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material safety data sheet technowrap 3k ... - PT. Harimau Putih

material safety data sheet technowrap 3k ... - PT. Harimau Putih

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MATERIAL SAFETY DATA SHEETTECHNOWRAP 3K PRIMER COATPART A1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANYPRODUCT NAME: TECHNOWRAP 3KPART NO:APPLICATIONS:SUPPLIER: WALKER TECHNICAL RESOURCES LTDTEL: +44 (0) 1224 822822FAX: +44 (0) 1224 822299E-MAIL:wtr@wtr.uk.comDATE ISSUED: 0601092. HAZARDS IDENTIFICATIONIrritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.CLASSIFICATION:Xi;R36/38. N;R51/53.3. COMPOSITION/INFORMATION ON INGREDIENTSNAMEECNO.CAS-NO.GLYCIDOXYPROPYLTRIMETHOXYSILANE 2530-83-8METHANOL 200- 67-56-659-6 1The full text for all R-phrases are shown in section 15CONTENTCLASSIFICATION60-100% Xi;R36/38. N;R51/53.< 1 F;R11T;R23/24/25,R39/23/24/254. FIRST AID MEASURESINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:Move the exposed person to fresh air at once. Get medical attention if anydiscomfort continues.Immediately rinse mouth and drink plenty of water (200-300 ml). Inducevomiting, if person is conscious. If vomiting occurs, keep head low so thatstomach content doesn't get into the lungs. Get medical attentionimmediately!Remove contaminated clothing immediately and wash skin with soap andwater. Get medical attention if irritation persists after washing.Promptly wash eyes with plenty of water while lifting the eye lids.Continue to rinse for at least 15 minutes and get medical attention.5. FIRE FIGHTING MEASURESEXTINGUISHING MEDIA:PROTECTIVE MEASURES INFIRE :SPECIFIC HAZARDS:Extinguish with foam, carbon dioxide or dry powder.Move container from fire area if it can be done without risk. Water sprayshould be used to cool containers. Cool containers exposed to flameswith water until well after the fire is out. Keep run-off water out of sewersand water sources. Dike for water control.In case of fire, toxic gases may be formed.W28-25


MATERIAL SAFETY DATA SHEETTECHNOWRAP 3K PRIMER COATPART APROTECTIVE MEASURES INFIRE:Use protective equipment appropriate for surrounding <strong>material</strong>s. Selfcontained breathing apparatus and full protective clothing must be worn incase of fire.6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTION:ENVIRONMENTALPRECAUTION:SPILL CLEANUP METHODS:Use protective gloves, goggles and suitable protective clothing. Avoidinhalation of vapours and contact with skin and eyes. Provide adequateventilation. In case of spills, beware of slippery floors and surfaces.Avoid release to the environment. Do not discharge into drains, watercourses or onto the ground. Contain spillages with sand, earth or anysuitable adsorbent <strong>material</strong>. The product should not be dumped in naturebut collected and delivered according to agreement with the localauthorities.Wear necessary protective equipment. Stop leak if possible without risk.Absorb in vermiculite, dry sand or earth and place into containers.Containers with collected spillage must be properly labelled with correctcontents and hazard symbol. Runoff or release to sewer, waterway orground is forbidden. Flush area clean with lots of water. Be aware ofpotential for surfaces to become slippery.7. HANDLING AND STORAGEUSAGE PRECAUTIONS:STORAGE PRECAUTIONS:STORAGE CLASS:Avoid spilling, skin and eye contact. Keep away from heat, sparks andopen flame. Do not eat, drink or smoke when using the product. Avoidinhalation of vapours.Store in tightly closed original container in a cool, dry well-ventilatedplace. Keep away from heat, sparks and open flame. Keep separate fromfood, feedstuffs, fertilisers and other sensitive <strong>material</strong>. Protect from light,including direct sunrays. Store separated from: Oxidising <strong>material</strong>.Chemical storage.8. EXPOSURE CONTROLS AND PERSONAL PROTECTIONNAME Std LT - ppm LT – mg/m3 ST- ppm ST – mg/m3METHANOL WEL 200266250 ppm(Sk) 333ppm(Sk) mg/m3(Sk)mg/m3(Sk)PROTECTIVE EQUIPMENT:PROCESS CONDITIONS:ENGINEERING MEASURES:RESPIRATORY EQUIPMENT:HAND PROTECTION:Provide eyewash station.All handling to take place in well-ventilated area.If ventilation is insufficient, suitable respiratory protection must beprovided.Use protective gloves. The most suitable glove must be chosen inconsultation with the gloves supplier, who can inform about thebreakthrough time of the glove <strong>material</strong>.W28-25


MATERIAL SAFETY DATA SHEETTECHNOWRAP 3K PRIMER COATPART AEYE PROTECTION:HYGIENE MESURES:SKIN PROTECTION:Wear splash-proof eye goggles to prevent any possibility of eye contact.Use face shield in case of splash risk.Wash at the end of each work shift and before eating, smoking and usingthe toilet. Wash promptly with soap & water if skin becomescontaminated. When using do not eat, drink or smoke.Wear apron or protective clothing in case of splashes.9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:LiquidCOLOUR:Clear ColourlessODOUR:Slightly pungent odour Ester.SOLUBILITY:Miscible with water. Miscible with Alcohol Ether. Benzene. OrganicsolventsBOILING POINT (°C) ~64 MELTING POINT (°C) ~ -97VAPOUR DENSITY: (air=1) 1.11 RELATVITY0.79DENSITY:FLAMMABILITY LIMIT-LOWER(%)6.7 FLAMMABILITYLIMIT- UPPER (%)3610. STABILITY AND REACTIVITYSTABILITY:CONDITIONS TO AVOID:HAZAERDOUSDECOMPOSITIONPRODUCTS:MATERIALS TO AVOID:Stable under the prescribed storage conditions.Avoid heat, flames and other sources of ignition.By fire, toxic gases (CO, CO2, NOx) may be formed.Strong acids. Strong alkalies. Strong oxidising substances. Water,moisture.11. TOXICOLOGICAL INFORMATIONINHALATION:INGESTION:SKIN CONTACT:EYE CONTACT:ROUTE OF ENTRY:TARGET ORGANS:MEDICAL SYM<strong>PT</strong>OMS:MEDICALCONSIDERATIONS:May cause irritation to the respiratory system.Harmful if swallowed. May cause nausea, headache, dizziness andintoxication. May cause liver and/or renal damage. May causeunconsciousness, blindness and possibly death.Irritating to skin. Prolonged and frequent contact may cause redness andirritation. May be absorbed through the skin.May cause severe irritation to eyes. May cause blurred vision and seriouseye damage.Inhalation. Ingestion. Skin and/or eye contact.Skin. Eyes. Gastro-intestinal tract. Respiratory system, lungs.Upper respiratory irritation. Skin irritation. Eye contact may cause:Extreme irritation of eyes and mucous membranes, including burning andtearing. Ingestion may cause: Severe abdominal pain. Visualdisturbances, incl. blurred vision. Headache. Nausea, vomiting.Unconsciousness, possibly death.Splash in eye requires examination by eye specialist.W28-25


MATERIAL SAFETY DATA SHEETTECHNOWRAP 3K PRIMER COATPART A12. ECOLOGICAL INFORMATIONECOTOXICITYBIOACCUMULATION:DEGRADABILITY:The product contains a substance which is toxic to aquatic organismsand which may cause long term adverse effects in the aquaticenvironment.LC 50, 96 Hrs, FISH mg/l >100EC 50, 48 Hrs, DAPHNIA, mg/l 473IC 50, 72 Hrs, ALGAE, mg/l >255No <strong>data</strong> available on bioaccumulation.The product is not readily biodegradable.13. DISPOSAL CONSIDERATIONSDISPOSAL METHODS:Do not allow runoff to sewer, waterway or ground. Dispose of waste andresidues in accordance with local authority requirements.14. TRANSPORT INFORMATIONGENERAL:The product is not covered by international regulation on the transport ofdangerous goods (IMDG, IATA, ADR/RID).15. REGULATORY INFORMATIONLABEL FOR SUPPLY:IrritantDangerous to the environmentRISK PHRASES: R36/38 Irritating to eyes and skin.R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.SAFETY PHRASES: S24/25 Avoid contact with skin and eyes.S26 In case of contact with eyes, rinse immediately with plentyof water and seek medical advice.S36/37/39 Wear suitable protective clothing, gloves and eye/faceprotection.S60 This <strong>material</strong> and its container must be disposed of ashazardous waste.UK REGULATORYHealth and Safety at Work Act 1974.REFERENCES:EU DIRECTIVES:System of specific information relating to Dangerous Preparations.2001/58/EEC. Dangerous Substance Directive 67/548/EEC asamended. Dangerous Preparations Directive 1999/45/EEC.STATUTORY INSTRUMENTS: Chemicals (Hazard Information and Packaging for Supply) Regulations2002 (SI 1689)APPROVED CODE OFControl of Substances Hazardous to Health Regulations 2002.PRACTICE:GUIDANCE NOTES:Workplace Exposure Limits EH40.W28-25


MATERIAL SAFETY DATA SHEETTECHNOWRAP 3K PRIMER COATPART A16. OTHER INFORMATIONREVISION DATE: 10/08/10SDS NO: 10509SAFETY DATA SHEETSTATUS:ApprovedR-PHRASES IN FULL R11 Highly Flammable.R23/24/25 Toxic by inhalation, in contact with skin and ifswallowed.R36/38 Irritating to eyes and skinR39/23/24/25 Toxic: danger of very serious irreversible effects throughinhalation, in contact with skin and if swallowed.R51/53 Toxic to aquatic organisms, may cause long-termadverse effects in the aquatic environment.DISCLAIMERTHIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHERMATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THE BEST OF THE COMPANY’S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED.HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER’S RESPONSIBILITY TO SATISFYHIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE.W28-25

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