Hóa học phức chất
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Trong ion phøc bèn mÆt:<br />
3AO-d: d xy , d xz , d yz cã c¸c nh¸nh híng tíi gÇn c¸c<br />
phèi tö h¬n, chÞu t¸c dông ®Èy lín h¬n nªn n¨ng<br />
lîng t¨ng lªn m¹nh h¬n<br />
2AO-d: d Z2 , d x2-y2 cã c¸c nh¸nh xa c¸c phèi tö h¬n<br />
nªn chÞu t¸c dông ®Èy yÕu h¬n, n¨ng lîng thấp<br />
hơn<br />
KÕt qu díi t¸c dông ®iÖn trêng cña 4 phèi tö<br />
5AO-d ®ång n¨ng lîng cña ion tù do M n+ bÞ<br />
ph©n t¸ch thµnh 2 møc:<br />
+ t 2g gåm 3AO d xy , d xz , d yz<br />
+ e g gåm 2AO d Z2 , d x2-y2
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