A survey and health assessment of cosmetic products for children

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INCI Name CAS No. CI 16255 2611-82-7 30 Chemical name (as stated in the INCI list) Trisodium 1-(1-naphthylazo)-2hydroxynaphthalene- 4',6,8trisulphonate. Function In number of products Average ranking cosmetic colorant 16 19.8 BUTYLPHENYL METHYLPROPIONAL 80-54-6 2-(4-tert-Butylbenzyl)propionaldehyde masking 16 14.7 EUGENOL 97-53-0 Phenol, 2-methoxy-4-(2-propenyl) FUCUS VESICULOSUS EXTRACT 84696-13-9 Fucus Vesiculosus Extract is an extract of the dried thallus of the bladderwrack algae, Fucus vesiculosus, Fucaceae denaturant / tonic 15 11.2 soothing / smoothing / emollient / skin conditioning 15 5.0 METHYLISOTHIAZOLINONE 2682-20-4 2-Methyl-2H-isothiazol-3-one. preservative 15 15.6 METHYLCHLOROISOTHIAZO LINONE 26172-55-4 5-Chloro-2-methyl-2H-isothiazol-3one. preservative 15 14.7 5-BROMO-5-NITRO-1,3- DIOXANE 30007-47-7 5-Bromo-5-nitro-1,3-dioxane. preservative binding / emulsion stabilising / viscosity controlling / gel 15 6.0 XANTHAN GUM 11138-66-2 Xanthan gum. forming 14 8.9 Disodium 6-hydroxy-5-[(2-methoxy-4sulphonato-m-tolyl)azo]naphthalene- 2-sulphonate and its permitted lakes cosmetic CI 16035 25956-17-6 and salts colorant 14 19.6 CINNAMYL ALCOHOL 104-54-1 Cinnamyl alcohol. masking 14 17.4 1,2-Benzisothiazol-3(2H)-one 1,1- oral care / SODIUM SACCHARIN 128-44-9 dioxide, sodium salt. masking emollient / emulsifying / opacifying / viscosity controlling / skin 14 11.0 GLYCOL DISTEARATE 627-83-8 Ethylene distearate. conditioning 13 18.8 SODIUM BENZOATE 532-32-1 Sodium benzoate. preservative abrasive / oral care / buffering / 13 11.7 SODIUM BICARBONATE 144-55-8 Sodium hydrogencarbonate. deodorant 13 2.0 1 Is an expression of the concentration as substances with ranking 1 are found in each product in the highest concentration (in largest quantity). As it is seen from the table water and perfume are the two constituents which are most frequently used in the cosmetic products for children. Of the 26 fragrances mandatory to declare (see a detailed description in section 4.3.11 ”Content of perfume”) 13 of these are on the list of the 50 most frequently used substances in cosmetic products for children. Of other frequently used constituents in the cosmetic products for children parabens (preservatives) can be mentioned. Listed below after declining frequency: • Methylparaben (in 79 products) • Propylparaben (in 70 products) • Butylparaben (in 48 products)
• Ethylparaben (in 46 products) • Isobutylparaben (in 39 products) 4.3.7 Constituents with hazard classification Out of the 461 different chemical substances which form a part of the 208 cosmetic products for children 19 of these are classified as hazardous in pure form according to the List of dangerous substances (Stat. Ord. 923, 2005). In practice, this is checked via a data run where CAS numbers as stated on the INCI list are compared with CAS numbers from the List of dangerous substances. The result is seen below. Table 4.6: Constituents in the cosmetic products for children which in pure form are classified as hazardous. INCI Name Function (as stated in the INCI list) CAS no. Classification In number of products Average ranking PHENOXYETHANOL preservative 122-99-6 Xn;R22 Xi;R36 50 9.2 LIMONENE 1 5989-27-5 R10 Xi;R38 R43 N;R50/53 48 14.0 ALCOHOL solvent 64-17-5 F;R11 20 7.1 BENZYL ALCOHOL preservative / solvent 100-51-6 Xn;R20/22 20 16.3 BENZYL BENZOATE solvent 120-51-4 Xn;R22 17 11.3 CITRAL masking 2 5392-40-5 Xi;R38 R43 17 16.1 SODIUM FLUORIDE oral care 3 / antiplaque 7681-49-4 T;R25 R32 Xi;R36/38 11 10.1 SODIUM HYDROXIDE buffering / denaturant 1310-73-2 C;R35 8 13.0 BUTANE propellant 106-97-8 Fx;R124 7 24.1 DIMETHYL ETHER propellant / solvent 115-10-6 Fx;R12 7 4.0 ISOBUTANE propellant 75-28-5 Fx;R124 7 6.3 PROPANE propellant 74-98-6 Fx;R12 7 19.3 2-BROMO-2- NITROPROPANE-1,3- DIOL preservative 52-51-7 Xn;R21/22 Xi;R37/38-41 N;R50 6 12.7 ETHYLHEXYLGLYCERIN skin conditioning 70445-33-9 Xi;R41 R52/53 3 12.0 AMINOMETHYL PROPANOL buffering 124-68-5 Xi;R36/38 R52/53 1 10.0 CYCLOMETHICONE antistatic / emollient / humectant / solvent / viscosity controlling / hair conditioning 556-67-2 Rep3;R62 R53 1 17.0 HC VIOLET NO. 2 hair dyeing 104226-19-9 R43 R52/53 1 7.0 HEXYLENE GLYCOL solvent / emulsifying / surfactant / skin conditioning 107-41-5 Xi;R36/38 1 8.0 ZINC OXIDE bulking / uv absorber 1314-13-2 / skin protecting N;R50/53 1 7.0 1 The function of Limonene is a solvent and aroma/fragrance 2 The function of Citral is also aroma/fragrance 3 Sodium fluoride strengthens against caries 4 Propelling gases as butane and isobutene are prohibited to use as propelling gas with Carc1 classification 4.3.8 Constituents in the guiding list for self-classification of the Danish Environmental Protection Agency Of the in total 461 different chemical substances which form a part of the 208 cosmetic products for children, 38 of them are in the guiding list for selfclassification of dangerous substances of the Danish Environmental Protection Agency (Environmental Project 635, 2001). The list is prepared as 31
Page 1 and 2: A survey and health assessment of c
Page 3 and 4: Contents PREFACE 5 SUMMARY AND CONC
Page 5: Preface This project ”A survey an
Page 8 and 9: 8 that cosmetic products for childr
Page 10 and 11: 10 fragrances in the product. For t
Page 12 and 13: 12 2 Definition of cosmetic product
Page 14 and 15: 14 3 Legislation In the following t
Page 16 and 17: 16 According to §13 of the Cosmeti
Page 18 and 19: 18 4 Survey One of the purposes of
Page 20 and 21: 20 Shops where we have looked for p
Page 22 and 23: 22 Table 4.2: information about the
Page 24 and 25: 24 • There are spelling mistakes
Page 26 and 27: 26 in the survey period from mid-Ap
Page 28 and 29: 28 whereas a high number (low ranki
Page 32 and 33: 32 an offer to importers/producers
Page 34 and 35: 34 4.3.9 Constituents with restrict
Page 36 and 37: 36 Table 4.9: Overview of products
Page 38 and 39: 38 The 26 fragrances mandatory to d
Page 40 and 41: 40 INCI Name 5-BROMO-5-NITRO-1,3- D
Page 42 and 43: 42 INCI Name Function (as stated in
Page 44 and 45: 44 things. According to the Toys St
Page 46 and 47: 46 5 Analysis results The purpose o
Page 48 and 49: 48 Kathon - one series of five prod
Page 50 and 51: 50 relevant to examine for a possib
Page 52 and 53: Table 5.7: Results from the analysi
Page 54 and 55: Table 5.7 (cont’d): Results from
Page 56 and 57: Table 5.7 (cont’d): Results from
Page 58 and 59: 58 As it can be seen from the analy
Page 60 and 61: 60 5.3 Analyses of selected packagi
Page 62 and 63: 62 5.3.2.2 Content of heavy metals
Page 64 and 65: 64 Table 5.15: Content of phthalate
Page 66 and 67: 66 6 Health assessment 6.1 Selectio
Page 68 and 69: 68 Identification Chemical name Ben
Page 70 and 71: 70 Tabel 6-1: Acute toxicy (LD50) o
Page 72 and 73: 72 fragrance/preservative benzyl al
Page 74 and 75: 74 regards sodium benzoate as being
Page 76 and 77: 76 Table 6.3: Identification of Kat
Page 78 and 79: 78 Table 6.5: Acute toxicity (LD50)
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80 this test a NOAEL of 250 ppm act
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82 Identification Chemical name 2-p
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84 Phenoxyethanol has shown damagin
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86 Table 6.8: Acute toxicity (LD50)
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88 7.1 Kathon Product type Number o
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90 100% of the Kathon to which the
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92 the content corresponds to a sma
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94 8 Discussion 8.1 Risk assessment
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96 Recommendations to consumers •
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98 http://www.videncenterforallergi
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100 Graham & Kuizenga, 1945. Graham
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102 NPIRI, 1974. ”Raw Materials D
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104 SCCNFP 0670, 2003. The Scientif
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106 Wibbertmann et al, Fraunhofer I
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108
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110 the product whereas a high numb
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112 2 All chemical substances found
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Chemical name as described in Is in
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118 INCI Name CAS No. Chemical name
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124 INCI Name CAS No. BRASSICA CAMP
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148 INCI Name CAS No. CITRUS AURANT
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164 Chemical name as described in I
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170 3 Chemical substances in the ma
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172 Is in number of Average INCI Na
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176 3.2 Balsam Is in number of Aver
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180 3.3 Body lotion/cream Is in num
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190 3.4 Body shampoo/bath gel Is in
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196 3.5 Shampoo Is in number of Ave
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198 2-BROMO-2- NITROPROPANE- 1,3-DI
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200 CI 42051 CI 16185 ECHINACEA ANG
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202 SODIUM LAUROAMPHOACE TATE PRUNU
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204 MAGNESIUM LAURETH-8 SULFATE sur
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Is in number of Average INCI Name C
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216 4 Constituents with restriction
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218 INCI Name CAS N. Function Is in
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A survey and health assessment of cosmetic products for children

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