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Three-dimensional Lagrangian Tracer Modelling in Wadden Sea ...

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CHAPTER 2. THEORY 13<br />

j<br />

∆y<br />

k<br />

i<br />

i<br />

∆x<br />

H, ζ, k, ε, ν , ν'<br />

u, U<br />

v, V<br />

ρ, C i<br />

u<br />

w, k, ε, ν , ν'<br />

t t<br />

Fig. 2.1.2: a) horizontal model grid and b) vertical grid. Each grid box refers<br />

to the tracer po<strong>in</strong>t (T-po<strong>in</strong>t) <strong>in</strong> its centre. The physical quantities located on the<br />

grid are expla<strong>in</strong>ed <strong>in</strong> the text. The follow<strong>in</strong>g symbols are used: +: T-po<strong>in</strong>ts; ×:<br />

u-po<strong>in</strong>ts; ⋆: v-po<strong>in</strong>ts; △: w-po<strong>in</strong>ts; •: x-po<strong>in</strong>ts; ◦: x u -po<strong>in</strong>ts. The <strong>in</strong>serted frames<br />

denote grid po<strong>in</strong>ts with the same <strong>in</strong>dex (i, j) and (i, k), respectively. The figures<br />

have been adapted from Burchard and Bold<strong>in</strong>g [2002].<br />

nature, and transport is from regions of high concentration to low concentration.<br />

To derive a diffusive flux equation, two rows of molecules side-by-side<br />

and centred at x = 0 are considered (Fig. 2.2.1a). Each of these molecules<br />

moves about randomly <strong>in</strong> response to the temperature. For simplicity’s sake<br />

only the x-component of their three-<strong>dimensional</strong> motion is taken <strong>in</strong>to account<br />

(i.e. motion to the left or right) with the same constant diffusion<br />

velocity for each particle. The mass of molecules on the left is def<strong>in</strong>ed as Ml<br />

and the mass of molecules on the right as Mr while the probability (transfer<br />

rate per time) that one of them moves across x = 0 is k. After some time<br />

∆t, approximately half of the particles have taken steps to the right and the<br />

other half has taken steps to the left as depicted by Fig. 2.2.1b and 2.2.1c.<br />

The particle histograms <strong>in</strong> Fig. 2.2.1 show that maximum concentrations<br />

decrease while the total region conta<strong>in</strong><strong>in</strong>g molecules <strong>in</strong>creases (the particle<br />

cloud spreads out). Mathematically, the average flux of particles from the<br />

left-hand column to the right is −k Ml and the average flux of particles from<br />

the right-hand column to the left is −k Mr where the m<strong>in</strong>us sign is used to<br />

dist<strong>in</strong>guish direction. Thus, the net flux qx is<br />

qx = k (Ml − Mr). (2.2.1)<br />

t<br />

t<br />

b)<br />

a)

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