material safety data sheet technowrap ... - PT. Harimau Putih

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART B1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGPRODUCT NAME:TECHNOWRAP SPLASHZONE PART BPART NO:APPLICATIONS:SUPPLIER:WALKER TECHNICAL RESOURCES LTDTEL: +44 (0) 1224 822822FAX: +44 (0) 1224 822299E-MAIL:wtr@wtr.uk.comDATE ISSUED: 26/11/093. HAZARDS IDENTIFICATIONC: Corrosive; The product has to be labelled due to the calculations procedure of the “General Classificationguideline for preparations of the EU” In the latest valid version.CLASSIFICATION: Xn; R21/22; R34. R43. R52/53R21 / 22Harmful in contact to the skin and if swallowedR34Causes burnsR43R52 / 53May cause sensitisation by skin contactHarmful to aquatic organisms, may cause long term adverse effects in theaquatic environment2. COMPOSITION/INFORMATION ON INGREDIENTSNAME EC NO. CAS- NO. CONTENT CLASSIFICATIONBenzyl alcohol 603-057- 100-51-6 25-50% XN; R 20/2200-53-AMINOMETHYL-3,5,5-612-067- 2855-13- 2.5-10% C,Xn; R 21/22-34-43-52/53TRIMETHYLCYCLOHEXYLAMINE 00-9 2m-phenylenebis(methylamine) 1477-55- 2.5-10% C,Xn; R 20/22-34-43-52/530bisphenol a 604-030- 80-05-7 2.5-10% repr.cat.3;Xn,Xi; r 37-41-43-6200-03-aminopropyldimethylamine 612-061- 109-55-7 2.5-10% C,Xn; R 10-21/22-34-4300-62,4,6-TRIS603-069- 90-72-2 2.5-10% Xn,Xi; R 22-36/38(DIMETHYLAMINOMETHYL)PHENOL00-0The full text for all R-phrases are shown in section 164. FIRST AID MEASURESINHALATION:Take affected persons into the open air and position comfortably. Seek medicaltreatment in case of complaints.W28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART BINGESTION:SKIN CONTACT:EYE CONTACT:Instantly call for doctor.Instantly wash with water and soap and rinse thoroughly. If skin irritationcontinues call for the doctor.Rinse opened eye for several minutes under running water. Then consult doctor5. FIRE FIGHTING MEASURESEXTINGUISHING MEDIA:SPECIFIC HAZARDS:PROTECTIVE MEASURES INFIRE:C02 Extinguish with powder or water jet. Fight larger fires with water jet oralcoholic-resistant foam.In case of fire, toxic gases may be formed.Use protective equipment appropriate for surrounding materials. Self containedbreathing apparatus and full protective clothing must be worn in case of fire.6. ACCIDENTAL RELEASE MEASURESPERSONAL PROTECTION:ENVIRONMENTALPRECAUTIONS:SPILL CLEAN-UP METHODS:Use protective gloves, goggles and suitable protective clothing. Avoidinhalation of vapours and contact with skin and eyes by adequate ventilation.Avoid release to the environment. Do not discharge into drains, water coursesor onto the ground. Contain spillages with sand, earth or any suitable absorbentmaterial. The product should not be dumped in nature, but collected anddelivered according to agreement with the local authorities.Wear necessary protective equipment. Absorb in vermiculite, dry sand,diatomite, acid binders, universal binders or sawdust. Use neutralizing agents.7. HANDLING AND STORAGEUSAGE PRECAUTIONS:STORAGE PRECAUTIONS:STORAGE CLASS:Avoid spilling, skin and eye contacts. Keep away from heat sparks and openflame. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours.Store only in the original container, Provide floor through without outletChemical Storage8. EXPOSURE CONTROLS AND PERSONAL PROTECTIONNAME Std LT - ppm LT – mg/m3 ST- ppm ST – mg/m3DIETHYLENETRIAMINE WEL 1 ppm(Sk) 4.3mg/m3(Sk)W28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART BComponents with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical valuesthat have to be monitored at the workplace.Additional Information:The lists that were valid during the compilation were used as basis.PPE, General protective and hygienic measures:Keep away from foodstuffs, beverages and food. Take off immediately allcontaminated clothing, wash hands during breaks and at the end of the working day.Avoid contact with the eyes and skin.Breathing Equipment:Not necessary if the room is well-ventilateOnly use chemical protective gloves with CE-labelling of category III.To minimize the wetness in the glove due to perspiration changing of gloves duringa shift is required.Check the permeability prior to each new use of gloves.Preventive skin protection by use of skin protecting agents is recommended.Material of Gloves:Nitrile rubber - NBR, Fluorocarbon rubber (viton), Recommended material thickness>0.5mm. The selection of the suitable gloves does not only depend on the material,but also on further marks of quality and varies from manufacturer. As the product isa preparation of several substances, the resistance of the glove material can not becalculated in advance and has therefore to be checked prior to the application.Penetration time of glove material:The exact break through time has to be found out by the manufacturer of theprotective gloves and has to be observed. Suitable gloves for splash back wouldconsist of PVC Gloves, not suitable would be Leather or Strong Gloves.Tightly sealed eye protection along with Protective work clothing are also required.PROTECTIVE EQUIPMENT:Plastic GlovesTightly sealed safety glassesCombination Filter A-P2W28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART BPROCESS CONDITIONS:ENGINEERING MEASURES:RESPIRATORY EQUIPMENT:HAND PROTECTION:EYE PROTECTION:HYGIENE MESURES:SKIN PROTECTION:Provide eyewash station.All handling to take place in a well ventilated area.If ventilation is insufficient, suitable respiratory protection must be provided.Use protective gloves. The most suitable glove must be chosen in consultation withthe gloves supplier, who can inform about the breakthrough time of the glovematerial.Wear splash proof eye goggles to prevent any possibility of eye contact. Use faceshield in case of splash risk.Wash at the end of each work shift and before eating, smoking and using the toilet.Wash promptly with soap and water if skin becomes contaminated. When using donot eat, drink or smoke.Wear apron or protective clothing in case of splashes9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:COLOUR:ODOUR:Liquid.YellowishAmine-likeChange in condition:melting point/melting range:boiling point/boiling range:Flash Point:Ignition Temperature:Self-In-flammability:Danger of explosion:Critical values for explosion :Lower:Upper:Vapour Pressure at 20c:Not determindca. 135cca. 86c380cProduct is not selfignitingProduct is not explosive1.3 vol %13.0 vol %0.3hpaDensity at 23c: 1.02g/cm3 (iso 2811-2)Solubility in / miscibility withwater:not misible or difficult to mixviscosity:Dynamic at 25c 600 – 1400mpas (iso 3219)Solvent content:Organic solvents: 0.0%10. STABILITY AND REACTIVITYThermal decompostion /conditions to be avoided:Materials to be avoided:Dangerous reactionsDangerous products ofdecompostion:No decomposition if used according to specificationsStrong oxidizing agentsNo dangerous reactions knownIn the event of fire; Poisonous gases/vapours, Corrosive gases/vapoursW28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART B11. TOXICOLOGICAL INFORMATIONACUTE TOXICITY:LD/LC50 VALUES THAT ARE RELEVANT FOR CALSSIFICATION:100-51-6 BENZYL ALCOHOLoraldermalinhalativeLD50LD50LC50/4h2855-13-2 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINEORALLD50DERMALLD501230 mg / kg (rat)2000 mg / kg (rbt)4178 mg / l (rat)1030 MG / KG (RAT)1840 MG / KG (RAB)1477-55-0 M-PHENYLENEBIS (METHYLAMINE)ORALLD50DERMALLD50INHALATIVELC50/4 H80-05-7 BISPHENOL AORALDERAL80-05-7 BISPHENOL AORALDERMALINHALATIVELD50LD50LD50LD50LC50/4 H109-55-7 3-AMINOPROPYLDIMETHYLAMINEORALLD50DERMALLD50INHALATIVELC50/4 H90-72-2 2,46 – TRIS ( DIMETHYLAMINOMETHYL) PHENOLoralld50dermalld50930 MG / KG (RAT)2000 MG / KG (RAB)2.4 MG / L (RAT)3250 MG / KG (RAT)3000 MG / KG (RBT)3250 MG / KG (RAT)3000 MG / KG (RBT)> 5 MG / L (RAT)1640 MG / KG (RAT)490 MG / KG (RBT)4.31 MG / L (RAT)1670 mg / kg (rat)1242 mg / kg (rab)General notes:Water hazard class 2 (German Regulations) (self-assessment): hazardous for water.Do not allow product to reach ground water, water bodies or sewage systems.INHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:ROUTE OF ENTRY:TARGET ORGANS:MEDICAL SYMPTOMS:MEDICAL CONSIDERATIONS:May cause irritation to the respiratory system.May cause discomfort if swallowed.May cause skin irritation/eczema. May cause sensitisation by skin contact.Causes burns. May be absorbed through the skin.May cause severe irritation to eyes. Risk of corneal damage.Inhalation. Ingestion. Skin and/or eye contact.Skin. Eyes. Gastro-intestinal tract. Respiratory system, lungs.Upper respiratory system irritation. Skin irritation. Skin contact may cause:Allergic rash. Eye contact may cause: Extreme irritation of eyes and mucousmembranes, including burning and tearing. Ingestion may cause: Severeabdominal pain.Skin disorders and allergies. Persons with rash are directed to skin expert forexamination of allergic eczema.W28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART B12. ECOLOGICAL INFORMATIONECOTOXICAL EFFIECTS: NOT DETERMINEDACQUATIC TOXICITY:100-51-6 BENZYL ALCOHOLALGENTOZIZITATBAKTERIEN-TOXIITATDAPHNIENTOXIZITATFISCHTOXIZITAT79 (3H) MG / L (SCENEDESMUS QUADRICUDA)71.42 (30MIN) MG / L (PHOTOBACTERIUM PHOSPHOREUM)400 (24H) MG / L ((PSEUDOMONAS PUTIDA)400 (24H) MG / L (DAPHNIA MAGNA (WASSERFLOH))645 (48H) MG / L (GOLDORFE)10 (96H) MG / L (LEPOMIS MACROCHIRUS)2855-13-2 3-AMINOMETHYL-3, 5, 5-TRIMETHYLCYCLOHEXYLAMINEALGENTOZIZITATEC50/72h: 37 mg / l (scenedesmus subspicatus)BAKTERIEN-TOXIITATEC10/18h: 1120 mg / l (pseudomonas putida)DAPHNIENTOXIZITATEC50/28h: 23 mg / l (daphnia magna (wasserfloh))FISCHTOXIZITATLC50/96h: 110 mg / l (brachydanio rerio)1477-55-0 M-PHENYLENEBIS (METHYLAMINE)ALGENTOZIZITATDAPHNIENTOXIZITATFISCHTOXIZITAT80-05-7 BISPHENOL AALGENTOZIZITATFISCHTOXIZITAT109-55-7 3-AMINOPROPYLDIMETHYLAMINEBAKTERIEN-TOXIITATDAPHNIENTOXIZITATFISCHTOXIZITAT(72h) >10- 10-100 mg / l (Zebrabarbling) 1 < 10 mg / l (-) 1 < 10 mg / l (-)90-72-2-2,4,6-TRIS (DIMETHYLAMIN OMETHYL)PHENOLDAPHNIENTOXIZITATFISCHTOXIZITATEC50/17H: 95 MG / L (PSEUDOMONAS PUTIDA)EC50/48H: 60 MG / L (DAPHNIA MAGNA (WASSERFLOH)LC50/96H: 122 MG / L (LEUCISCUS IDUS)(96H) 750 MG / L (MANGROVENKRABBE (NEOPANOPE))(24H) 222 MG / L (OCHORHYNCUS MYKISS (REGENBOGENFORELLE)(96H) 718 MG / L (CYPRINUS CARPIO)EXOTOXICITY:BIOACCUMULATION:DEGRADABILITY:The product contains a substance which is harmful to aquatic organisms andwhich may cause long term adverse effects in the aquatic environment.No data available on bioaccumulation.No data available.W28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART B13. DISPOSAL CONSIDERATIONSProduct:Recommendation:For disposal, local regulations issued by the authorities must be observed. Dispose of liquid components at a suitableincineration plant. After curing, the product can be disposed of with household waste.European waster catalogue08 00 00 Wastes from the manufacturer, formulation, supply and use (MFSU) ofCoatings (Paints, varnishes and vitreous enamels), Adhesives, sealants and printing inks.08 02 00 Wastes from MFSU of other coatings (including ceramic materials)08 02 99 Wastes not otherwise specified.14. TRANSPORT INFORMATIONLABEL (S) FOR CONVEYANCE:UK ROAD CLASS: 8PROPER SHIPPING NAME:CORROSIVECORROSIVE LIQUID, N.O.S, N.O.S (DIETHYLENETRIAMINE,TETRAETHYLENEPENTAMINE )UN NO ROAD: 1760 UK ROAD PACK GR. IIIADR CLASS NO: 8 ADR CLASS: Class 8: Corrosivesubstances.ADR PACK GROUP: III HAZARD NO: (ADR): 80ADR LABEL NO: 8 HAZCHEM CODE:: 2XCERTIFICATION NO: 80GC7-11=111 RID CLASS NO: 8RID PACK GROUP: III UN NO SEA: 1760IMDG CLASS: 8 EMS: F-A, S-BMFAG: See Guide. MARINE POLLUTANT: No.UN NO AIR: 1760 ICAO CLASS: 8AIR PACKAGE GR:IIIW28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART B15. REGULATORY INFORMATIONLABELLING:CONTAINS:RISKPHRASES:SAFETYPHRASES:CORROSIVEIRRITANT HARMFUL TO ENVIRONMENTDIETHYLENETRIAMINE TETRAETHYLENEPENTAMINER34 Causes burns.R43 May cause sensitisation by skin contact.R20/22 Harmful in contact with skin and if swallowed.R62 Possible Risk of impaired fertilityS25 Avoid contact with eyesS26S60UK REGULATORYREFERENCES:EU DIRECTIVES:S36/37/39S45STATUTORY INSTRUMENTS:APPROVED CODE OFPRACTICE:GUIDANCE NOTES:In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (showlabel where possible).This material and it’s container must be disposed of as hazardous waste.Health and Safety at Work Act 1974.System of specific information relating to Dangerous Preparations. 2001/58/EC.Dangerous Substance Directive 67/548/EEC as amended.Chemicals (Hazard Information and Packaging for Supply)Regulations 2002 (SI1689).Control of Substances Hazardous to Health Regulations 2002.Workplace Exposure Limits EH40.W28-34

MATERIAL SAFETY DATA SHEETTECHNOWRAP SPLASHZONE PART B16. OTHER INFORMATIONThese data are based on out present knowledge. However, they shall not constitute a guarantee for any specificproduct features and shall not establish a legally binding contractual relationship.Relevant R-Phrases:10 Flammable.20/22 Harmful by inhalation and if swallowed.21/22 Harmful in contact with skin and if swallowed.22 Harmful if swallowed34 Causes Burns36/38 Irritating to eyes and skin41 Risk of serious damage to eyes42 May cause sensitisation by skin contact.52/53 Harmful to aquatic organisms, may cause long-term adverse effect in the aquaticenvironment62 Possible risk of impaired fertility.REVISION DATE: 10/08/10REV. NO./REPL. SDSGENERATED:SDS No:SAFETY DATA SHEET ApprovedSTATUS:DISCLAIMERTHIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCHMATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THEBEST OF THE COMPANY’S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER,NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. ITIS THE USER’S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWNPARTICULAR USE.W28-34