material safety data sheet technoseal™ uw - resin - PT. Harimau Putih

MATERIAL SAFETY DATA SHEETTECHNOSEAL UW - RESIN1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGPRODUCT NAME:TECHNOSEAL TMPART NO:APPLICATIONS:SUPPLIER:WALKER TECHNICAL RESOURCES LTDTEL: +44 (0) 1224 822822FAX: +44 (0) 1224 822299E-MAIL:wtr@wtr.uk.comDATE ISSUED: 0601092. HAZARDS IDENTIFICATIONToxic by inhalation, irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation andskin contact.CLASSIFICATION:T;R23 R42/43 Xi; R36/37/383. COMPOSITION/INFORMATION ON INGREDIENTSNAME EC NO. CAS- NO. CONTENT CLASSIFICATION4.4 METHYLENEDI(CYCLOHEXYL ISOCYANATE)225-863-025124-30-1 1-5% R;R23 R42/43 Xi;R 36/37/38DIPHENYLMETHANEDIISOCYANATE9016-87-9 1-5% XN;R20 XI;R36/37/38, R42- Isomers & HomologuesThe full text for all R-phrases are shown in section 164. FIRST AID MEASURESINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:Move the exposed person to fresh air at once. If respiratory problems, artificialrespiration/oxygen. Get medical attention.Rinse mouth thoroughly. DO NOT induce vomiting. Get medical attentionimmediately.Remove contaminated clothing immediately and wash skin with soap and water.Get medical attention if irritation persists after washing.Promptly wash eyes with plenty of water lifting the eye lids. Continue to rinsefor at least 15 minutes and get medical attention.W28-15

MATERIAL SAFETY DATA SHEETTECHNOSEAL UW - RESIN5. FIRE FIGHTING MEASURESEXTINGUISHING MEDIA:SPECIAL FIRE FIGHTINGPROCEDURES:SPECIFIC HAZARDS:PROTECTIVE MEASURES INFIRE:Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Foam. Do not usewater as an extinguisher.Move container from fire area if it can be done without risk. Water spray shouldbe used to cool containers. Cool containers exposed to flames with water untilwell after the fire is out. Keep run-off water of sewers and water sources. Dikefor water control.In case of fire, toxic gases may be formed. Fire creates: Carbon monoxide(CO). Carbon dioxide (CO2). Oxides of: Nitrogen. Hydrogen cyanide (HCN).Use protective equipment appropriate for surrounding materials. Self containedbreathing apparatus and full protective clothing must be worn in case of fire.6. ACCIDENTAL RELEASE MEASURESPERSONAL PROTECTIONS:ENVIRONMENTALPRECAUTIONS:SPILL CLEAN-UP METHODS:Use protective gloves, goggles and suitable protective clothing. Avoidinhalation of vapours and contact with skin and eyes. Provide adequateventilation. In case of spills, beware of slippery floors and surfaces.Avoid release to the environment. Do not discharge into drains, water coursesor onto the ground. Contain spillages with sad, earth or any suitable adsorbentmaterial. The product should not be dumped in nature but collected anddelivered according to agreement with the local authorities.Wear necessary protective equipment. Stop leak if possible without risk.Absorb in vermiculite, dry sand or earth and place into containers. Containerswith collected spillage must be properly labelled with correct contents andhazard symbol. Runoff or release to sewer waterway or ground is forbidden.Flush area clean with lots of water. Be aware of potential for surfaces tobecome slippery.7. HANDLING AND STORAGEUSAGE PRECAUTIONS:STORAGE PRECAUTIONS:STORAGE CLASS:Avoid spilling, skin and eye contact. Keep away from heat, sparks and openflame. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours.Store in tightly closed original container. Store at moderate temperatures in dry,well ventilated area. Keep separate from food, feedstuffs, fertilisers and othersensitive material. Store separated from: Water, Acids, Alkalies. Oxidisingmaterial.Water reactive storageW28-15

MATERIAL SAFETY DATA SHEETTECHNOSEAL UW - RESIN8. EXPOSURE CONTROLS AND PERSONAL PROTECTIONNAME Std LT - ppm LT – mg/m3 ST- ppm ST – mg/m34.4 METHYLENEDI (CYCLOHEXYL WEL0.02 mg/m30.07 mg/m3(Sen)ISOCYANATE)(Sen)DIPHENYLMETHANEDIISOCYANATE- Isomers & HomologuesWEL0.02 mg/m3(Sen)0.07 mg/m3(Sen)PROTECTIVE EQUIPMENT:PROCESS CONDITIONS:ENGINEERING MEASURES:RESPIRATORY EQUIPMENT:HAND PROTECTION:EYE PROTECTION:HYGIENE MESURES:SKIN PROTECTION:Provide eyewash station.Provide adequate general and local exhaust ventilation.If ventilation is insufficient, suitable respiratory protection must be provided.Use protective gloves. The most suitable glove must be chosen in consultationwith the gloves supplier, who can inform about the breakthrough time of the glovematerial.Wear splash-proof eye goggles to prevent any possibility of eye contact. Use faceshield in case of splash risk.Wash at the end of each work shift and before eating, smoking and using the toilet.Wash promptly with soap & water if skin becomes contaminated. When using donot eat, drink or smoke.Wear apron.9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:Viscous liquidCOLOUR:ClearODOUR:Slight odourSOLUBILITY:Insoluble in waterBOILING POINT/RANGE: >200VAPOUR PRESSURE: 188 VISCOSITY 3500m Pas25W28-15

MATERIAL SAFETY DATA SHEETTECHNOSEAL UW - RESINADR CLASS NO: 0 MARINE POLLUTANT NoPROPER SHIPPING NAME:UN NO ROAD:15. REGULATORY INFORMATIONLABELLING:CONTAINS:RISKPHRASES:SAFETYPHRASES:R23Xn - Harmful4.4 METHYLENEDI (CYCLOHEXYL ISOCYANATE)DIPHENYLMETHANEDIISOCYANATE - Isomers & HomologuesToxic by inhalationR36/37/38 Irritating to eyes, respiratory system and skin.R42/43 May cause sensitisation by inhalation and skin contact.S23 Do not breathe vapour/spray.S24/25 Avoid contact with skin and eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.S36/37/39 Wear suitable protective clothing, gloves ad eye/face protection.S38 In case of insufficient ventilation, wear suitable respiratory equipmentS45 In case of accident or if you feel unwell, seek medical advice immediately (showlabel where possible)S60 This material and its container must e disposed of as hazardous wasteP4 Contains isocyanates. See information supplied by the manufacturer.UK REGULATORYHealth and Safety at Work Act 1974REFERENCES:EU DIRECTIVES:System of specific information relating to Dangerous preparations, 2001/58/EEC.Dangerous Substance Director 67/548/EEC as amended. DangerousPreparations Directive 1999/45/EEC.STATUTORY INSTRUMENTS:APPROVED CODE OFPRACTICE:GUIDANCE NOTES:Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 (SI1689)Control of Substances Hazardous to Health Regulations 2002.Workplace Exposure Limits EH40.W28-15

MATERIAL SAFETY DATA SHEETTECHNOSEAL UW - RESIN16. OTHER INFORMATIONREVISION DATE: 10/08/10SDS No: 10518SAFETY DATA SHEET STATUS: Approved.R-PHRASES IN R20 Harmful by inhalation.FULL:R23 Toxic by inhalation.R36/37/38 Irritating to eyes, respiratory system and skin.R42 May cause sensitisation by inhalation.R42/43 May cause sensitisation by inhalation and skin contact.DISCLAIMERTHIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATIONWITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THE BEST OF THE COMPANY’S KNOWLEDGE AND BELIEF, ACCURATEAND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY,RELIABILITY OR COMPLETENESS. IT IS THE USER’S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HISOWN PARTICULAR USE.W28-15