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CIMAC Congress - Schiff & Hafen

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<strong>CIMAC</strong> CONGRESS | BERGEN 2010<br />

reduction rate at each load and the effects of a kind of the reducing<br />

agent, which are ammonia gas and urea water. As the results, it is<br />

confi rmed that the SCR system has suitable NOx reduction<br />

performance at each load. It is also clarifi ed that there is no deference<br />

by the kind of reducing agent in enough high temperature of the<br />

exhaust gas. On the other hand, we have investigated control<br />

methods with the experimental SCR system. In the control system,<br />

the reducing agent is controlled by a calculated exhaust gas fl ow rate<br />

and a measured NOx concentration. It is confi rmed that the control<br />

system has suitable performance in our early tests. Based on the<br />

above test results, we have designed and developed a SCR system for<br />

a marine Diesel generator on a ship. The SCR system is installed to<br />

the ship and examined on board at sea. In the actual ship, there is<br />

not enough wide space for the SCR. Therefore the distance between<br />

the injection nozzle and the catalyst of the SCR system must be<br />

short, though it is needed a long distance for the conversion to<br />

ammonia from urea generally. We developed a special injection<br />

nozzle for the system and achieved suitable NOx reduction<br />

performance. In conclusion, we got a lot of benefi cial results to<br />

apply a SCR system to a middle-speed marine diesel engine. In the<br />

next step, in order to develop a practical SCR system, it is necessary<br />

to develop a simple and low-cost control system and to estimate a<br />

durability performance of catalyst. Also, in order to apply the SCR<br />

system to large two-stroke diesel engine, we need to examine the<br />

SCR system performance in detail, because the engine has too low<br />

temperature of exhaust gas.<br />

Development of a NOx fast sampling<br />

system for marine diesel engines<br />

M. Ioannou, K. Xepapa, T. Stelios, N. Kyrtatos, NTUA,<br />

Greece<br />

Cylinder specifi c NOx measurements for large marine engines can<br />

provide important information for the combustion system that can<br />

be used by the engine design and development engineers. In<br />

addition, signifi cant cost savings can result from reduced test bed<br />

running times which are usually required to characterise the<br />

combustion system. Furthermore, detailed NOx measured data can<br />

be used for the development and calibration of combustion system<br />

simulation models. Emission measurement equipment that allow<br />

cylinder specifi c measurements are currently only available to<br />

automotive industry applications. Due to the size of marine diesel<br />

engines, and more specifi cally the exhaust system, this equipment<br />

needs to be suitably modifi ed in order to be used in large engines.<br />

The work reported here describes the further design and development<br />

of a NOx fast sampling system applicable to marine diesel engines<br />

towards a more reliable and robust system. The most important<br />

considerations when sampling exhaust gases from a marine engine<br />

is the strong possibility of probe’s blockage due to excessive soot<br />

deposition and the mechanical reliability, without compromising<br />

the performance of the measuring system. All these factors were<br />

considered during the design phase and the developed sampling<br />

system satisfi es all requirements successfully. The main design<br />

parameters of the sampling system were fi rst evaluated though<br />

theoretical analysis, followed by fl ow bench investigations, and the<br />

fi nal evaluation of the design was done on the test bed by performing<br />

NOx measurements on a marine diesel research engine. The<br />

emission measurements were supported by detailed measurements<br />

of the engine performance parameters. The fi nal probe design is a<br />

customised sampling system for a fast response chemiluminescence<br />

detector that can measure NOx in the exhaust gases downstream<br />

the exhaust valve of a specifi c cylinder of a marine diesel engine.<br />

The extremely fast response time of the system enables the<br />

characterization of NOx during an engine cycle with a one degree<br />

crank-angle resolution.<br />

46<br />

Ship & Offshore | 2010 | No. 3<br />

Development of sulfur-tolerant SCR type<br />

De-NOx system for marine applications<br />

Y.-M. Lee, S.-K. An, DSME, Korea, K.-H. Kang, Y.-D.<br />

Yoo, IAE, Korea, Ø. Toft, BW Fleet Management AS,<br />

Norway<br />

Nitrogen oxides (NOx) are mainly generated by combustion of<br />

fossil fuels used for marine vessels. Nowadays, a consensus has been<br />

reached internationally to limit emission of air-polluting<br />

compounds. And the NOx emission level requirements of marine<br />

diesel engine are getting more stringent these days. Especially to<br />

meet the Tier III requirement of IMO MPEC 58, external fl ue gas<br />

treatment system may be necessary as the requirements cannot be<br />

met by NOx reduction system in diesel engine boundary. One of the<br />

possible solutions of the NOx reduction could be the Selective<br />

Catalytic Reduction (SCR) type De-NOx system. However, it is well<br />

known that the SCR performance is greatly affected by the fl ue gas<br />

temperature and the existence of sulfur contents and that the<br />

temperature of exhaust gas from the marine diesel engine is relatively<br />

low and sulfur components are detrimental to the catalyst. In marine<br />

diesel oil, some amount of sulfur is contained in most of the cases.<br />

The typical contents of the sulfur in marine fuel oil could be 1.0<br />

4 ~ .5% range. It is believed that the allowable sulfur level contained in<br />

fuel oil will be gradually reduced. Nevertheless, the complete<br />

removal of the sulfur in fuel oil is impractical due to high<br />

desulfurization cost in the process of fuel oil production. With the<br />

reason, the De-NOx system which can be operated in the existence<br />

of some range of sulfur, typically 1% in fuel oil, might be practically<br />

implemented in the marine diesel engine in the near future. Daewoo<br />

Shipbuilding and Marine Engineering Co., Ltd. (DSME) and BW<br />

Group are developing “Sulfurtolerant SCR type De-NOx system for<br />

Marine Applications”. We have evaluated the durability and<br />

optimum conditions for NOx reduction performance using selected<br />

commercial catalysts and have developed SCR catalyst suitable for<br />

low temperature and existence of SOx contents with a manufacturer<br />

specialized in the SCR catalyst. The infl uences of the SOx contents<br />

and dust for the developed SCR have been compared by extensive<br />

experiments. For the verifi cation of the developed SCR, bench scale<br />

test facility has been utilized. With the facility, various performance<br />

comparisons of SOx and dust have been achieved. The test has been<br />

carried with the collaboration of Institute of Advanced Engineering<br />

(IAE). In addition to the bench scale test, we have been selected<br />

optimum combination of catalyst and SCR operational variables<br />

with the aid of computational fl uid dynamics (CFD). Through the<br />

studies, we expect sulfur-tolerant SCR element and practical De-<br />

NOx system for marine applications would be developed. Based on<br />

the results obtained from the test and CFD analysis, detailed<br />

engineering design and actual onboard tests will be carried out for<br />

targeted vessel. We expect the developed De-NOx system would<br />

contribute to the emission reduction in the marine industry.<br />

10:30 June 15th Room Troldtog<br />

(6–3) Product Development, Component<br />

& Maintenance Technology –<br />

Gas Engines – Technology, Fuels & Emissions<br />

Methane slip reduction in Wärtsilä lean<br />

burn gas engines<br />

A. Järvi, Wärtsilä, Finland<br />

Global warming set reduction needs for all greenhouse gases. Lean<br />

burn gas engines are having superior effi ciency and thanks to lowcarbon<br />

fuel, CO 2 emissions are low compared to diesel engines and<br />

gas turbines. Though the main emissions (CO 2 and NOx) are

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