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The Nature of the Cooper Pair - University of Liverpool

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So we have found a bound pair - a wavefunction <strong>of</strong> two<br />

electrons that has a finite size. This is in spite <strong>of</strong> <strong>the</strong> fact that<br />

<strong>the</strong> kinetic energies <strong>of</strong> <strong>the</strong> electrons, which are close to E F , are<br />

much larger than <strong>the</strong> binding energy ∆.<br />

Ma<strong>the</strong>matically, we have seen that this solution is obtained<br />

after we impose <strong>the</strong> condition that <strong>the</strong> wavefunction sum<br />

Ψ = � α k sin kr<br />

must not contain any wavevector below that Fermi level.<br />

We can interpret this physically. If <strong>the</strong> bound pair <strong>of</strong> electrons<br />

separate, <strong>the</strong>y become plane waves and would have to occupy<br />

two <strong>of</strong> <strong>the</strong> energy states below E F . However, we are talking<br />

about 0 K, and all states below E F are fully. <strong>The</strong>re is no room<br />

for any more electron, because <strong>of</strong> <strong>the</strong> exclusion principle. That<br />

is why <strong>the</strong> pair must, with an energy just below E F (by ∆),<br />

must remain bound.<br />

Superconductivity 25

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