Synthesis and Characterization of Various Amino Acids Complexes ...

Olns po$ibL binding 3it s n.y .le b. an ibur.d io hisridir. Fsidues, for rurhdiun
.fu @plq6 withii por.iB. Th.EfoE, rh. @.ri@ of L-ni$idinc with I(16-
Bip)R(s)ClllPF6l ir aqu.@ eluid vs d$ hlrsig.tcd .r 3 t O K. Tnis c&ri@ is rinc-
coosuning, dd nnishB t*o iMaic L-His .dd@ls boud by iDirilaL, I(16-
Bip)tu(mlcNFLHirl:' dd (rt6,Bip)Ru{e.X}!d-L-Hclr*. Ar auilibrib ons!,ni of o.t4
mM w6 6thlish.d @nsidering both ih€ ism6, for lhe @tior betrcGn a4uatd ftohtGs,
(rd-Bip)R(dxH1o)l! ad $. L,His. Complien of$h Elu. sjrh L. ncthionitu (0.j4
nlM) ed L{ysr.iic (0.60 nM) $gg.sLd rhx tn i q..rior ofrh. (r.-Bip)Ru(.nrt' fo,
th* hjm *ids d@s.d in th. ont r L4ylliF > LM.rnionin. > LHjsridinc. Radio6
or t(f-Bip)Ru(en)clllPFdl wi0! rtE h@ Ft in .,r@hrch. c !s de cldied Frl.
Cltochon. c ha e .xpos€d Qlis33) .l@gwirh a hidda hislidirc 6id& (Hit6)_
ElelrolpFy m6s sperom.trt ealysis show.d thar in both trielhyl!@orim !.daL bufr.r
bH 7.q od waro (!ti 8.7), fronoorhoal.d cri@hrene c poducr w4 elct, fomel.
inSilc ofr.n-fold ftold dB of (taBip)R(6)CUlPF6l. ICP-AES Atulysk shord thaL
clr@hFnc c *a rolhasEd uFo 5AZ. 2D [H, lsN] NMR dar. dnibir.d th,| thc
lnhaiM @mpld6 wF bood.d !o dE MnD rEnitru (e ?0e,4) 8d .lboxyld. gout
(@ 3094), Elha th& hinidine cidu6 of cr{4hl1fu c. l6ill fth my b. alriblred io de
stedc @nslr.irts appli€d on tn 6insle .ddin tion sit of {( n6-Bip)R(.n)l} noity by d.
On fi€ anlrary. X{ay cryst llognthic ddysG fo. lhc ene-tuthenimszyn
@mPhx (t'4ym)Ru(lyszyn.)CLl, dcpicted ihat rulhdiun is bonded sledively lo N ol
the inid&|. rirg, gssisr.d with Hhl5. lo.r.d .! rhe porein surf&. [6]1, Ruthddio.
stre.ts diddy rh. Maini.g .nzt@ srudla. Tlc bindd! el*rivity of ( 16€ym)RuCL)
I5