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Enclosure fires

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Heat of combustion, This measures the amount of energy the material releases<br />

DH c when it burns. The unit used is MJ/kg or kJ/g.<br />

Heat of vaporisation, The heat of vaporisation is the amount of heat required to<br />

DH v (sometimes L v) produce 1 g gas from the fuel surface.<br />

170<br />

Laminar fl ow There are two different types of fl ow. This is evident when,<br />

for instance, smoke fl ows up and out of a narrow chimney.<br />

First of all, the smoke moves in a parallel layer without<br />

mixing. But at a certain distance from the outlet the fl ow<br />

type changes and smoke particles move in irregular paths, in<br />

a swirling motion. The layered type of fl ow is known as<br />

laminar and the irregular as turbulent. The word “laminar” is<br />

taken from the Latin word “lamina”, meaning plate, board,<br />

and “turbulent” is taken from the Latin word “turbulentur”,<br />

meaning disturbed or tempestuous.<br />

Mass loss rate The mass loss rate is the speed at which pyrolysis occurs<br />

from a material, sometimes also known as the rate of<br />

pyrolysis. This is often measured in the unit g/m 2 s.<br />

Premixed fl ames A premixed fl ame occurs when the fuel and air are well<br />

mixed with each other before ignition occurs.<br />

Pulsation Pulsations occur occasionally when the fi re is entering a<br />

ventilation-controlled stage. If there is an opening in the<br />

room the fi re can have access to air to allow combustion to<br />

take place. As a result of this, positive pressure builds up in<br />

the room and the temperature rises. The fi re subsides due to<br />

oxygen defi ciency and the temperature falls as new air can be<br />

drawn into the room.<br />

Pyrolysis Pyrolysis is a chemical decomposition process or other<br />

chemical conversion from complex to simpler constituents,<br />

caused by the effect of heat.<br />

Smoke gas explosion When unburnt smoke gases leak into an area adjacent to the<br />

fi re room they can mix very well with air to produce a<br />

combustible mixture. If there is an ignition source available<br />

or one becomes available some other way, the smoke gases<br />

can ignite, with an extremely devastating effect. As a rule, this<br />

phenomenon occurs seldom.

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