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Ignition<br />

Figure 10.<br />

Combustion process.<br />

Infl ammability in<br />

solid materials is<br />

estimated using<br />

the time it takes for<br />

ignition to occur.<br />

20<br />

+ O2 Energy + H2O + CO2+ CO + carbon particles, etc.<br />

Exothermic process<br />

2.2 Ignition of solid material<br />

Combustion is a chemical reaction. It involves, to be more<br />

precise, a whole series of chemical reactions when the fuel is<br />

oxidised. Fuel and oxidising agents react with each other. This<br />

releases heat and light. As a result, the chemical process is accompanied<br />

by physical effects. Heat is the physical energy<br />

which is released during the chemical process. Light is the<br />

physical consequence of the fact that there is energy stored in<br />

the soot particles, for instance.<br />

Ignition is the fi rst visible sign of combustion. The combustible<br />

material may auto-ignite due to the high temperature<br />

or it can be ignited by an external source such as a match or<br />

spark. In the case of solid materials, there is a critical temperature<br />

at which ignition takes place. But this generally varies according<br />

to the material which is burning and can therefore<br />

not be used as a measure of infl ammability. With solid materials,<br />

the surface must be heated up to 300–400°C for ignition to<br />

occur with a pilot fl ame. If there is no fl ame nearby the surface<br />

temperature must be higher. Wood needs to reach a surface<br />

temperature of 500–600°C before it auto-ignites. 5<br />

Infl ammability in solid materials is estimated using the<br />

time it takes for ignition to occur. Ignition takes place when<br />

suffi cient combustible gases have built up on the solid material’s<br />

surface for them to be ignited by a small fl ame.<br />

Materials such as wood or paper (organic polymers) need<br />

to emit 2 g/m 2 s (grams per square metre and second) of combustible<br />

gases to be able to ignite. As for plastics (synthetic<br />

polymers), which have a high energy content, they need about<br />

1 g/m 2 s of combustible gases to be able to ignite.<br />

Figure 11 shows what happens on the fuel surface when the

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