A survey and health assessment of cosmetic products for children

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32 an offer to importers/producers on classification of chemical substances where no other reliable data are available. The list is prepared on basis of QSAR models. The result is seen below. In practice, a database run is made where CAS numbers as stated in the INCI list are compared to CAS numbers from the guiding list for self-classification of dangerous substances of the Danish Environmental Protection Agency. The result is seen below.
Table 4.7: Constituents in cosmetic products for children which in pure form are in the guiding list for selfclassification of dangerous substances of the Danish Environmental Protection Agency INCI Name Function CAS number (as stated in the INCI list) Recommended classification In number of products Average ranking BUTYLPARABEN preservative 94-26-8 N;R51/53 48 14.1 GERANIOL tonic 1 106-24-1 N;R50 25 11.8 BENZYL SALICYLATE uv absorber 118-58-1 R43 N;R50/53 20 12.4 5-BROMO-5-NITRO-1,3- DIOXANE preservative 30007-47-7 Xn;R22 R43 15 6.0 BUTYLPHENYL METHYLPROPIONAL masking 1 80-54-6 R43 N;R51/53 16 14.7 EUGENOL denaturant / tonic 1 97-53-0 Xn;R22 Mut3;R40 R43 15 11.2 METHYLCHLOROISOTHIAZO preservative LINONE 26172-55-4 R43 15 14.7 METHYLISOTHIAZOLINONE preservative 2682-20-4 R43 15 15.6 CINNAMYL ALCOHOL masking 1 104-54-1 R43 N;R50 14 17.4 HYDROXYCITRONELLAL masking 1 107-75-5 R43 13 13.7 DMDM HYDANTOIN preservative 6440-58-0 R43 11 9.2 GLYCERYL STEARATE emollient / emulsifying 31566-31-1 N;R51/53 10 7.9 BHT antioxidant 128-37-0 Xn;R22 N;R50/53 8 12.5 TRIETHANOLAMINE buffering 102-71-6 R43 8 9.0 IMIDAZOLIDINYL UREA preservative 39236-46-9 R43 7 21.1 LAURETH-12 emulsifying / surfactant 3056-00-6 N;R50/53 7 2.0 AMYLCINNAMYL ALCOHOL 1 101-85-9 N;R51/53 6 6.0 BENZYL CINNAMATE masking 1 103-41-3 N;R50/53 6 5.0 FARNESOL soothing / solvent / 4602-84-0 N;R50/53 6 21.0 deodorant 1 GLYCERYL OLEATE emollient / emulsifying 25496-72-4 N;R51/53 6 7.3 GLYCOL STEARATE emollient / emulsifying / opacifying / surfactant 111-60-4 N;R51/53 6 7.3 4-AMINO-3-NITROPHENOL hair dyeing 610-81-1 Xn;R22 R52/53 4 9.0 ISOPROPYLPARABEN preservative 4191-73-5 R43 4 15.0 CETYL ALCOHOL emollient / emulsifying / opacifying / viscosity controlling 36653-82-4 N;R51/53 3 5.0 HC BLUE NO. 2 hair dyeing 33229-34-4 R43 3 7.3 ISOPROPYL MYRISTATE binding / emollient / solvent / skin conditioning 110-27-0 N;R51/53 3 2.7 CINNAMAL denaturant 1 104-55-2 R43 N;R50 2 15.0 LAURETH-7 emulsifying / surfactant 3055-97-8 N;R50/53 2 14.0 CITRONELLAL masking 1 106-23-0 R43 N;R51/53 1 27.0 HC RED NO. 7 hair dyeing 24905-87-1 R43 1 10.0 ISOEUGENOL masking 1 97-54-1 Xn;R22 R43 1 34.0 LAURAMIDE DEA antistatic / viscosity controlling / foam boosting / surfactant 120-40-1 R43 1 3.0 LAURETH-4 emulsifying / surfactant / 5274-68-0 masking / antistatic N;R50/53 1 10.0 OCTOXYNOL-9 emulsifying / surfactant 42173-90-0 N;R50/53 1 11.0 OLEAMIDE DEA antistatic / viscosity controlling / foam boosting 93-83-4 R43 N;R50/53 1 10.0 PEG-2 STEARATE emulsifying / opacifying 106-11-6 N;R51/53 1 8.0 POTASSIUM SORBATE preservative 24634-61-5 R43 1 14.0 STEARAMIDE MEA antistatic / viscosity controlling / foam boosting 111-57-9 N;R51/53 1 7.0 1 Geraniol, butylphenyl methylpropional, eugenol, cinnamyl alcohol, hydorxycitronellal, amyl cinnamyl alcohol, benzyl cinnamate, farnesol, cinnamal, citronellal and isoeugenol have also a function as aroma/fragrance 33
Page 1 and 2: A survey and health assessment of c
Page 3 and 4: Contents PREFACE 5 SUMMARY AND CONC
Page 5: Preface This project ”A survey an
Page 8 and 9: 8 that cosmetic products for childr
Page 10 and 11: 10 fragrances in the product. For t
Page 12 and 13: 12 2 Definition of cosmetic product
Page 14 and 15: 14 3 Legislation In the following t
Page 16 and 17: 16 According to §13 of the Cosmeti
Page 18 and 19: 18 4 Survey One of the purposes of
Page 20 and 21: 20 Shops where we have looked for p
Page 22 and 23: 22 Table 4.2: information about the
Page 24 and 25: 24 • There are spelling mistakes
Page 26 and 27: 26 in the survey period from mid-Ap
Page 28 and 29: 28 whereas a high number (low ranki
Page 30 and 31: INCI Name CAS No. CI 16255 2611-82-
Page 34 and 35: 34 4.3.9 Constituents with restrict
Page 36 and 37: 36 Table 4.9: Overview of products
Page 38 and 39: 38 The 26 fragrances mandatory to d
Page 40 and 41: 40 INCI Name 5-BROMO-5-NITRO-1,3- D
Page 42 and 43: 42 INCI Name Function (as stated in
Page 44 and 45: 44 things. According to the Toys St
Page 46 and 47: 46 5 Analysis results The purpose o
Page 48 and 49: 48 Kathon - one series of five prod
Page 50 and 51: 50 relevant to examine for a possib
Page 52 and 53: Table 5.7: Results from the analysi
Page 54 and 55: Table 5.7 (cont’d): Results from
Page 56 and 57: Table 5.7 (cont’d): Results from
Page 58 and 59: 58 As it can be seen from the analy
Page 60 and 61: 60 5.3 Analyses of selected packagi
Page 62 and 63: 62 5.3.2.2 Content of heavy metals
Page 64 and 65: 64 Table 5.15: Content of phthalate
Page 66 and 67: 66 6 Health assessment 6.1 Selectio
Page 68 and 69: 68 Identification Chemical name Ben
Page 70 and 71: 70 Tabel 6-1: Acute toxicy (LD50) o
Page 72 and 73: 72 fragrance/preservative benzyl al
Page 74 and 75: 74 regards sodium benzoate as being
Page 76 and 77: 76 Table 6.3: Identification of Kat
Page 78 and 79: 78 Table 6.5: Acute toxicity (LD50)
Page 80 and 81: 80 this test a NOAEL of 250 ppm act
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82 Identification Chemical name 2-p
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84 Phenoxyethanol has shown damagin
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86 Table 6.8: Acute toxicity (LD50)
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88 7.1 Kathon Product type Number o
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90 100% of the Kathon to which the
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92 the content corresponds to a sma
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94 8 Discussion 8.1 Risk assessment
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96 Recommendations to consumers •
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98 http://www.videncenterforallergi
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100 Graham & Kuizenga, 1945. Graham
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102 NPIRI, 1974. ”Raw Materials D
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104 SCCNFP 0670, 2003. The Scientif
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106 Wibbertmann et al, Fraunhofer I
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108
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110 the product whereas a high numb
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112 2 All chemical substances found
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Chemical name as described in Is in
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118 INCI Name CAS No. Chemical name
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124 INCI Name CAS No. BRASSICA CAMP
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148 INCI Name CAS No. CITRUS AURANT
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164 Chemical name as described in I
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170 3 Chemical substances in the ma
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172 Is in number of Average INCI Na
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176 3.2 Balsam Is in number of Aver
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180 3.3 Body lotion/cream Is in num
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190 3.4 Body shampoo/bath gel Is in
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196 3.5 Shampoo Is in number of Ave
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198 2-BROMO-2- NITROPROPANE- 1,3-DI
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200 CI 42051 CI 16185 ECHINACEA ANG
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202 SODIUM LAUROAMPHOACE TATE PRUNU
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204 MAGNESIUM LAURETH-8 SULFATE sur
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Is in number of Average INCI Name C
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216 4 Constituents with restriction
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218 INCI Name CAS N. Function Is in
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220
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A survey and health assessment of cosmetic products for children

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