Issue 06/2021
Highlights: Coating Films, Flexibles, Bags Basics: Cellulose based bioplastics
Highlights:
Coating
Films, Flexibles, Bags
Basics: Cellulose based bioplastics
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Bioplastics - CO 2<br />
-based Plastics - Advanced Recycling<br />
bioplastics MAGAZINE Vol. 16<br />
Highlights<br />
Coating | 10<br />
Films, Flexibles, Bags | 40<br />
Basics<br />
Cellulose based bioplastics | 50<br />
Cover Story<br />
First straw bans<br />
begin to topple | 7<br />
<strong>06</strong> / <strong>2021</strong><br />
ISSN 1862-5258 ... is read in 92 countries Nov/Dec
BECOME CIRCULAR WITH<br />
THE BIOPLASTIC<br />
SPECIALIST<br />
Produce, consume, throw away: that’s over now. Starting in September,<br />
we will again show you in person and onsite how FKuR bioplastics and<br />
recyclates support you on your way to a circular economy and achieving<br />
your sustainability goals. Visit our website www.fkur.com and learn more<br />
about circular economy, bioplastics, recyclability and sustainable<br />
product design.<br />
Together we make a shift towards innovation!
dear<br />
Editorial<br />
readers<br />
Alex Thielen, Michael Thielen<br />
The Cover Story this time may only look like a “small news” segment<br />
on page 7, but we felt that it was a story worthwhile to highlight. The first<br />
straw ban toppled in California. The community of Fort Myers Beach<br />
decided to update its plastic straw ban ordinance to allow for marine<br />
biodegradable bioplastic straws. The decision is based on the insight that<br />
new marine biodegradable technologies have emerged including PHA.<br />
One year ago, we wrote on this page to be optimistic that in <strong>2021</strong> we can<br />
return to normal, step by step. However, even if it looked promising in late<br />
summer, our conference business has unfortunately suffered another<br />
corona-related setback. Due to an again significantly rising number of<br />
new infections in the so-called fourth wave, we had to postpone our 4 th<br />
bio!PAC to March 2022. We sincerely hope to be able to hold the event<br />
then as well as the 7 th PLA World Congress in May or June. The call for<br />
papers is open. We are looking forward to your proposals.<br />
The issue you are holding in your hand right now or read online<br />
features Coatings as one highlight. Other highlights include an opinion<br />
article about the versatility of natural PHA materials that, in addition<br />
to traditional plastic applications can also be used in other application<br />
areas, such as animal feed, medical care (both humans and animals),<br />
denitrification, or cosmetics. One article is not exactly about a<br />
renewable carbon plastics topic, but interesting enough to find its way<br />
in this issue: Scientists are developing a ship to clean the oceans from<br />
plastic waste converting the collected waste into, what they call “Blue<br />
Diesel” to fuel to ship. So that it doesn’t even have to go back to a harbour<br />
for refuelling.<br />
Finally, in our Basics section, we take a closer look at cellulose as a raw<br />
material.<br />
We hope you will enjoy reading this issue of bioplastics MAGAZINE.. We<br />
also hope to go to Berlin next week to meet some of you at the 16th<br />
European Bioplastics Conference. Here, we will present our 15th Global<br />
Bioplastics Award. This year, for the first time, the winner will be chosen by<br />
the audience of the conference.<br />
And finally, we hope you all find some rest during the holidays to come.<br />
Stay safe, stay healthy.<br />
Yours.<br />
bioplastics MAGAZINE Vol. 16<br />
Bioplastics - CO 2<br />
-based Plastics - Advanced Recycling<br />
Highlights<br />
Coating | 10<br />
Films, Flexibles, Bags | 40<br />
Basics<br />
Cellulose based bioplastics | 50<br />
Cover Story<br />
First straw bans<br />
begin to topple | 7<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
Like us on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
<strong>06</strong> / <strong>2021</strong><br />
ISSN 1862-5258 ... is read in 92 countries Nov/Dec<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 3
Imprint<br />
Content<br />
34 Porsche launches cars with biocomposites<br />
32 Bacteriostatic PLA compound for 3D printingz<br />
Nov/Dec <strong>06</strong>|<strong>2021</strong><br />
3 Editorial<br />
5 News<br />
8, 49 Events<br />
16 Application News<br />
22 Material News<br />
40 10 years ago<br />
46 Suppliers Guide<br />
50 Companies in this issue<br />
Coating<br />
10 Waterborne biobased coatings<br />
13 Biobased binders for coatings<br />
14 Biobased or renewable carbon<br />
based coatings<br />
From Science and<br />
Research<br />
15 Clean-up ships fuelled by garbage<br />
(Ocean plastics)<br />
28 Biobased polymers to fertilizers<br />
Materials<br />
18 Useful sample kit<br />
24 Custom-made PHA<br />
26 Fill the gap, not the landfill<br />
Applications<br />
19 Carbon neutral toothbrush<br />
20 100 % biobased PET bottle<br />
Recycling<br />
30 Merging high-quality recycling with<br />
lowered emissions<br />
32 Upcycling process for PAN<br />
from textile waste<br />
Report<br />
33 Patent situation<br />
Opinion<br />
34 Natural PHA materials<br />
Basics<br />
38 Cellulose<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Alex Thielen (AT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
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info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
sb@bioplasticsmagazine.com<br />
Michael Thielen (English Language)<br />
(see head office)<br />
Layout/Production<br />
Kerstin Neumeister<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Print run: 3300 copies<br />
bioplastics magazine<br />
Volume 16 - <strong>2021</strong><br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified subscribers<br />
(169 Euro for 6 issues).<br />
bioplastics MAGAZINE is read in<br />
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Every effort is made to verify all Information<br />
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cannot accept responsibility for any errors<br />
or omissions or for any losses that may<br />
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All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
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in any form, including electronic format,<br />
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Opinions expressed in articles do not necessarily<br />
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bioplastics MAGAZINE welcomes contributions<br />
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The fact that product names may not be<br />
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is not an indication that such names are<br />
not registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped bioplastic envelopes<br />
sponsored by BIOTEC Biologische<br />
Naturverpackungen GmbH & Co. KG,<br />
Emmerich, Germany<br />
Cover<br />
Shutterstock (wavebreakmedia)<br />
Follow us on twitter:<br />
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Emballator launches<br />
bio-PP product<br />
Emballator (Ulricehamn, Sweden)) a leading<br />
producer of packaging solutions, and Borealis<br />
(Vienna, Austria)) are expanding their portfolio in<br />
close partnership.<br />
Borealis is providing Emballator with biobased<br />
polypropylene for pails and containers. The raw<br />
material is made from used and recovered residue<br />
vegetable oil and cooking oils.<br />
“For PE products it has been possible for many<br />
years to produce a product in biobased material<br />
but for PP, until now, it has only been possible to<br />
produce bio-PP based products from renewable<br />
resources with the ISCC PLUS certified mass<br />
balance principle. With this new grade the product<br />
contains at least 30 % biobased polypropylene,”<br />
says Richard Johansson, Sales and Marketing<br />
Manager at Emballator Lagan.<br />
The packaging produced by Emballator is 100 %<br />
recyclable as PP create a circular solution, that<br />
reduces the carbon footprint further.<br />
“At Borealis, we continue to re-invent our<br />
circular product portfolio for more sustainable<br />
living. This partnership with Emballator is another<br />
step in our commitment to renewable/biobased<br />
products that significantly reduce the carbon<br />
footprint of packaging,” says Trevor Davis, Global<br />
Commercial Director, Consumer Products.<br />
“With Borealis as a partner we significantly<br />
lower our carbon footprint, while maintaining the<br />
existing quality standards of our product.” says<br />
Richard Johansson. MT<br />
www.emballator.com | www.borealis.com<br />
Danimer Scientific and<br />
Total Corbion PLA<br />
collaborate<br />
Danimer Scientific (Bainbridge, GA, USA) and Total Corbion<br />
PLA (Gorinchem, The Netherlands), both leading bioplastics<br />
companies focused on the development and production of<br />
biodegradable materials, recently announced that they have<br />
entered into a long-term collaborative arrangement for the<br />
supply of Luminy ® PLA.<br />
As Danimer continues to scale up the commercial production<br />
of Nodax ® , its signature polyhydroxyalkanoate (PHA), this<br />
agreement enhances Danimer’s ability to fulfil customer needs<br />
for resins that require a blend of PLA- and PHA-based inputs.<br />
Stephen E. Croskrey, Chairman and CEOof Danimer, said,<br />
“While growing commercial production of PHA remains the<br />
focus of our business, PLA is a part of some compounds that<br />
we formulate to meet specific customers’ functionality needs for<br />
different applications. Teaming with Total Corbion PLA provides<br />
an ideal solution to support our long-term growth strategy while<br />
ensuring our short-term customer needs remain fulfilled.”<br />
Danimer works with each of its customers to develop<br />
customized formulas for biobased resins that meet<br />
biodegradability and functionality expectations. Blending various<br />
inputs, such as PHA and PLA, enables Danimer to expand<br />
the applications of its materials across a number of different<br />
industries.<br />
Total Corbion PLA is a 50/50 joint venture between<br />
TotalEnergies and Corbion focused on the manufacturing and<br />
marketing of Luminy PLA resins.<br />
Thomas Philipon, Chief Executive Officer of Total Corbion PLA,<br />
said, "The biopolymers market is experiencing strong growth,<br />
and customers are requesting innovative solutions tailor-made<br />
to their market needs. In today’s dynamic market, strategic<br />
arrangements throughout the value chain are key to ensuring<br />
security of supply in both product and technology that will allow<br />
brand owners and ultimately consumers to be comfortable with<br />
selecting bioplastics as a sustainable alternative to traditional<br />
plastics." MT<br />
www.danimerscientific.com | www.total-corbion.com<br />
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
Picks & clicks<br />
Most frequently clicked news<br />
Here’s a look at our most popular online content of the past two months.<br />
The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />
tinyurl.com/news-<strong>2021</strong>1027<br />
Sabic debuts world’s first biobased, certified<br />
renewable high-performance amorphous polymer<br />
(27 October <strong>2021</strong>)<br />
Sabic has launched a new portfolio of biobased ULTEM resins (...)<br />
These breakthrough polyetherimide (PEI) materials are the first certified<br />
renewable high-temperature, amorphous resins available in the industry for<br />
potential use in challenging applications in consumer electronics, aerospace,<br />
automotive and other industries.<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 5
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
Chemically recycled<br />
PLA now available<br />
Total Corbion PLA (Gorinchem, The Netherlands)<br />
has launched the world’s first commercially available<br />
chemically recycled bioplastics product. The Luminy ®<br />
recycled PLA grades boast the same properties,<br />
characteristics and regulatory approvals as virgin<br />
Luminy PLA, but are partially made from post-industrial<br />
and post-consumer PLA waste. Total Corbion PLA is<br />
already receiving and depolymerizing reprocessed PLA<br />
waste, which is then purified and polymerized back into<br />
commercially available Luminy rPLA.<br />
The commercial availability of recycled PLA (rPLA)<br />
offers brand owners the opportunity to make products<br />
from rPLA, with the luxury of having original food<br />
contact and other certifications in place. Using rPLA<br />
can contribute to meeting the recycled content targets<br />
of brand owners.<br />
Thomas Philipon, CEO at Total Corbion PLA, sees<br />
this as a logical step towards an even more sustainable<br />
offering: “Our company’s vision is to create a better<br />
world for today and generations to come. This ability to<br />
now efficiently receive, repurpose and resupply PLA is a<br />
further demonstration of the sustainability of our product<br />
and the demonstration of our commitment to enable the<br />
circular economy through value chain partnership.”<br />
François de Bie, Senior Marketing Director at Total<br />
Corbion PLA is proud to launch this new product line of<br />
Luminy PLA and encourages interested parties to get in<br />
touch: “The ability to chemically recycle post-industrial<br />
and post-consumer PLA waste allows us to not only<br />
reduce waste but also keep valuable resources in use<br />
and truly ‘close the loop’. For our customers, the new,<br />
additional end-of-life avenue this provides could be the<br />
missing piece in their own sustainability puzzle, and we<br />
look forward to solving these challenges together.”<br />
As an initial offering, grades will be supplied with 20 %<br />
recycled content using the widely accepted principles<br />
of mass balance. “As we are currently ramping up this<br />
initiative, the initial volumes are limited but we are<br />
confident that rPLA will grow to be a significant part<br />
of our overall sales revenues” states de Bie. Currently,<br />
Looplife in Belgium and Sansu in Korea are among the<br />
first active partners that support collecting, sorting and<br />
cleaning of post-industrial and post-consumer PLA<br />
waste. The resulting PLA feedstock is then used by Total<br />
Corbion PLA to make new Luminy PLA polymers via the<br />
chemical recycling process. Total Corbion PLA is actively<br />
looking for additional partners from around the world<br />
that will help to close the loop. We invite interested<br />
parties to contact their local sales representative.<br />
Total Corbion PLA expects that the growing demand<br />
for rPLA will also boost the collecting, sorting and<br />
reprocessing of post-use PLA for both mechanical and<br />
chemical recycling, as de Bie explains further: “At Total<br />
Corbion PLA, we are actively seeking to purchase more<br />
post-industrial and post-consumer PLA waste, creating<br />
value for the recycle industry as a whole.”MT<br />
www.total-corbion.com<br />
Kolon and Origin<br />
to codevelop and<br />
commercialise PEF<br />
Carbon negative materials company Origin Materials<br />
(West Sacramento, California, USA) and Kolon Industries<br />
(Seoul, South Korea) recently announced a strategic<br />
partnership to industrialize novel polymers and drop-in<br />
solutions for select applications, with an initial focus on<br />
automotive applications.<br />
This strategic partnership aims to rapidly develop and<br />
industrialize new sustainable carbon-negative products<br />
based on Origin Materials’ patented technology platform,<br />
leveraging Kolon’s polymerization expertise, application<br />
development and supply chain strength. As part of<br />
the partnership, Kolon signed a multi-year capacity<br />
reservation agreement to purchase sustainable carbonnegative<br />
materials from Origin Materials.<br />
The partnership includes co-development aimed<br />
at commercializing polyethylene furanoate, or PEF, a<br />
polymer with an attractive combination of performance<br />
characteristics for packaging and other applications,<br />
including enhanced barrier properties when compared<br />
with PET, and other qualities. Origin Materials’ technology<br />
platform is expected to produce cost-competitive,<br />
sustainable, carbon-negative furandicarboxylic acid<br />
(FDCA), the primary precursor to PEF. Kolon Industries’<br />
polymer expertise in novel FDCA-based polymers,<br />
including PEF, is expected to introduce world-class<br />
carbon-negative polymers and chemistries.<br />
“Origin is a pioneer and a global leader in carbon<br />
negative chemical technology, and Kolon Industries is a<br />
world leader in chemicals and polymers,” said Sung Han,<br />
Chief Technology Officer of Kolon Group. “Therefore, the<br />
collaboration between these two companies will ensure<br />
both carbon-negative and cost-effective Sustainable<br />
Polymer Economy, which will further enable the<br />
realization of the Circular Economy.”<br />
Origin Materials has developed a platform for turning<br />
the carbon found in inexpensive, plentiful, non-food<br />
biomass such as sustainable wood residues into useful<br />
materials while capturing carbon in the process. Origin’s<br />
patented technology platform can help revolutionize the<br />
production of a wide range of end products. In addition,<br />
Origin’s technology platform is expected to provide stable<br />
pricing largely decoupled from the petroleum supply<br />
chain, which is exposed to more volatility than supply<br />
chains based on sustainable wood residues.<br />
Founded in 1957, Kolon Industries is an innovative<br />
chemical and material company. The company has over<br />
60 years of experience in polyester polymerization and its<br />
application technology including fibre, film, and others.<br />
Kolon Industries’ experience and proven success in<br />
cutting-edge polymer commercialization are expected to<br />
secure novel biobased polymers. MT<br />
www.kolonindustries.com | www.originmaterials.com<br />
6 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
First straw bans begin to topple<br />
While well-intended, many straw bans inadvertently prohibit the use of emerging<br />
alternatives to petroleum plastic and require the use of paper straws. Since this<br />
wave of bans began, new, sustainable solutions have emerged into the marketplace,<br />
while questions have been raised about paper straws’ impact on human health and<br />
the environment (e.g., many paper straws contain PFAS, also known as the "forever<br />
chemical").<br />
WinCup (Stone Mountain, Georgia, USA) applauds the community of Fort Myers<br />
Beach (California, USA) decision to update its plastic straw ban ordinance to allow for<br />
marine biodegradable bioplastic straws. The new ordinance strengthens the city’s<br />
previous policy, which banned the use of any type of straw other than paper straws.<br />
New marine biodegradable technologies that have emerged since the passage of<br />
the initial policy in 2017, including WinCup’s polyhydroxyalkanoate (PHA) phade ®<br />
straw, made with Nodax ® -based resins from Danimer Scientific (Bainbridge, Georgia, USA), are now able to be distributed in<br />
the community and achieve the city’s goal of protecting the area’s beaches and waterways.<br />
“We commend Fort Myers Beach for its leadership and demonstrating the community’s commitment to meaningfully address<br />
plastic pollution by strengthening its straw ban to allow for groundbreaking marine biodegradable solutions like phade PHA<br />
straws,” said WinCup CEO Brad Laporte. “Straw bans are being enacted across the country that, while well-meaning, ultimately<br />
limit the positive impacts that emerging technologies designed to replace traditional plastic can bring. Innovative bioplastics<br />
must be a part of the movement away from petroleum-based plastics. Our hope is that communities across the country will<br />
follow Fort Myers Beach’s lead by ensuring their straw ban policies are as strong as possible by allowing ecologically superior<br />
alternatives to petro plastic, like PHA.”<br />
The update to the Fort Myers Beach straw ban comes as communities and governments worldwide look for sustainable<br />
solutions to combat plastic pollution. With the Town Council’s vote, Fort Myers Beach provides a model for other policy makers<br />
to modernize straw bans that prohibit non-paper, sustainable alternatives to traditional plastic.<br />
The Global Organisation for PHA (GO!PHA, Amsterdam, The Netherlands) also welcomes this move. “This is a great first step<br />
in the right direction and highlights the solution that PHA can provide in our joint mission to end plastics pollution”, said Rick<br />
Passenier, Executive Board Member of GO!PHA. “Communities and governments around the globe should consider similar<br />
corrective moves that should also be expanded to other, if not all SUP bans.” MT<br />
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
www.wincup.com | www.phadeproducts.com | www.gopha.org<br />
Polyamide 6 from 92 % sustainable raw materials<br />
LANXESS (Cologne, Germany) recently introduced its new<br />
brand extension, called “Scopeblue”. The first product in this<br />
new line is Durethan BLUEBKV60H2.0EF. 92 % of the raw<br />
materials used in this easy-flowing PA 6 compound have<br />
been replaced with sustainable alternatives –<br />
that’s more than in any other prime quality<br />
glass-fibre-reinforced plastic.<br />
The new brand label identifies products<br />
that either consist of at least 50 % circular<br />
(recycled or biobased) raw materials, or<br />
whose carbon footprint is at least 50 % lower<br />
than that of conventional products.<br />
One of the raw materials used in the<br />
production of this PA 6 based highperformance<br />
plastic is cyclohexane from<br />
sustainable sources – meaning cyclohexane<br />
that is either biobased, recycled biobased or<br />
produced by means of chemical recycling.<br />
The material is also strengthened with 60 %<br />
by weight of glass fibres comprising industrial glass waste<br />
instead of mineral raw materials. The alternative raw<br />
materials that Lanxessuses in the precursors for polyamide<br />
6 are chemically identical to their equivalents of fossil origin<br />
(drop-in solutions), so Durethan BLUEBKV60H2.0EF exhibits<br />
the same characteristics as the virgin material and can be<br />
processed just as easily using exactly the same production<br />
tools and facilities with no conversion work needed.<br />
But developers are setting their sights<br />
on more than 92 % sustainable raw<br />
materials. “We’re currently working on<br />
increasing the content of sustainable<br />
raw materials in this compound to<br />
100 %,” says Günter Margraf, Head of<br />
Global Management at Lanxess’ High<br />
performance Materials division (HPM).<br />
This requires ammonia synthesized<br />
with carbon-neutral hydrogen. Over the<br />
medium term, the specialty chemicals<br />
company is also planning to replace<br />
the additives used in its plastics with<br />
sustainable equivalents.<br />
In mid-November, Lanxess announced<br />
they will transfer its HPM business unit to an independent<br />
legal corporate structure. MT<br />
www.lanxess.com<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 7
Events<br />
bioplastics MAGAZINE presents:<br />
The fourth bio!PAC conference on biobased packaging in Düsseldorf,<br />
Germany, organised by bioplastics MAGAZINE andGreen Serendipity, needed<br />
to be postponed again due to the Corona pandemic. bio!PAC is the mustattend<br />
conference for anyone interested in sustainable packaging made from<br />
renewably-sourced materials. The hybrid (on-site and online) conference<br />
offers expert presentations from major players in the packaging value chain,<br />
from raw material suppliers and packaging manufacturers to brand owners<br />
experienced in using biobased packaging. bio!PAC offers excellent opportunities<br />
for attendees to connect and network with other professionals in the field.<br />
The programme of the conference is provided below. Please visit our<br />
conference website for full details and information about registration.<br />
bio PAC<br />
www.bio-pac.info<br />
biobased packaging<br />
conference<br />
15 - 16 march 2022<br />
maritim düsseldorf<br />
Wednesday, March 15, 2022<br />
08:00 - 08:40 Registration, Welcome-Coffee<br />
08:45 - 09:00 Michael Thielen Welcome remarks<br />
09:00 - 09:25 Caroli Buitenhuis, Green Serendipity Future of bioplastics & packaging<br />
09:25 - 09:50 Constance Ißbrücker, European Bioplastics European bioplastics perspective for bioplastics<br />
09:50 - 10:15 Christopher vom Berg, nova Institute Renewable Carbon<br />
10:15 - 10:30 Q&A<br />
10:30 - 10:55 Coffee- and Networking Break<br />
10:55 - 11:20 Heidi Koljonen, Sulapac Microplastics & Packaging<br />
11:20 - 11:45 Thijs Rodenburg, Rodenburg Biopolymers Starch based compounds for packaging applications<br />
11:45 - 12:10 Patrick Zimmermann, FKuR From linear to circular - how bioplastics provides solutions for packaging<br />
12:10 - 12:25 Q&A<br />
12:25 - 13:30 Lunch- and Networking Break<br />
13:30 - 13:55 Ingrid Goumans, Avantium Plant-based solutions to realize a fossil-free & circular economy<br />
13:55 - 14:20 Martin Bussmann, Neste Renewable carbon solutions for packaging<br />
14:20 - 14:45 Allegra Muscatello, Taghleef Industries New developments in biobased and biodegradable packaging solutions<br />
14:45 - 15:00 Q&A<br />
15:00 - 15:25 Coffee- and Networking Break<br />
15:25 - 15:50 Patrick Gerritsen, Bio4pack Bio4Pack moves the earth<br />
15:50 - 16:15 Blake Lindsey, RWDC Moving Past Recycling: Can We Stem the Microplastics Crisis?<br />
16:15 - 16:40 Jane Franch, Numi Organic Tea Practical application of bioplastics in packaging: Brand perspective<br />
16:40 - 16:55 Q&A<br />
Thursday, March 16, 2022<br />
08:45 - 09:00 Michael Thielen Welcome remarks<br />
09:00 - 09:25 Lise Magnier, TU Delft Insights in consumer behaviour in relation to sustainable packaging<br />
09:25 - 09:50 Bruno de Wilde, OWS Environmental Benefits of biodegradable packaging?<br />
09:50 - 10:15 Johann Zimmermann, NaKu PLA packaging: returnable, recyclable, re...<br />
10:15 - 10:40 Erwin Vink, NatureWorks A review of JRC’s report: LCA of alternative feedstocks for plastics t.b.c.<br />
10:40 - 10:55 Q&A<br />
10:55 - 11:20 Coffee- and Networking Break<br />
11:20 - 11:45 François de Bie, Total Corbion Expanding end-of-life options for PLA bioplastics<br />
11:45 - 12:10 Remy Jongboom, Biotec The added value of compostable materials in packaging applications<br />
12:10 - 12:35 Vincent Kneefel, TIPA Creating a circular bio-economy through compostable packaging<br />
12:35 - 12:50 Q&A<br />
12:50 - 14:00 Lunch- and Networking Break<br />
Tom Bowden, Earthfirst Biopolymer Films by Evolutions of Biopolymer Film Performance and<br />
14:00 - 14:25<br />
Sidaplax<br />
Environmental Degradability<br />
14:25 - 14:50 Jojanneke Leistra, Superfoodguru PLA bottles from a brand owners perspective<br />
14:50 - 15:15 Alberto Castellanza, Novamont Mater-Bi ® : Novel Developments in Food Packaging Applications<br />
15:15 - 15:30 Q&A<br />
15:30 - 15:45 Caroli Buitenhuis, Michael Thielen Closing remarks<br />
Subject to changes<br />
8 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
io PAC<br />
bioplastics MAGAZINE presents:<br />
New date<br />
#biopac<br />
www.bio-pac.info<br />
Conference on Biobased Packaging<br />
15 - 16 March 2022 - Düsseldorf, Germany<br />
Most packaging is only used for a short period and therefore give rise to large quantities of waste. Accordingly, it is vital to<br />
make sure that packaging fits into nature‘s eco-systems and therefore use the most suitable renewable carbon materials<br />
and implement the best ‘end-of-life’ solutions.<br />
That‘s why bioplastics MAGAZINE (in cooperation with Green Serendipity) is now organizing the 4 th edition of the<br />
bio!PAC ‐ conference on packaging made from renewable carbon plastics, i.e. from renewable resources. Experts from all<br />
areas of renewable carbon plastics and circular packaging will present their latest developments. The conference will also<br />
cover discussions like end-of-life options, consumer behaviour issues, availability of agricultural land for material use<br />
versus food and feed etc.<br />
The full 2-day hybrid (on-site and online) conference will be held on 15-16 March 2022 in Düsseldorf, Germany (Maritim Airport<br />
Hotel).<br />
Silver Sponsors<br />
Bronze Sponsors<br />
Coorganized by<br />
supported by<br />
Media Partner
Coating<br />
Waterborne biobased coatings<br />
From the point of view of polymer manufacturers to the<br />
coatings and inks market, there are several ways to<br />
improve business sustainability. Some examples are<br />
reducing water usage, greenhouse gas emissions, net<br />
waste, and non-renewable energy consumption during<br />
manufacture or transport.<br />
The long-term effective route to become truly sustainable<br />
is to approach via new product developments that would<br />
include all aspect of innovation: the research of new<br />
sustainable raw materials and polymers, the measurement<br />
and development of performance applied to final materials,<br />
partnership with customer, and end-users for innovative<br />
useful solutions for final market and brand.<br />
How are the Specialty Chemical Manufacturers<br />
for the Coatings Industry addressing current<br />
issues in order to improve sustainability?<br />
As surfaces are boundaries exposed to external<br />
agents that, in some cases, can be extremely harsh and<br />
challenging, they are also the gateways through which we<br />
perceive the objects we use in our everyday life. Whether<br />
it is aesthetic appearance, durability, corrosion protection,<br />
or barrier properties, the right treatment on surfaces can<br />
boost these characteristics.<br />
The coating or surface treatment is one of the smallest<br />
component of the final product. Surfaces are generally<br />
coated from minimum of 5 g/m 2 to maximum of 100 g/m 2 ,<br />
depending on the type of substrate, however they impart<br />
essential sustainable attributes. In all materials or<br />
substrates that we touch everyday these are superficial<br />
coatings whether it is paper, textile, wood, metal, or plastic.<br />
At Lamberti from Gallarate, Italy, The Surface Treatment<br />
Division is fostering their path towards sustainability<br />
and circular economy by moving in four main directions<br />
of waterborne polyurethane and acrylic polymers<br />
development. These are used as coatings, or in adhesive, or<br />
rheology modifiers and crosslinkers.<br />
Performance: higher durability of goods.<br />
Durability is an added value for a coating, especially when<br />
is necessary to protect everlasting surfaces with specific<br />
properties like chemical resistance, physical properties,<br />
abrasion resistance, and adhesions. This is apparently in<br />
contrast with biodegradability – degradation of the polymer<br />
during a specific period of time.<br />
The knowledge of the performance required over the lifetime<br />
of the final object permits us to design the waterborne<br />
polymers with more sustainable attributes. Thus designing<br />
for the right purpose.<br />
• Biobased content: it is possible to increase the renewable<br />
raw materials content in waterborne polyurethane and<br />
acrylic emulsions without decreasing the performance.<br />
Biobased content of up to 70 % can be realistically achieved<br />
however the limitations today are related to the relatively<br />
new biobased supply chain that has limited capacity. The<br />
majority of suppliers are still at pilot or initial industrial<br />
scale, and consequently with higher prices.<br />
The focus for the coating industries is to get biobased raw<br />
materials without affecting the food chain, and this trend is<br />
really in progress with new technologies at industrial scale<br />
today.<br />
The biobased content at product level could be measured,<br />
for example using the C 12 /C 14 analysis (biogenic carbon<br />
content according to ASTM D6866) in order to express the<br />
content of renewable carbon present in the waterborne<br />
polymer sold to the markets.<br />
Waterborne products.<br />
Lamberti’s aim is to reduce the usage of volatile organic<br />
compounds in coatings and they continuously focus on the<br />
reduction of cosolvents and Volatile Organic Compound<br />
(VOC) to optimize the performance of superficial effects.<br />
Process optimization:<br />
Another important factor is the constant improvement of<br />
industrial processes with the aim to reduce the consumption<br />
of energy, water and air emissions, improving process<br />
efficiency, and related sustainable impact.<br />
All four directions confluence in analysis of product<br />
sustainability, by emissions (Product Carbon Footprint) and<br />
by assessment (Life Cycle Analysis) on final products and<br />
products for end-users.<br />
Thanks to their consolidated expertise and passion<br />
for collaboration, Lamberti supplies a complete range of<br />
ingredients for the coating, inks & finishing industries:<br />
• A full range of innovative waterborne polyurethane<br />
Esacote ® and Rolflex ® , UV curable polyurethane, acrylicurethane<br />
hybrids, and acrylic dispersions for soft and<br />
hard substrates;<br />
• Fully reacted waterborne polyurethane microspheres<br />
(Decosphaera ® ) suitable for solvent, waterborne and<br />
UV 100 % system used as polymeric matting agents to<br />
enhance scratch & burnishing resistance and slip control.<br />
As well as fashion deco paints with pigmented coloured<br />
Decospharea ® ;<br />
•Synthetic (Viscolam ® ) and natural (Esacol ® and<br />
Carbocel ® ) rheology modifiers to control the viscosity of<br />
formulations during production, storage. and application.<br />
• Natural and synthetic solvent based and waterborne<br />
waxes (Adiwax) to control and improve gloss, scratch. and<br />
slip for multiple surfaces. Special additives & auxiliaries<br />
(e.g. dispersing & wetting agents, defoamers, plasticizer.<br />
and crosslinkers).<br />
10 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
By:<br />
Gabriele Costa<br />
Global Product Manager<br />
Lamberti<br />
Gallarate, Italy<br />
Coating<br />
The key challenge is to replace the demand for fossil<br />
carbon by alternative sources;<br />
Moreover, with a dedicated team of experts, the Italian<br />
company is pleased to support customers in the development<br />
of waterborne ink & digital ink for inkjet printing.<br />
They offer renewable biobased solutions for several<br />
coating application on synthetic material, textile for printing<br />
and finishing, for natural leather, plastic and paper coatings,<br />
wood and metal coatings.<br />
https://surfacetreatment.lamberti.com<br />
• Vegetable<br />
• Sustainable Biomass<br />
• Sustainable Oil extracted<br />
• Carbohydrates<br />
• CO 2<br />
• Recycling<br />
CO 2<br />
BIOBASED WATERBASED<br />
POLYMERS<br />
• Coating, Crosslinkers & Adhesives<br />
• Additives for surface treatment<br />
SURFACANTS AND FATTY<br />
DERIVATIVES<br />
• Not made by EO and PO<br />
• Biodegradable<br />
• Low irritation<br />
• 100% Biobased<br />
RHEOLOGY MODIFIERS<br />
• Carbohydrates feedstock<br />
• Hydrocolloids<br />
• Cellulosics<br />
10-12 May – Cologne, Germany<br />
The Answer to Your Hunt for Renewable Materials<br />
The unique concept of presenting all renewable material solutions at<br />
one event hits the mark: bio-based, CO2-based and recycled are the only<br />
alternatives to fossil-based chemicals and materials.<br />
ORGANISED BY<br />
NOVA-INSTITUTE<br />
RENEWABLE<br />
MATERIAL<br />
OF THE<br />
YEAR 2022<br />
First day:<br />
• Chemical Industry:<br />
Challenges and Strategies<br />
• Renewable Chemicals<br />
and Building Blocks<br />
• Biorefineries<br />
• Chemical Recycling<br />
Second day:<br />
• Renewable Polymers<br />
and Plastics<br />
• Fine Chemicals<br />
• Policy and Markets<br />
• Innovation Award<br />
Third day:<br />
• Renewable Plastics<br />
and Composites<br />
• Biodegradation<br />
• The Brands View on<br />
Renewable Materials<br />
1<br />
INNOVATION AWARD<br />
Call for Innovation<br />
Submit your Application<br />
for the “Renewable<br />
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Sponsor<br />
Sponsors<br />
renewable-materials.eu<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 11
Coating<br />
Biopolymer coatings<br />
market preview<br />
The global biopolymer coatings market size was valued<br />
at USD 1.04 billion in 2020, is projected to hit around<br />
USD 1.79 billion by 2030 and is expected to grow at a<br />
compound annual growth rate (CAGR) of 5.4 % from <strong>2021</strong> to<br />
2030.<br />
The reasons for this predicted growth are twofold, on the<br />
one hand, it is due to superior properties of coated materials<br />
and on the other, it is due to more environmental awareness.<br />
Biopolymer coating screate protective layers that shield the<br />
packaged product from exterior environmental conditions.<br />
These coatings prevent the transfer of unwanted moisture in<br />
food products as well as serve as oxygen and oil barrier. It is<br />
possible to incorporate antimicrobial agents with biopolymer<br />
coatings in order to create active paper packaging materials<br />
that offers an effective option for the protection of food items<br />
from microorganism infiltration. Hence, biopolymer coatings<br />
are a better substitute for synthetic paper and paperboard<br />
coatings.<br />
In addition, increasing global awareness for environmental<br />
pollution and the use of biodegradable products also propel<br />
the demand for the biopolymer coatings market. With the<br />
rising level of concern regarding environmental degradation,<br />
the use for biodegradable products and biopolymer coatings<br />
are estimated to flourish at a significant pace during the<br />
forecast timeframe. This also triggers the rate of research &<br />
development in the field of biopolymer coatings and bioplastics.<br />
This is amplified by increasing government support for the use<br />
of biodegradable plastics in various fields including packaging<br />
and coatings. Further, impending government regulations<br />
against the manufacturing of single-use plastics in key<br />
markets like China has compelled plastic manufacturers to<br />
ramp up their biodegradable plastic production.<br />
Apart from notable developments in the fields of bioplastics<br />
and biopolymer coatings, the market is still at its emerging<br />
phase and has a promising future growth opportunity. In<br />
order to curb the environmental pollution load, governments<br />
and plastic manufacturing companies are collaborating or<br />
partnering to move towards a more renewable future and a<br />
greener environment. Henceforth, the aforementioned factors<br />
are likely to support the market growth of biopolymer coatings<br />
remarkably in the upcoming years.<br />
At the link below interested readers find more information<br />
and can purchase a comprehensive report. AT<br />
www.precedenceresearch.com/biopolymer-coatings-market<br />
23 – 24 March • Hybrid Event<br />
Leading Event on Carbon Capture & Utilisation<br />
• Strategy & Policy<br />
• Green Hydrogen Production<br />
• Carbon Capture Technologies<br />
• Carbon Utilisation (Power-to-X): Fuels for Transport and Aviation, Building Blocks,<br />
Bulk and Fine Chemicals, Advanced Technologies / Artificial Photosynthesis<br />
• Innovation Award “Best CO2 Utilisation 2022“<br />
Call for Innovation<br />
Submit your application<br />
Innovation Award Sponsor Innovation Award Co-Organiser Sponsor<br />
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Utilisation 2022”<br />
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dominik.vogt@nova-institut.de<br />
Tel.: +49 2233 / 481449<br />
co2-chemistry.eu<br />
nova-institute.eu<br />
12 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Coating<br />
Biobased Binders for Coatings<br />
Approach or Reality?<br />
The world of coatings is a wide open field for the use of<br />
biobased materials.<br />
But what exactly are coatings? By definition a coating<br />
is one of the main manufacturing processes according to<br />
DIN 8580 [1]. Less formal in everyday language, we speak<br />
of a coating whenever a type of substrate is covered with<br />
another layer. This could be for example lacquer on metal,<br />
paint on the wall, stain on wood or even printing ink on<br />
paper or foil.<br />
Nearly all of these coatings have one thing in common:<br />
one of the main components is a resin used as the so called<br />
binder. They are known for example as polyesters, acrylic<br />
resins, polyurethanes, alkyd resins, epoxies and many more.<br />
In the past most of these binders were based solely on<br />
petrochemical components. Exemptions were the alkyds<br />
where the fatty acid content is biobased and resins based<br />
on gum rosin. Nowadays there are two approaches for the<br />
use of more renewable raw materials as building blocks for<br />
these coating binders:<br />
The mass-balance-approach and the use of real<br />
renewable, biobased raw materials. For details about the<br />
mass-balance-approach see [2] or bM issue 02/<strong>2021</strong>.<br />
The other approach is the use of real and directly biosourced<br />
building blocks which are now available in an<br />
industrial scale. These are not only the old-fashioned raw<br />
materials which have been in use for a long time, such as<br />
vegetable oils, glycerol, fatty acids or shellac, but also a<br />
growing number of new raw materials, especially polyols<br />
or carbon acids. They are derived for example from sugars,<br />
starch, natural oils, cellulose or lignin. [3, 4]<br />
A common, not so well-known building block with a high<br />
potential is gum rosin, which can be cropped from pine<br />
trees without the need for clear cutting the forests; thus<br />
helping to protect the environment from too much human<br />
disruption.<br />
By using smart ways of chemical synthesis, these natural<br />
based raw materials can be used to develop binders with<br />
the same performance as their fossil counterparts.<br />
A leading pioneer in the modification of gum rosin is the<br />
Robert Kraemer GmbH & Co. KG from Rastede, Germany.<br />
They started with the gum rosin business in the late 1920s.<br />
In the past 20 years, since the early 2000s, they developed<br />
from the classical rosin modifier to an innovative developer<br />
and producer for a wide range of biobased resins with a<br />
large R&D investment. [5]<br />
By creative chemical combination of gum rosin with other<br />
building blocks as described above, binders with up to 100 %<br />
biobased content can be designed for nearly every kind of<br />
coating<br />
Amongst classical binders for the lacquer and paints<br />
industries like rosin esters, alkyd resins or maleic modified<br />
rosin, as well as high performance resins like polyesters,<br />
urethanes or UV-curing binders are available. [6]<br />
They can also be used as combination partners to<br />
bring more green chemistry into formulations. As an<br />
example, biobased polyesters are used as pre-polymers for<br />
polyurethane dispersions; or special modified rosin resins<br />
are utilized in branching classical acrylic polymers to give<br />
them up to 50 % biobased content.<br />
These formerly 100 % fossil resins are now ready-made<br />
to bring significant amounts of renewable raw materials<br />
into coatings by these modifications.<br />
But the potential for biobased binders is even higher.<br />
In studies between the University of Technology Chemnitz<br />
and the company Robert Kraemer, resins derived<br />
from renewable raw-materials were found to be highperformance<br />
modifiers for bio-plastics such as poly-lactic<br />
acid (PLA). [7]<br />
Conclusion:<br />
Nowadays binders for a high content of renewable raw<br />
materials in coatings are already available on an industrial<br />
scale.<br />
Their performance is as good as their petrochemical<br />
counterparts’. Formulators and application technologists<br />
even have the choice between mass-balanced or directly<br />
sourced biobased materials. MT<br />
www.rokra.com<br />
References:<br />
[1] https://www.beuth.de/en/standard/din-8580/65031153, access date 14th<br />
Nov <strong>2021</strong><br />
[2] H. K.Jeswania, C. Krüger, A. Kicherer, F. Antony, A. Azapagica; Science of<br />
The Total Environment 2019, 687, 380-391<br />
[3] Fachagentur Nachwachsende Rohstoffe e. V.; Marktanalyse<br />
Nachwachsende Rohstoffe, ISBN 978-3-942147-18-7, 2014<br />
[4] https://www.biooekonomie-bw.de/fachbeitrag/dossier/lignin-einrohstoff-mit-viel-potenzial,<br />
access date 14th Nov <strong>2021</strong><br />
[5] http://www.rokra.com/en/company/company/history.html, access date<br />
14th Nov <strong>2021</strong><br />
[6] http://www.rokra.com/en/products/our-delivery-programme.html,<br />
access date 14th Nov <strong>2021</strong><br />
[7] Fachagentur Nachwachsende Rohstoffe e. V.; Entwicklung neuartiger<br />
Modifikatoren auf Basis nachwachsender Rohstoffe für Compounds und<br />
Blends aus biobasierten Kunststoffen, final report 2019<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 13
Coating<br />
Biobased or renewable<br />
carbon based coatings<br />
O<br />
ne way for fashion, footwear, and upholstery<br />
manufacturers to improve their environmental<br />
footprint is to replace fossil fuel-based chemistry with<br />
renewable carbon-based materials. Stahl’s NuVera ® range of<br />
renewable carbon polyurethanes can help you do exactly that.<br />
The NuVera product range can help manufacturers increase<br />
their sustainability without compromising on quality and<br />
performance. The introduction of this portfolio is in line with<br />
Stahl’s Responsible Chemistry Initiative, with which they commit<br />
to speed up the transition from fossil carbon to renewable<br />
carbon for all organic chemicals and materials. The efforts are<br />
focused on aligning Stahl’s product portfolio to the future needs<br />
of their customers and the markets they serve while offering<br />
solutions that improve their environmental footprint. The<br />
company from Waalwijk, the Netherlands does this by using<br />
low-impact manufacturing chemicals, contributing to a more<br />
circular economy and, in the case of Stahl NuVera, replacing<br />
petrochemicals with renewable resources.<br />
The Stahl NuVera Range<br />
Stahl NuVera modern carbon based products are derived<br />
from plant-based biomass (typically vegetable oils or sugars),<br />
alternatively, they can also be made from captured carbon,<br />
where CO 2<br />
released from industrial processes is captured and<br />
used as a feedstock for producing polymeric building blocks.<br />
The NuVera range of sustainable polyurethanes has been<br />
tested and certified using the ASTM 6866 radio-carbon (C 12 /<br />
C 14 ) method for biobased carbon content. The NuVera D range<br />
of polyurethane dispersions consists of four products: RU-<br />
94-226, RU-94-227, RU-94-225 and RU-94-414. The company<br />
is currently developing additional solutions as part of its<br />
commitment to responsible chemistry.<br />
The first two solutions – NuVera D RU-94-226 and RU-94-<br />
227 – are the two harder resins in the portfolio. They are ideal<br />
for use as a pre-skin component in transfer coating processes<br />
or as a top-coat component in finishing or lacquering of flexible<br />
synthetic articles, which may be used in consumer articles<br />
such as shoes, garment or fashion bags, and accessories.<br />
NuVera D RU-94-225 is a softer PUD that can be used<br />
as adhesive or alternatively as a mix component to make a<br />
chosen pre-skin formulation more flexible. It is a soft PUD<br />
that can also be used in a transfer-coating process as a skin<br />
layer or as a soft resin component in finishing or lacquering<br />
formulations that use a combination of biobased and captured<br />
carbon-based raw materials.<br />
NuVera D RU-94-414 is a soft polyester dispersion. It can be<br />
used in adhesive formulations or alternatively serve as a soft<br />
component in basecoat finishing or lacquering.<br />
Introducing new Stahl NuVera Q HS-94-490 high<br />
solids resin<br />
An important factor for creating high renewable carbon content<br />
in any synthetic article will also depend on the availability of a<br />
flexible high solids resin that offers biobased content. In many<br />
transfer coated articles, the middle layer (skin) is the thickest<br />
layer, which typically determines mostly the handle and flexibility.<br />
In some cases, this can be selected from WB PUD offering, but<br />
in most synthetic articles it needs the use of a bigger quantity<br />
or thicker layer to be applied, due to boost performance. The<br />
use of a high solids resin is often bringing the solution. With<br />
the introduction of NuVera Q HS-94-490, Stahl can now offer a<br />
product that can be used for applying thick layers in one pass.<br />
HS-94-490 is available as an approximately 100 % solids resin<br />
with very soft film characteristics, ideally suited for creating<br />
flexible articles like upholstery or shoe upper. This new NuVera<br />
product addition is currently in the pre-industrialization phase,<br />
available for small scale prototyping.<br />
ZDHC MRSL Compliancy<br />
It goes without saying that all NuVera renewable carbonbased<br />
products comply with the latest standards and<br />
regulations, including the Zero Discharge of Hazardous<br />
Chemicals (ZDHC) Version 2.0 Manufacturing Restricted<br />
Substances List (MRSL).<br />
In addition to these four water-based polyurethane<br />
dispersions, R&D engineers at Stahl are also looking at<br />
expanding their portfolio of products in other directions. They<br />
soon hope to announce the introduction of a 100 % solids prepolymer<br />
resin. MT<br />
www.stahl.com<br />
Type of use Product code Type Status Solids 100% (Mpa)<br />
Pre-skin or Top<br />
Coat resin<br />
General PUD<br />
resin or Mix<br />
component<br />
Adhesive or<br />
Base Coat<br />
Skin High<br />
solids resin<br />
E @ break<br />
(%)<br />
VOC %1<br />
Bio-based<br />
content<br />
Total<br />
renewable<br />
content<br />
Sustainable<br />
source<br />
NuVeraTM D RU-<br />
94-226 TM PE/PC Launch 40 12 475 0.5% 46%2 46% Sugar Crop<br />
NuVeraTM D RU-<br />
94-227<br />
NuVeraTM D RU-<br />
94-225<br />
NuVeraTM D RU-<br />
94-414<br />
NuVeraTM Q HS-<br />
94-490<br />
PE Launch 35 4 730 0.8% 66%2 66% Sugarcrop<br />
PE Launch 35 1.5 > 1,000 0.3% 53%2 54%<br />
Sugar crop,<br />
CO 2<br />
PES Launch 45 1.1 840 0.8% 48%2 48% Oil crop<br />
PE/PES<br />
Pre-<br />
Launch<br />
1: VOC content is according to the definition of EU directive 2004/42/EC<br />
2: Measured ASTM6866 Method B<br />
3: Calculated based on mass balance<br />
100 1.6 860 < 0.1% 45%3 45% Sugarcrop<br />
14 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Clean-up ships fuelled<br />
by garbage<br />
Millions of tonnes of synthetic plastics are released to<br />
the environment each year. Of this, a fraction ends<br />
up in one of several oceanic gyres, natural locations<br />
where the currents tend to accumulate floating debris –<br />
including plastics. The largest and best known of these is<br />
the Great Pacific Garbage Patch (GPGP), which is estimated<br />
to cover an area roughly the size of the state of Texas (or<br />
France), and which seems to be increasing in size over time.<br />
Removing this plastic from the oceanic gyres has promise<br />
to return the ocean to a more pristine state and alleviate the<br />
associated burden on wildlife and the food chain. Current<br />
methods to remove this plastic use a boom system to<br />
concentrate the plastic and a ship to harvest it and return to<br />
port to unload the plastic cargo and refuel [1].<br />
Plastic is a natural energy carrier, which suggests the<br />
question: is there enough energy embodied in the plastic to<br />
power the ship and eliminate or reduce the need to return to<br />
port? If so, then can a process be devised to convert plastic<br />
into a form of fuel appropriate for modern diesel engines<br />
that are used to power ships?<br />
Thermodynamic analysis of the energy available in plastics<br />
answered the first question –<br />
yes, there is enough energy in<br />
the ocean plastics, provided that<br />
they are first concentrated using A<br />
booms and that the ship is small<br />
and efficient enough to minimize<br />
its fuel consumption.<br />
The next question was<br />
answered by designing a<br />
process to convert plastics into<br />
a liquid fuel precursor. The most<br />
important step of the process is a<br />
high-temperature reaction called<br />
hydrothermal liquefaction or<br />
HTL. HTL depolymerizes plastics<br />
at high temperature (300–550 °C)<br />
and high pressure (250–300<br />
bar), thereby converting it into a<br />
liquid form. Oil yields from HTL<br />
are typically >90 % even in the<br />
absence of catalysts and, unlike<br />
pyrolysis, yields of solid byproducts<br />
– which would need to<br />
be stored or burned in a special<br />
combustor – are less than 5, thus<br />
conferring certain comparative<br />
advantages to HTL.<br />
Current data on the GPGP<br />
indicates that it contains mainly<br />
polyethylene and polypropylene,<br />
a mixture that is especially<br />
Great Pacific<br />
Garbage Patch<br />
C<br />
~ 1900 km<br />
San Francisco Port<br />
Current with Plastic<br />
Boom 600 m<br />
appropriate for HTL. By-products include a gas that might<br />
be used as a cooking fuel; a solid that could be burned on<br />
board or stored; and process water that is cleaned prior to<br />
release. Further analysis indicated that the use of plasticderived<br />
fuels could reduce fuel consumption, and effectively<br />
eliminate fossil fuel use. The HTL derived fuel could be<br />
termed blue diesel, to reference its marine origin and in<br />
contrast with both traditional marine diesel and green<br />
diesel, derived from land-based renewable resources. The<br />
full feasibility study is available for free online (link below<br />
[1]). Future work will construct the process and test it at<br />
pilot-scale for realistic feeds, to ultimately transition to<br />
shipboard use. AT<br />
[1] Belden, E.R.; Kazantzis, N.K.; Reddy,C.M.; Kite-Powell, H; Timko,M.T.;<br />
Italiani, E.; Herschbach D.R.: Thermodynamic feasibility of shipboard<br />
conversion of marine plastics to blue diesel for self-powered ocean<br />
cleanup; https://doi.org/10.1073/pnas.2107250118<br />
www.wpi.edu<br />
California<br />
0.5 knots<br />
B<br />
D<br />
Current 14 cm s -1<br />
Boom Array System<br />
Reactor<br />
15 knots<br />
Overview of the process for plastic removal out of the GPGP showing (A) the total system overview,<br />
(B) part of the system of collection booms, (C) a single collection boom, and (D) the HTL reactor.<br />
Science and Research<br />
San Francisco Port<br />
Current bioplastics 14 cm s MAGAZINE [<strong>06</strong>/21] Vol. 16 15<br />
-1
Application News<br />
Home compostable transparent laminate<br />
TIPA (Hod Hasharon, Israel), announced in late October<br />
the launch of its first home compostable, highly transparent<br />
laminate for food packaging.<br />
The new laminate has the same functionality as Tipa’s<br />
world- leading T.LAM 607 but<br />
is TÜV OK Home Compost<br />
certified.<br />
The innovation comes as<br />
demand for eco-friendly<br />
packaging continues to<br />
grow among brands and<br />
consumers. Tipa has<br />
developed T.LAM 608 to<br />
respond to this demand<br />
with a 2-ply laminate that<br />
offers the same good barrier,<br />
excellent sealing, superior mechanical properties, and<br />
excellent transparency as its other compostable laminate<br />
solutions, with the added benefit of being home compostable,<br />
giving end-consumers authority over their own waste<br />
management. It can be converted into pre-made bags such<br />
as stand-up pouches, zipper pouches, open pouches, side<br />
gusseted pouches, pillow bags, and bar wrappers. And is<br />
available as reels for VFFS and HFFS machinery.<br />
Developed to support pioneering food and supplement<br />
brands transitioning away from conventional plastic, it is<br />
suitable for packing energy<br />
bars, dried fruit, nuts,<br />
pulses, grains, cereals,<br />
granola, spices, dry pasta,<br />
ready meals and more.<br />
Eli Lancry, VP Technology<br />
of Tipa said: “Tipa is<br />
constantly innovating and<br />
developing new solutions<br />
built with the environment<br />
and our customers in<br />
mind, and T.LAM 608 is<br />
one of the most exciting developments I’ve worked on. We’ve<br />
created a packaging solution that really does work for both<br />
people and planet. It’s home compostable and it performs<br />
like conventional plastic, offering consumer convenience<br />
alongside reassurance for brands that the quality of their<br />
product will be protected.” MT<br />
www.tipa-corp.com<br />
New packaging for Herbal Essences<br />
Eastman (Kingsport, Tennessee, USA) and Procter & Gamble<br />
(Cincinnati, Ohio, USA) recently announced that Herbal<br />
Essences will be the first P&G brand to use Eastman<br />
Renew molecular-recycled plastic in its packaging. Beginning in<br />
November, Herbal Essences, one of P&G’s most iconic brands,<br />
started introducing five shampoo and conditioner collections<br />
in primary packaging made from Eastman<br />
Renew resins with 50 % certified recycled<br />
plastic.*<br />
In August, P&G and Eastman<br />
announced a landmark agreement<br />
to collaborate on initiatives that<br />
will advance the recycling of more<br />
materials, encourage recycling<br />
behaviour and prevent plastic from<br />
going to waste. The launch of Herbal<br />
Essences in packaging from Eastman<br />
Renew materials, timed to coincide with<br />
America Recycles Day on November 15, is<br />
the first concrete step the companies are<br />
taking to leverage Eastman’s molecular<br />
recycling technologies and advance their<br />
shared commitment to the circular economy.<br />
Five Herbal Essences bio:renew sulfate-free collections,<br />
including the Aloe Vera lineup, started to be upgraded to<br />
Eastman Renew materials beginning in early November. These<br />
will be followed by two new collections coming to market in<br />
January 2022. The new packages will also include standardized<br />
How2Recycle ® labels to clarify recycling instructions and<br />
encourage recycling behaviour, even in the bathroom.<br />
“It’s on all of us to make a difference and create a more<br />
sustainable future where plastics are truly recycled, reused<br />
and out of nature,” explains Herbal Essences principal scientist<br />
Rachel Zipperian. “Making this package change to Eastman<br />
Renew materials reduces the brand’s dependence on virgin<br />
plastic and helps us bring the world one step closer to making<br />
plastic a circular resource. By including the standard<br />
How2Recycle label, Herbal Essences is<br />
encouraging people to recycle their empty<br />
bottles.”<br />
Eastman Renew materials are made<br />
via Eastman’s molecular recycling<br />
technologies using waste plastic that,<br />
without this technology, would end<br />
up in landfills or incineration. These<br />
advanced recycling technologies<br />
complement traditional recycling,<br />
expanding the types and amounts of<br />
plastics that can be recycled. This gives<br />
materials an extended useful life and<br />
diverts plastic waste from landfills or the<br />
environment.<br />
“We are excited to see our partnership with Procter & Gamble<br />
reach consumers’ hands with the launch of these Herbal<br />
Essences packages,” said Chris Layton, Eastman sustainability<br />
director for plastics and circular solutions. “We are delivering<br />
solutions to the plastic waste problem right now and look forward<br />
to the continued collaboration with P&G as a leading partner.” MT<br />
*The recycled content is achieved by allocating the recycled waste plastic to<br />
Eastman Renew materials using a mass balance process certified by ISCC.<br />
www.eastman.com | www.pg.com<br />
16 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Biobased packaging for Chanel<br />
CHANEL (London, UK) recently announced that the new<br />
Les Eaux De Chanel fragrance bottle caps will be made<br />
using biobased Sulapac ® material.<br />
It all began with a desire. In 2018, Les Eaux De Chanel<br />
introduced a new olfactory world to the fragrances of the<br />
House: a singular collection, inspired by Mademoiselle<br />
Coco Chanel’s favourite places, fuelled by the imaginary,<br />
and composed around freshness.<br />
Consistently, Les Eaux De Chanel was conceived<br />
with sustainability in mind. Its glass perfume<br />
bottles are thinner and lighter (compared to other<br />
Chanel Eaux de Toilette of the same size), which<br />
means a smaller volume of raw materials and<br />
optimized transport. Additionally, the corrugated<br />
cardboard that is normally hidden was<br />
transformed into clean, simple outer packaging<br />
whose lack of lamination or glossy coating makes<br />
it easier to recycle.<br />
Since <strong>2021</strong>, all of the 125 ml bottles in the Les Eaux<br />
De Chanel collection are topped with a biobased<br />
cap, which Chanel has developed in partnership<br />
with Sulapac (Helsinki). For two years, Chanel teams<br />
worked hand-in-hand with the Finnish start-up to create<br />
an unprecedented cap composed of three layers, made<br />
out of 91% biobased materials obtained from renewable<br />
resources and FSC certified wood chips (by-products of<br />
industrial side-streams).<br />
In keeping with the rigorous standards of the House of<br />
Chanel, every detail was carefully thought out, including<br />
the sensory nature of the material, its resistance to<br />
fluctuations in temperature, the unique sound the bottle<br />
makes when the cap is put on, the grip, and the depth of the<br />
satiny matte finish on the iconic double C engraving. It<br />
took no fewer than 48 tries to reach the final product.<br />
The project is part of a long-term, collaborative<br />
approach that puts sustainability at the centre of<br />
Chanel research and development.<br />
Sulapac was pleased to welcome Chanel,<br />
a leading brand representing the most<br />
demanding luxury segment, among its early<br />
investors in 2018.<br />
“Chanel is definitely one of the forerunners<br />
in the luxury industry as they want to invest in<br />
the latest sustainable material and technology<br />
innovations. We have set a very high-quality<br />
standard for our sustainable material, with<br />
an ambition to replace conventional plastics,”<br />
stated Suvi Haimi, CEO and Co-founder of<br />
Sulapac, on the announcement in 2018.<br />
Now, Haimi says: “This first product launch of our<br />
collaboration with Chanel, the biobased Les Eaux De<br />
Chanel cap made with Sulapac material, is a remarkable<br />
milestone for us. It proves that Sulapac meets the highest<br />
quality standards.” AT<br />
wwwsulapac.com<br />
Application News<br />
Sustainable packaging for plant-based milk<br />
JOI (Miami, Florida, USA), the rapidly growing clean label food company, is further shaping the alternative plant-based milk<br />
category with the announcement of their brand refresh and shift to 100 % sustainable packaging.<br />
“JOI was founded to reduce the impact of our milk consumption on the environment by finding a more sustainable solution to<br />
enjoy plant-based milk while significantly improving taste and elevating nutrition,” shared Co-Founder Tony Jimenez. “We are<br />
excited to transition to fully sustainable materials to further push our company to be the most sustainable plant-based milk<br />
company in the World.”<br />
By creating plant milk concentrates, JOI can offer a<br />
dramatically longer shelf life than their competitors and<br />
exponentially reduce the need to ship heavy water weight<br />
across the country, thereby reducing food waste from<br />
spoilage and cutting down on carbon emissions. The<br />
transition of all JOI product packaging to 100 % recyclable<br />
glass jars and fully compostable pouches is a major step<br />
for the company as it works towards a zero waste carbon<br />
footprint.<br />
The compostable pouches for the JOI Oat Milk Powder are made of wood pulp (paper and cellulose), as Tony Jimenez,<br />
Co-founder & Chief Evangelist of JOI told bioplastics MAGAZINE. The packaging film is FDA approved for use in direct food<br />
contact and is guaranteed to be free from the 10 priority allergens as described by Health Canada, as well as the FDA’s list of<br />
8 major food allergens. It is the first-ever dairy alternative packaging that will completely biodegrade in home and community<br />
composting, where accepted. One glass jar of JOI Plant Milk Concentrate makes up to seven quarts of plant-based milk, while<br />
the compostable pouch makes a gallon of plant-based milk, significantly reducing the amount of packaging that regular milk<br />
cartons would require for the same amount. MT<br />
www.addjoi.com<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 17
Applictions<br />
Carbon-neutral toothbrush<br />
GSK Consumer Healthcare (Brentford, UK), the worldleading<br />
consumer healthcare business, whose brands<br />
include Sensodyne, parodontax, Voltaren, and Advil, is<br />
contributing to raising sustainability standards in the oral<br />
care industry with its first carbon neutral toothbrush.<br />
GSKCH, which is due to separate into a new company next<br />
year, has found an innovative way to leverage renewable<br />
raw materials for high-performance oral care products<br />
– helping reduce the use of fossil fuels for virgin plastic.<br />
The company is piloting this with its Dr.BEST GreenClean<br />
toothbrush, which builds new sustainable handle technology<br />
onto its previous innovations with sustainable bristles and<br />
packaging.<br />
The Dr.Best GreenClean toothbrush handle is made from<br />
renewable cellulose and ‘tall oil’ – a wood-based bioplastic<br />
that is derived from pine, spruce, and birch trees in sustainable<br />
forests, and is being applied in oral care for the first time<br />
by GSKCH. It is a by-product of paper production and would<br />
otherwise be disposed of.<br />
The bristles are made of 100 %<br />
renewable castor oil (presumably<br />
a biobased polyamide MT),<br />
as already used in GSKCH’s<br />
Aquafresh and Dr.Best bamboo<br />
brushes.<br />
The product’s 100 % plasticfree<br />
packaging includes GSKCH’s<br />
innovative cellulose window (which<br />
is also made with renewable<br />
cellulose. The packaging can be<br />
completely disposed of through a<br />
wide range of municipal recycling<br />
schemes (depending on local<br />
systems).<br />
GSKCH has formed a<br />
partnership with ClimatePartner<br />
(Munich, Germany), Europe’s<br />
leading solution provider for<br />
corporate climate action, to<br />
analyse and minimise the carbon<br />
impact of the product and its<br />
manufacturing – reducing the<br />
carbon footprint of the brush<br />
by over 50 % compared to the<br />
standard Dr.Best toothbrush.<br />
The remaining footprint is<br />
offset through a communitybased<br />
ClimatePartner project<br />
in Madagascar. With offsetting<br />
being a secondary measure to the<br />
avoidance and reduction of carbon<br />
impact, GSKCH scientists are<br />
exploring ways to achieve carbon<br />
neutrality without offsetting in<br />
future oral care launches.<br />
GSKCH’s Dr.Best is Germany’s favourite manual<br />
toothbrush brand. The company – which holds an ambition<br />
to become the world’s most sustainable toothbrush<br />
manufacturer – already has global plans to apply the<br />
technology across other toothbrushes in its portfolio –<br />
including in its market-leading Sensodyne brand. It is<br />
working hard to increase the development of sustainable<br />
options across its oral care portfolio in recognition of<br />
growing global consumer preference for more sustainable<br />
products. A recent Nielsen study showed that 73 % of<br />
consumers say they would “change their consumption<br />
habits to reduce their impact on the environment.” [1]<br />
The launch of the carbon neutral toothbrush is another<br />
step in GSKCH’s ongoing sustainability journey in oral<br />
care, which began with the rollout of its first sustainably<br />
grown bamboo toothbrushes in September 2020 in Europe.<br />
This March it launched its first plastic-free toothbrush<br />
packaging, which included Sensodyne Pronamel and<br />
parodontax brushes in the US. Asia Pacific rollout of this<br />
commenced in Australia.<br />
The new carbon-neutral<br />
toothbrush is part of GSKCH’s<br />
overall mission to reduce the<br />
carbon it generates. The company<br />
has a two-pronged approach to<br />
carbon reduction. Firstly, it is<br />
reducing energy through more<br />
efficient manufacturing systems<br />
(including energy-efficient lights,<br />
heating systems, and motors; and<br />
the switching off of power when<br />
feasible). Secondly, it is investing<br />
in renewable energy for GSKCH<br />
sites – with a commitment for all<br />
to use 100 % renewable electricity<br />
by 2025. It is also working closely<br />
with suppliers to reduce the<br />
amount of carbon content in all<br />
of its materials and the overall<br />
amount of plastic used across<br />
the product portfolio.<br />
While it remains a part of GSK,<br />
GSKCH’s sustainability initiatives<br />
support GSK’s companywide<br />
commitment to achieve a netzero<br />
impact on climate and a<br />
positive impact on nature by<br />
2030, announced by CEO Emma<br />
Walmsley in November 2020. AT<br />
[1] global-sustainable-shoppersreport-2018.pdf<br />
(nielsen.com)<br />
www.gsk.com<br />
18 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Useful sample kit<br />
PositivePlastics is bridging the gap<br />
Materials<br />
Positive Plastics (Karjaa, Finland) recently launched its<br />
first sample kit, featuring plastic materials with a reduced<br />
environmental footprint: PCR, PIR, biobased, biocomposite<br />
and mass balanced plastics of various manufacturers.<br />
Positive Plastics, aims to convey a more accepting<br />
outlook on plastics to designers, engineers, and product<br />
managers. In October, they launched their first Positive<br />
Plastics Kit, an invaluable tool for materials understanding<br />
and communication between non-technical and technical<br />
team members.<br />
The founders, Efrat Friedland, Erik Moth-Müller, and<br />
Markus Paloheimo, experts, consultants, and educators<br />
in the materials and polymers field, created and curated<br />
a sample collection of various innovative, commercially<br />
available polymers. The kit holds Arkema, Biowert Industrie,<br />
Borealis, Lignin Industries, Mocom, Sappi, Sirmax, Stora<br />
Enso, Trinseo, UBQ, and UPM materials. The kit includes<br />
post-consumer recyclates (PCR), post-industrial recyclates<br />
(PIR), mass balanced grades, biobased grades, and biocomposites.<br />
All grades are suitable for injection molding to<br />
produce durable products, such as consumer electronics,<br />
home appliances, sports goods, automotive interiors,<br />
accessories, etc.<br />
Positive Plastics will continuously expand the kit as new<br />
responsible polymers reach the market.<br />
“Try to imagine your life without plastic” proposed Efrat,<br />
“not without plastic waste, but without products and services<br />
we have all grown to rely on in almost every aspect of our<br />
lives. It seems that we can’t get along without this material,<br />
but we must eliminate its waste and negative impact.”<br />
“Thinking positively about plastics,” adds Erik ”there<br />
are many new grades on the market that are composed<br />
of natural materials or recycled materials, or both….they<br />
can replace traditional, fossil-fuel based plastics in every<br />
industry and product imaginable. Sadly, very few designers<br />
and engineers are familiar with them. Our goal is to change<br />
that.”<br />
Besides presenting new materials, Positive Plastics<br />
offers a novel design of the plastic sample, no longer a<br />
flat, square, piece of plastic that reveals little about the<br />
material’s characteristics.<br />
“Our unique sample design portrays the material’s<br />
properties and its possible applications tangibly,” explains<br />
Markus. “Holding our sample, one can easily discover<br />
various surface structure options, different wall thicknesses,<br />
corners, hinges, fluidity indication, draft angle, shrinkage,<br />
warpage…so many features in one piece!”<br />
Positive Plastics will present a complimentary kit to<br />
one hundred brands and design agencies to encourage an<br />
informed choice of materials and sensible implementation.<br />
Kits will be available for purchase online.<br />
Positive Plastics is definitely a useful toolbox for<br />
discovering plastics with a positive impact. MT<br />
www.positiveplastics.eu<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 19
Applications<br />
100 % Plant Based, Labels and caps<br />
not included, not for commercial<br />
scale (Picture: The Coca-Cola<br />
Company)<br />
100 % biobased PET bottle<br />
Coca-Cola unveiled first prototypes<br />
The Coca Cola Company’s sustainable packaging<br />
journey crossed a major milestone in late October with<br />
the unveiling of its first-ever beverage bottle made<br />
from 100 % plant-based plastic, excluding the cap and label,<br />
that has been made using technologies that are ready for<br />
commercial scale. The prototype bottle comes more than<br />
a decade after the company’s PlantBottle debuted as the<br />
world’s first recyclable PET plastic bottle made with up to<br />
30 % plant-based material. A limited run of approximately<br />
900 of the prototype bottles has been produced.<br />
“We have been working with technology partners for<br />
many years to develop the right technologies to create a<br />
bottle with 100 % plant-based content — aiming for the<br />
lowest possible carbon footprint — and it’s exciting that we<br />
have reached a point where these technologies exist and<br />
can be scaled by participants in the value chain,” said Nancy<br />
Quan, Chief Technical and Innovation Officer, The Coca Cola<br />
Company.<br />
PET, the world’s most recycled plastic, comprises two<br />
molecules: approximately 30 % monoethylene glycol (MEG)<br />
and 70 % terephthalic acid (PTA). The original PlantBottle,<br />
introduced in 2009, includes MEG from sugarcane, but the<br />
PTA has been from oil-based sources until now. PlantBottle<br />
packaging looks, functions and recycles like traditional PET<br />
but has a lighter footprint on the planet and its resources.<br />
Coca-Cola’s new prototype plant-based bottle is made<br />
from plant-based paraxylene (bPX) – using a new process<br />
by Virent (Madison, Wisconsin, USA) – which has been<br />
converted to plant-based terephthalic acid (bPTA). As<br />
the first beverage packaging material resulting from bPX<br />
produced at demonstration scale, this new technology<br />
signals a step-change in the commercial viability of the<br />
biomaterial. The bPX for this bottle was produced using<br />
sugar from corn, though the process lends itself to flexibility<br />
in feedstock.<br />
The second breakthrough technology, which The Coca-<br />
Cola Company co-owns with Changchun Meihe Science<br />
& Technology (Changchun, Jilin, China), streamlines the<br />
bMEG production process and also allows for flexibility in<br />
feedstock, meaning more types of renewable materials<br />
can be used. Typically, bMEG is produced by converting<br />
sugarcane or corn into bioethanol as an intermediate,<br />
which is subsequently converted to bioethylene glycol. Now,<br />
sugar sources can directly produce MEG, resulting in a<br />
simpler process. UPM (Helsinki, Finland), the technology’s<br />
first licensee, is currently building a full-scale commercial<br />
facility in Germany to convert certified, sustainably sourced<br />
hardwood feedstock taken from sawmill and other wood<br />
industry side-streams to bMEG. This marks a significant<br />
milestone toward the commercialization of the technology.<br />
“The inherent challenge with going through bioethanol<br />
is that you are competing with fuel,” said Dana Breed,<br />
Global R&D Director, Packaging and Sustainability, The<br />
Coca-Cola Company. “We needed a next-generation MEG<br />
solution that addressed this challenge, but also one that<br />
could use second-generation feedstock like forestry waste<br />
or agricultural byproducts. Our goal for plant-based PET<br />
is to use surplus agricultural products to minimize carbon<br />
footprint, so the combination of technologies brought by<br />
the partners for commercialization is an ideal fit for this<br />
strategy.”<br />
In 2015, Coca-Cola unveiled its first prototype for a 100 %<br />
biobased PlantBottle at the Milan Expo using lab-scale<br />
production methods to produce bPX. This next-generation<br />
100 % plant-based bottle, however, has been made using<br />
new technologies to produce both biochemicals that make<br />
the bottle and are ready for commercial scaling.<br />
20 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
“Our goal is to develop sustainable solutions for the entire<br />
industry,” Breed said. “We want other companies to join us<br />
and move forward, collectively. We don’t see renewable or<br />
recycled content as areas where we want a competitive<br />
advantage.”<br />
Since introducing PlantBottle, Coca-Cola has allowed<br />
non-competitive companies to use the technology and<br />
brand in their products — from Heinz Ketchup to the fabric<br />
interior in Ford Fusion hybrid cars. In 2018, the company<br />
opened up the PlantBottle IP more broadly [1] to competitors<br />
in the beverage industry to scale up demand and drive down<br />
pricing.<br />
As part of its World Without Waste vision, Coca-Cola<br />
is working to make all its packaging more sustainable,<br />
including maximizing the use of recycled and renewable<br />
content while minimizing the use of virgin, fossil material.<br />
The company has pledged to collect back the equivalent of<br />
every bottle it sells by 2030, so none of its packaging ends<br />
up as waste and old bottles are recycled into new ones, to<br />
make 100 % of its packaging recyclable, and to ensure 50 %<br />
of its packaging comes from recycled material.<br />
This innovation supports the World Without Waste vision,<br />
specifically the recently announced target to use 3 million<br />
tons less of virgin plastic from oil-based sources by 2025.<br />
The Coca Cola Company will pursue this 20 % reduction<br />
by investing in new recycling technologies like enhanced<br />
recycling, packaging improvements such as light-weighting,<br />
alternative business models such as refillable, dispensed<br />
and fountain systems, as well as the development of new<br />
renewable materials.<br />
In Europe and Japan, Coca-Cola, with its bottling<br />
partners, aims to eliminate the use of oil-based virgin PET<br />
from plastic bottles altogether by 2030, using only recycled<br />
or renewable materials. While the majority of plastic<br />
packaging material will come from mechanically recycled<br />
content, some virgin material will still be needed to maintain<br />
quality standards. That’s why Coca-Cola is investing in and<br />
driving innovation to boost the supply of feedstock from<br />
renewable technologies as well as from enhanced recycling<br />
technologies. Enhanced recycling upcycles previously used<br />
PET plastics of any quality to high quality, food-grade PET.<br />
“We are taking significant steps to reduce the use of<br />
virgin, oil-based plastic, as we work toward a circular<br />
economy and in support of a shared ambition of net-zero<br />
carbon emissions by 2050,” Quan said. “We see plant-based<br />
plastics as playing a critical role in our overall PET mix in<br />
the future, supporting our objectives to reduce our carbon<br />
footprint, reduce our reliance on virgin fossil fuels and boost<br />
collection of PET in support of a circular economy.” MT/AT<br />
[1] Coca-Cola Expands Access to PlantBottle IP; https://www.cocacolacompany.com/news/coca-cola-expands-access-to-plantbottle-ip<br />
www.coca-colacompany.com<br />
COMPEO<br />
Leading compounding technology<br />
for heat- and shear-sensitive plastics<br />
Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />
With its new COMPEO Kneader series, BUSS continues<br />
to offer continuous compounding solutions that set the<br />
standard for heat- and shear-sensitive applications, in all<br />
industries, including for biopolymers.<br />
• Moderate, uniform shear rates<br />
• Extremely low temperature profile<br />
• Efficient injection of liquid components<br />
• Precise temperature control<br />
• High filler loadings<br />
Applications<br />
www.busscorp.com<br />
2015 Coca-Cola presented the first 100 % biobased<br />
PlantBottle Prototype using lab-scale production methods to<br />
produce bPX scale (Picture: The Coca-Cola Company)<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 21
Material News<br />
Flax/PLA biocomposite<br />
LANXESS (Cologne, Germany) recently introduced a new<br />
product in the Tepex range of continuous-fibre-reinforced<br />
thermoplastic composites. “We have combined fabrics<br />
made from natural flax fibres with biobased PLA as a matrix<br />
material and thereby developed a composite manufactured<br />
entirely from natural resources. We are now able to produce<br />
it to a level of quality suitable for large-scale production,”<br />
explains Stefan Seidel, head of Tepex research and<br />
development at Lanxess.<br />
Low-density flax fibres<br />
Flax fibres have a significantly lower density than glass<br />
fibres. Thus, the composites made with these fibres<br />
are noticeably lighter in weight than their glass-fibrereinforced<br />
counterparts. The flax fibres are used in the form<br />
of continuous-fibre reinforced fabrics. This enables the<br />
biocomposites to demonstrate the outstanding mechanical<br />
performance typical of Tepex, which is based mainly on the<br />
continuous flax yarns arranged in particular directions. The<br />
weight-specific stiffness of the biocomposite is comparable<br />
to that of the equivalent glass-fibre-reinforced material<br />
variants. Designing the composite components to suit the<br />
expected loads enables most of the force to be transferred<br />
via the continuous fibres. According to Seidel, “This ensures<br />
that the high strength and stiffness characteristic of fibrereinforced<br />
plastics are achieved.”<br />
To be used in cars, industry, electronics, and<br />
sports<br />
When coupled with transparent matrix plastics such as PLA,<br />
the reinforcing flax fabric yields surfaces with a brown natural<br />
carbon-fibre look. “This appearance highlights the natural<br />
origin of the fibres and the entire composite and creates added<br />
visual appeal in sporting goods, for example,” explains Seidel.<br />
In addition to sports equipment, the new biocomposite could<br />
be used in cars, such as for manufacturing interior parts, or<br />
in electronics for the production of such things as housing<br />
components.<br />
At Fakuma (12 th — 16 th October, Friedrichshafen, Germany)<br />
Lanxess showed bioplastics MAGAZINE a sample part made of<br />
a flax/PLA Tepex organo-sheet with astounding deep-drawratios<br />
for a woven fabric.<br />
Easy to recycle<br />
Like the variants of Tepex based solely on fossil raw materials,<br />
the new biocomposites can be completely recycled as purely<br />
thermoplastic systems as part of closed-loop material cycles.<br />
“Offcuts and production waste can be regranulated and<br />
easily injection-moulded or extruded, either alone or mixed<br />
with unreinforced or short-fibre reinforced compound new<br />
materials,” says Seidel.<br />
In the medium term, Lanxess is planning to use other<br />
biobased thermoplastics such as polyamide 11 and other<br />
natural and recycled fibres in the production of Tepex. MT<br />
www.tepex.com | https://lightweight-solutions.lanxess.com<br />
Reclaimed fibre project<br />
Green Dot Bioplastics (Emporia, Kansas, USA) and<br />
Mayco International (Sterling Heights, Michigan, USA) have<br />
partnered to reclaim trim and scrap fibres for Natural Fiber<br />
Reinforced Plastic (NFRP).<br />
Mayco International, an award-winning tier 1 automotive<br />
supplier, wanted a sustainable solution for waste produced<br />
during the manufacture of automotive components.<br />
Green Dot Bioplastics launched Terratek ® NFRP in 2020, a<br />
type of biocomposite using fibres such as hemp, jute, sisal,<br />
American Bamboo, and flax, instead of glass or carbon fibre.<br />
Together, the two companies developed an NFRP<br />
composite material using the trim and scrap fibres,<br />
removing them from the waste stream and expanding the<br />
lifespan of the original materials. “We wanted to find a<br />
better use of the waste stream from our latest natural fibre<br />
composite technologies,” said Mayco International Advanced<br />
Development Engineer Chris Heikkila. “We partnered up<br />
with Green Dot who specializes in bioresins & natural<br />
filled plastic products, because of their expertise & current<br />
natural filled product portfolio.”<br />
“We were excited when Mayco came to us looking for<br />
a solution to their waste issue,” Green Dot Director of<br />
Research & Development Mike Parker said. “They are<br />
committed to creating products that are environmentally<br />
responsible through sustainable, efficient processes which<br />
is exactly what we do at Green Dot.”<br />
Both Green Dot and Mayco International value<br />
environmental responsibility, sustainability, and innovation.<br />
The new material using Terratek NFRP technology aligns<br />
with those values, providing a sustainable alternative to<br />
carbon-based and traditional plastics. While they have<br />
similar physical properties, aesthetics, and chemical<br />
makeup, Terratek NFRP is lighter, quieter, and, in the case of<br />
this collaboration with Mayco International, reclaims fibres<br />
that would otherwise be disposed of as waste.<br />
Green Dot recently featured this new product at CAMX<br />
<strong>2021</strong> in Dallas. AT<br />
www.greendotbioplastics.com | https://maycointernational.com<br />
22 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
New biobased plasticizer<br />
Cargill (Wayzata, Minnesota, USA) is adding to its<br />
bioindustrial solutions portfolio with Biovero TM biobased<br />
plasticizer, which is used for a wide variety of product<br />
manufacturing applications such as flooring, clothing,<br />
wires, cables, and plastic films and sheets for its industrial<br />
customers throughout North America, with plans to expand<br />
the product globally.<br />
“As governments and consumers look to cut the use<br />
of phthalates due to potential health concerns, and<br />
overall demand for PVC products used in infrastructure<br />
expands globally, we’re anticipating a significant increase<br />
in plant-based product manufacturing across multiple<br />
categories,” said Kurtis Miller, managing director of<br />
Cargill’s bioindustrial business. “Biovero plasticizers are<br />
one of our contributions to a more sustainable supply<br />
chain in commercial manufacturing, which provides<br />
new applications for our renewable feedstocks while<br />
delivering more environmentally-conscious products to the<br />
marketplace.”<br />
The first application for Biovero plasticizers will be in<br />
the production of home and commercial flooring. Flooring<br />
manufacturers are seeing high performance with the plantbased<br />
product while meeting regulatory requirements and<br />
consumer demands for phthalate-free products.<br />
Biovero plasticizer’s plant-based qualities allow<br />
manufacturers to produce goods more efficiently than<br />
conventional plasticizers while reducing energy, scrap, and<br />
material usage. The plasticizer joins a diverse portfolio of<br />
Cargill Bioindustrial plant-based solutions, ranging from<br />
asphalt rejuvenation, adhesives and binders, wax, dielectric<br />
fluids, lubricants and paints, coatings and inks. AT<br />
www.cargill.com<br />
Material News<br />
New bio-filled polymer grades<br />
At Fakuma (October 12 th - 16 th , Friedrichshafen, Germany)<br />
Avient (Luxemburg) announced the launch of new biofilled<br />
polymer grades. This new offering strengthens its<br />
sustainable solutions portfolio and responds to customer<br />
needs. bioplastics MAGAZINE spoke to Deborah Sondag,<br />
Senior Marketing Manager, Specialty Engineered Materials<br />
at Avient.<br />
The new reSound NF bio-filled grades are based on<br />
polymers such as polypropylene (PP) with 15 to 20 % biobased<br />
filler. The filler is sourced from plant waste that would<br />
otherwise be landfilled, which in turn could release the<br />
greenhouse gas methane into the atmosphere if the landfill<br />
is not properly covered and managed.<br />
The new materials have a pleasing aesthetic compared<br />
to alternative natural fibre-filled polymer grades, are fully<br />
colourable, and can be formulated to meet various regulatory<br />
compliance standards, making them suitable for consumer<br />
applications such as household items and personal care<br />
products.<br />
One early adopter of the new materials is Turkish toothbrush<br />
brand, Difaş (Istanbul, Turkey). Looking to differentiate in the<br />
market and meet the desires of consumers, Difaş worked<br />
with Avient to develop a solution for toothbrush handles,<br />
combs, and hairbrush handles that utilizes natural fillers<br />
while also offering high-end colorability and durability.<br />
“The new bio-filled polymer from Avient has enabled us<br />
to reduce the carbon footprint of a range of our products by<br />
reducing the consumption of petroleum-based polymers.<br />
This has enabled us to work toward our sustainability goals,<br />
while bringing new competitive solutions to the market,” said<br />
Cevdet Yüceler Owner and Chairman of the Board at Difaş.<br />
“Demand is rising for consumer products that utilize more<br />
recycled and renewable materials. Avient material science<br />
experts are continuously developing innovative solutions that<br />
enable our customers to achieve their sustainability goals<br />
and reduce the overall impact on the world’s resources,” said<br />
Matt Mitchell, director, global marketing at Avient.<br />
“The bio-filled grades can also be made with ABS. But as<br />
of now, we are not using recycled PP, recycled ABS nor any<br />
biobased plastics as a matrix. But costumers are approaching<br />
us every day with different demands”, said Deborah Sondag.<br />
On July 1 st , 2020, PolyOne, a leading global provider of<br />
specialized polymer materials, services and sustainable<br />
solutions, had acquired the colour masterbatch businesses<br />
of Clariant and Clariant Chemicals India PolyOne had then<br />
announced that it has changed its name in Avient.<br />
www.avient.com<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 23
Materials<br />
Custom-made PHA<br />
formulations<br />
PHAradox makes the next step to custom PHA based development<br />
Helian Polymers (Belfeld, The Netherlands) positions<br />
itself as a bridge between raw material suppliers and<br />
converters. With its nearly fifteen years of experience<br />
in biopolymers it is uniquely suited to transform its<br />
industry and material knowledge into effective application<br />
development and help customers to go from idea to product<br />
and make the transition from traditional plastics to PHA<br />
based solutions.<br />
Through its new brand PHAradox, launched this summer,<br />
it has formed strategic partnerships with the likes of<br />
Tianan Biologic (China) and CJ BIO (South Korea) amongst<br />
others. With access to their products (various PHA family<br />
members) Helian Polymers is able to utilize these natural<br />
building blocks and create unique formulations designed<br />
to mimic properties of, say, PP and ABS. By copying, or at<br />
least approaching, the properties and thus the functionality<br />
of these materials the transition is easier to make and to<br />
communicate with converters and customers alike.<br />
Almost 2 years of R&D lab-scale compounding,<br />
combining various PHA grades like P3HB / PHBV / PHBHx<br />
and P3HB4HB including various fillers has resulted in<br />
dozens of potentially commercial grades with a wide variety<br />
of characteristics. By working closely with its customers<br />
Helian Polymers creates shared value with its unique and<br />
custom-made PHA based formulations. Both innovative<br />
startups and existing brands, looking for replacement<br />
materials, have found their way to Helian Polymers to<br />
discuss ideas and let them evolve to sustainable business<br />
Helian Polymers compound pilot line in Belfeld, The Netherlands<br />
cases. There are currently more than ten projects in<br />
active testing phases, varying from horticulture to leisure<br />
sportswear and from food packaging to tool casings.<br />
Operating from the south of the Netherlands, near the<br />
German border, Helian Polymers has its own in-house<br />
compounding pilot line, testing and warehousing facilities<br />
(entirely powered by solar energy, to keep in line with its<br />
environmentally conscious philosophy). Keeping everything<br />
under one roof ensures flexibility and a fast turnaround<br />
when it comes to the development of new biobased and<br />
biodegradable materials. MT<br />
www.helianpolymers.com<br />
The Maxado tool case injection moulding test at GL Plastics (Son, The Netherlands)<br />
with custom made PHA based PHAradox formulation by Helian Polymers. (Used with<br />
permission)<br />
24 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
fossil<br />
available at www.renewable-carbon.eu/graphics<br />
Refining<br />
Polymerisation<br />
Formulation<br />
Processing<br />
Use<br />
renewable<br />
Depolymerisation<br />
Solvolysis<br />
Thermal depolymerisation<br />
Enzymolysis<br />
Purification<br />
Dissolution<br />
Recycling<br />
Conversion<br />
Pyrolysis<br />
Gasification<br />
allocated<br />
Recovery<br />
Recovery<br />
Recovery<br />
conventional<br />
© -Institute.eu | <strong>2021</strong><br />
© -Institute.eu | 2020<br />
PVC<br />
EPDM<br />
PMMA<br />
PP<br />
PE<br />
Vinyl chloride<br />
Propylene<br />
Unsaturated polyester resins<br />
Methyl methacrylate<br />
PEF<br />
Polyurethanes<br />
MEG<br />
Building blocks<br />
Natural rubber<br />
Aniline Ethylene<br />
for UPR<br />
Cellulose-based<br />
2,5-FDCA<br />
polymers<br />
Building blocks<br />
for polyurethanes<br />
Levulinic<br />
acid<br />
Lignin-based polymers<br />
Naphtha<br />
Ethanol<br />
PET<br />
PFA<br />
5-HMF/5-CMF FDME<br />
Furfuryl alcohol<br />
Waste oils<br />
Casein polymers<br />
Furfural<br />
Natural rubber<br />
Saccharose<br />
PTF<br />
Starch-containing<br />
Hemicellulose<br />
Lignocellulose<br />
1,3 Propanediol<br />
polymer compounds<br />
Casein<br />
Fructose<br />
PTT<br />
Terephthalic<br />
Non-edible milk<br />
acid<br />
MPG NOPs<br />
Starch<br />
ECH<br />
Glycerol<br />
p-Xylene<br />
SBR<br />
Plant oils<br />
Fatty acids<br />
Castor oil<br />
11-AA<br />
Glucose Isobutanol<br />
THF<br />
Sebacic<br />
Lysine<br />
PBT<br />
acid<br />
1,4-Butanediol<br />
Succinic<br />
acid<br />
DDDA<br />
PBAT<br />
Caprolactame<br />
Adipic<br />
acid<br />
HMDA DN5<br />
Sorbitol<br />
3-HP<br />
Lactic<br />
acid<br />
Itaconic<br />
Acrylic<br />
PBS(x)<br />
acid<br />
acid<br />
Isosorbide<br />
PA<br />
Lactide<br />
Superabsorbent polymers<br />
Epoxy resins<br />
ABS<br />
PHA<br />
APC<br />
PLA<br />
available at www.renewable-carbon.eu/graphics<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
O<br />
OH<br />
HO<br />
OH<br />
HO<br />
OH<br />
O<br />
OH<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
HO<br />
OH<br />
O<br />
OH<br />
O<br />
OH<br />
© -Institute.eu | <strong>2021</strong><br />
All figures available at www.bio-based.eu/markets<br />
Adipic acid (AA)<br />
11-Aminoundecanoic acid (11-AA)<br />
1,4-Butanediol (1,4-BDO)<br />
Dodecanedioic acid (DDDA)<br />
Epichlorohydrin (ECH)<br />
Ethylene<br />
Furan derivatives<br />
D-lactic acid (D-LA)<br />
L-lactic acid (L-LA)<br />
Lactide<br />
Monoethylene glycol (MEG)<br />
Monopropylene glycol (MPG)<br />
Naphtha<br />
1,5-Pentametylenediamine (DN5)<br />
1,3-Propanediol (1,3-PDO)<br />
Sebacic acid<br />
Succinic acid (SA)<br />
© -Institute.eu | 2020<br />
nova Market and Trend Reports<br />
on Renewable Carbon<br />
The Best Available on Bio- and CO2-based Polymers<br />
& Building Blocks and Chemical Recycling<br />
Automotive<br />
Bio-based Naphtha<br />
and Mass Balance Approach<br />
Status & Outlook, Standards &<br />
Certification Schemes<br />
Bio-based Building Blocks and<br />
Polymers – Global Capacities,<br />
Production and Trends 2020 – 2025<br />
Polymers<br />
Carbon Dioxide (CO 2) as Chemical<br />
Feedstock for Polymers<br />
Technologies, Polymers, Developers and Producers<br />
Principle of Mass Balance Approach<br />
Building Blocks<br />
Feedstock<br />
Process<br />
Products<br />
Intermediates<br />
Use of renewable feedstock<br />
in very first steps of<br />
chemical production<br />
(e.g. steam cracker)<br />
Utilisation of existing<br />
integrated production for<br />
all production steps<br />
Allocation of the<br />
renewable share to<br />
selected products<br />
Feedstocks<br />
Authors: Michael Carus, Doris de Guzman and Harald Käb<br />
March <strong>2021</strong><br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Authors: Pia Skoczinski, Michael Carus, Doris de Guzman,<br />
Harald Käb, Raj Chinthapalli, Jan Ravenstijn, Wolfgang Baltus<br />
and Achim Raschka<br />
January <strong>2021</strong><br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Authors: Pauline Ruiz, Achim Raschka, Pia Skoczinski,<br />
Jan Ravenstijn and Michael Carus, nova-Institut GmbH, Germany<br />
January <strong>2021</strong><br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Chemical recycling – Status, Trends<br />
and Challenges<br />
Technologies, Sustainability, Policy and Key Players<br />
Production of Cannabinoids via<br />
Extraction, Chemical Synthesis<br />
and Especially Biotechnology<br />
Current Technologies, Potential & Drawbacks and<br />
Future Development<br />
Commercialisation updates on<br />
bio-based building blocks<br />
Plastic recycling and recovery routes<br />
Bio-based building blocks<br />
Evolution of worldwide production capacities from 2011 to 2024<br />
Primary recycling<br />
(mechanical)<br />
Virgin Feedstock Renewable Feedstock<br />
Monomer<br />
Polymer<br />
Plastic<br />
Product<br />
Secondary recycling<br />
(mechanical)<br />
Tertiary recycling<br />
(chemical)<br />
Secondary<br />
valuable<br />
materials<br />
CO 2 capture<br />
Chemicals<br />
Fuels<br />
Others<br />
Plant extraction<br />
Chemical synthesis<br />
Cannabinoids<br />
Plant extraction<br />
Genetic engineering<br />
Biotechnological production<br />
Production capacities (million tonnes)<br />
4<br />
3<br />
2<br />
1<br />
2011 2012 2013 2014 2015 2016 2017 2018 2019 2024<br />
Product (end-of-use)<br />
Quaternary recycling<br />
(energy recovery)<br />
Energy<br />
Landfill<br />
Author: Lars Krause, Florian Dietrich, Pia Skoczinski,<br />
Michael Carus, Pauline Ruiz, Lara Dammer, Achim Raschka,<br />
nova-Institut GmbH, Germany<br />
November 2020<br />
This and other reports on the bio- and CO 2-based economy are<br />
available at www.renewable-carbon.eu/publications<br />
Authors: Pia Skoczinski, Franjo Grotenhermen, Bernhard Beitzke,<br />
Michael Carus and Achim Raschka<br />
January <strong>2021</strong><br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Author:<br />
Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />
Updated Executive Summary and Market Review May 2020 –<br />
Originally published February 2020<br />
This and other reports on the bio- and CO 2-based economy are<br />
available at www.bio-based.eu/reports<br />
Levulinic acid – A versatile platform<br />
chemical for a variety of market applications<br />
Global market dynamics, demand/supply, trends and<br />
market potential<br />
HO<br />
O<br />
O<br />
OH<br />
diphenolic acid<br />
O<br />
O<br />
H 2N<br />
OH<br />
O<br />
levulinate ketal<br />
O<br />
OH<br />
O<br />
OH<br />
5-aminolevulinic acid<br />
O<br />
O<br />
O<br />
O<br />
levulinic acid<br />
OR<br />
levulinic ester<br />
O<br />
O<br />
ɣ-valerolactone<br />
OH<br />
HO<br />
H<br />
N<br />
O<br />
O<br />
O<br />
succinic acid<br />
5-methyl-2-pyrrolidone<br />
OH<br />
Succinic acid – From a promising<br />
building block to a slow seller<br />
What will a realistic future market look like?<br />
Pharmaceutical/Cosmetic<br />
Acidic ingredient for denture cleaner/toothpaste<br />
Antidote<br />
Calcium-succinate is anticarcinogenic<br />
Efferescent tablets<br />
Intermediate for perfumes<br />
Pharmaceutical intermediates (sedatives,<br />
antiphlegm/-phogistics, antibacterial, disinfectant)<br />
Preservative for toiletries<br />
Removes fish odour<br />
Used in the preparation of vitamin A<br />
Food<br />
Bread-softening agent<br />
Flavour-enhancer<br />
Flavouring agent and acidic seasoning<br />
in beverages/food<br />
Microencapsulation of flavouring oils<br />
Preservative (chicken, dog food)<br />
Protein gelatinisation and in dry gelatine<br />
desserts/cake flavourings<br />
Used in synthesis of modified starch<br />
Succinic<br />
Acid<br />
Industrial<br />
De-icer<br />
Engineering plastics and epoxy curing<br />
agents/hardeners<br />
Herbicides, fungicides, regulators of plantgrowth<br />
Intermediate for lacquers + photographic chemicals<br />
Plasticizer (replaces phtalates, adipic acid)<br />
Polymers<br />
Solvents, lubricants<br />
Surface cleaning agent<br />
(metal-/electronic-/semiconductor-industry)<br />
Other<br />
Anodizing Aluminium<br />
Chemical metal plating, electroplating baths<br />
Coatings, inks, pigments (powder/radiation-curable<br />
coating, resins for water-based paint,<br />
dye intermediate, photocurable ink, toners)<br />
Fabric finish, dyeing aid for fibres<br />
Part of antismut-treatment for barley seeds<br />
Preservative for cut flowers<br />
Soil-chelating agent<br />
Standards and labels for<br />
bio-based products<br />
Authors: Achim Raschka, Pia Skoczinski, Raj Chinthapalli,<br />
Ángel Puente and Michael Carus, nova-Institut GmbH, Germany<br />
October 2019<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Raj Chinthapalli, Ángel Puente, Pia Skoczinski,<br />
Achim Raschka, Michael Carus, nova-Institut GmbH, Germany<br />
October 2019<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
nova-Institut GmbH, Germany<br />
May 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
renewable-carbon.eu/publications<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 25
Materials<br />
Fill the gap, not the landfill<br />
Governments and institutions have been scrambling<br />
to rectify the global environmental disaster caused<br />
by the accumulation of plastic waste. This plastic<br />
waste comes in macroscopic forms such as bottles, plastic<br />
bags, and polyester clothing. In the best-case scenario, it is<br />
regulated and dumped into overcrowded landfills or in the<br />
worst case, it escapes into the open environment as litter<br />
directly endangering the health and safety of wildlife and<br />
local populations [1]. Alarmingly an even more insidious<br />
type of plastic, ‘microplastic’, or plastic waste so small it<br />
is invisible to the eye, has been making headlines as it can<br />
be found in the water, soil, and even inside of our bodies [1].<br />
The steps being taken to address this issue focus<br />
on banning specific single-use plastic items or their<br />
substitution with more sustainable alternatives (reusable,<br />
recyclable, or compostable). This is part of an overall shift<br />
from a linear economy to a circular economy. To accelerate<br />
this change, governments have passed their own single-use<br />
plastics bans or have committed themselves to initiatives<br />
such as the New Plastics Economy, Global Commitment led<br />
by the Ellen Macarthur Foundation (EMF) [2].<br />
The goal is to ‘build a circular economy around plastics’<br />
by initially setting strict goals around certain single-use<br />
plastic items for 2025. With these measures in place there<br />
is an incentive for building a future where plastics are either<br />
replaced and or are fully circular. In the meantime, there are<br />
still large gaps that need to be filled by addressing singleuse-items<br />
that fall outside of traditional packaging or<br />
consumer products. Personal protective equipment, sterile<br />
items, and chemically contaminated consumables are<br />
items that are not easily substituted with other materials as<br />
these applications require high-performance and durability<br />
that only plastics can currently provide. Additionally, these<br />
items have recyclability challenges due to contamination or<br />
are used in remote environments (such as for agricultural<br />
applications) where they cannot be efficiently collected [3].<br />
These items are usually landfilled or incinerated, both of<br />
which do not fall under the Ellen Macarthur Foundation’s<br />
definition of circular [2]. The current COVID-19 pandemic<br />
has only exacerbated this type of waste due to the significant<br />
increase of personal protective equipment (PPE) and sterile<br />
consumables. Sources have cited that over four million<br />
tonnes of polypropylene waste from PPE have been disposed<br />
of over the course of the pandemic and will continue to grow<br />
[3]. These hard to remediate items are important and will<br />
not disappear.<br />
A solution is to develop innovative materials and circular<br />
product design. Biodegradable and compostable plastics<br />
are viable options to tackle this problem, as they have<br />
the potential to match the performance needed for these<br />
applications [4]. On the other hand, some of these plastics<br />
display incomplete degradation ultimately leading to<br />
microplastics. To elevate degradable plastics into truly<br />
sustainable and viable alternatives major improvements<br />
and innovations are needed.<br />
Scientists have been designing materials that allow rapid<br />
degradation – much more efficient than their traditional<br />
counterparts. In addition, the onset of degradation can<br />
be controlled or triggered. In recent years, triggered<br />
degradation plastics that utilise hydrolytic enzymes<br />
have created attention in the media due to their speed of<br />
degradation and broad applicability. The idea of enzymes<br />
that can degrade plastic, particularly polyesters, is not new<br />
as the entire concept of microbial biodegradation hinges on<br />
this process.<br />
Scientists managed to remove the microbe from the<br />
picture by directly mixing the enzymatic material with the<br />
plastic – a sort of trojan horse plastic composite. Under the<br />
right conditions, degradation happens from the inside out for<br />
these novel plastics. Scientists around the world are working<br />
on developing and optimizing these materials. At Scion, a<br />
Crown Research Institute in New Zealand, researchers<br />
have been exploring how to design and manufacture these<br />
materials using solvent-free thermoplastic processing<br />
techniques. Being able to thermally process them is key to<br />
ensuring their viability commercially.<br />
Day 0 Day 3 Day 8<br />
26 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
By:<br />
Angelique Greene<br />
Kate Parker<br />
Scion<br />
Rotorua, New Zealand<br />
Materials<br />
One major issue to overcome when working with enzymes<br />
is that they denature when exposed to elevated temperatures<br />
outside of their optimal range of activity. However, certain<br />
solid-state commercial lipases (a type of enzyme) maintain<br />
activity in a solvent-free environment even when exposed<br />
to temperatures upwards of 130 °C [5]. This temperature<br />
range is ideal for lower melting point biodegradable<br />
plastics, meaning that the enzyme and the plastic can be<br />
compounded directly without any additional steps.<br />
To test this theory, the researchers 3D printed the<br />
enzymatic bioplastic into single and multi-material objects<br />
such as a hatching Kiwi bird (see pictures). These objects<br />
were then degraded resulting in total degradation after a 3<br />
to 8-day period and avoiding any microplastics formation.<br />
Being able to directly compound the enzyme with lower<br />
temperature bioplastics is certainly promising and a cheaper<br />
option, however, this direct compounding technique will not<br />
work for higher melting point bioplastics. Scion is currently<br />
exploring polymeric or inorganic supports to protect the<br />
enzyme during processing with high melting point plastics.<br />
A place where high-temperature processing could make<br />
a significant impact is by giving industrially relevant but<br />
problematic bioplastics like PLA the ability to degrade faster<br />
and to completion.<br />
Complementary to this work at Scion, the French startup,<br />
Carbios (Saint-Beauzire), has been working on utilising<br />
polyester degrading enzymes developed by Novozyme<br />
(Bagsværd, Denmark) to develop novel process-scale<br />
enzymatic recycling methods that are milder and more<br />
eco-friendly than conventional chemical recycling [6].<br />
Additionally, research groups at the University of California,<br />
Berkeley, have been looking at ways to improve the efficiency<br />
of the enzymes during degradation and investigating<br />
the mechanistic considerations of the process [7], and<br />
the Fraunhofer Institute for Applied Polymer Materials<br />
(Potsdam, Germany) has been working on processing these<br />
materials into films [8]. At the same time biotechnologists<br />
and enzymologists are working hard to engineer enzymes<br />
that are more efficient at degradation than currently<br />
available alternatives.<br />
This technology is just emerging and there are still<br />
scientitic challenges to be addressed. It will require a<br />
significant effort to get these technologies to a truly<br />
commercially ready stage. There will be no magic silver<br />
bullet to solve the issue of hard to remediate single-use<br />
plastic waste and it will take a multitude of approaches like<br />
the ones mentioned above and more traditional approaches<br />
such as consumer education and improvements to existing<br />
recycling technology.<br />
www.scionresearch.com<br />
References:<br />
[1] The Royal Society Te Apaarangi. (2019, July). Plastics in the Environment<br />
Te Ao Hurihuri – The Changing World. https://www.royalsociety.org.nz/<br />
assets/Uploads/Plastics-in-the-Environment-evidence-summary.pdf<br />
[2] Ellen Macarthur Foundation. (2020, February). New plastics economy<br />
global commitment commitments, vision and definitions. https://<br />
www.newplasticseconomy.org/assets/doc/Global-Commitment_<br />
Definitions_2020-1.pdf<br />
[3] Nghiem, L. D., Iqbal, H. M. N., & Zdarta, J. (<strong>2021</strong>). The shadow pandemic<br />
of single use personal protective equipment plastic waste: A blue<br />
print for suppression and eradication. Case Studies in Chemical and<br />
Environmental Engineering, 4, 100125. doi: https://doi.org/10.1016/j.<br />
cscee.<strong>2021</strong>.100125<br />
[4] European Environmental Agency. (<strong>2021</strong>, April). Biodegradable and<br />
compostable plastics challenges and opportunities. https://www.eea.<br />
europa.eu/publications/biodegradable-and-compostable-plastics/<br />
biodegradable-and-compostable-plastics-challenges<br />
[5] Greene, A. F., Vaidya, A., Collet, C., Wade, K. R., Patel, M., Gaugler,<br />
M., . . . Parker, K. (<strong>2021</strong>). 3D-Printed Enzyme-Embedded Plastics.<br />
Biomacromolecules, 22(5), 1999-2009. doi:10.1021/acs.biomac.1c00105<br />
[6] Enzymes. (<strong>2021</strong>, April 9). Carbios. https://www.carbios.com/en/enzymes/<br />
[7] New process makes ‘biodegradable’ plastics truly compostable |<br />
College of Chemistry. (<strong>2021</strong>, April 21). Berkeley College of Chemistry.<br />
https://chemistry.berkeley.edu/news/new-process-makes-<br />
%E2%80%98biodegradable%E2%80%99-plastics-truly-compostable-0<br />
[8] Fraunhofer Institute for Applied Polymer Research IAP. (<strong>2021</strong>, June 1).<br />
Enzymes successfully embedded in plastics. Press Release. https://<br />
www.fraunhofer.de/en/press/research-news/<strong>2021</strong>/june-<strong>2021</strong>/enzymessuccessfully-embedded-in-plastics.html<br />
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bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 27
From Science & Research<br />
By:<br />
Takumi Abe, Rikito Takashima, Hideyuki Otsuka, Daisuke Aoki<br />
Department of Chemical Science and Engineering, Tokyo Institute of Technology<br />
Takehiro Kamiya<br />
The Laboratory of Plant Nutrition and Fertilizers, Graduate School of Agricultural<br />
and Life Sciences, The University of Tokyo<br />
Choon Pin Foong, Keiji Numata<br />
Department of Material Chemistry, Graduate School of Engineering, Kyoto<br />
University<br />
B<br />
ioplastics can be chemically recycled into nitrogenrich<br />
fertilizers in a facile and environmentally<br />
friendly way, as recently demonstrated by<br />
scientists from the Tokyo Institute of Technology (Tokyo<br />
Tech). Their findings pave the way towards sustainable<br />
circular systems that simultaneously address issues such<br />
as plastic pollution, petrochemical resource depletion, and<br />
world hunger.<br />
To solve the plastic conundrum, circular systems need to<br />
be developed, in which the source materials used to produce<br />
the plastics come full circle after disposal and recycling. At<br />
the Tokyo Institute of Technology, a team of scientists led<br />
by Daisuke Aoki and Hideyuki Otsuka is pioneering a novel<br />
concept. In their new environmentally friendly process,<br />
plastics produced using biomass are chemically recycled<br />
back into fertilizers. This study was published in Green<br />
Chemistry [1], a journal of the Royal Society of Chemistry<br />
focusing on innovative research on sustainable and ecofriendly<br />
technologies.<br />
The team focused on poly (isosorbide carbonate), or<br />
PIC, a type of biobased polycarbonate that has garnered<br />
much attention as an alternative to petroleum-based<br />
polycarbonates. PIC is produced using a non-toxic material<br />
derived from glucose called isosorbide (ISB) as a monomer.<br />
The interesting part is that the carbonate links that join the<br />
ISB units can be severed using ammonia (NH 3<br />
) in a process<br />
known as ammonolysis. The process produces urea, a<br />
nitrogen-rich molecule that is widely used as a fertilizer.<br />
While this chemical reaction was no secret to science,<br />
few studies on polymer degradation have focused on the<br />
potential uses of all the degradation products instead of<br />
only the monomers.<br />
First, the scientists investigated how well the complete<br />
ammonolysis of PIC could be conducted<br />
in water at mild conditions (30 °C and<br />
atmospheric pressure). The rationale<br />
behind this decision was to avoid the<br />
use of organic solvents and excessive<br />
amounts of energy. The team carefully<br />
analyzed all the reaction products through<br />
various means, including nuclear<br />
magnetic resonance spectroscopy,<br />
the fourier transform infrared<br />
spectroscopy, and gel<br />
permeation chromatography.<br />
Although they managed to<br />
produce urea in this way, the<br />
degradation of PIC was not<br />
complete even after 24 hours,<br />
with many ISB derivatives still<br />
Biobased<br />
polymers<br />
to fertilizers<br />
present. Therefore, the researchers tried increasing the<br />
temperature and found that complete degradation could be<br />
achieved in about six hours at 90 °C. Daisuke Aoki highlights<br />
the benefits of this approach, “The reaction occurs without<br />
any catalyst, demonstrating that the ammonolysis of PIC<br />
can be easily performed using aqueous ammonia and<br />
heating. Thus, this procedure is operationally simple and<br />
environmentally friendly from the viewpoint of chemical<br />
recycling.”<br />
Finally, as a proof-of-concept that all PIC degradation<br />
products can be directly used as a fertilizer, the team<br />
conducted plant growth experiments with Arabidopsis<br />
thaliana, a model organism. They found that plants treated<br />
with all PIC degradation products grew better than plants<br />
treated with just urea.<br />
The overall results of this study showcase the feasibility<br />
of developing fertilizer-from-plastics systems (see<br />
picture). The systems can not only help fight off pollution<br />
and resource depletion but also contribute to meeting the<br />
world’s increasing food demands. Daisuke Aoki concludes<br />
on a high note, “We are convinced that our work represents<br />
a milestone toward developing sustainable and recyclable<br />
polymer materials in the near future. The era of bread from<br />
plastics is just around the corner!”<br />
Reference<br />
[1] Plastics to Fertilizers: Chemical Recycling of a Biobased Polycarbonate<br />
as a Fertilizer Source; Green Chemistry; Oct. <strong>2021</strong>; DOI: https://doi.<br />
org/10.1039/d1gc02327f<br />
www.titech.ac.jp/english | www.jst.go.jp/EN<br />
28 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
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bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 29
Recycling<br />
Merging high-quality recycling<br />
with lowered emissions<br />
Changing the way we think about plastics is a task facing<br />
the entire value chain, but the main focus still lies<br />
where a product’s life meets its smelly end’ – on waste<br />
management. While keeping an eye on the ongoing need to<br />
reduce climate impact, we also need to broaden our recycling<br />
technology horizons. Ultimately, high-quality recycling is what is<br />
going to be needed to make the plastics economy truly circular.<br />
The Newcycling ® process<br />
APK AG was founded in 2008 with the vision of producing pure<br />
polymers with properties close to virgin plastics from mixed<br />
plastic waste, including multilayer film waste. Researchers and<br />
engineers at APK have developed a physical recycling process<br />
that combines mechanical recycling steps with a targeted<br />
solvent-based step – their Newcycling technology.<br />
Where is this process positioned on the spectrum of<br />
plastics recycling technologies? A comprehensive overview of<br />
technological innovation is badly needed in order to understand<br />
which elements each technology branch (mechanical/<br />
advanced physical or chemical) can contribute to creating a<br />
circular economy for plastics – and how these processes can<br />
complement each other.<br />
Recycling technology delineation<br />
APK’s technology is a physical (also referred to as material)<br />
recycling technology. The molecular structure of the polymer is<br />
kept intact, as is the case in standard mechanical recycling. This<br />
is the major difference in comparison to chemical processes.<br />
Recently, the delineation of innovative recycling processes has<br />
begun to become more refined and therefore clearer. The use of<br />
a solvent does not automatically designate the recycling process<br />
as being chemical. There are innovative approaches on both<br />
the physical side of the spectrum (dissolution, etc.) and on the<br />
chemical side (for example, solvolysis).<br />
Because physical, solvent-based recycling does not break<br />
down molecular chains, no energy needs to be invested in repolymerisation<br />
– one reason for the low carbon footprint of<br />
recyclates produced via such technology.<br />
Newcycling consists of the following steps:<br />
Waste from PA/PE multi-layer film production is first<br />
mechanically pre-treated, undergoing, among other things,<br />
shredding and classification. Next, the PE layer is dissolved and<br />
liquefied in a solvent bath, leading to separation of the polymers<br />
and polymer layers.<br />
The undissolved PA is then separated from the dissolved<br />
PE using conventional solid-liquid separation technology and<br />
the polymers are subsequently further processed in separate<br />
material streams.<br />
The PA is introduced into a twin-screw extruder, where it<br />
passes through various process sections and is processed into<br />
a high-quality PA melt, using very high dispersion performance<br />
and intensive devolatilization. Finally, it is pelletized into firstclass<br />
PA recyclates.<br />
Any remaining contaminants in the liquefied PE, such<br />
as degraded additives, inks, etc. are removed (purification).<br />
Then an additive package is added (re-additivation). Following<br />
pre-evaporation, the PE is likewise introduced into a twinscrew<br />
extruder, together with the solvent. There, intensive<br />
devolatilization of the liquid takes place, which has been<br />
precisely calibrated for this application so that even when PE/<br />
solvent ratios fluctuate, first-class results will be produced.<br />
The solvent is completely volatilized and added back into the<br />
Newcycling process in a closed loop. The PE remains in the form<br />
of a homogeneous, high-quality melt, which is then pelletized.<br />
The resulting PE recyclate is of a quality similar to that of virgin<br />
plastics.<br />
In April <strong>2021</strong>, the renowned recyclability certifier ARGE<br />
cyclos/HTP (Aachen, Germany) audited APK’s recycling facility<br />
in Merseburg, Germany, for conformance with the EuCertPlast<br />
certification scheme. The audit focussed on the suitability of<br />
APK’s plants for the recycling of post-consumer waste from<br />
plastic films as well as of waste from PE/PA multilayer film<br />
production. All test requirements were successfully fulfilled<br />
and in July <strong>2021</strong>, ARGE cyclos/HTP awarded APK the official<br />
EuCertPlast certificate.<br />
Recycing technology delineation (© APK)<br />
30 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
The recyclate products<br />
The two fully commercialized recyclate products created in<br />
Merseburg are marketed as Mersalen ® (LDPE) and Mersamid ®<br />
(PA). Both recyclate types have been certified with the flustix<br />
RECYCLED sustainability seal, ensuring that they meet DIN<br />
standards for recyclate content.<br />
Mersamid PA recyclates are suitable for a number of<br />
applications – from simple dowels and cable binders to<br />
sophisticated sports gear or parts in the automotive segment. A<br />
recent example of products made with APK’s PA recyclates are<br />
the fastening hooks on outdoor equipment company VAUDE’s<br />
ReCycle pannier. For these hooks, VAUDE (Tettnang, Germany)<br />
required a recycled material that could withstand high loads<br />
under a wide variety of outdoor conditions as well as provide<br />
outstanding durability. To account for design-relevant factors,<br />
it was also necessary to ensure that the material had good<br />
colouring capability.<br />
Mersalen LDPE recyclates provide a very high level of purity<br />
and are transparent in colour. They can be used in a number<br />
of flexible packaging applications. A recent example is APK’s<br />
collaboration with Huhtamaki (Ronsberg, Germany), where<br />
recycled content was introduced into their PBL tubes. A total<br />
of 19 % of the material was replaced with recyclates from APK.<br />
The tubes are suitable for such applications as facial and body<br />
cosmetics. Moreover, the PBL tubes, including recycled content,<br />
have been certified recyclable by EuCertPlast.<br />
When it comes to climate impact, the carbon footprint of<br />
APK’s recyclates is an average of 66 % lower than that of their<br />
virgin plastics version.<br />
The future: scaling Newcycling across the EU<br />
Based on its industrial-scale plant in Merseburg and its<br />
successfully commercialized products, APK is planning to scale<br />
its Newcycling technology across the EMEA region. Newcycling<br />
technology is able to valorize a broad feedstock base, including<br />
post-industrial and post-consumer sources, whether in the<br />
form of multilayer film waste or mixed unsorted plastic streams.<br />
In collaboration with initial partners from the plastics industry,<br />
planning is underway for the construction of additional plants<br />
for the processing of post-consumer waste in the very near<br />
future. With an initial focus on LDPE, APK is already working<br />
on additional recyclate solutions, such as PP, HDPE, and other<br />
PCR streams.<br />
www.apk-ag.de/en<br />
By:<br />
Hagen Hanel<br />
Head of Plastics Recycling Innovation Center<br />
APK AG.<br />
Merseburg, Germany<br />
Product<br />
examples –<br />
Mersalen:<br />
Huhtamaki<br />
PBL tube,<br />
2020 (top right)<br />
Mersamid,<br />
VAUDE pannier,<br />
<strong>2021</strong> (bottom).<br />
Mersalen (LDPE) recyclate produced with<br />
APK’s Newcycling technology<br />
Recycling<br />
Newcycling – the closest loop back into packaging (© APK)<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 31
Recycling<br />
By:<br />
Fig. 2: small scarf containing 50 % Recycled PAN<br />
S. Schonauer & T. Gries<br />
Institute of Textile Technology,<br />
RWTH Aachen University<br />
Aachen, Germany<br />
Upcycling<br />
process for<br />
PAN from<br />
textile waste<br />
Most synthetic fibres are made from fossil material<br />
sources. Since these are only available in finite<br />
quantities and their use is not always compatible<br />
with today’s environmental goals, it is necessary to develop<br />
an innovative recycling process and close material cycles.<br />
Currently, polyacrylonitrile (PAN)-containing waste from<br />
production and end-of-use waste is sent for thermal<br />
waste treatment, used as a filler, or processed into lowvalue<br />
blended yarns. Although energy recovery is possible,<br />
incineration also releases harmful emissions, and the<br />
material can no longer be fed into a cycle. [1] At ITA of RWTH<br />
Aachen University, approaches to the chemical recycling<br />
of PAN fibres are being pursued under the project name<br />
industrial RePAN, as a step towards closed-loop economy.<br />
The technical feasibility along the entire process chain from<br />
polymer recovery and fibre production up until the finished<br />
product (blankets) is being mapped.<br />
Assuming that newly acquired products replace old<br />
textiles, around 24,500 tonnes of end-of-use waste is<br />
annually generated in the house and home textiles sector<br />
in Germany. Even if only half of this waste could be recycled,<br />
it would offer 12,250 tonnes of new resources. During the<br />
production of PAN staple fibres, about 1 % by weight, and<br />
additionally during processing up to 10 % by weight, of fibre<br />
materials are generated as production waste [2, 3]. This<br />
type of waste served as a secondary raw material source<br />
for these research trials.<br />
The individual stages of the process are presented in<br />
Figure 1, starting with the collection of textile waste from<br />
the blanket production. The waste is dissolved in DMSO<br />
(dimethyl sulphoxide) and chemically precipitated to<br />
produce RePAN-pellets.<br />
During the preparation of the spinning solution, RePANpellets<br />
are mixed with new PAN-powder to equal parts,<br />
resulting in a 50 %- RePAN solution. These fibres with 50 %<br />
recycled material could be spun into yarns that could meet<br />
the same requirements as virgin material.<br />
These characteristics of the produced RePAN fibres<br />
therefore, lead to the assumption that an industrial<br />
feasibility of recycled fibres is possible. The scientists are<br />
now proofing the processability of the yarns and upscale<br />
to semi-industrial scale. Figure 2 shows a product using<br />
RePAN fibres.<br />
[1] Gries, T.: Fibre-tables based on P.-A. Koch, Polyacrylic fibres, 6. <strong>Issue</strong>,<br />
2002<br />
[2] Herbert, C. (Research and development at Dralon GmbH): Interview,<br />
25.05.2016<br />
[3] Rensmann, R. (managing director of Hermann Biederlack GmbH + Co<br />
KG): Interview, 25.05.2016<br />
www.ita.rwth-aachen.de<br />
Fig. 1: Recycling<br />
process from<br />
waste to new<br />
yarn<br />
Textile waste<br />
RePAN-pellets<br />
Spinning solution<br />
Staple fibres<br />
32 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Patent situation<br />
Europe and USA are leading innovation in plastic recycling<br />
and alternative plastics globally, patent data shows<br />
Report<br />
From a global perspective, Europe and the USA are<br />
leading innovation in plastic recycling and alternative<br />
plastics technologies, i.e. renewable carbon plastics,<br />
a new study published in October by the European Patent<br />
Office (EPO, headquartered in Munich, Germany) shows.<br />
Europe and the USA each accounted for 30 % of patenting<br />
activity worldwide in these sectors between 2010 and 2019,<br />
or 60 % combined. Within Europe, Germany posted the<br />
highest share of patent activity in both plastic recycling and<br />
bioplastic technologies (8 % of global total), while France,<br />
the UK, Italy, the Netherlands and Belgium stand out for<br />
their higher specialisation in these fields.<br />
Titled Patents for tomorrow’s plastics: Global innovation<br />
trends in recycling, circular design and alternative sources<br />
[1], the study presents a comprehensive analysis of the<br />
innovation trends for the period 2010 to 2019 that are<br />
driving the transition to a circular economy for plastics. The<br />
report looks at the number of international patent families<br />
(IPFs), each of which represents an invention for which<br />
patent applications have been filed at two or more patent<br />
offices worldwide (so-called high-value inventions). It aims<br />
to provide a guide for business leaders and policymakers<br />
to direct resources towards promising technologies, to<br />
assess their comparative advantage at different stages of<br />
the value chain, and to highlight innovative companies and<br />
institutions that could contribute to long-term sustainable<br />
growth.<br />
Chemical and biological recycling methods with<br />
the highest number of patents<br />
The study highlights that of all recycling technologies,<br />
the fields of chemical and biological recycling methods<br />
generated the highest level of patenting activity in the period<br />
under review. These methods accounted for 9,000 IPFs in<br />
2010–19, double the number filed for mechanical recycling<br />
(4,500 IPFs). While the patenting of standard chemical<br />
methods (such as cracking and pyrolysis) reached a peak<br />
in 2014, emerging technologies such as biological methods<br />
using living organisms (1,500 IPFs) or plastic-to-monomer<br />
recycling (2,300 IPFs) now offer new possibilities to degrade<br />
polymers and produce virgin-like plastics.<br />
Healthcare and cosmetics & detergent<br />
industries lead in bioplastic innovation<br />
In the area of bioplastic inventions, the study finds that the<br />
healthcare sector has by far the most patenting activity in<br />
total (more than 19,000 IPFs in 2010–19), despite accounting<br />
for less than 3 % of the total demand for plastics in Europe.<br />
However, the cosmetics and detergents sector has the<br />
largest share of its patenting activity in bioplastics, with the<br />
ratio of bioplastics IPFs to conventional plastics IPFs being<br />
1:3, compared to 1:5 in the healthcare sector. Packaging,<br />
electronics and textiles are also significant contributors to<br />
innovation in bioplastics.<br />
CO 2<br />
based plastics<br />
Finally, with regard to alternative plastics technologies,<br />
the report also looks at the role of plastics production<br />
from CO 2<br />
, which has been launched by a small number<br />
of companies, mainly from Europe – such as Covestro in<br />
Germany – and South Korea and can play an important role<br />
on the road to the circular economy. MT<br />
[1] Patents for tomorrow’s plastics: Global innovation trends in recycling,<br />
circular design and alternative sources;<br />
Download from www.bioplasticsmagazine.de/<strong>2021</strong><strong>06</strong>/PATENTS.pdf<br />
www.epo.org<br />
Source: European Patent Office<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 33
Opinion<br />
Natural PHA materials<br />
The most versatile materials platform in the world?<br />
By:<br />
Jan Ravenstijn<br />
Board member of GO!PHA<br />
Advisory board member of AMIBM<br />
Meerssen, The Netherlands<br />
Guo-Qiang (George) Chen<br />
Advisory board member of GO!PHA<br />
Tsinghua University<br />
Beijing, China<br />
We think that natural PHA materials show a much<br />
larger application versatility than any other existing<br />
material platforms can mimic. The reason for this<br />
thought is that natural PHA materials are already used in<br />
nature for many purposes and for much longer than the<br />
existence of mankind.<br />
PHA stands for Polyhydroxyalkanoate of which there can<br />
be an infinite number of different moieties. So it’s nonsense<br />
to claim properties for PHA, because different PHAmolecules<br />
have different properties. Even the well-known<br />
polylactic acid (PLA) and polycaprolactone (PCL) belong to<br />
the PHA group of materials.<br />
However, a number of PHA-materials are naturally<br />
occurring materials, like PHB and a number of its<br />
copolymers like PHBV, PHBHx, P3HB4HB, PHBO, and<br />
PHBD. These materials are not plastics, but are natural<br />
materials made and found in nature, like cellulose or starch<br />
[1].<br />
These natural macromolecular materials are not<br />
made by polymerization, but by enzymatically controlled<br />
biochemical conversion of naturally occurring nutrients<br />
(sugars, vegetable oils, starches, etc.) and they all have a<br />
role to play in nature.<br />
These natural PHAs are part of the metabolism in all<br />
living organisms (plants, animals, and humans) since<br />
the beginning of life on earth. They function as nutritious<br />
and energy storage materials, so they are supposed to be<br />
used for that purpose. One can call that biodegradation,<br />
but one could also call that feed for living organisms<br />
in every environment. In addition, they can fully meet a<br />
comprehensive combination of end-of-life options, unlike<br />
most other material platforms [2].<br />
Today, these bio-benign materials are made at industrial<br />
scale, just by mimicking nature. Many manufacturing<br />
capacity expansions are planned and built, especially in<br />
Asia/Pacific and North America. The materials appear to be<br />
excellent candidates for a very large variety of applications<br />
in thermoplastics, thermosets, elastomers, lubricants,<br />
glues, adhesives, but also in several non-traditional polymer<br />
applications like animal feed, cell regeneration in humans<br />
and animals, denitrification, and cosmetics for instance.<br />
Without further ado, we present a limited number of<br />
applications that have been successfully developed and<br />
already use these PHA materials:<br />
1.Traditional thermoplastic applications<br />
During the past ten years manufacturing companies have<br />
invested billions of dollars to develop and build significant<br />
capacity to make natural PHA-materials at industrial<br />
scale. Simultaneously, applications were developed using<br />
these materials, focussing primarily on applications where<br />
biodegradability in many environments was seen to be an<br />
advantage and added value.<br />
Indeed, the natural PHA-materials are feed for living<br />
organisms in every environment, so they biodegrade<br />
(= carbon conversion to CO 2<br />
) in every environment, albeit<br />
the rate of biodegradation depends on part geometry and<br />
external conditions like temperature, humidity, and others<br />
[3].<br />
The result of the BioSinn project [4], on request of the<br />
German Federal Ministry of Food and Agriculture, describes<br />
25 product-market combinations where biodegradation is a<br />
viable end-of-life option. Biodegradability is an advantage<br />
when it is difficult or even impossible to separate plastics<br />
from organic materials that are destined for home or<br />
industrial composting and when it is challenging or<br />
(Photo: MAIP)<br />
(Photo: Nuez Lounge Bio ® )<br />
34 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
prohibitively expensive to avoid fragments ending<br />
up in the open environment or to remove them<br />
after use.<br />
Natural PHA-based end products<br />
that are currently in the market are<br />
for instance coffee capsules, waste<br />
bags, mulch films, clips, non-wovens,<br />
film for food packaging, microplastics<br />
in cosmetics, and natural<br />
PHA coated paper for coffee cups.<br />
The last application has also been<br />
accepted as recyclable by the paper<br />
industry. There are many more<br />
application opportunities according<br />
to the BioSinn report. Currently, the<br />
main challenge is the total global<br />
manufacturing capacity of these natural PHA-materials,<br />
but many new plant constructions are underway.<br />
(Photo: Prodir)<br />
That biodegradability is not the only Unique Selling Point<br />
(USP) to talk about has been made clear by a compounding<br />
company that significantly elevated the science level and<br />
knowledge base for natural PHA-materials [5]. They develop<br />
new PHA-compounds that are 100 % bio-based, have high<br />
temperature resistance, are easy to process, and are tailormade<br />
for a large variety of durable applications.<br />
This compounding company has developed more than<br />
500 different natural PHA-based formulations from stiff to<br />
extremely flexible, thermal resistance up to 130 °C, weather<br />
and UV resistance, fast nucleation from the melt, and<br />
improved barrier properties, demonstrating that natural<br />
PHA-materials can be turned into a new series of biotechnopolymers<br />
that can be processed at as fast as or even<br />
faster than the currently used polymers in the industry for<br />
all conversion technologies currently in use.<br />
Today we see compounders using a combination<br />
of different natural PHA-materials to make them the<br />
only polymers in compounds for film or 3D printing<br />
for instance, while they were often used as additives<br />
in combination with PBAT or PLA a few years ago. The<br />
availability of high molecular weight amorphous and/or<br />
very low crystallinity PHA grades (like P3HB4HB with<br />
50 % 4HB or PHBHx with 30 % Hx) offer the opportunity<br />
(Photo: Ohmie by Krill Design)<br />
to blend low and high E-modulus grades to control<br />
properties.<br />
Several examples of these so-called bio-technopolymers<br />
have been demonstrated and are used in applications for<br />
spectacle cases (replacing ABS or PP Talc), pens (replacing<br />
ABS), design chairs (replacing GFR-PP), lamps, electrical<br />
light switches (replacing PC/ABS), etc. The design chair has<br />
an injection moulded core of a 12 kg shot weight made in a<br />
2,500 tonnes injection moulding machine. The chair comes<br />
in several colours.<br />
Also, some natural PHA-materials with low E-modulus<br />
have been developed for use in hot melt adhesives, pressure<br />
sensitive adhesives, and laminating adhesives & sealants.<br />
So far, the use is still limited due to the low manufacturing<br />
Opinion<br />
generic picture<br />
(Photo: Reef Interest)<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 35
Opinion<br />
capacities, but this is a matter of time. Several materials<br />
are used for matting agents in coatings to replace silica and<br />
resulting in much better transparency and haptic properties<br />
(soft feel). These haptic properties are one of the USPs of<br />
these materials.<br />
Finally, due to the enormous amount of plastic microfibres<br />
ending up in our oceans every year many parties<br />
are actively involved in developing fibres from natural<br />
PHA-materials for both woven (textiles) and non-woven<br />
applications. Although the first applications are on the<br />
market, it is still small and application developments are in<br />
an early stage, especially for textile applications. There are<br />
fibres for textile applications on the market, but those are<br />
based on compounds that also contain other polymers in<br />
addition to natural PHA-material, so far.<br />
2. Non-traditional plastic applications<br />
Several non-traditional plastic applications have been<br />
developed and result in business, given the long-known<br />
role and appearance of natural PHA-materials in natural<br />
habitats. One could consider applications in animal feed,<br />
medical care (both humans and animals), denitrification,<br />
artificial turf, and cosmetics for instance.<br />
Denitrification is required when there is too much<br />
ammonia in a certain environment (wastewater treatment,<br />
aquaria, shrimp, fish and turtle farms, etc.). Ammonia<br />
turns into nitrates and nitrites by oxidation. Natural PHAmaterials<br />
are an excellent carbon source to reduce the<br />
nitrates and nitrites to nitrogen or N 2<br />
because through<br />
biodegradation it provides the carbon for this denitrification<br />
process. Today, material is being sold for these applications.<br />
A completely different segment is to use natural PHAmaterials<br />
for medical applications. Within the human<br />
body one can use microspheres for the cultivation of stem<br />
cells. These have a degradation time of about one year,<br />
while the degradation product helps cell growth. They can<br />
be used for bone/cartilage regeneration, skin damage<br />
repair (wound closures), nerve guidance conduits, among<br />
others. Scaffoldings made from such materials have been<br />
demonstrated to take care of bone repair, but also repair<br />
of a damaged oesophagus. The company Tepha (Lexington,<br />
Massachusetts, USA) makes several products for the<br />
abovementioned purposes for about 10 years and Medpha<br />
(Beijing, China) is also active in this field and further extends<br />
it. One of the newer applications is to use these materials<br />
for controlled drug delivery.<br />
Artificial sports fields like those for soccer always use a<br />
filler. Although often ground old car tires have been used<br />
for this application for a while, it has become unacceptable<br />
for health and environmental safety reasons. Today also<br />
natural PHA materials are used for artificial turf infill (FIFA<br />
approved).<br />
PHB and other natural PHA-materials are or can be used<br />
as feed or feed additives for animals:<br />
Feeding PHB to aquatic organisms has been well studied<br />
[6, 7], confirming that PHB had a positive impact on<br />
growth, survival, intestinal microbial structure, and disease<br />
resistance of aquatic animals, serving as an energy source<br />
for European sea bass Dicentrarchus labrax juveniles [7],<br />
helping to increase the lipid content of the whole body [6].<br />
PHB was also used as an alternative to antibiotics for<br />
protecting shrimps from pathogenic Vibrio campbelli [8], it<br />
was observed to induce heat shock protein (Hsp) expression<br />
and contribute partially to the protection of shrimp against V.<br />
campbelli [9], improving the growth performance, digestive<br />
enzyme activity, and function of the immune system of<br />
rainbow trout [9], enhancing the body weights of Chinese<br />
mitten crab Eriocheir sinensis juveniles [10].<br />
PHB also improved the survival of prawn Macrobrachium<br />
rosenbergii larvae [11], blue mussel Mytilus edulis larvae<br />
[12] and Nile tilapia Oreochromis niloticus juveniles [13].<br />
PHB can not only affect marine organisms but also large<br />
livestock. The feed composition shapes the gut bacterial<br />
communities and affects the health of large livestock [14,<br />
15].<br />
It is concluded that PHB has no negative effect on the<br />
growth of marine animals like large yellow croakers and<br />
popular land animals like weaned piglets with sensitivity to<br />
foods. In the future, plastics made of PHB, perhaps including<br />
its copolymers PHBV and P3HB4HB, can be used again as<br />
feed additives for animals. More positively, plastics made<br />
of natural PHA-materials could replace petrochemical<br />
plastics to avoid the death of marine or land animals that<br />
mistakenly consume plastic packaging garbage [16].<br />
Based on the origin of this natural PHA-materials<br />
platform and on the application examples discussed here,<br />
we are convinced that this new material platform is a<br />
sleeping giant [5] with a very promising future.<br />
www.gopha.org<br />
References:<br />
[1] Michael Carus, Which polymers are “natural polymers” in the sense of<br />
single-use plastic ban?, Open letter to DG Environment signed by 18<br />
scientific experts, 8 October 2019.<br />
[2] Jan Ravenstijn and Phil Van Trump, What about recycling of PHApolymers?,<br />
bioplastics MAGAZINE, Volume 15, 03/20, 30-31.<br />
[3] Bruno De Wilde, Biodegradation: one concept, many nuances,<br />
Presentation at the 2 nd PHA-platform World Congress, 22 September<br />
<strong>2021</strong>.<br />
[4] Verena Bauchmüller et.al., BioSinn: Products for which biodegradation<br />
makes sense, Report from nova Institute and IKT-Stuttgart, 25 May<br />
<strong>2021</strong>.<br />
[5] Eligio Martini, The compounding will be the success of the Sleeping<br />
Giant, Presentation at the 2 nd PHA-platform World Congress, 22<br />
September <strong>2021</strong>.<br />
[6] Najdegerami, E. H. et.al., Aquacult. Res. 2015, 46, 801-812.<br />
[7] De Schryver, P. et.al., Appl. Microbiol. Biotechnol. 2010, 86, 1535-1541.<br />
[8] Defoirdt, T., Halet, D., Vervaeren, H., Boon, N., Van de Wiele, T.,<br />
Sorgeloos, P., Bossier, P., Verstraete, W., Environ. Microbiol. 2007, 9,<br />
445-452.<br />
[9] Baruah, K. et.al., Sci. Rep. 2015, 5, 9427.<br />
[10] Sui, L. et.al., Ma, G., Aquacult. Res. 2016, 47, 3644-3652.<br />
[11] Thai, T. Q. et.al., Appl. Microbiol. Biotechnol. 2014, 98, 5205-5215.<br />
[12] Hung, N. V. et.al., Aquaculture 2015, 446, 318-324.<br />
[13] Situmorang, M. L. et.al., Vet. Microbiol. 2016, 182, 44-49.<br />
[14] Lalles, J. P. et.al., Proc. Nutr. Soc. 2007, 66, 260-268.<br />
[51] Ma, N. et.al., Front Immunol. 2018, 9.<br />
[16] Wang, X. et.al., Biotechnol J. 2019, e1900132.<br />
36 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
7 th PLA World Congress<br />
EARLY JUNE 2022 MUNICH › GERMANY<br />
organized by<br />
Call for papers is now open<br />
www.pla-world-congress.com<br />
PLA is a versatile bioplastics raw material from renewable<br />
resources. It is being used for films and rigid packaging, for<br />
fibres in woven and non-woven applications. Automotive,<br />
consumer electronics and other industries are thoroughly<br />
investigating and even already applying PLA. New methods<br />
of polymerizing, compounding or blending of PLA have<br />
broadened the range of properties and thus the range of<br />
possible applications. That‘s why bioplastics MAGAZINE is<br />
now organizing the 7 th PLA World Congress on:<br />
Early June 2022 in Munich / Germany<br />
Experts from all involved fields will share their knowledge<br />
and contribute to a comprehensive overview of today‘s<br />
opportunities and challenges and discuss the possibilities,<br />
limitations and future prospects of PLA for all kind<br />
of applications. Like the five previous congresses the<br />
7 th PLA World Congress will also offer excellent networking<br />
opportunities for all delegates and speakers as well as<br />
exhibitors of the table-top exhibition. Based on the good<br />
experices with the hybrid format (bio!TOY and PHA World<br />
Congress <strong>2021</strong>) we will offer this format also for future<br />
conferences, hoping the pandemic does no longer force us<br />
to. So the participation at the 7 th PLA World Congress will<br />
be possible on-site as well as online.<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 37
Basics<br />
Cellulose<br />
A needed shift towards a sustainable biobased circular economy and<br />
the role of cellulose in it<br />
Residue<br />
producer<br />
Storage &<br />
Logistics<br />
Biomass<br />
digaestion<br />
Direct<br />
utilisation<br />
Sustainability<br />
assessment<br />
(e.g. LCA)<br />
Lignocellulose<br />
Nutrients /<br />
valuables<br />
Food<br />
sections<br />
Fibre and<br />
textile<br />
production<br />
Food<br />
production<br />
Agricultural<br />
production<br />
End products<br />
Textile<br />
Food<br />
Agriculture<br />
Figure 1: New value<br />
chains based on<br />
biogenic residues<br />
for textile, food<br />
and agricultural<br />
industries in<br />
INGRAIN<br />
Overview of possibilities presented by utilization<br />
of cellulose<br />
Cellulose is one of the most important scaffold formers<br />
in the biosphere and an abundant raw material with highly<br />
interesting properties to science and industry. Cellulose is<br />
formed by linkages of single D-glucose building blocks. It<br />
is considered 100 % biodegradable [2], semi crystalline [3],<br />
and can be chemically modified. As cellulose is the primary<br />
component of plant-based cell walls, it can be found in<br />
high weight percentages especially in wood and cotton but<br />
also in crops such as corn and wheat to name a few known<br />
examples, that are currently in technical use. [4] However,<br />
from an ecological point of view, the use of potential food<br />
crops or cotton is not sustainable in the long run, as<br />
precious space and resources that would otherwise have<br />
been used for the food or textile industry, now has to be<br />
converted for technical use. [5] Various pioneers took the<br />
mission to focus on sustainable biobased solutions and<br />
shifted from using primary cellulose feedstocks to utilizing<br />
readily available waste materials such as various straw and<br />
grass types, wood chips, and chaff which indicates the shift<br />
from 1 st generation to 2 nd generation feedstocks, enabled by<br />
physical or chemical biomass transformation technologies<br />
such as Steam Explosion, Soda-, Kraft-, Organosolv, and<br />
the holistic Organocat process. [6–9]<br />
Focusing on the rapidly expanding research and product<br />
development worldwide over the past decade, the current<br />
knowledge of cellulose and its chemistry including the use<br />
of derivatives are found in well-known products such as<br />
coatings, films, membranes, building materials, textiles,<br />
composite materials and biobased polymers. [10]<br />
While direct plant fibres are easily accessible for the textile<br />
industry the need for refined materials with customizable<br />
properties are of higher interest. Pure cellulose can be<br />
industrially found predominantly in form of paper pulp or<br />
chemical pulp. Depending on whether the pulp is intended<br />
for regeneration or derivatization, each field requires its<br />
own set of processes. While paper pulp tolerates higher<br />
impurities such as lignin and hemicellulose the chemical<br />
pulp also known as dissolving grade pulp is mainly defined<br />
through its high cellulose quality. Due to its susceptibility<br />
to certain chemicals, cellulose can be effectively<br />
functionalized in processes such as etherification, nitration,<br />
acetylation, and xanthation. Cellulose ethers can be used<br />
as food additives, binders, and glues. The well-known<br />
nitrocellulose for film bases from the early 20 th century<br />
can be made via nitration. Cellulose acetates are used<br />
as filaments in cigarette filters or mouldings, and films.<br />
Xanthation is one step especially well known through the<br />
viscose process, heavily used in the textile industry. The<br />
highly versatile viscose process is one way to generate<br />
filaments, staple fibres, cords and yarns as well as<br />
cellophane films, sponges, and casings. Other processes<br />
that are of importance in regard to regeneration are Cupro,<br />
Lyocell/Tencell, Vulcanized fibre as well as Loncell that are<br />
of importance in the textile industry. Among others, the<br />
regenerated cellulose finds application in apparel-, home-,<br />
and technical textiles. Technical textiles include geo-agro<br />
textiles, insulation and composite materials. [11, 12]<br />
Since cellulose consists of single unit glucose molecules,<br />
the possible use cases once biotechnology comes into play<br />
are enormous. With enzymes being able to break down<br />
cellulose and organisms being able to process glucose to<br />
platform chemicals, the path to future biobased plastics is<br />
accessible.<br />
By far the best-known platform chemical known to date is<br />
ethanol. Bioethanol has been in the spotlight for the last few<br />
decades with multiple companies, investing in commercial<br />
facilities to process either lignocellulose, starch or sugar<br />
in ethanol that can be used in fuel mixing to produce e.g.<br />
the E20 high-performance biofuel mixture. Other uses for<br />
biobased ethanol include bio-PE or MEG (monoethylene<br />
glycol) e.g.to produce bio-PET or PEF.<br />
Other important platform-chemicals are succinic<br />
acid, levulinic acid, 3-hydropropionic acid, furfural,<br />
hydroxymethylfurfural (5 HMF), and lactic acid.<br />
Through these platform chemicals, polymers such as<br />
polylactic acid (PLA) and Polybutylene succinate (PBS) can<br />
38 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Figure 1: Overview of a<br />
simplified cellulose value chain<br />
from biomass<br />
Basics<br />
be synthesized. PLA originates from lactic acid while PBS<br />
has its origin from succinic acid as a building block.<br />
Under certain conditions these biopolymers are<br />
biodegradable and thus interesting to the food, packaging,<br />
agro- and textile industry especially. On the other hand,<br />
drop-in solutions such as polyethylene furanoate (PEF)<br />
from bio-MEG and 5 HMF based FDCA present a suitable<br />
option for the industry as PEF is currently known to be a<br />
perfect replacement of polyethylene terephthalate (PET).<br />
[13-15]<br />
Sources:<br />
[1] https://ingrain.nrw/<br />
[2] https://renewable-carbon.eu/publications/product/biodegradablepolymers-in-various-environments-%E2%88%92-graphic-pdf/<br />
[3] M. Mariano, N.E. Kissi, A. Dufresne, J. Polym. Sci. Part B: Polym. Phys.,<br />
2014, 52: 791-8<strong>06</strong>.<br />
[4] C. Ververis, K. Georghiou, N. Christodoulakis, P. Santas, R. Santas, J.<br />
Ind. Crop. 2004, 3, 245-254<br />
[5] Eisentraut, A., IEA Energy Papers, 2010, No. 2010/01, OECD Publishing,<br />
Paris<br />
[6] H-Z. Chen, Z-H. Liu, Biotechnol. J. 2015, 10, 6, 866-885<br />
[7] D. Montane, X. Farriol, J. Salvado, P. Jollez, E.Chornet, Biomass and<br />
Energy, 1998, 14, 3, 241-276<br />
[8] A. Johansson, O. Aaltonen, P. Ylinen, Biomass, 1987, 13, 1, 45-65<br />
[9] P.M. Grande, J. Viell, N.Theyssen, W. Marquardt, P. D. Maria, W. Leitner,<br />
Green Chem., 2015,17, 3533-3539<br />
[10] Nova-Institute GmbH, Industrial Material Use of Biomass in Europe<br />
2015,<br />
[11] Strunk, Peter. “Characterization of cellulose pulps and the influence of<br />
their properties on the process and production of viscose and cellulose<br />
ethers.” (2012).<br />
[12] Seisl S., Hengstmann R., Manmade Cellulosic Fibres (MMCF)—A<br />
Historical Introduction and Existing Solutions to a More Sustainable<br />
Production. In: Matthes A., Beyer K., Cebulla H., Arnold M.G., Schumann<br />
A. (eds) Sustainable Textile and Fashion Value Chains. Springer, Cham.<br />
(2020)<br />
[13] Biopolymers- Facts and statistics, Institute for Bioplastics and Bio<br />
composites, 2018<br />
[14] McAdam, B., Brennan Fournet, M., McDonald, P., & Mojicevic, M. (2020).<br />
Polymers, 12(12), 2908<br />
[15] S. Saravanamurugan, A. Pandey, R. S. Sangwan, Biofuels, 2017, 51-67<br />
www.ita.rwth-aachen.de<br />
INGRAIN, short for “Spitze im Westen: Innovationsbündnis<br />
Agrar-Textil-Lebensmittel” (Innovation Alliance – Agro-Textile-Nutrition)<br />
has a set goal to upcycle residual streams to<br />
valuables and nutrition. Since the approval by the German<br />
Federal Ministry of Education and Research (BMBF) in<br />
late August <strong>2021</strong>, the project focuses on and around the<br />
westernmost administrative district in Germany, the rural<br />
district of Heinsberg (State: North Rhine-Westphalia), which<br />
has been characterized by various structural changes for<br />
decades including the decline of the formerly formative<br />
textile industry, end of coal mining, including its regional<br />
neighbourhood. With a possible funding capped at EUR 15<br />
million for a duration of 6 years, INGRAIN focuses to create<br />
a biobased circular economy within that project region.<br />
The program will be self-governed by the key consortium<br />
creating a new approach to fast-track projects that are of<br />
high importance to the overall goal. The key consortium<br />
consists of the Wirtschaftsförderungsgesellschaft für den<br />
Kreis Heinsberg mbH, Institute of Textile technology and<br />
Chair for Information Management in Material Engieering<br />
of the RWTH Aachen University, Niederrhein University of<br />
Applied Sciences Mönchengladbach as well as Rhine-Waal<br />
University of Applied Sciences Kleve. In this program, cellulose<br />
among other important resources is of high interest<br />
due to the mass flux within and around the project region.[1]<br />
By:<br />
Sea-Hyun, Lee<br />
Scientific Assistant<br />
Institut für Textiltechnik RWTH Aachen University<br />
Aachen, Germany<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 39
Automotive<br />
10<br />
Years ago<br />
Published in<br />
bioplastics MAGAZINE<br />
Opinion<br />
By<br />
Stefano Facco<br />
New Business Development Director<br />
Novamont SpA<br />
Novara, Italy<br />
The Future of the<br />
Shopping Bag in Italy<br />
Are newly developed, biodegradable and<br />
compostable polymers the ideal solution?<br />
C<br />
urrently we are facing a quite chaotic debate about the ideal<br />
solution for the incredible amount of disposable shopping<br />
bags used by consumers today. Recycling, environmental<br />
impact, re-use, littering and especially marine litter are<br />
some of the main keywords arising when this important topic is<br />
discussed.<br />
Some facts related to the use of such bags are quite impressive.<br />
In Italy, some 300 bags per year per capita are used, which<br />
corresponds roughly to 25% of the total European consumption,<br />
and corresponding to 100 billion units. About 2/3 of these products<br />
are imported from countries such as China, Indonesia or Thailand,<br />
where many of them are being produced under conditions which<br />
are not allowed in Europe. This creates an unfair competitive<br />
advantage. The recycling quota of post-consumer shopping bags<br />
is below 1% on a world-wide level, albeit in some countries the<br />
collection rate is much higher, but not all collected bags end up<br />
in recycling.<br />
At this point, I feel that beside the environmental discussion<br />
about raw materials and products, we should strongly bear<br />
in mind the fact that right now the plastic converting industry,<br />
especially the European companies producing bags and sacks,<br />
are not facing easy times. The competing converters, mainly<br />
located in the Asia/Pacific area, quite often accept commercial<br />
conditions which may be described as dumping conditions (on<br />
an EU level, only a few years ago, some anti-dumping measures<br />
were taken). Especially in the southern European region, where<br />
most of the European production was located, more and more<br />
medium and small size companies are struggling to survive.<br />
Taking these aspects into account, it really may be considered<br />
a natural reaction to somehow strengthen again our European<br />
industry by converting new families of polymers (also produced in<br />
the EU) locally. A fair competition would arise again, and the basis<br />
for a healthy economic growth.<br />
Furthermore, the use of renewable resources combined with<br />
the property of being B&C (biodegradable and compostable)<br />
would, in addition to the aspects related to the growth of local<br />
companies, help us to better deal with the scarcity of fossil raw<br />
materials and to add new end-of-life options such as the organic<br />
recycling of polymers.<br />
The new Italian decree, which came in force on January 1 st ,<br />
2011, imposing the use of B&C shopping bags, somehow<br />
perfectly supported the three major aspects I have described<br />
above: the strengthening of local or European enterprises,<br />
the use of renewable resources (as most of the polymers<br />
available on the market do contain a significant amount of<br />
renewable raw materials (RRMs)) and their compostability,<br />
which finally offers an end-of-life option which may help<br />
the Italian composting industry to get rid of some of the<br />
100,000 tonnes of plastic film pollutants sieved out during<br />
the composting process itself.<br />
The incredible speed with which major Italian B&C polymer<br />
producers (such as Novamont) and other European groups<br />
(such as BASF) were able to increase production capacity has<br />
enabled most of the traditional shopping bag converters to<br />
switch to these new materials in order to satisfy the growing<br />
market request. Due to the high technological level of these<br />
materials, the production switch was immediately carried out<br />
without loss of time and without additional investment.<br />
22 bioplastics MAGAZINE [<strong>06</strong>/11] Vol. 6<br />
40 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
Automotive<br />
In November 2011, Stefano Facco,<br />
New Business Development Director,<br />
Novamont, said:<br />
Ten years ago, plastic bags were one of the main<br />
topics of discussion in Europe. In 2011 Italy paved<br />
the way to implement legislation banning single-use<br />
plastic bags and allowing only very thick reusable<br />
ones and compostable singl-use ones. A few years<br />
later the European Union applied a very similar Plastic<br />
Bags Directive.<br />
Films|Flexibles|Bags<br />
In the last ten years, in Italy, the consumption of<br />
carrier bags heavily decreased (-58 % between 2010<br />
and 2020 [1]), the quantity and quality of organic recycling<br />
improved (Italy collects around 47 % of biowaste<br />
against the 16 % European average [2] ) and the compostable<br />
plastics value chain grew (2,775 employees<br />
and a turnover of 815 million Euros [3]), allowing the<br />
development of a virtuous model, an example of circular<br />
bioeconomy, with the production of high-quality<br />
compost.<br />
In 2020 Biorepack started its activity, the world’s<br />
first National Consortium for the biological recycling<br />
of compostable plastics. It is the first European-wide<br />
system of extended responsibility to manage the end<br />
of life of certified compostable packaging.<br />
This circular bioeconomy model of a European MS<br />
is now ready to be extended as well to foodserviceware<br />
and compostable packaging.<br />
www.novamont.com<br />
Major groups such as Matrica (ENI/Novamont JV),<br />
Roquette, Cereplast and other companies started, or<br />
have announced, huge investments in the production of<br />
monomers, intermediates and polymers based on RRMs or<br />
in compounding facilities. Therefore, the coming into force<br />
of this new decree not only boosted once more the optimism<br />
of local converters, but it also helped to attract huge<br />
investments in future-oriented technologies such as fully<br />
integrated biorefineries.<br />
References:<br />
[1] Plastic Consult, <strong>2021</strong>, La filiera dei polimeri compostabili. Dati<br />
2020 e prospettive<br />
[2] BIC and Zero Waste Europe, Bio-waste generation in the EU:<br />
Current capture levels and future potential<br />
[3] Plastic Consult, <strong>2021</strong>, La filiera dei polimeri compostabili. Dati<br />
2020 e prospettive<br />
Briefly summarizing the positive outcome of the new<br />
situation that we are experiencing in Italy, we may affirm<br />
that the composting industry is easily able to handle the<br />
increase and treatment of the new compostable shopping<br />
bags. Retailers have reduced consumption of shopping<br />
bags in general by 30% to 50%, which may be considered<br />
environmentally beneficial, converters are again increasing<br />
their production and replacing partially imported products,<br />
and new industrial investments have proven that investors<br />
believe firmly in the future of these new technologies.<br />
tinyurl.com/shoppingbags2011<br />
www.novamont.com<br />
bioplastics MAGAZINE [<strong>06</strong>/11] Vol. 6 23
Basics<br />
Glossary 5.0 last update issue <strong>06</strong>/<strong>2021</strong><br />
In bioplastics MAGAZINE the same expressions appear again<br />
and again that some of our readers might not be familiar<br />
with. The purpose of this glossary is to provide an overview<br />
of relevant terminology of the bioplastics industry, to avoid<br />
repeated explanations of terms such as<br />
PLA (polylactic acid) in various articles.<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different kinds<br />
of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable plastics<br />
according to EN13432 or similar standards (the<br />
focus is the compostability of the final product;<br />
biodegradable and compostable plastics can<br />
be based on renewable (biobased) and/or nonrenewable<br />
(fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
Advanced Recycling | Innovative recycling<br />
methods that go beyond the traditional mechanical<br />
recycling of grinding and compoundig<br />
plastic waste. Advanced recycling includes<br />
chemical recycling or enzyme mediated recycling<br />
Aerobic digestion | Aerobic means in the presence<br />
of oxygen. In →composting, which is an<br />
aerobic process, →microorganisms access the<br />
present oxygen from the surrounding atmosphere.<br />
They metabolize the organic material to<br />
energy, CO 2<br />
, water and cell biomass, whereby<br />
part of the energy of the organic material is released<br />
as heat. [bM 03/07, bM 02/09]<br />
Anaerobic digestion | In anaerobic digestion,<br />
organic matter is degraded by a microbial<br />
population in the absence of oxygen<br />
and producing methane and carbon dioxide<br />
(= →biogas) and a solid residue that can be<br />
composted in a subsequent step without practically<br />
releasing any heat. The biogas can be<br />
treated in a Combined Heat and Power Plant<br />
(CHP), producing electricity and heat, or can be<br />
upgraded to bio-methane [14]. [bM <strong>06</strong>/09]<br />
Amorphous | Non-crystalline, glassy with unordered<br />
lattice.<br />
Amylopectin | Polymeric branched starch molecule<br />
with very high molecular weight (biopolymer,<br />
monomer is →Glucose). [bM 05/09]<br />
Since this glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (tinyurl.com/bpglossary).<br />
[bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is →Glucose). [bM 05/09]<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from →biomass. When making a biobasedclaim,<br />
the unit (→biobased carbon content,<br />
→biobased mass content), a percentage and the<br />
measuring method should be clearly stated [1].<br />
Biobased carbon | Carbon contained in or<br />
stemming from →biomass. A material or product<br />
made of fossil and →renewable resources<br />
contains fossil and →biobased carbon.<br />
The biobased carbon content is measured via<br />
the 14 C method (radiocarbon dating method) that<br />
adheres to the technical specifications as described<br />
in [1,4,5,6].<br />
Biobased labels | The fact that (and to<br />
what percentage) a product or a material is<br />
→biobased can be indicated by respective labels.<br />
Ideally, meaningful labels should be based<br />
on harmonised standards and a corresponding<br />
certification process by independent third-party<br />
institutions. For the property biobased such<br />
labels are in place by certifiers →DIN CERTCO<br />
and →TÜV Austria who both base their certifications<br />
on the technical specification as described<br />
in [4,5]. A certification and the corresponding<br />
label depicting the biobased mass content was<br />
developed by the French Association Chimie du<br />
Végétal [ACDV].<br />
Biobased mass content | describes the amount<br />
of biobased mass contained in a material or<br />
product. This method is complementary to the<br />
14<br />
C method, and furthermore, takes other chemical<br />
elements besides the biobased carbon into<br />
account, such as oxygen, nitrogen and hydrogen.<br />
A measuring method has been developed<br />
and tested by the Association Chimie du Végétal<br />
(ACDV) [1].<br />
Biobased plastic | A plastic in which constitutional<br />
units are totally or partly from →<br />
biomass [3]. If this claim is used, a percentage<br />
should always be given to which extent<br />
the product/material is → biobased [1].<br />
[bM 01/07, bM 03/10]<br />
Biodegradable Plastics | are plastics that are<br />
completely assimilated by the → microorganisms<br />
present a defined environment as food<br />
for their energy. The carbon of the plastic must<br />
completely be converted into CO 2<br />
during the microbial<br />
process.<br />
The process of biodegradation depends on the<br />
environmental conditions, which influence it<br />
(e.g. location, temperature, humidity) and on the<br />
material or application itself. Consequently, the<br />
process and its outcome can vary considerably.<br />
Biodegradability is linked to the structure of the<br />
polymer chain; it does not depend on the origin<br />
of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard, for example, is ISO or in Europe:<br />
EN 14995 Plastics - Evaluation of compostability<br />
- Test scheme and specifications.<br />
[bM 02/<strong>06</strong>, bM 01/07]<br />
Biogas | → Anaerobic digestion<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2].<br />
Biorefinery | The co-production of a spectrum<br />
of biobased products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass. [bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers.<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause health<br />
problems, because it behaves like a hormone.<br />
Therefore, it is banned for use in children’s<br />
products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of →greenhouse gas<br />
emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based on a →<br />
Life Cycle Assessment. The CO 2<br />
equivalent of a<br />
specific amount of a greenhouse gas is calculated<br />
as the mass of a given greenhouse gas<br />
multiplied by its → global warming potential<br />
[1,2,15]<br />
Carbon neutral, CO 2<br />
neutral | describes a<br />
product or process that has a negligible impact<br />
on total atmospheric CO 2<br />
levels. For example,<br />
carbon neutrality means that any CO 2<br />
released<br />
when a plant decomposes or is burnt is offset<br />
by an equal amount of CO 2<br />
absorbed by the<br />
plant through photosynthesis when it is growing.<br />
Carbon neutrality can also be achieved by buying<br />
sufficient carbon credits to make up the difference.<br />
The latter option is not allowed when<br />
communicating → LCAs or carbon footprints<br />
regarding a material or product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of-life).<br />
42 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
If an assessment of a material, however, is<br />
conducted (cradle-to-gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life cycle<br />
has to be clarified [1].<br />
Cascade use | of →renewable resources means<br />
to first use the →biomass to produce biobased<br />
industrial products and afterwards – due to<br />
their favourable energy balance – use them<br />
for energy generation (e.g. from a biobased<br />
plastic product to → biogas production). The<br />
feedstock is used efficiently and value generation<br />
increases decisively.<br />
Catalyst | Substance that enables and accelerates<br />
a chemical reaction<br />
CCU, Carbon Capture & Utilisation | is a broad<br />
term that covers all established and innovative<br />
industrial processes that aim at capturing<br />
CO2 – either from industrial point sources or<br />
directly from the air – and at transforming it<br />
into a variety of value-added products, in our<br />
case plastics or plastic precursor chemicals.<br />
[bM 03/21, 05/21]<br />
CCS, Carbon Capture & Storage | is a technology<br />
similar to CCU used to stop large amounts of<br />
CO2 from being released into the atmosphere,<br />
by separating the carbon dioxide from emissions.<br />
The CO2 is then injecting it into geological<br />
formations where it is permanently stored.<br />
Cellophane | Clear film based on →cellulose.<br />
[bM 01/10, <strong>06</strong>/21]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also the<br />
most common polysaccharide (multi-sugar)<br />
[11]. Cellulose is a polymeric molecule with<br />
very high molecular weight (monomer is →Glucose),<br />
industrial production from wood or cotton,<br />
to manufacture paper, plastics and fibres.<br />
[bM 01/10, <strong>06</strong>/21]<br />
Cellulose ester | Cellulose esters occur by<br />
the esterification of cellulose with organic acids.<br />
The most important cellulose esters from<br />
a technical point of view are cellulose acetate<br />
(CA with acetic acid), cellulose propionate (CP<br />
with propionic acid) and cellulose butyrate (CB<br />
with butanoic acid). Mixed polymerisates, such<br />
as cellulose acetate propionate (CAP) can also<br />
be formed. One of the most well-known applications<br />
of cellulose aceto butyrate (CAB) is the<br />
moulded handle on the Swiss army knife [11].<br />
Cellulose acetate CA | → Cellulose ester<br />
CEN | Comité Européen de Normalisation (European<br />
organisation for standardization).<br />
Certification | is a process in which materials/<br />
products undergo a string of (laboratory) tests<br />
in order to verify that they fulfil certain requirements.<br />
Sound certification systems should be<br />
based on (ideally harmonised) European standards<br />
or technical specifications (e.g., by →CEN,<br />
USDA, ASTM, etc.) and be performed by independent<br />
third-party laboratories. Successful<br />
certification guarantees a high product safety<br />
- also on this basis, interconnected labels can<br />
be awarded that help the consumer to make an<br />
informed decision.<br />
Circular economy | The circular economy is a<br />
model of production and consumption, which<br />
involves sharing, leasing, reusing, repairing,<br />
refurbishing and recycling existing materials<br />
and products as long as possible. In this way,<br />
the life cycle of products is extended. In practice,<br />
it implies reducing waste to a minimum.<br />
Ideally erasing waste altogether, by reintroducing<br />
a product, or its material, at the end-of-life<br />
back in the production process – closing the<br />
loop. These can be productively used again and<br />
again, thereby creating further value. This is a<br />
departure from the traditional, linear economic<br />
model, which is based on a take-make-consume-throw<br />
away pattern. This model relies<br />
on large quantities of cheap, easily accessible<br />
materials, and green energy.<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM <strong>06</strong>/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under →composting conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timeframe. To make<br />
accurate and specific claims about compostability,<br />
the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards exist<br />
for clearer definitions, for example, EN 14995<br />
Plastics - Evaluation of compostability - Test<br />
scheme and specifications. [bM 02/<strong>06</strong>, bM 01/07]<br />
Composting | is the controlled →aerobic, or oxygen-requiring,<br />
decomposition of organic materials<br />
by →microorganisms, under controlled<br />
conditions. It reduces the volume and mass<br />
of the raw materials while transforming them<br />
into CO 2<br />
, water and a valuable soil conditioner<br />
– compost.<br />
When talking about composting of bioplastics,<br />
foremost →industrial composting in a managed<br />
composting facility is meant (criteria defined in<br />
EN 13432).<br />
The main difference between industrial and<br />
home composting is, that in industrial composting<br />
facilities temperatures are much higher<br />
and kept stable, whereas in the composting<br />
pile temperatures are usually lower, and<br />
less constant as depending on factors such as<br />
weather conditions. Home composting is a way<br />
slower-paced process than industrial composting.<br />
Also, a comparatively smaller volume of<br />
waste is involved. [bM 03/07]<br />
Compound | Plastic mixture from different raw<br />
materials (polymer and additives). [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system boundaries<br />
of an environmental →Life Cycle Assessment<br />
(LCA) which covers all activities from the<br />
cradle (i.e., the extraction of raw materials, agricultural<br />
activities and forestry) up to the factory<br />
gate.<br />
Cradle-to-Cradle | (sometimes abbreviated as<br />
C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy, in which<br />
waste is used as raw material (‘waste equals<br />
food’). Cradle-to-Cradle is not a term that is<br />
typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (cradle) to use phase and<br />
disposal phase (grave).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure.<br />
Density | Quotient from mass and volume of a<br />
material, also referred to as specific weight.<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization).<br />
DIN-CERTCO | Independant certifying organisation<br />
for the assessment on the conformity of<br />
bioplastics.<br />
Dispersing | Fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture.<br />
Drop-In bioplastics | are chemically indentical<br />
to conventional petroleum-based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET; the<br />
monoethylene glycol made from bio-ethanol.<br />
Developments to make terephthalic acid from<br />
renewable resources are underway. Other examples<br />
are polyamides (partly biobased e.g. PA<br />
4.10 or PA 6.10 or fully biobased like PA 5.10 or<br />
PA10.10).<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic packaging<br />
products.<br />
Energy recovery | Recovery and exploitation of<br />
the energy potential in (plastic) waste for the<br />
production of electricity or heat in waste incineration<br />
plants (waste-to-energy).<br />
Environmental claim | A statement, symbol<br />
or graphic that indicates one or more environmental<br />
aspect(s) of a product, a component,<br />
packaging, or a service. [16].<br />
Enzymes | are proteins that catalyze chemical<br />
reactions.<br />
Enzyme-mediated plastics | are not →bioplastics.<br />
Instead, a conventional non-biodegradable<br />
plastic (e.g. fossil-based PE) is enriched with<br />
small amounts of an organic additive. Microorganisms<br />
are supposed to consume these<br />
additives and the degradation process should<br />
then expand to the non-biodegradable PE and<br />
thus make the material degrade. After some<br />
time the plastic is supposed to visually disappear<br />
and to be completely converted to carbon<br />
dioxide and water. This is a theoretical concept<br />
which has not been backed up by any verifiable<br />
proof so far. Producers promote enzymemediated<br />
plastics as a solution to littering. As<br />
no proof for the degradation process has been<br />
provided, environmental beneficial effects are<br />
highly questionable.<br />
Ethylene | Colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking or<br />
from bio-ethanol by dehydration, the monomer<br />
of the polymer polyethylene (PE).<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded in Germany<br />
in 1993 as IBAW, European Bioplastics<br />
today represents the interests of about 50<br />
member companies throughout the European<br />
Union and worldwide. With members from the<br />
agricultural feedstock, chemical and plastics<br />
industries, as well as industrial users and recycling<br />
companies, European Bioplastics serves<br />
as both a contact platform and catalyst for<br />
advancing the aims of the growing bioplastics<br />
industry.<br />
Extrusion | Process used to create plastic<br />
profiles (or sheet) of a fixed cross-section consisting<br />
of mixing, melting, homogenising and<br />
shaping of the plastic.<br />
FDCA | 2,5-furandicarboxylic acid, an intermediate<br />
chemical produced from 5-HMF. The<br />
dicarboxylic acid can be used to make → PEF =<br />
Glossary<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 43
Basics<br />
polyethylene furanoate, a polyester that could<br />
be a 100% biobased alternative to PET.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g. the<br />
transformation of sugar into lactic acid).<br />
FSC | The Forest Stewardship Council. FSC is<br />
an independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
Gelatine | Translucent brittle solid substance,<br />
colourless or slightly yellow, nearly tasteless<br />
and odourless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) | Organisms,<br />
such as plants and animals, whose<br />
genetic material (DNA) has been altered are<br />
called genetically modified organisms (GMOs).<br />
Food and feed which contain or consist of such<br />
GMOs, or are produced from GMOs, are called<br />
genetically modified (GM) food or feed [1]. If GM<br />
crops are used in bioplastics production, the<br />
multiple-stage processing and the high heat<br />
used to create the polymer removes all traces<br />
of genetic material. This means that the final<br />
bioplastics product contains no genetic traces.<br />
The resulting bioplastics are therefore well<br />
suited to use in food packaging as it contains<br />
no genetically modified material and cannot interact<br />
with the contents.<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global warming<br />
is said to be accelerated by → greenhouse<br />
gases.<br />
Glucose | is a monosaccharide (or simple<br />
sugar). It is the most important carbohydrate<br />
(sugar) in biology. Glucose is formed by photosynthesis<br />
or hydrolyse of many carbohydrates<br />
e. g. starch.<br />
Greenhouse gas, GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of infrared<br />
radiation emitted by the Earth’s surface,<br />
the atmosphere, and clouds [1, 9].<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices of a<br />
company, or the environmental benefits of a<br />
product or service [1, 10].<br />
Granulate, granules | Small plastic particles<br />
(3-4 millimetres), a form in which plastic is sold<br />
and fed into machines, easy to handle and dose.<br />
HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />
organic compound derived from sugar dehydration.<br />
It is a platform chemical, a building<br />
block for 20 performance polymers and over<br />
175 different chemical substances. The molecule<br />
consists of a furan ring which contains<br />
both aldehyde and alcohol functional groups.<br />
5-HMF has applications in many different industries<br />
such as bioplastics, packaging, pharmaceuticals,<br />
adhesives and chemicals. One of<br />
the most promising routes is 2,5 furandicarboxylic<br />
acid (FDCA), produced as an intermediate<br />
when 5-HMF is oxidised. FDCA is used to<br />
produce PEF, which can substitute terephthalic<br />
acid in polyester, especially polyethylene terephthalate<br />
(PET). [bM 03/14, 02/16]<br />
Home composting | →composting [bM <strong>06</strong>/08]<br />
Humus | In agriculture, humus is often used<br />
simply to mean mature →compost, or natural<br />
compost extracted from a forest or other spontaneous<br />
source for use to amend soil.<br />
Hydrophilic | Property: water-friendly, soluble<br />
in water or other polar solvents (e.g. used in<br />
conjunction with a plastic which is not waterresistant<br />
and weatherproof, or that absorbs<br />
water such as polyamide. (PA).<br />
Hydrophobic | Property: water-resistant, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weatherproof, or that does not<br />
absorb any water such as polyethylene (PE) or<br />
polypropylene (PP).<br />
Industrial composting | is an established process<br />
with commonly agreed-upon requirements<br />
(e.g. temperature, timeframe) for transforming<br />
biodegradable waste into stable, sanitised products<br />
to be used in agriculture. The criteria for industrial<br />
compostability of packaging have been<br />
defined in the EN 13432. Materials and products<br />
complying with this standard can be certified<br />
and subsequently labelled accordingly [1,7]. [bM<br />
<strong>06</strong>/08, 02/09]<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
Land use | The surface required to grow sufficient<br />
feedstock (land use) for today’s bioplastic<br />
production is less than 0.02 % of the global<br />
agricultural area of 4.7 billion hectares. It is not<br />
yet foreseeable to what extent an increased use<br />
of food residues, non-food crops or cellulosic<br />
biomass in bioplastics production might lead to<br />
an even further reduced land use in the future.<br />
[bM 04/09, 01/14]<br />
LCA, Life Cycle Assessment | is the compilation<br />
and evaluation of the input, output and the<br />
potential environmental impact of a product<br />
system throughout its life cycle [17]. It is sometimes<br />
also referred to as life cycle analysis,<br />
eco-balance or cradle-to-grave analysis. [bM<br />
01/09]<br />
Littering | is the (illegal) act of leaving waste<br />
such as cigarette butts, paper, tins, bottles,<br />
cups, plates, cutlery, or bags lying in an open<br />
or public place.<br />
Marine litter | Following the European Commission’s<br />
definition, “marine litter consists of<br />
items that have been deliberately discarded,<br />
unintentionally lost, or transported by winds<br />
and rivers, into the sea and on beaches. It<br />
mainly consists of plastics, wood, metals,<br />
glass, rubber, clothing and paper”. Marine debris<br />
originates from a variety of sources. Shipping<br />
and fishing activities are the predominant<br />
sea-based, ineffectively managed landfills as<br />
well as public littering the mainland-based<br />
sources. Marine litter can pose a threat to living<br />
organisms, especially due to ingestion or<br />
entanglement.<br />
Currently, there is no international standard<br />
available, which appropriately describes the<br />
biodegradation of plastics in the marine environment.<br />
However, several standardisation<br />
projects are in progress at the ISO and ASTM<br />
(ASTM D6691) level. Furthermore, the European<br />
project OPEN BIO addresses the marine<br />
biodegradation of biobased products. [bM 02/16]<br />
Mass balance | describes the relationship between<br />
input and output of a specific substance<br />
within a system in which the output from the system<br />
cannot exceed the input into the system.<br />
First attempts were made by plastic raw material<br />
producers to claim their products renewable<br />
(plastics) based on a certain input of biomass<br />
in a huge and complex chemical plant,<br />
then mathematically allocating this biomass<br />
input to the produced plastic.<br />
These approaches are at least controversially<br />
disputed. [bM 04/14, 05/14, 01/15]<br />
Microorganism | Living organisms of microscopic<br />
sizes, such as bacteria, fungi or yeast.<br />
Molecule | A group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | Molecules that are linked by polymerization<br />
to form chains of molecules and then<br />
plastics.<br />
Mulch film | Foil to cover the bottom of farmland.<br />
Organic recycling | means the treatment of<br />
separately collected organic waste by anaerobic<br />
digestion and/or composting.<br />
Oxo-degradable / Oxo-fragmentable | materials<br />
and products that do not biodegrade! The<br />
underlying technology of oxo-degradability or<br />
oxo-fragmentation is based on special additives,<br />
which, if incorporated into standard resins, are<br />
purported to accelerate the fragmentation of<br />
products made thereof. Oxo-degradable or oxofragmentable<br />
materials do not meet accepted<br />
industry standards on compostability such as<br />
EN 13432. [bM 01/09, 05/09]<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources. [bM <strong>06</strong>/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased. [bM 03/12]<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum-based and not degradable, used for<br />
e.g. for baby bottles or CDs. Criticized for its<br />
BPA (→ Bisphenol-A) content.<br />
PCL | Polycaprolactone, a synthetic (fossilbased),<br />
biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol). [bM 05/10]<br />
PEF | Polyethylene furanoate, a polyester made<br />
from monoethylene glycol (MEG) and →FDCA<br />
(2,5-furandicarboxylic acid , an intermediate<br />
chemical produced from 5-HMF). It can be a<br />
100% biobased alternative for PET. PEF also<br />
has improved product characteristics, such as<br />
better structural strength and improved barrier<br />
behaviour, which will allow for the use of PEF<br />
bottles in additional applications. [bM 03/11, 04/12]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film. The polyester<br />
is made from monoethylene glycol (MEG),<br />
that can be renewably sourced from bio-ethanol<br />
(sugar cane) and, since recently, from plantbased<br />
paraxylene (bPX) which has been converted<br />
to plant-based terephthalic acid (bPTA).<br />
[bM 04/14. bM <strong>06</strong>/<strong>2021</strong>]<br />
PGA | Polyglycolic acid or polyglycolide is a<br />
biodegradable, thermoplastic polymer and the<br />
simplest linear, aliphatic polyester. Besides its<br />
44 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
use in the biomedical field, PGA has been introduced<br />
as a barrier resin. [bM 03/09]<br />
PHA | Polyhydroxyalkanoates (PHA) or the polyhydroxy<br />
fatty acids, are a family of biodegradable<br />
polyesters. As in many mammals, including<br />
humans, that hold energy reserves in the form<br />
of body fat some bacteria that hold intracellular<br />
reserves in form of of polyhydroxyalkanoates.<br />
Here the micro-organisms store a particularly<br />
high level of energy reserves (up to 80% of their<br />
own body weight) for when their sources of nutrition<br />
become scarce. By farming this type of<br />
bacteria, and feeding them on sugar or starch<br />
(mostly from maize), or at times on plant oils or<br />
other nutrients rich in carbonates, it is possible<br />
to obtain PHA‘s on an industrial scale [11]. The<br />
most common types of PHA are PHB (Polyhydroxybutyrate,<br />
PHBV and PHBH. Depending on<br />
the bacteria and their food, PHAs with different<br />
mechanical properties, from rubbery soft<br />
trough stiff and hard as ABS, can be produced.<br />
Some PHAs are even biodegradable in soil or in<br />
a marine environment.<br />
PLA | Polylactide or polylactic acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar or<br />
starch with the help of micro-organisms. Lactic<br />
acid comes in two isomer forms, i.e. as laevorotatory<br />
D(-)lactic acid and as dextrorotary L(+)<br />
lactic acid.<br />
Modified PLA types can be produced by the use<br />
of the right additives or by certain combinations<br />
of L- and D- lactides (stereocomplexing), which<br />
then have the required rigidity for use at higher<br />
temperatures [13]. [bM 01/09, 01/12]<br />
Plastics | Materials with large molecular chains<br />
of natural or fossil raw materials, produced by<br />
chemical or biochemical reactions.<br />
PPC | Polypropylene carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene oxide<br />
(PO). [bM 04/12]<br />
PTT | Polytrimethylterephthalate (PTT), partially<br />
biobased polyester, is produced similarly to<br />
PET, using terephthalic acid or dimethyl terephthalate<br />
and a diol. In this case it is a biobased<br />
1,3 propanediol, also known as bio-PDO. [bM<br />
01/13]<br />
Renewable Carbon | entails all carbon sources<br />
that avoid or substitute the use of any additional<br />
fossil carbon from the geosphere. It can come<br />
from the biosphere, atmosphere, or technosphere,<br />
applications are, e.g., bioplastics, CO2-<br />
based plastics, and recycled plastics respectively.<br />
Renewable carbon circulates between<br />
biosphere, atmosphere, or technosphere, creating<br />
a carbon circular economy. [bM 03/21]<br />
Renewable resources | Agricultural raw materials,<br />
which are not used as food or feed, but as<br />
raw material for industrial products or to generate<br />
energy. The use of renewable resources<br />
by industry saves fossil resources and reduces<br />
the amount of → greenhouse gas emissions.<br />
Biobased plastics are predominantly made of<br />
annual crops such as corn, cereals, and sugar<br />
beets or perennial cultures such as cassava<br />
and sugar cane.<br />
Resource efficiency | Use of limited natural<br />
resources in a sustainable way while minimising<br />
impacts on the environment. A resourceefficient<br />
economy creates more output or value<br />
with lesser input.<br />
Seedling logo | The compostability label or<br />
logo Seedling is connected to the standard<br />
EN 13432/EN 14995 and a certification process<br />
managed by the independent institutions<br />
→DIN CERTCO and → TÜV Austria. Bioplastics<br />
products carrying the Seedling fulfil the criteria<br />
laid down in the EN 13432 regarding industrial<br />
compostability. [bM 01/<strong>06</strong>, 02/10]<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are named for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | Plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finished products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group to an<br />
additional hydroxyl group. It is used as a plasticiser<br />
for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate) consisting<br />
of → amylose and → amylopectin, gained<br />
from maize, potatoes, wheat, tapioca etc. When<br />
glucose is connected to polymer chains in a<br />
definite way the result (product) is called starch.<br />
Each molecule is based on 300 -12000-glucose<br />
units. Depending on the connection, there are<br />
two types known → amylose and → amylopectin.<br />
[bM 05/09]<br />
Starch derivatives | Starch derivatives are<br />
based on the chemical structure of → starch.<br />
The chemical structure can be changed by<br />
introducing new functional groups without<br />
changing the → starch polymer. The product<br />
has different chemical qualities. Mostly the hydrophilic<br />
character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connected with an<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate | Starch<br />
propionate and starch butyrate can be synthesised<br />
by treating the → starch with propane<br />
or butanoic acid. The product structure is still<br />
based on → starch. Every based → glucose<br />
fragment is connected with a propionate or butyrate<br />
ester group. The product is more hydrophobic<br />
than → starch.<br />
Sustainability | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One famous definition of sustainability is the<br />
one created by the Brundtland Commission, led<br />
by the former Norwegian Prime Minister G. H.<br />
Brundtland. It defined sustainable development<br />
as development that ‘meets the needs of the<br />
present without compromising the ability of future<br />
generations to meet their own needs.’ Sustainability<br />
relates to the continuity of economic,<br />
social, institutional and environmental aspects<br />
of human society, as well as the nonhuman environment.<br />
This means that sustainable development<br />
involves the simultaneous pursuit of economic<br />
prosperity, environmental protection, and<br />
social equity. In other words, businesses have to<br />
expand their responsibility to include these environmental<br />
and social dimensions. It also implies<br />
a commitment to continuous improvement<br />
that should result in a further reduction of the<br />
environmental footprint of today’s products, processes<br />
and raw materials used. Impacts such as<br />
the deforestation of protected habitats or social<br />
and environmental damage arising from poor<br />
agricultural practices must be avoided. Corresponding<br />
certification schemes, such as ISCC<br />
PLUS, WLC or Bonsucro, are an appropriate tool<br />
to ensure the sustainable sourcing of biomass<br />
for all applications around the globe.<br />
Thermoplastics | Plastics which soften or melt<br />
when heated and solidify when cooled (solid at<br />
room temperature).<br />
Thermoplastic Starch | (TPS) → starch that was<br />
modified (cooked, complexed) to make it a plastic<br />
resin<br />
Thermoset | Plastics (resins) which do not soften<br />
or melt when heated. Examples are epoxy<br />
resins or unsaturated polyester resins.<br />
TÜV Austria Belgium | Independant certifying<br />
organisation for the assessment on the conformity<br />
of bioplastics (formerly Vinçotte)<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fibre/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide, European<br />
Bioplastics, Berlin, Germany, 2012<br />
[2] ISO 14<strong>06</strong>7. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation of biopolymers<br />
and bioplastics, 2010<br />
[4] CEN/TS 16137, Plastics - Determination of<br />
bio-based carbon content, 2011<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of Solid,<br />
Liquid, and Gaseous Samples Using Radiocarbon<br />
Analysis<br />
[6] SPI: Understanding Biobased Carbon Content,<br />
2012<br />
[7] EN 13432, Requirements for packaging recoverable<br />
through composting and biodegradation.<br />
Test scheme and evaluation criteria<br />
for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14<strong>06</strong>4 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 20<strong>06</strong><br />
[10] Terrachoice, 2010, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher, 2012<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 2005<br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> <strong>06</strong>/2009<br />
[15] ISO 14<strong>06</strong>7 onb Corbon Footprint of Products<br />
[16] ISO 14021 on Self-declared Environmental<br />
claims<br />
[17] ISO 14044 on Life Cycle Assessment<br />
Glossary<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 45
1. Raw Materials<br />
Suppliers Guide<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
bioplastics.starch@agrana.com<br />
www.agrana.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 22 90 90 9<br />
Mob: +86 187 99 283 100<br />
chenjianhui@lanshantunhe.com<br />
www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
Global Biopolymers Co.,Ltd.<br />
Bioplastics compounds<br />
(PLA+starch;PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 10310<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-99951<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
Mixcycling Srl<br />
Via dell‘Innovazione, 2<br />
36042 Breganze (VI), Italy<br />
Phone: +39 04451911890<br />
info@mixcycling.it<br />
www.mixcycling.it<br />
1.1 bio based monomers<br />
1.2 compounds<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 51<strong>06</strong>63<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.kingfa.com<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be listed among top suppliers in the<br />
field of bioplastics.<br />
Gianeco S.r.l.<br />
Via Magenta 57 10128 Torino - Italy<br />
Tel.+390119370420<br />
info@gianeco.com<br />
www.gianeco.com<br />
Cardia Bioplastics<br />
Suite 6, 205-211 Forster Rd<br />
Mt. Waverley, VIC, 3149 Australia<br />
Tel. +61 3 85666800<br />
info@cardiabioplastics.com<br />
www.cardiabioplastics.com<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
For Example:<br />
39 mm<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41<strong>06</strong>6 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
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www.bioplasticsmagazine.com<br />
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three month before expiry.<br />
www.facebook.com<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 211 520 54 662<br />
Julian.Schmeling@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0)2 51 65 71 43<br />
fabien.resweber@mcpp-europe.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30030, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 519<strong>06</strong>21<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Earth Renewable Technologies BR<br />
Estr. Velha do Barigui 10511, Brazil<br />
slink@earthrenewable.com<br />
www.earthrenewable.com<br />
Trinseo<br />
1000 Chesterbrook Blvd. Suite 300<br />
Berwyn, PA 19312<br />
+1 855 8746736<br />
www.trinseo.com<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Green Dot Bioplastics<br />
527 Commercial St Suite 310<br />
Emporia, KS 66801<br />
Tel.: +1 620-273-8919<br />
info@greendotbioplastics.com<br />
www.greendotbioplastics.com<br />
Plásticos Compuestos S.A.<br />
C/ Basters 15<br />
08184 Palau Solità i Plegamans<br />
Barcelona, Spain<br />
Tel. +34 93 863 96 70<br />
info@kompuestos.com<br />
www.kompuestos.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
46 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
1.3 PLA<br />
1.5 PHA<br />
2. Additives/Secondary raw materials<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
a brand of<br />
Helian Polymers BV<br />
Bremweg 7<br />
5951 DK Belfeld<br />
The Netherlands<br />
Tel. +31 77 398 09 09<br />
sales@helianpolymers.com<br />
https://pharadox.com<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
Total Corbion PLA bv<br />
Stadhuisplein 70<br />
4203 NS Gorinchem<br />
The Netherlands<br />
Tel.: +31 183 695 695<br />
Fax.: +31 183 695 604<br />
www.total-corbion.com<br />
pla@total-corbion.com<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
ECO-GEHR PLA-HI®<br />
- Sheets 2 /3 /4 mm – 1 x 2 m -<br />
GEHR GmbH<br />
Mannheim / Germany<br />
Tel: +49-621-8789-127<br />
laudenklos@gehr.de<br />
www.gehr.de<br />
1.4 starch-based bioplastics<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
1.6 masterbatches<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
3. Semi finished products<br />
3.1 Sheets<br />
Customised Sheet Xtrusion<br />
James Wattstraat 5<br />
7442 DC Nijverdal<br />
The Netherlands<br />
+31 (548) 626 111<br />
info@csx-nijverdal.nl<br />
www.csx-nijverdal.nl<br />
4. Bioplastics products<br />
Bio4Pack GmbH<br />
Marie-Curie-Straße 5<br />
48529 Nordhorn, Germany<br />
Tel. +49 (0)5921 818 37 00<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
Suppliers Guide<br />
Biofibre GmbH<br />
Member of Steinl Group<br />
Sonnenring 35<br />
D-84032 Altdorf<br />
Fon: +49 (0)871 308-0<br />
Fax: +49 (0)871 308-183<br />
info@biofibre.de<br />
www.biofibre.de<br />
Natureplast – Biopolynov<br />
11 rue François Arago<br />
14123 IFS<br />
Tel: +33 (0)2 31 83 50 87<br />
www.natureplast.eu<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7<strong>06</strong>2/97687-0<br />
www.tecnaro.de<br />
P O L i M E R<br />
GEMA POLIMER A.S.<br />
Ege Serbest Bolgesi, Koru Sk.,<br />
No.12, Gaziemir, Izmir 35410,<br />
Turkey<br />
+90 (232) 251 5041<br />
info@gemapolimer.com<br />
http://www.gemabio.com<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Plásticos Compuestos S.A.<br />
C/ Basters 15<br />
08184 Palau Solità i Plegamans<br />
Barcelona, Spain<br />
Tel. +34 93 863 96 70<br />
info@kompuestos.com<br />
www.kompuestos.com<br />
UNITED BIOPOLYMERS S.A.<br />
Parque Industrial e Empresarial<br />
da Figueira da Foz<br />
Praça das Oliveiras, Lote 126<br />
3090-451 Figueira da Foz – Portugal<br />
Phone: +351 233 403 420<br />
info@unitedbiopolymers.com<br />
www.unitedbiopolymers.com<br />
Albrecht Dinkelaker<br />
Polymer- and Product Development<br />
Talstrasse 83<br />
60437 Frankfurt am Main, Germany<br />
Tel.:+49 (0)69 76 89 39 10<br />
info@polyfea2.de<br />
www.caprowax-p.eu<br />
Treffert GmbH & Co. KG<br />
In der Weide 17<br />
55411 Bingen am Rhein; Germany<br />
+49 6721 403 0<br />
www.treffert.eu<br />
Treffert S.A.S.<br />
Rue de la Jontière<br />
57255 Sainte-Marie-aux-Chênes,<br />
France<br />
+33 3 87 31 84 84<br />
www.treffert.fr<br />
www.granula.eu<br />
Plant-based and Compostable PLA Cups and Lids<br />
Great River Plastic Manufacturer<br />
Company Limited<br />
Tel.: +852 95880794<br />
sam@shprema.com<br />
https://eco-greatriver.com/<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, Vice president<br />
Yunlin, Taiwan(R.O.C)<br />
Mobile: (886) 0-982 829988<br />
Email: esmy@minima-tech.com<br />
Website: www.minima.com<br />
w OEM/ODM (B2B)<br />
w Direct Supply Branding (B2C)<br />
w Total Solution/Turnkey Project<br />
Naturabiomat<br />
AT: office@naturabiomat.at<br />
DE: office@naturabiomat.de<br />
NO: post@naturabiomat.no<br />
FI: info@naturabiomat.fi<br />
www.naturabiomat.com<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 47
7. Plant engineering<br />
10. Institutions<br />
10.1 Associations<br />
Suppliers Guide<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.601<br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
6. Equipment<br />
6.1 Machinery & Molds<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
6.2 Degradability Analyzer<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6155<br />
Fax: +81-54-623-8623<br />
info_fds@saidagroup.jp<br />
www.saidagroup.jp/fds_en/<br />
EREMA Engineering Recycling Maschinen<br />
und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
9. Services<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
Innovation Consulting Harald Kaeb<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62831<br />
silvia.kliem@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
Michigan State University<br />
Dept. of Chem. Eng & Mat. Sc.<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
10.3 Other Institutions<br />
GO!PHA<br />
Rick Passenier<br />
Oudebrugsteeg 9<br />
1012JN Amsterdam<br />
The Netherlands<br />
info@gopha.org<br />
www.gopha.org<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
Our new<br />
frame<br />
colours<br />
Bioplastics related topics,<br />
i.e., all topics around<br />
biobased and biodegradable<br />
plastics, come in the familiar<br />
green frame.<br />
All topics related to<br />
Advanced Recycling, such<br />
as chemical recycling<br />
or enzymatic degradation<br />
of mixed waste into building<br />
blocks for new plastics have<br />
this turquoise coloured<br />
frame.<br />
When it comes to plastics<br />
made of any kind of carbon<br />
source associated with<br />
Carbon Capture & Utilisation<br />
we use this frame colour.<br />
The familiar blue<br />
frame stands for rather<br />
administrative sections,<br />
such as the table of<br />
contents or the “Dear<br />
readers” on page 3.<br />
If a topic belongs to more<br />
than one group, we use<br />
crosshatched frames.<br />
Ochre/green stands for<br />
Carbon Capture &<br />
Bioplastics, e. g., PHA made<br />
from methane.<br />
Articles covering Recycling<br />
and Bioplastics ...<br />
Recycling & Carbon Capture<br />
We’re sure, you got it!<br />
As you may have already noticed, we are expanding our scope of topics. With the main target in focus – getting away from fossil resources – we are strongly<br />
supporting the idea of Renewable Carbon. So, in addition to our traditional bioplastics topics, about biobased and biodegradable plastics, we also started covering<br />
topics from the fields of Carbon Capture and Utilisation as well as Advanced Recycling.<br />
To better differentiate the different overarching topics in the magazine, we modified our layout.<br />
48 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
08/09/20 16:54<br />
<strong>06</strong> / <strong>2021</strong><br />
Subscribe<br />
now at<br />
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Event Calendar<br />
You can meet us<br />
16th European Bioplastics Conference<br />
30.11. - 01.12.<strong>2021</strong> - Berlin, Germany<br />
https://www.european-bioplastics.org/events/eubp-conference<br />
International Conference on Cellulose Fibres 2022<br />
02.02. - 03.02.2022 - Cologne, Germany<br />
https://cellulose-fibres.eu/<br />
8th European Biopolymer Summit<br />
03.02. - 04.02.2022 - London, UK<br />
https://www.wplgroup.com/aci/event/european-biopolymer-summit<br />
bio!PAC <strong>2021</strong>/22 (NEW DATE !)<br />
by bioplastics MAGAZINE<br />
15.03. - 16.03.2022 - Düsseldorf, Germany<br />
www.bio-pac.info<br />
Conference on CO2-based Fuels and Chemicals<br />
23.03. - 24.03.2022 - Cologne, Germany<br />
http://co2-chemistry.eu/<br />
CHINAPLAS 2022<br />
25.04. - 28.04.2022 - Shanghai, China<br />
https://www.chinaplasonline.com/CPS22<br />
Events<br />
daily updated eventcalendar at<br />
www.bioplasticsmagazine.com<br />
The Renewable Materials Conference<br />
10.05. - 12.05.2022 - Cologne, Germany<br />
https://renewable-materials.eu/<br />
Plastics for Cleaner Planet - Conference<br />
26.<strong>06</strong>. - 28.<strong>06</strong>.2022 - New York City Area, USA<br />
Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />
hell<br />
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bioplastics MAGAZINE Vol. 16<br />
Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />
Highlights<br />
Fibres, Textiles, Nonwovens | 16<br />
Biocomposites | 34<br />
Basics<br />
CO 2 based plastics | 50<br />
bioplastics MAGAZINE Vol. 16<br />
Highlights<br />
... is read in 92 countries<br />
Cover Story<br />
Caroline Kjellme,<br />
entrepreneurial speaker<br />
at bio!TOY <strong>2021</strong> | 8<br />
Coating | 10<br />
Films, Flexibles, Bags | 40<br />
Basics<br />
... is read in 92 countries<br />
05 / <strong>2021</strong><br />
Cellulose based bioplastics | 50<br />
ISSN 1862-5258 Sep/Oct<br />
Cover Story<br />
First straw bans<br />
begin to topple | 7<br />
ISSN 1862-5258 ... is read in 92 countries Nov/Dec<br />
https://innoplastsolutions.com/conference<br />
Bioplastix India<br />
29.07. - 30.07.2022 - Bangalore, India<br />
https://bioplastex.com/<br />
Subject to changes.<br />
For up to date event-info visit https://www.bioplasticsmagazine.com/en/event-calendar/<br />
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Use the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
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3) Gratis-Buch in Deutschland leider nicht möglich (Buchpreisbindung).<br />
Watch as long as supply lasts.<br />
bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16 49
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
Agrana Starch Bioplastics 46 Green Dot Bioplastics 22 46 Polyone 23<br />
APK 30<br />
Green Serendipity 8 48 Positive Plastics 19<br />
ARGE cyclos / HTTP 31<br />
GSK 18<br />
Precedence Research 12<br />
Arkema 19<br />
Helian Polymers 24 47 Procter & Gamble 16<br />
Avantium 8<br />
Herbal Essences 16<br />
Prodir 35<br />
Avient 23<br />
HS Niederrhein 39<br />
PTT/MCC 46<br />
BASF (Ecovio) 46 HS Rhein-Waal Kleve 39<br />
Reef Interest 35<br />
Bio4Pack 8 47 Huhtamaki 31<br />
Robert Kraemer 13<br />
Bio-Fed Branch of Akro-Plastic 46 INGRAIN 39<br />
Rodenburg Biopolymers 8<br />
Biofibre 47 Inst. F. Bioplastics & Biocomposites 48 RWDC 8<br />
Biotec 8 47 Institut f. Kunststofftechnik, Stuttgart 48 Sabic 5<br />
Biowert Industrie 19<br />
Institute of Textile Technology RWTH 32,28<br />
Saida 48<br />
BMEL 34<br />
JinHui ZhaoLong High Technology 46 Sansu 6<br />
Borealis 5,19<br />
JOI 17<br />
Sappi 19<br />
BPI 48 Kaneka Belgium 10 47 Scion 26<br />
Buss 21,48<br />
Caprowachs, Albrecht Dinkelaker 47<br />
Cardia Bioplastics 46<br />
Cargill 23<br />
Chanel 17<br />
Changchun Meihe Science & Techn. 20<br />
CJ Bio 24<br />
Clariant 23<br />
Climate Partner 18<br />
Coca-Cola 20<br />
Corbion 26<br />
Covestro 33<br />
Customized Sheet Extrusion 47<br />
Danimer Scientific 5,7<br />
Difas 23<br />
Dr. Heinz Gupta Verlag 29<br />
Earth Renewable technologies 46<br />
Earthfirst Biopolymer Films by Sidaplax 8<br />
Eastman Chemical Company 16<br />
Emballator 5<br />
Erema 48<br />
European Bioplastics 3,8 48<br />
European Patent Office 33<br />
FKuR 8 2, 46<br />
Fraunhofer IAP 27<br />
Fraunhofer UMSICHT 48<br />
Gehr 47<br />
Gema Polimers 47<br />
Gianeco 46<br />
Global Biopolymers 46<br />
Go!PHA 7,34 48<br />
Grafe 46,47<br />
Granula 47<br />
Kingfa 46<br />
Kolon 6<br />
Kompuestos 46,47<br />
Krill Design 35<br />
Kyoto Univ. 28<br />
Lamberti 10<br />
Lanxess 7,22<br />
Lignin Industries 19<br />
Looplife 6<br />
MAIP 34<br />
Mayco International 22<br />
MedPHA 36<br />
Michigan State University 48<br />
Microtec 46<br />
Minima Technology 47<br />
Mixcycling 46<br />
Mocom 19<br />
NaKu 8<br />
narocon InnovationConsulting 48<br />
Naturabiomat 47<br />
Natureplast-Biopolynov 47<br />
NatureWorks LLC 8<br />
Natur-Tec 48<br />
Neste 8<br />
nova Institute 8 11,12,25,49<br />
Novamont 40 48,52<br />
Novamont 8<br />
Novozymes 26<br />
Numi Organic Tea 8<br />
Nurel 47<br />
Origin Materials 6<br />
OWS 8<br />
plasticker 27<br />
Silbo 8<br />
Sirmax 19<br />
Stahl 14<br />
StoraEnso 19<br />
Sukano 47<br />
Sulapac 8<br />
Sulapac 17<br />
Superfoodguru 8<br />
Taghleef Industries 8<br />
Tecnaro 43 47<br />
Tepha 36<br />
TianAn Biopolymer 24 47<br />
Tipa 8,16<br />
Tokyo Inst. of Techn. 28<br />
Total Corbion PLA 5,6,8 47<br />
Treffert 47<br />
Trinseo 46<br />
Tsinghua Univ. 34<br />
TU Delft 8<br />
UBQ 19<br />
United Biopolymers 47<br />
Univ. California Berkley 26<br />
Univ. Stuttgart (IKT) 48<br />
Univ. Tech. Chemitz 13<br />
Univ. Tokyo 28<br />
UPM 19, 20<br />
Vaude 31<br />
Virent 20<br />
WinCup 7<br />
Wirtsch.Förderungsges. Heinsberg 39<br />
Worcester Polytechnic Institute 15<br />
Xinjiang Blue Ridge Tunhe Polyester 46<br />
Zeijiang Hisun Biomaterials 47<br />
Great River Plastic Manuf. 47<br />
Next issues<br />
<strong>Issue</strong><br />
Month<br />
Publ.<br />
Date<br />
edit/ad/<br />
Deadline<br />
polymediaconsult 48<br />
Edit. Focus 1 Edit. Focus 2 Basics<br />
01/2022 Jan/Feb 07.02.2022 23.12.<strong>2021</strong> Automotive Foams Biodegradadation<br />
02/2022 Mar/Apr 04.04.2022 04.03.2022 Thermoforming /<br />
Rigid Packaging<br />
Additives /<br />
Masterbatch / Adh.<br />
03/2022 May/Jun 07.<strong>06</strong>.2022 <strong>06</strong>.05.2022 Injection moulding Beauty &<br />
Healthcare<br />
04/2022 Jul/Aug 01.08.2022 01. Jul 22 Blow Moulding Polyurethanes/<br />
Elastomers/Rubber<br />
05/2022 Sep/Oct 04.10.2022 02.09.2022 Fiber / Textile /<br />
Nonwoven<br />
<strong>06</strong>/2022 Nov/Dec 05.12.2022 04.11.2022 Films/Flexibles/<br />
Bags<br />
Building &<br />
Construction<br />
Consumer<br />
Electronics<br />
plastic or "no plastic" -<br />
that's the question<br />
Biocompatability of PHA<br />
FDCA and PEF<br />
Feedstocks, different<br />
generations<br />
Chemical recycling<br />
Trade-Fair<br />
Specials<br />
Chinaplas Preview<br />
Chinaplas Review<br />
K'2022 Preview<br />
K'2022 Review<br />
Subject to changes<br />
50 bioplastics MAGAZINE [<strong>06</strong>/21] Vol. 16
SMART<br />
SOLUTIONS<br />
FOR<br />
EVERYDAY<br />
PRODUCTS<br />
• Food contact grade<br />
• Odourless<br />
• Plasticizer free<br />
• Industrial and home<br />
compostable<br />
100%<br />
compostable<br />
(according to EN 13432)
WWW.MATERBI.COM<br />
as chestnut shell<br />
EcoComunicazione.it<br />
r4_09.2020