A survey and health assessment of cosmetic products for children

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28 whereas a high number (low ranking) indicates that the substance is an additive, for instance preservatives. Appendix A (chapter 3) shows the chemical substances in the cosmetic products for children divided on the type of product. I.e. which substances are found in shampoo, tooth paste, hair styling products, perfume etc. At the same time Appendix A (chapter 3) shows which average ranking the substances form a part of for the mentioned product type, i.e. which average relative concentration the substances form a part of. Table 4.5 below shows the 50 most abundant chemical substances in the mapped products. At the same time the table shows how many of the 208 products the substances form a part of as well as with which average ranking. Table 4.5: the 50 most abundant constituents in the cosmetic products for children. INCI Name CAS No. Chemical name (as stated in the INCI list) Function In number of products Average ranking AQUA 7732-18-5 Water. solvent 176 1.6 Perfume and aromatic compositions deodorant / PARFUM and their raw materials masking denaturant / humectant / 153 10.4 GLYCERIN 56-81-5 Glycerol. solvent 95 5.5 METHYLPARABEN 99-76-3 Methyl 4-hydroxybenzoate. preservative 79 11.2 SODIUM LAURETH SULFATE 9004-82-4 Poly(oxy-1,2-ethanediyl), .α.-sulfo- ω.- (dodecyloxy)-, sodium salt surfactant / cleansing / foaming 77 2.3 1-Propanaminium, 3-amino-N- (carboxymethyl)-N,N-dimethyl-, N- surfactant / coco acyl derivs., hydroxides, inner cleansing / foam COCAMIDOPROPYL BETAINE 61789-40-0 salts. boosting 72 4.1 PROPYLPARABEN 94-13-3 Propyl 4-hydroxybenzoate. preservative 70 13.2 CITRIC ACID 77-92-9 CI 42090 3844-45-9 SODIUM CHLORIDE 7647-14-5 Sodium chloride. 2-Hydroxy-1,2,3-propanetricarboxylic acid Dihydrogen (ethyl)[4-[4-[ethyl(3sulphonatobenzyl)]amino]-2'sulphonatobenzhydrylidene]cyclohexa-2,5-dien-1-ylidene](3sulphonatobenzyl)ammonium, disodium salt and other permitted lakes and salts buffering / chelating 70 10.0 cosmetic colorant viscosity controlling / 62 15.6 bulking 54 6.1 Disodium 5-amino-4-hydroxy-3- (phenylazo)naphthalene-2,7disulphonate and its permitted lakes cosmetic CI 17200 3567-66-6 and salts colorant 50 13.7 PHENOXYETHANOL 122-99-6 2-Phenoxyethanol. preservative 50 9.2 BUTYLPARABEN 94-26-8 Butyl 4-hydroxybenzoate. preservative 48 14.1 LIMONENE 5989-27-5 48 14.0 ETHYLPARABEN 120-47-8 Ethyl 4-hydroxybenzoate. preservative 46 11.6
INCI Name CAS No. Chemical name (as stated in the INCI list) Function In number of products LINALOOL 78-70-6 1,6-Octadiene-3-ol, 3,7-dimethyl- deodorant emulsifying / emulsion stabilising / surfactant / viscosity controlling / 45 13.7 COCAMIDE DEA 68603-42-9 Amides, coco, N,N-bis(hydroxyethyl). foam boosting 42 4.7 Trisodium 5-hydroxy-1-(4sulphophenyl)-4-(4sulphophenylazo)pyrazole-3carboxylate and its permitted lakes cosmetic CI 19140 1934-21-0 and salts colorant 40 16.3 ISOBUTYLPARABEN 857-25-9 Isobutyl 4-hydroxybenzoate. preservative humectant / solvent / skin conditioning / viscosity 39 15.0 PROPYLENE GLYCOL 57-55-6 Propane-1,2-diol. controlling denaturant / emulsifying / surfactant / 33 7.5 SODIUM LAURYL SULFATE 151-21-3 Sodium dodecyl sulphate. foaming 32 6.2 TETRASODIUM EDTA 64-02-8 Average ranking Tetrasodium ethylenediaminetetraacetate. chelating 30 10.7 GERANIOL 106-24-1 2,6-Octadiene-1-ol, 3,7-dimethyl-, (2E)- tonic 25 11.8 CITRONELLOL 106-22-9 Citronellol. masking humectant / plasticiser / skin 22 11.9 SORBITOL 50-70-4 D-Glucitol. conditioning 22 3.0 HEXYL CINNAMAL 101-86-0 21 19.4 ALCOHOL 64-17-5 Ethanol. solvent 20 7.1 BENZYL SALICYLATE 118-58-1 Benzyl salicylate. uv absorber preservative / 20 12.4 BENZYL ALCOHOL 100-51-6 Benzyl alcohol. solvent 20 16.3 BENZYL BENZOATE 120-51-4 Benzyl benzoate. solvent antistatic / hair conditioning / 19 11.6 Butanamide, 2,4-dihydroxy-N-(3- skin PANTHENOL 81-13-0 hydroxypropyl)-3,3-dimethyl-, (2R)- conditioning emollient / emulsifying / emulsion stabilising / opacifying / viscosity 18 9.3 CETEARYL ALCOHOL 67762-27-0 Alcohols, C16-18. controlling 18 5.6 AROMA Flavours or aromatic compositions and their ingredients 18 8.6 CITRAL 5392-40-5 2,6-Octadienal, 3,7-dimethyl- masking abrasive / absorbent / opacifying / viscosity controlling / anticaking / 17 16.1 HYDRATED SILICA 10279-57-9 Silicic acid. bulking 17 2.9 AMYL CINNAMAL 122-40-7 2-Benzylideneheptanal. masking 17 22.1 29
Page 1 and 2: A survey and health assessment of c
Page 3 and 4: Contents PREFACE 5 SUMMARY AND CONC
Page 5: Preface This project ”A survey an
Page 8 and 9: 8 that cosmetic products for childr
Page 10 and 11: 10 fragrances in the product. For t
Page 12 and 13: 12 2 Definition of cosmetic product
Page 14 and 15: 14 3 Legislation In the following t
Page 16 and 17: 16 According to §13 of the Cosmeti
Page 18 and 19: 18 4 Survey One of the purposes of
Page 20 and 21: 20 Shops where we have looked for p
Page 22 and 23: 22 Table 4.2: information about the
Page 24 and 25: 24 • There are spelling mistakes
Page 26 and 27: 26 in the survey period from mid-Ap
Page 30 and 31: INCI Name CAS No. CI 16255 2611-82-
Page 32 and 33: 32 an offer to importers/producers
Page 34 and 35: 34 4.3.9 Constituents with restrict
Page 36 and 37: 36 Table 4.9: Overview of products
Page 38 and 39: 38 The 26 fragrances mandatory to d
Page 40 and 41: 40 INCI Name 5-BROMO-5-NITRO-1,3- D
Page 42 and 43: 42 INCI Name Function (as stated in
Page 44 and 45: 44 things. According to the Toys St
Page 46 and 47: 46 5 Analysis results The purpose o
Page 48 and 49: 48 Kathon - one series of five prod
Page 50 and 51: 50 relevant to examine for a possib
Page 52 and 53: Table 5.7: Results from the analysi
Page 54 and 55: Table 5.7 (cont’d): Results from
Page 56 and 57: Table 5.7 (cont’d): Results from
Page 58 and 59: 58 As it can be seen from the analy
Page 60 and 61: 60 5.3 Analyses of selected packagi
Page 62 and 63: 62 5.3.2.2 Content of heavy metals
Page 64 and 65: 64 Table 5.15: Content of phthalate
Page 66 and 67: 66 6 Health assessment 6.1 Selectio
Page 68 and 69: 68 Identification Chemical name Ben
Page 70 and 71: 70 Tabel 6-1: Acute toxicy (LD50) o
Page 72 and 73: 72 fragrance/preservative benzyl al
Page 74 and 75: 74 regards sodium benzoate as being
Page 76 and 77: 76 Table 6.3: Identification of Kat
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78 Table 6.5: Acute toxicity (LD50)
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80 this test a NOAEL of 250 ppm act
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82 Identification Chemical name 2-p
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84 Phenoxyethanol has shown damagin
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86 Table 6.8: Acute toxicity (LD50)
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88 7.1 Kathon Product type Number o
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90 100% of the Kathon to which the
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92 the content corresponds to a sma
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94 8 Discussion 8.1 Risk assessment
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96 Recommendations to consumers •
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98 http://www.videncenterforallergi
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100 Graham & Kuizenga, 1945. Graham
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102 NPIRI, 1974. ”Raw Materials D
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104 SCCNFP 0670, 2003. The Scientif
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106 Wibbertmann et al, Fraunhofer I
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108
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110 the product whereas a high numb
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112 2 All chemical substances found
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Chemical name as described in Is in
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118 INCI Name CAS No. Chemical name
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124 INCI Name CAS No. BRASSICA CAMP
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148 INCI Name CAS No. CITRUS AURANT
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164 Chemical name as described in I
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170 3 Chemical substances in the ma
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172 Is in number of Average INCI Na
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176 3.2 Balsam Is in number of Aver
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180 3.3 Body lotion/cream Is in num
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190 3.4 Body shampoo/bath gel Is in
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196 3.5 Shampoo Is in number of Ave
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198 2-BROMO-2- NITROPROPANE- 1,3-DI
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200 CI 42051 CI 16185 ECHINACEA ANG
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202 SODIUM LAUROAMPHOACE TATE PRUNU
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204 MAGNESIUM LAURETH-8 SULFATE sur
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Is in number of Average INCI Name C
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216 4 Constituents with restriction
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218 INCI Name CAS N. Function Is in
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220
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