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Predmet:Subject Title:Univerza v MariboruUniversity <strong>of</strong> MariborFakulteta za kemijo inkemijsko tehnologijoFaculty <strong>of</strong> Chemistry <strong>and</strong>Chemical EngineeringUČNI NAČRT PREDMETA / SUBJECT SPECIFICATIONFizikalna kemijaPhysical ChemistryŠtudijski programStudy programmeKemijska tehnologijaChemical TechnologyŠtudijska smerStudy fieldLetnikYear2.SemesterSemesterzimskiAutumnUniverzitetna koda predmeta / University subject code:PredavanjaLecturesSeminarSeminarSem. vajeTutorialLab. vajeLabor workTeren. vajeField workSamost. deloIndivid. work60 60 4ECTSNosilec predmeta / Lecturer:Aljana PetekJeziki /Languages:Predavanja / Lecture: slovenski / SloveneVaje / Tutorial: slovenski / SlovenePogoji za vključitev v delo oz. za opravljanještudijskih obveznosti:Osnovno znanje matematike in fizikePrerequisits:Basic knowledge <strong>of</strong> mathematics <strong>and</strong> physicsVsebina:Plini in sile med molekulami: idealni plin,kinetična teorija plinov, interakcije medmolekulami, van der Waalsov plinEnergija: prvi zakon termodinamike, spremembenotranje energije in entalpije v fizikalnokemijskihprocesih, termokemijaEntropija: drugi zakon termodinamike, entropijaplinov in plinastih mešanic, entropijskespremembe v fizikalno-kemijskih procesih, tretjizakon termodinamikeGibbsova prosta energija: posebna formulacijadrugega zakona, spremembe proste energije vfizikalno-kemijskih procesih, kemijski potencial,ravnoteţje v fizikalno-kemijskih sistemihRavnoteţje čistih snovi: fazni diagram,termodinamika ravnoteţnih črt, zamrzovanje,tlak tekočin in parni tlakBinarne mešanice: fazno pravilo, idealnemešanice, idealne razredčene mešanice,koligativne lastnosti, topnost, realni plini,fugativnost, realne raztopine, aktivnostFazni diagrami: diagram parnih tlakov, vrelnidiagrami, ravnoteţje tekoče-tekoče, ravnoteţjetrdno-tekočeKemijsko ravnoteţje: homogeno kemijskoravnoteţje, heterogeno ravnoteţjeContent (Syllabus outline):Gasses <strong>and</strong> intermolecular forces : the ideal gas,kinetic theory <strong>of</strong> gases, intermolecularinteractions, the van der Waals gasEnergy: the first law <strong>of</strong> thermodynamics,changes <strong>of</strong> internal energy <strong>and</strong> enthalpy inphysico<strong>chemical</strong> processes, thermo<strong>chemistry</strong>Entropy: the second law <strong>of</strong> thermodynamics,entropy <strong>of</strong> gasses <strong>and</strong> gas mixtures, entropychanges in physico<strong>chemical</strong> processes, the thirdlaw <strong>of</strong> thermodynamicsGibbs free energy: specific formulations <strong>of</strong> thesecond law, free energy changes inphysico<strong>chemical</strong> processes, the <strong>chemical</strong>potential, equilibrium in in physico<strong>chemical</strong>systemsEqulibrium in pure substances: the phasediagram, thermodynamics <strong>of</strong> equilibrium lines,refrigeration, liquid pressure <strong>and</strong> vapourpressureBinary mixtures: the phase rule, ideal mixtures,ideally diluted mixtures, colligative properties,solubility, real gases, fugacity, real liquidmixtures, activityPhase diagrams:vapour pressure diagrams,temperature-composition diagrams, liquid-lquidphase diagrams, liquid-solid phase digrams25

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