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Enclosure fires

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Figure 41. Flame<br />

distribution in a<br />

premixed gaseous<br />

mass. 12<br />

62<br />

as more energy is released. It is not the case, however, that the<br />

burning velocity will increase, the higher the proportion of<br />

fuel in the gaseous mass. It is rather that the burning velocity<br />

reaches its highest value when the stoichiometric mixture is<br />

roughly achieved and it then drops towards the upper fl ammability<br />

limit.<br />

Figure 40 shows the rate of laminar burning velocity for<br />

methane and propane respectively. The burning velocity will<br />

affect the build-up of pressure in a room. The nearer to the<br />

stoichiometric point, the faster the burning velocity.<br />

If we compare the heat released at the lower fl ammability<br />

limit and when the stoichiometric point is reached, more energy<br />

is released in the latter case, as there is a higher percentage<br />

of fuel combusted. This means that the burning velocity will<br />

be higher with the stoichiometric mixture, compared to at the<br />

lower fl ammability limit.<br />

Similar comparisons can be made between the stoichiometric<br />

point and the upper fl ammability limit. When we get<br />

into this upper section of the fl ammability range, it is the<br />

amount of oxygen which determines how much energy can be<br />

released.<br />

The richer in energy the gases are, the faster the burning<br />

velocity will be. The burning velocity (S u) is dependent on the<br />

energy released.<br />

Some plastics have a high energy value, which means that<br />

the smoke gases can contain a lot of potential energy if com-<br />

Ignition source<br />

Thin reaction zone<br />

Zone with unburnt gas<br />

Burning velocity<br />

Flame speed

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