strong>.02.2024 23.12.<strong>2023</strong> Automotive Foam<br />

02/2024 Mar/Apr 10.04.2024 10.03.2024 Thermoforming / Rigid Packaging Masterbatch / Additives NPE Preview<br />

03/2024 May/Jun 03.06.2024 06.<strong>05</strong>.2024 Injection moulding Beauty / Healthcare NPE Review<br />

Subject to changes.<br />

bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18<br />

49


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

1Hotels 36<br />

GO!PHA 48 Qmilk 32<br />

ADBioplastics 42<br />

Grafe 46,47 Ramof 38<br />

Adidas 22<br />

Green Dot Bioplastics 47 Remondis 39<br />

Agrana 46 Green Serendipity 48 Renewable Carbon Initiative 10<br />

AIMPLAS 30<br />

Hamburg Univ. Techn. 38<br />

Res. Ctr. GHG Innovation 6<br />

Amaplast 12<br />

Helian Polymers 47 Riman 42<br />

Ambiente Consulenza & Ing. 12<br />

Helmholtz Ctr. f. Envir. Res. 18<br />

Ruian Gregeo 12<br />

Americal Chemical Society 9<br />

Husky 7<br />

RWTH Univ. Aachen 34<br />

Arkema 46 Inst. F. Biopl & Biocomposites 48 Saida 48<br />

Arteco 30<br />

Inst. Texttechnik RWTH Aachen 20,22<br />

Samsara Eco 24<br />

Asahi Kasei 16,27<br />

Inst. za molekularnu genetiku 30<br />

SCG Chemicals 8<br />

Atlantic Sea Foundation 36<br />

Institut f. Kunststofftechn., Stuttgart 48 Shenzhen Esun Industries 12 47<br />

Australian National Univ. 24<br />

JinHui ZhaoLong 46 Sinclair & Rush 36<br />

Avecom 30<br />

JM Polymes Group 12<br />

Sirmax 12<br />

BASF 46 Kaneka 47 SKZ 6<br />

Beijing Inst. Techn. 30<br />

Kingfa 47 Sukano 47<br />

Bio4Pack 47 Kompuestos 47 Sumitomo Chemical 6<br />

Bio-Fed 46 Korteks 28<br />

Sunar NP 12 47<br />

Biofibre 46 LAB CDA 30<br />

Suntory 5<br />

Biotec 12 47,51 Lenzing 25<br />

Tech. Univ. Clausthal 30<br />

BluePHA 47 LG Chem 46 Tech. Univ. Shannon 30<br />

BPI 48 Loliware 36<br />

TECNARO 47<br />

Braskem 5,6,8,16<br />

Lululemon 24<br />

Texas A&M Univ. 9<br />

BUSS 23,48 Lummus Technology 8<br />

Tianan Biologic’s 47<br />

Capricho Andaluz 42<br />

LUT Univ. 8<br />

Tintex 7<br />

Caprowax Dinkelaker 47 Michigan State University 48 TotalEnergies Corbion 47<br />

CeNTI 7<br />

Microtec 47 Treffert 47<br />

Chevron Phillips 8<br />

Minima Technology 48 Trinseo 47<br />

Chinaplas (Adsale) 19 Mitsubishi Corporation 5<br />

TÜV Austria 40,42,44<br />

CJ Biomaterials 42 47 Mixcycling 46 United Biopolymers 7 47<br />

COIM 40<br />

Montachem 36<br />

United Resin 7<br />

Conagen 6<br />

narocon InnovationConsulting 48 Univ. Leipzig 18<br />

Cortec Corporation 41<br />

Nat. Tech. Univ. Athens 30<br />

Univ. São Carlos 6<br />

Cossa Polimeri 12<br />

Naturabiomat 48 Univ. São Paulo 5,6<br />

CTK 47 Natural Fiber Welding 25<br />

Univ. Stuttgart (IKT) 48<br />

Customized Sheet Xtrusion 47 Natureplast-Biopolynov 12 47 Vita Group 39<br />

CUTEVE 7<br />

NaturTec 48 VTT 8<br />

Danimer Scientific 8<br />

Neste 5,44<br />

Werner Siemens Foundation 34<br />

Earth Renewable Technologies 46 nova-Institute 15,37,43,48 Wingram Industrial 43<br />

Elixance 46 Novamont 48,52 Xiamen Changsu Industries 46<br />

ENEOS 5<br />

NPE 35 Xinjiang Blue Ridge Tunhe 46<br />

Erema 48 NTUA 30<br />

Zeijiang Hisun Biomaterials 47<br />

European Bioplastics 1,14 29, 48 Nurel 47 Zeijiang Huafon 46<br />

Evonik 39<br />

Origin Materials 7<br />

Univ. Stuttgart (IKT) 46 64<br />

Fakuma (Schall) 27 Planet Bioplastics 12<br />

University of Queensland 16<br />

FKuR 16 2,46 PLAST Milan 12<br />

UPM Biofuels 53<br />

Fraunhofer IFAM 6<br />

Plasticker 34 Wageningen UR 16<br />

Fraunhofer UMSICHT 16 48 Plásticos Compuestos 34 47 Xiamen Changsu Industries 10 62<br />

Futerro 12<br />

polymediaconsult 48 Xinjiang Blue Ridge Tunhe 62<br />

Gema Polimer 12 46 Polytopoly 12<br />

Zeijiang Hisun Biomaterials 63<br />

Gianeco 12 46 PTT/MCC 46 Zeijiang Huafon 62<br />

Global Biopolymers 46<br />

50 bioplastics MAGAZINE | Renewable Carbon Plastics [<strong>05</strong>/23] Vol. 18


NEW NEW NEW NEW NEW NEW<br />

ADVANCED BIOPOLYMER COMPOUNDS<br />

FOR BUILDING A BETTER TOMORROW<br />

BIOPLAST 700<br />

BIOPLAST 800<br />

PLA-free Transparent Biodegradable<br />

Food contact Compostable Sealable<br />

Compostable >60% BBC High Temperature<br />

Heat Stable Biodegradable Thermoforming<br />

www.biotec.de


_01.<strong>2023</strong>

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