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Engineering Chemistry S Datta

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66 ENGINEERING CHEMISTRY

4. What are α-, β- and γ-rays? Compare their ionising power, range and velocity.

5. Explain the terms:

(i) Disintegration constant

(ii) Half-life period

6. What are the units of radioactivity?

7. Give a relation between half-life and the decay constant of a radioactive substance.

8. What are the causes of nuclear instability? Explain with suitable examples.

9. State and explain the law of radioactive disintegration. What do you mean by the half-life period

of a radioactive element? Show that the half-life is independent of the amount of the substance.

10. Explain artificial radioactivity with suitable examples.

11. What is radioactive displacement law?

12. Write notes on:

(i) Radioactive equilibrium

(ii) Atomic weight of lead in radioactive minerals

(iii) Tracer technique.

13. Why is natural radioactivity mostly limited among heavier elements?

14. What is a nuclear reaction? Discuss some uses of nuclear reactions.

15. What is nuclear binding energy?

16. What are radio-isotopes? How are they prepared? Mention their uses.

17. Give a comparative account of the nuclear binding energy curve and packing fraction curve.

What informations are available from these curves?

18. Write a short note on nuclear transmutation.

19. What is nuclear fission? Show how nuclear fission is a chain reaction.

20. Write a short note on nuclear fusion.

21. Give a brief account of the nuclear reactors. Derive a relation between mass defect and nuclear

binding energy.

22. Where is the radioactive displacement law invalid?

23. Calculate the amount of energy released during the bombardment of 1 235

0 n on 92 U .

24. Write a short note on radio-carbon dating.

25. Complete the following nuclear reactions:

4 9 4 2 12

6

10

5

Be + He ⎯⎯→ C + ...

24

11

238

92

4

2

24

12

Na ⎯⎯→ Mg + ...

239

90

U ⎯⎯→ Th + ...

1

1

B + He ⎯⎯→ ... + H

7

3

1

1

7

4

Li + H ⎯⎯→ ... + Be.

26. Calculate the time required for 10% disintegration of a sample of thorium. Given the t 1/2

of

thorium = 1.4 × 10 10 yrs.

[Ans. 6.93 × 10 –5 yrs.]

27. Calculate the binding energy in MeV per nucleon of 12 6C .

Given: Mass of H-atom = 1.00782 a.m.u.

Mass of neutron = 1.00866 a.m.u.

Actual mass of C-atom = 12.04

1 amu = 931.4 MeV. [Ans. 54.76 MeV]

28. The half-life of radium is 1590 years. How long will it take for 1 g of the element to lose 0.1 g?

[Ans. 2385 yrs.]

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