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Thesis - Oztek_Muzaffer_T_200508_MA

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3.5<br />

3.0<br />

2.5<br />

Wt. % H desorbed<br />

2.0<br />

1.5<br />

1.0<br />

0.5<br />

0.0<br />

-0.5<br />

0 1000 2000 3000 4000 5000 6000 7000<br />

corrected time (s)<br />

Figure 12: Percent hydrogen desorbed for dehydriding of Mg 2 Ni.<br />

Ball milled Mg 2 Ni reacted at lower temperatures and H 2 pressures to react than<br />

previously reported values [23]. The amount of H absorbed, 3.04 %, (Mg 2 NiH 3.23 ) was<br />

lower than the reported value of 3.60 % (Mg 2 NiH 4 ). The uptake reaction was complete in<br />

about 15 minutes.<br />

3.1.2. VTiNi<br />

V, Ti and Ni were alloyed using the Spex8000 Mixer Mill. Since the starting<br />

materials were pure elements, a relatively long milling time, 90 minutes, was used. The<br />

40

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