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Thesis - Oztek_Muzaffer_T_200508_MA

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1.4<br />

1.2<br />

1.0<br />

(a)<br />

Wt. % H absorbed<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

(b)<br />

0.0<br />

-0.2<br />

0 500 1000 1500 2000 2500 3000<br />

corrected time (s)<br />

(a) Under H 2 , partial pressure of H 2 = 5.07 atm.<br />

(b) Under 50% H 2 -He (v/v), partial pressure of H 2 = 3.31 atm.<br />

Figure 27: Percent hydrogen curves of VTiNi hydrided with 50% (v/v) H 2 -He mixture<br />

and pure H 2 .<br />

3.2.2.2. LaNi 5<br />

The percent hydrogen release profile with time is given in Figure 28, including<br />

that of LaNi 5 hydrided with pure H 2 . After initial uptake of hydrogen of about 0.08%,<br />

about 0.38% terminal hydrogen capacity was reached in the following several hours. The<br />

presence of helium was shown to slow down the reaction and reduce hydrogen capacity.<br />

62

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