A survey and health assessment of cosmetic products for children

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40 INCI Name 5-BROMO-5-NITRO-1,3- DIOXANE Occurrence in number of products Remarks Maximum permissible concentration 1 15 Allergenic (according to 0.1% self-classification of the Only to be used in products Danish EPA) which are to be cleansed after Separates apply formaldehyde SODIUM BENZOATE 13 0.5% (like acid) DMDM HYDANTOIN 11 Allergenic (according to self-classification of the Danish EPA) Separates formaldehyde 0.6% CETRIMONIUM CHLORIDE 9 0.1% IMIDAZOLIDINYL UREA BEHENTRIMONIUM CHLORIDE 2-BROMO-2- NITROPROPANE-1,3- DIOL 7 Allergenic (according to self-classification of the Danish EPA) Separates formaldehyde 7 6 Potentially allergenic. Separates formaledehyde DIAZOLIDINYL UREA 4 Potentially allergenic. Separates formaldehyde ISOPROPYLPARABEN 4 Under evaluation for hormone-disrupting properties. Allergenic (according to selfclassification of the Danish EPA) QUATERNIUM-15 2 Potentially allergenic. Separates formaldehyde LAURTRIMONIUM CHLORIDE 2 IODOPROPYNYL BUTYLCARBAMATE 0.6% 0.1% 0.1% 0.5% 0.4% (acid) for one ester 0.8% (acid) for ester mixtures 0.2% 0.1% 1 Allergenic 0.05% Must not be used in products for oral hygiene or for the lips. If the concentration in products which are not to be cleansed of the skin is higher than 0.02%, then “contains” iodine” must be stated POTASSIUM SORBATE 1 Allergenic (according to selfclassification of the Danish EPA) SODIUM METHYLPARABEN 0.6% (like acid) 1 0.4% (acid) for one ester 0.8% (acid) for ester mixtures 1 According to Appendix 5 in the Cosmetics Statutory Order (Stat. Ord. 422, 2006). 2 The mixture of methylisothiazolinone and methylchloroisothiazolinone is also called Kathon. The allergenic preservative MG (methyldibromo glutaronitrile) being mentioned much during the last couple of years is not found in any of the mapped products.
4.3.12.1 Preservatives with application limitations In general, there are concentration limitations on all the applied preservatives. Furthermore, two of the preservatives have application limitations. 5-bromo-5-nitro-1,3-dioxane must only be applied in products which are to be cleansed of after apply. This preservative is found in totally 15 products and all these products are body shampoo/bath gel or bobble bath; that means products being cleansed of after apply. Iodopropynyl butylcarbamate must not be used for oral hygiene or for the lips and if the concentration is higher than a certain level for products not being cleansed of after apply it must be stated on the product that it contains iodine. Iodopropynyl butylcarbamate is only in one product which is a balsam; that means a product being cleansed of after apply. 4.3.13 No content of triclosan None of the 208 mapped products contains triclosan. 4.3.14 Content of colouring agents 119 of the 208 products contain a colouring agent (where the function hair dyeing or cosmetic colorant is stated via the INCI list). In total 45 different colouring agents are found in the 208 mapped products. These are listed in the table below after frequency. Table 4.13: Applied colouring agents in cosmetic products for children INCI Name Function (as stated in the INCI list) Occurrence in number of products Remarks CI 42090 cosmetic colorant 62 CI 17200 cosmetic colorant 50 CI 19140 cosmetic colorant 40 CI 16255 cosmetic colorant 16 CI 16035 cosmetic colorant 14 CI 14700 cosmetic colorant 12 CI 77891 cosmetic colorant 10 CI 73360 cosmetic colorant 7 CI 47005 cosmetic colorant 6 CI 77007 cosmetic colorant 6 HC RED NO. 3 hair dyeing 6 Allergenic (according to selfclassification of the Danish EPA) 3-NITRO-p- HYDROXYETHYLAMINOPHENOL hair dyeing 5 CI 12085 cosmetic colorant 5 CI 15985 cosmetic colorant 5 CI 16185 cosmetic colorant 5 CI 59040 cosmetic colorant 5 CI 61570 cosmetic colorant 5 CI 75810 cosmetic colorant 5 4-AMINO-3-NITROPHENOL hair dyeing 4 CI 45100 cosmetic colorant 4 CI 45380 cosmetic colorant 4 CI 45430 cosmetic colorant 4 BASIC BLUE 99 hair dyeing 3 41
Page 1 and 2: A survey and health assessment of c
Page 3 and 4: Contents PREFACE 5 SUMMARY AND CONC
Page 5: Preface This project ”A survey an
Page 8 and 9: 8 that cosmetic products for childr
Page 10 and 11: 10 fragrances in the product. For t
Page 12 and 13: 12 2 Definition of cosmetic product
Page 14 and 15: 14 3 Legislation In the following t
Page 16 and 17: 16 According to §13 of the Cosmeti
Page 18 and 19: 18 4 Survey One of the purposes of
Page 20 and 21: 20 Shops where we have looked for p
Page 22 and 23: 22 Table 4.2: information about the
Page 24 and 25: 24 • There are spelling mistakes
Page 26 and 27: 26 in the survey period from mid-Ap
Page 28 and 29: 28 whereas a high number (low ranki
Page 30 and 31: INCI Name CAS No. CI 16255 2611-82-
Page 32 and 33: 32 an offer to importers/producers
Page 34 and 35: 34 4.3.9 Constituents with restrict
Page 36 and 37: 36 Table 4.9: Overview of products
Page 38 and 39: 38 The 26 fragrances mandatory to d
Page 42 and 43: 42 INCI Name Function (as stated in
Page 44 and 45: 44 things. According to the Toys St
Page 46 and 47: 46 5 Analysis results The purpose o
Page 48 and 49: 48 Kathon - one series of five prod
Page 50 and 51: 50 relevant to examine for a possib
Page 52 and 53: Table 5.7: Results from the analysi
Page 54 and 55: Table 5.7 (cont’d): Results from
Page 56 and 57: Table 5.7 (cont’d): Results from
Page 58 and 59: 58 As it can be seen from the analy
Page 60 and 61: 60 5.3 Analyses of selected packagi
Page 62 and 63: 62 5.3.2.2 Content of heavy metals
Page 64 and 65: 64 Table 5.15: Content of phthalate
Page 66 and 67: 66 6 Health assessment 6.1 Selectio
Page 68 and 69: 68 Identification Chemical name Ben
Page 70 and 71: 70 Tabel 6-1: Acute toxicy (LD50) o
Page 72 and 73: 72 fragrance/preservative benzyl al
Page 74 and 75: 74 regards sodium benzoate as being
Page 76 and 77: 76 Table 6.3: Identification of Kat
Page 78 and 79: 78 Table 6.5: Acute toxicity (LD50)
Page 80 and 81: 80 this test a NOAEL of 250 ppm act
Page 82 and 83: 82 Identification Chemical name 2-p
Page 84 and 85: 84 Phenoxyethanol has shown damagin
Page 86 and 87: 86 Table 6.8: Acute toxicity (LD50)
Page 88 and 89: 88 7.1 Kathon Product type Number o
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90 100% of the Kathon to which the
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92 the content corresponds to a sma
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94 8 Discussion 8.1 Risk assessment
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96 Recommendations to consumers •
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98 http://www.videncenterforallergi
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100 Graham & Kuizenga, 1945. Graham
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102 NPIRI, 1974. ”Raw Materials D
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104 SCCNFP 0670, 2003. The Scientif
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106 Wibbertmann et al, Fraunhofer I
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108
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110 the product whereas a high numb
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112 2 All chemical substances found
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Chemical name as described in Is in
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118 INCI Name CAS No. Chemical name
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124 INCI Name CAS No. BRASSICA CAMP
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148 INCI Name CAS No. CITRUS AURANT
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164 Chemical name as described in I
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170 3 Chemical substances in the ma
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172 Is in number of Average INCI Na
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176 3.2 Balsam Is in number of Aver
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180 3.3 Body lotion/cream Is in num
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190 3.4 Body shampoo/bath gel Is in
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196 3.5 Shampoo Is in number of Ave
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198 2-BROMO-2- NITROPROPANE- 1,3-DI
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200 CI 42051 CI 16185 ECHINACEA ANG
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202 SODIUM LAUROAMPHOACE TATE PRUNU
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204 MAGNESIUM LAURETH-8 SULFATE sur
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Is in number of Average INCI Name C
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216 4 Constituents with restriction
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218 INCI Name CAS N. Function Is in
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A survey and health assessment of cosmetic products for children

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