Eighth Condensed Phase and Interfacial Molecular Science (CPIMS)

Figure 2: A phase diagram for water confined to a disordered hydrophilic nanopore
of radius R. [Adapted from Ref. 16.] In this pictured case, the external
pressure is 1 atm. Lines are theoretical curves derived from effects of the
interfaces present as the result of confinement (there are no adjustable
parameters, only measured bulk transport properties, thermodynamics and liquidice
interfacial tension enter the theoretical analysis). Experimental data points are
from calorimetric observations of the water-ice and water-glass transitions.
Recent DOE Supported Research Publications
1. Patel, A. J., P. Varilly and D. Chandler, "Fluctuations of water near extended
hydrophobic and hydrophilic surfaces," J. Phys. Chem. B, 114, 1632–1637 (2010).
2. Willard, A.P. and D. Chandler, "Instantaneous Liquid Interfaces," J. Phys. Chem. B,
114, 1954–1958 (2010).
3. Chandler, D. and J.P. Garrahan, "Dynamics on the Way to Forming Glass: Bubbles in
Space-time" Annu. Rev. Phys. Chem., 61, 191-217 (2010).
4. Elmatad, Yael S., R.L. Jack, J.P. Garrahan and D. Chandler, "Finite-temperature
critical point of a glass transition," Proc. Natl. Acad. Sci. USA 107, 12793-12798 (2010).
5. Elmatad, Y.S., D. Chandler, and J.P. Garrahan, "Corresponding States of Structural
Glass Formers II", J. Phys. Chem. B 114, 17113-17119 (2010).
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