material safety data sheet technowrap core - PT. Harimau Putih

MATERIAL SAFETY DATA SHEETTECHNOWRAP CORE1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANYPRODUCT NAME: TECHNOWRAP COREPART NO:APPLICATIONS:SUPPLIER: WALKER TECHNICAL RESOURCES LTDTEL: +44 (0) 1224 822822FAX: +44 (0) 1224 822299E-MAIL:wtr@wtr.uk.comDATE ISSUED: 0601092. HAZARDS IDENTIFICATIONHarmful by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalationand skin contact.CLASSIFICATION:Xn;R20. R42/43. Xi;R36/37/38.3. COMPOSITION/INFORMATION ON INGREDIENTSINGREDIENT NAME: EINECS NO. CAS No. WEIGHT% RISK (R No.)Borosilicate glass fibre roving 65997-17-3 30-60%DIPHENYLMETHANEDIISOCYANATE-Isomers & homologues9016-87-9 10-30% Xn;R20.Xi;R36/37/38.R42.METHYLENEDIPHENYL247-714-0 26447-40-5 5-10% Xn;R20 R42/43DIISOCYANATEDIPHENYLMETHANE-4,4'-DI-ISOCYANATEThe full text for all R-phrases are shown in section 16Xi;R36/37/38202-966-0 101-68-8 < 1 Xn;R20 R42/43Xi;R36/37/384. FIRST AID MEASURESINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:Move the exposed person to fresh air at once. If respiratory problems,artificial respiration/oxygen. Get medical attention.DO NOT induce vomiting. Get medical attention immediately.Remove contaminated clothing immediately and wash skin with soapand water. Get medical attention if irritation persists after washing.Promptly wash eyes with plenty of water while lifting the eye lids.Continue to rinse for at least 15 minutes and get medical attention.5. FIRE FIGHTING MEASURESEXTINGUISHING MEDIA:SPECIAL FIRE FIGHTINGPROCEDURES:Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Foam. Waterspray, fog or mist.Move container from fire area if it can be done without risk. Water sprayshould be used to cool containers. Cool containers exposed to flameswith water until well after the fire is out. Keep run-off water out of sewersand water sources. Dike for water control.W28-17

MATERIAL SAFETY DATA SHEETTECHNOWRAP CORESPECIFIC HAZARDS:PROTECTIVE MEASURES INFIRE :In case of fire, toxic gases may be formed. Fire creates: Carbonmonoxide (CO). Carbon dioxide (CO2). Oxides of: Nitrogen. Hydrogencyanide (HCN).Use protective equipment appropriate for surrounding materials. Selfcontained breathing apparatus and full protective clothing must be wornin case of fire.6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTION:ENVIRONMENTALPRECAUTION:SPILL CLEANUP METHODS:Use protective gloves, goggles and suitable protective clothing. Avoidinhalation of vapours and contact with skin and eyes. Provide adequateventilation. In case of spills, beware of slippery floors and surfaces.Avoid release to the environment. Do not discharge into drains, watercourses or onto the ground. Contain spillages with sand, earth or anysuitable adsorbent material. The product should not be dumped innature but collected and delivered according to agreement with the localauthorities.Wear necessary protective equipment. Stop leak if possible without risk.Absorb in vermiculite, dry sand or earth and place into containers.Containers with collected spillage must be properly labelled with correctcontents and hazard symbol. Runoff or release to sewer, waterway orground is forbidden. Flush area clean with lots of water. Be aware ofpotential for surfaces to become slippery.7. HANDLING AND STORAGEUSAGE PRECAUTIONS:STORAGE CRITERIA:STORAGE CLASS:Avoid spilling, skin and eye contact. Keep away from heat, sparks andopen flame. Do not eat, drink or smoke when using the product. Avoidinhalation of vapours.Store in tightly closed original container. Store at moderatetemperatures in dry, well ventilated area. Keep separate from food,feedstuffs, fertilisers and other sensitive material. Store separated from:Water. Acids. Alkalies. Oxidising material.Water reactive storage.8. EXPOSURE CONTROLS AND PERSONAL PROTECTIONNAME Std LT - ppm LT – mg/m3 ST- ppm ST – mg/m3DIPHENYLMETHANE-4,4'-DI-ISOCYANATEWEL 0.02mg/m3(Sen)0.07mg/m3(Sen)METHYLENEDIPHENYLDIISOCYANATEWEL 0.02mg/m3(Sen)0.07mg/m3(Sen)DIPHENYLMETHANEDIISOCYANATE-Isomers & homologuesWEL 0.02mg/m3(Sen)0.07mg/m3(Sen)PROTECTIVE EQUIPMENT:PROCESS CONDITIONS:Provide eyewash station.W28-17

MATERIAL SAFETY DATA SHEETTECHNOWRAP COREallergic eczema. Splash in eye requires examination by eye specialist.12. ECOLOGICAL INFORMATIONECOTOXICITYBIOACCUMULATION:DEGRADABILITY:The product components are not classified as environmentallyhazardous. However, this does not exclude the possibility that large orfrequent spills can have a harmful or damaging effect on theenvironment.LC 50, 96 Hrs, FISH mg/l >500EC 50, 48 Hrs, DAPHNIA, mg/l >500IC 50, 72 Hrs, ALGAE, mg/l >500No data available on bioaccumulation.No data available.13. DISPOSAL CONSIDERATIONSDISPOSAL METHODS:CONTAMINATED PACKAGING:OTHER INFORMATION:Do not allow runoff to sewer, waterway or ground. Dispose of waste andresidues in accordance with local authority requirements.14. TRANSPORT INFORMATIONLABEL (S) FORCONVEYANCE:The product is not covered by international regulation on the transport ofdangerous goods (IMDG, IATA, ADR/RID).No transport warning sign required.ADR LABEL NO: 0 MARINE POLLUTANT NO15. REGULATORY INFORMATIONLABEL FOR SUPPLY:HarmfulCONTAINS:DIPHENYLMETHANEDIISOCYANATE -Isomers & homologuesMETHYLENEDIPHENYL DIISOCYANATEDIPHENYLMETHANE-4,4'-DI-ISOCYANATERISK PHRASES: R20 Harmful by inhalation.R36/37/38 Irritating to eyes, respiratory system and skin.R42/43 May cause sensitisation by inhalation and skin contact.SAFETY PHRASES: S23 Do not breathe vapour/spray.S24/25 Avoid contact with skin and eyes.S26 In case of contact with eyes, rinse immediately with plentyof water and seek medical advice.S36/37/39 Wear suitable protective clothing, gloves and eye/faceprotection.S38 In case of insufficient ventilation, wear suitable respiratoryequipment.S45 In case of accident or if you feel unwell, seek medicalW28-17

MATERIAL SAFETY DATA SHEETTECHNOWRAP COREUK REGULATORYREFERENCES:EU DIRECTIVES:STATUTORY INSTRUMENTS:APPROVED CODE OFPRACTICE:GUIDANCE NOTES:advice immediately (show label where possible).S60 This material and its container must be disposed of ashazardous waste.P4Contains isocyanates. See information supplied by themanufacturer.Health and Safety at Work Act 1974.System of specific information relating to Dangerous Preparations.2001/58/EEC. Dangerous Substance Directive 67/548/EEC asamended. Dangerous Preparations Directive 1999/45/EEC.Chemicals (Hazard Information and Packaging for Supply) Regulations2002 (SI 1689)Control of Substances Hazardous to Health Regulations 2002.Workplace Exposure Limits EH40.16. OTHER INFORMATIONREVISION DATE: 10/08/10SDS No: 10504SAFETY DATA SHEETSTATUS:ApprovedR20 Harmful by inhalation.R-PHRASES IN FULL:R36/37/38 Irritating to eyes, respiratory system and skin.R42 May cause sensitisation by inhalation.R42/43 May cause sensitisation by inhalation and skin contact.DISCLAIMERTHIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHERMATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THE BEST OF THE COMPANY’S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED.HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER’S RESPONSIBILITY TO SATISFYHIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE.W28-17