material safety data sheet technowrap 2k ... - PT. Harimau Putih

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K HARDENER PART B1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGPRODUCT NAME:TECHNOWRAP 2K TMPART NO:APPLICATIONS:SUPPLIER:WALKER TECHNICAL RESOURCES LTDTEL: +44 (0) 1224 822822FAX: +44 (0) 1224 822299E-MAIL:wtr@wtr.uk.comDATE ISSUED: 0601092. HAZARDS IDENTIFICATIONCauses burns. May cause sensitisation by skin contact. Harmful in contact with skin and if swallowed. Harmfulto aquatic organisms, may cause long term adverse effects in the aquatic environment.CLASSIFICATION: Xn;R21/22 C;R34. R43. R52/533. COMPOSITION/INFORMATION ON INGREDIENTSNAME EC NO. CAS- NO. CONTENT CLASSIFICATIONDIETHYLETRIAMINE 203-865- 111-40-0 60-100% C;R34 Xn;R21/22 R434TETRAETHYLENEPANTAMINE 203-986- 112-57-2 1-5% C;R34 Xn;R21/22 R43 N;R51/5324,4 ISOPROPYLIDENE 1-5%The full text for all R-phrases are shown in section 164. FIRST AID MEASURESINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:Move the exposed person to fresh air at once. If respiratory problems, artificialrespiration/oxygen. Get medical attentionImmediately rinse mouth and drink plenty of water (200-300 ml). DO NOTinduce vomiting. Get medical attention immediately.Remove contaminated clothing immediately and wash with soap and water.Get medical attention if irritation persists after washing.Promptly wash eyes with water while lifting the eye lids. Continue to rinse for atleast 15 minutes and get medical attention.W28-16

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K HARDENER PART B5. FIRE FIGHTING MEASURESEXTINGUISHING MEDIA:SPECIAL FIRE FIGHTINGPROCEDURES:SPECIFIC HAZARDS:PROTECTIVE MEASURES INFIRE:Extinguish with foam, carbon dioxide, dry powder or water fog.Move container from fire area if it can be done without risk. Water spray shouldbe used to cool containers. Cool containers exposed to flames with water untilwell after the fire is out. Keep run-off water out of sewers and water sources.Dike for water control.In case of fire, toxic gases may be formed.Use protective equipment appropriate for surrounding materials. Self containedbreathing apparatus and full protective clothing must be worn in case of fire.6. ACCIDENTAL RELEASE MEASURESPERSONAL PROTECTION:ENVIRONMENTALPRECAUTIONS:SPILL CLEAN-UP METHODS:Use protective gloves, goggles and suitable protective clothing. Avoidinhalation of vapours and contact with skin and eyes. Provide adequateventilation. In case of spills, beware of slippery floors and surfaces.Avoid release to the environment. Do not discharge into drains, water coursesor onto the ground. Contain spillages with sand, earth or any suitable absorbentmaterial. The product should not be dumped in nature, but collected anddelivered according to agreement with the local authorities.Wear necessary protective equipment. Stop leak if possible without risk.Absorb in vermiculite, dry sand or earth and place into containers. Containerswith collected spillage must be properly labelled with correct contents andhazard symbol. Runoff or release to swear, waterway or ground is forbidden.Flush area clean with lots of water. Be aware of potential for surfaces tobecome slippery.7. HANDLING AND STORAGEUSAGE PRECAUTIONS:STORAGE PRECAUTIONS:STORAGE CLASS:Avoid spilling, skin and eye contacts. Keep away from heat sparks and openflame. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours.Store in tightly closed original container in a cool, dry, well ventilated place. Keepaway from heat, sparks and open flame. Keep separate from food, feedstuffs,fertilisers and other sensitive material. Protect from light, including direct sunrays.Store separated from: Acids, Alkalis, Oxidising material.Chemical Storage8. EXPOSURE CONTROLS AND PERSONAL PROTECTIONNAME Std LT - ppm LT – mg/m3 ST- ppm ST – mg/m3DIETHYLENETRIAMINE WEL 1 ppm(Sk) 4.3mg/m3(Sk)W28-16

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K HARDENER PART BPROTECTIVE EQUIPMENT:PROCESS CONDITIONS:ENGINEERING MEASURES:RESPIRATORY EQUIPMENT:HAND PROTECTION:EYE PROTECTION:HYGIENE MESURES:SKIN PROTECTION:Provide eyewash station.All handling to take place in a well ventilated area.If ventilation is insufficient, suitable respiratory protection must be provided.Use protective gloves. The most suitable glove must be chosen in consultationwith the gloves supplier, who can inform about the breakthrough time of the glovematerial.Wear splash proof eye goggles to prevent any possibility of eye contact. Use faceshield in case of splash risk.Wash at the end of each work shift and before eating, smoking and using the toilet.Wash promptly with soap and water if skin becomes contaminated. When usingdo not eat, drink or smoke.Wear apron or protective clothing in case of splashes9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:Coloured liquid.COLOUR:AmberODOUR:FishySOLUBILITY:Soluble in waterRELATIVE DENSITY: 1.0510. STABILITY AND REACTIVITYSTABILITY:CONDITIONS TO AVOID:MATERIALS TO AVOID:HAZARDOUSDECOMPOSITION PRODUCTS:Stable under the prescribed storage conditions.Avoid heat, flames and other sources of ignition.Strong acids. Strong Alkalies. Strong oxidising substances.By fire toxic gasses (CO, CO2, NOx) may be formed11. TOXICOLOGICAL INFORMATIONINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:ROUTE OF ENTRY:TARGET ORGANS:MEDICAL SYMPTOMS:May cause irritation to the respiratory system.May cause discomfort if swallowed.May cause skin irritation/eczema. May cause sensitisation by skin contact.Causes burns. May be absorbed through the skin.May cause severe irritation to eyes. Risk of corneal damage.Inhalation. Ingestion. Skin and/or eye contact.Skin. Eyes. Gastro-intestinal tract. Respiratory system, lungs.Upper respiratory system irritation. Skin irritation. Skin contact may cause:Allergic rash. Eye contact may cause: Extreme irritation of eyes and mucousW28-16

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K HARDENER PART BMEDICAL CONSIDERATIONS:membranes, including burning and tearing. Ingestion may cause: Severeabdominal pain.Skin disorders and allergies. Persons with rash are directed to skin expert forexamination of allergic eczema.12. ECOLOGICAL INFORMATIONEXOTOXICITY:BIOACCUMULATION:DEGRADABILITY:The product contains a substance which is harmful to aquatic organisms andwhich may cause long term adverse effects in the aquatic environment.No data available on bioaccumulation.No data available.13. DISPOSAL CONSIDERATIONSDISPOSAL METHODS:Do not allow runoff to sewer, waterway or ground. Dispose of waste and residuesin accordance with local authority requirements.14. TRANSPORT INFORMATIONLABEL (S) FOR CONVEYANCE:CORROSIVEUK ROAD CLASS: 8PROPER SHIPPING NAME:AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE,N.O.S (DIETHYLENETRIAMINE, TETRAETHYLENEPANTAMINE)UN NO ROAD: 2735 UK ROAD PACK GR. 11ADR CLASS NO: 8 ADR CLASS: Class 8: Corrosivesubstances.ADR PACK GROUP: 11 HAZARD NO: (ADR): 80ADR LABEL NO: 8 HAZCHEM CODE:: 2XCEFIC TEC@NO: 80GC7-11=111 RID CLASS NO: 8RID PACK GROUP: II UN NO SEA: 2735IMDG CLASS: 8 EMS: F-A, S-BMFAG: See Guide. MARINE POLLUTANT: No.UN NO AIR: 2735 ICAO CLASS: 8AIR PACKAGE GR: 11W28-16

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K HARDENER PART B15. REGULATORY INFORMATIONLABELLING:CONTAINS:RISKPHRASES:SAFETYPHRASES:IRRITANT CORROSIVE HARMFUL TO ENVIRONMENTDIETHYLENETETIRAMINETETRAETHYLENEPENTAMINER34 Causes burns.R43 May cause sensitisation by skin contact.R21/22 Harmful in contact with skin and if swallowed.R52/53 Harmful to aquatic organisms, may cause long term adverse effects in the aquaticenvironment.S25 Avoid contact with eyesS26S60UK REGULATORYREFERENCES:EU DIRECTIVES:S36/37/39S45STATUTORY INSTRUMENTS:APPROVED CODE OFPRACTICE:GUIDANCE NOTES:In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (showlabel where possible).This material and it’s container must be disposed of as hazardous waste.Health and Safety at Work Act 1974.System of specific information relating to Dangerous Preparations. 2001/58/EC.Dangerous Substance Directive 67/548/EEC as amended.Chemicals (Hazard Information and Packaging for Supply)Regulations 2002 (SI1689).Control of Substances Hazardous to Health Regulations 2002.Workplace Exposure Limits EH40.W28-16

MATERIAL SAFETY DATA SHEETTECHNOWRAP 2K HARDENER PART B16. OTHER INFORMATIONREVISION DATE: 10/08/10SDS No: W28-16SAFETY DATA SHEET ApprovedSTATUS:R-PHRASES IN R21/22 Harmful in contact with skin and if swallowed.FULL:R34R43Causes burns.May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquaticenvironment.DISCLAIMERTHIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCHMATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THEBEST OF THE COMPANY’S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER,NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. ITIS THE USER’S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWNPARTICULAR USE.W28-16