material safety data sheet technowrap 2k ex - PT. Harimau Putih

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K EX1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKINGPRODUCT NAME:TECHNOWRAP 2K EXPART NO:APPLICATIONS:SUPPLIER:WALKER TECHNICAL RESOURCES LTDTEL: +44 (0) 1224 822822FAX: +44 (0) 1224 822299E-MAIL:wtr@wtr.uk.comDATE ISSUED: 2801062. HAZARDS IDENTIFICATIONHighly flammable. May cause sensitisation by skin contact. Irritating to eyes, respiratory system and skin.CLASSIFICATION Xi;R36/37/38. R43. F;R11.3. COMPOSITION/INFORMATION ON INGREDIENTSNAME EC NO. CAS- NO. CONTENT CLASSIFICATIONMETHYL201-297-1 80-62-6 60-100% F;R11 R43 XI;R37/38METHACRYLATEMETHACRYLIC ACID 201-204-4 79-41-4 1-5% C;R35 XN;R21/22The full text for all R-phrases are shown in section 164. FIRST AID MEASURESINHALATION: Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.INGESTION: Immediately rinse mouth and drink plenty of water (200-300 ml). DO NOT induce vomiting. Getmedical attention immediately.SKIN CONTACT: Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention ifirritation persists after washing.EYE CONTACT: Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutesand get medical attention.5. FIRE FIGHTING MEASURESEXTINGUISHING MEDIA: Extinguish with foam, carbon dioxide or dry powder.SPECIAL FIRE FIGHTING PROCEDURES: Keep up-wind to avoid fumes. Avoid water in straight hose stream; will scatter andspread fire. Cool containersexposed to flames with water until well after the fire is out. Keep run-off water out ofW28-11

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K EXsewers and water sources.Dike for water control.UNUSUAL FIRE & EXPLOSION HAZARDS HIGHLY FLAMMABLE! Vapours are heavier than air and may spread near ground tosources of ignition. May travel considerable distance to source of ignition and flash back.SPECIFIC HAZARDS:In case of fire, toxic gases may be formed.PROTECTIVE MEASURES IN FIRE: Use protective equipment appropriate for surrounding materials. Self containedbreathing apparatus and fullprotective clothing must be worn in case of fire.6. ACCIDENTAL RELEASE MEASURESPERSONAL PROTECTIONS:Use protective gloves, goggles and suitable protective clothing. Avoid inhalation ofvapours and contact withskin and eyes. Provide adequate ventilation. Take precautionary measures againststatic discharges.Do not smoke, use naked flames or other sources of ignition.ENVIRONMENTAL PRECAUTIONS: Avoid release to the environment. Do not discharge into drains, water courses or ontothe ground. Spillages oruncontrolled discharges into watercourses must be IMMEDIATELY alerted to theEnvironmental Agency orother appropriate regulatory body. Contain spillages with sand, earth or any suitableadsorbent material. Theproduct should not be dumped in nature but collected and delivered according toagreement with the localauthorities.SPILL CLEAN-UP METHODS: Wear necessary protective equipment. Remove sources of ignition. Stop leak if possiblewithout risk. Absorb in vermiculite, dry sand or earth and place into containers.Containers with collected spillage must be properlylabelled with correct contents and hazard symbol. Run off or release to sewer, waterwayor ground is forbidden.Flush area clean with lots of water. Be aware of potential for surfaces to becomeslippery.7. HANDLING AND STORAGEUSAGE PRECAUTIONS:STORAGE PRECAUTIONS:STORAGE CLASS:Avoid spilling, skin and eye contact. Keep away from heat, sparks and openflame. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours. Mechanical ventilation or local exhaust ventilation is required. Storagetanks and other containers must be grounded.Store in tightly closed original container in a cool, dry well-ventilated place.Keep away from heat, sparks and open flame. Keep separate from food,feedstuffs, fertilisers and other sensitive material. Protect from light, includingdirect sunrays. Store separated from: Acids. Alkalies. Oxidising material.Chemical storage.W28-11

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K EX8. EXPOSURE CONTROLS AND PERSONAL PROTECTIONMAME Std LT - ppm LT – mg/m3 ST- ppm ST – mg/m3METHYL METHACRYLATE WEL 50 PPM 208 MG/M3 100 PPM 416 MG/M3METHACRYLIC ACID WEL 20 PPM 72 MG/M3 40 PPM 143 MG/M3PROTECTIVE EQUIPMENT:PROCESS CONDITIONS:ENGINEERING MEASURES:RESPIRATORY EQUIPMENT:HAND PROTECTION:EYE PROTECTION:HYGIENE MESURES:SKIN PROTECTION:Provide eyewash station.Provide adequate general and local exhaust ventilation.In case of inadequate ventilation or when the product is heated, use suitablerespiratory equipment with gas filter (type A2).Use protective gloves made of: Rubber or plastic.Wear splash-proof eye goggles to prevent any possibility of eye contact.Wash at the end of each work shift and before eating, smoking and using thetoilet. Wash promptly with soap & water if skin becomes contaminated. Whenusing do not eat, drink or smoke.Wear apron or protective clothing in case of splashes.9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:PASTECOLOUR:WHITE/OFF-WHITEODOUR:SLIGHTLY PUNGENTBOILING POINT/RANGE: (°C) 101 RELATVITY DENSITY: 0.93 - 1.05 20VAPOUR DENSITY (AIR=1) > 1 FLASH POINT ( O C) 10FLAMMABILITY LIMIT – LOWER (%) 2.1 FLAMMABILITY LIMIT – UPPER (%) 12.510. STABILITY AND REACTIVITYSTABILITY:Stable under normal temperature conditions and recommended use.CONDITIONS TO AVOID:Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolongedperiods of time. Avoidexposure to high temperatures or direct sunlight.MATERIALS TO AVOID:Strong acids. Strong alkalies. Strong oxidising substances. Strong reducing agents.HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition or combustion may liberate carbon oxides and other toxicgases or vapours.HAZARDOUS POLYMERISATION May polymerise.W28-11

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K EX11. TOXICOLOGICAL INFORMATIONINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:ROUTE OF ENTRY:TARGET ORGANS:MEDICAL SYMPTOMS:Vapours may irritate throat and respiratory system and cause headache, dizziness anddullness. Vapours may causeheadache, fatigue, dizziness and nausea.Irritating. May be absorbed in the body and cause dizziness, nausea and vomiting.May be absorbed through the skin. Irritating to skin. Repeated exposure may cause skindryness or cracking. May cause sensitisation by skin contact.Irritating to eyes. Irritation, burning, lachrymation, blurred vision after liquid splash.Inhalation. Skin and/or eye contact. Ingestion.Central nervous system. Eyes. Kidneys. Liver. Respiratory system, lungs.Skin irritation. Allergic rash. Irritation of eyes and mucous membranes. Upper respiratoryirritation. Central nervoussystem depression. May cause discomfort if swallowed.MEDICAL CONSIDERATIONS: Chronic respiratory and obstructive airway diseases. Skin disorders and allergies. Liver and/orkidney problems. Personswith rash are directed to skin expert for examination of allergic eczema. Splash in eye requiresexamination by eyespecialist.12. ECOLOGICAL INFORMATIONECOTOXICITYThe product components are not classified as environmentally hazardous. However, this doesnot exclude thepossibility that large or frequent spills can have a harmful or damaging effect on theenvironment.BIOACCUMULATION No data available on bioaccumulation.DEGRADABILITY: No data available.WATER HAZARD CLASS WGK 113. DISPOSAL CONSIDERATIONSDISPOSAL METHODS: Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues inaccordance with local authorityrequirements.CONTAMINATED PACKAGING:OTHER INFORMATION: WASTE CLASS 08 04 09W28-11

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K EX14. TRANSPORT INFORMATIONLABEL (S) FOR CONVEYANCE:UK ROAD CLASS: Class 3PROPER SHIPPING NAME: ADHESIVESUN NO ROAD: 1133 UK ROAD PACK GR. IIADR CLASS NO: 3 ADR CLASS: Class 3: Flammable liquids.ADR PACK GROUP: II HAZARD NO: (ADR): 33ADR LABEL NO: 3 HAZCHEM CODE:: 3YECEFIC TEC@NO: 30GF1-I+II RID CLASS NO: 3RID PACK GROUP: II UN NO SEA: 1133IMDG CLASS: 3 EMS: F-E, S-DMFAG: SEE GUIDE MARINE POLLUTANT: NOUN NO AIR: 1133 ICAO CLASS: 3AIR PACKAGE GR: II15. REGULATORY INFORMATIONLABELLING:IrritantHighly FlammableCONTAINS: METHYL METHACRYLATE , METHACRYLIC ACIDRISK PHRASES:R11R43R36/37/38SAFETY PHRASES:S9S16S24/25S33S36/37/39S60UK REGULATORY REFERENCES: Health and Safety at Work Act 1974.EC DIRECTIVES:Highly flammable.May cause sensitisation by skin contact.Irritating to eyes, respiratory system and skin.Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Avoid contact with skin and eyes.Take precautionary measures against static discharges.Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardouswaste.System of specific information relating to Dangerous Preparations. 2001/58/EEC. DangerousSubstance Directive67/548/EEC as amended. Dangerous Preparations Directive 1999/45/EEC.STATUTORY INSTRUMENTS: Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 (SI 1689)APPROVED CODE OF PRACTICE: Control of Substances Hazardous to Health Regulations 2002.GUIDANCE NOTES: Workplace Exposure Limits EH40.W28-11

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K EX16. OTHER INFORMATIONREVISION DATE: 10/08/10SDS No: 10512SAFETY DATA SHEET STATUS: ApprovedR-PHRASES IN FULL:R11R21/22R35R37R37/38R43Highly flammableHarmful in contact with skin and if swallowedCauses severe burns.Irritating to respiratory system.Irritating to respiratory system and skin.May cause sensitisation by skin contact.DISCLAIMERTHIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATIONWITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THE BEST OF THE COMPANY’S KNOWLEDGE AND BELIEF, ACCURATEAND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY,RELIABILITY OR COMPLETENESS. IT IS THE USER’S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HISOWN PARTICULAR USE.W28-11