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antimony - Sciencemadness.org

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Chemical<br />

Composition.<br />

(STH4)2Sb4S7<br />

Ba3Sb2S68H2O<br />

Ba2Sb2S68H,O<br />

Sr^SbaSelOH^O<br />

Sr2Sb2S5f5HoO<br />

CaoSb2S615H - o0<br />

Ag3SbS3<br />

KAg2SbS3<br />

Zn3Sb2S6<br />

KZnSbS3<br />

Mn3Sb2S6<br />

KMnSbS,<br />

Pb3Sb2S6<br />

KPbSbS3<br />

Fe3Sb2S6<br />

Ni3Sb2S6<br />

Co3Sb2S6<br />

Cu3Sb2S6<br />

Cu3SbS3<br />

KCu2SbS3<br />

THE CHEMISTRY OF ANTIMONY.<br />

Colour.<br />

Red.<br />

Golden<br />

yellow.<br />

Grayish<br />

green.<br />

White.<br />

Yellow.<br />

Brown.<br />

Brown.<br />

Orange.<br />

White.<br />

Rose.<br />

Brown.<br />

Brown.<br />

...<br />

Black.'<br />

Reddish<br />

brown.<br />

Yellow.<br />

Crystal Formv<br />

Microscopic<br />

needles.<br />

Crystalline.<br />

...<br />

Crystalline.<br />

Crystalline.<br />

Crystalline.<br />

Amorphous.<br />

Crystalline.<br />

Amorphous.<br />

('rystalline.<br />

Amorphous.<br />

Crystalline.<br />

V- Amorphous.<br />

Amorphous.<br />

Crystalline.<br />

Crystalline.<br />

Solubility.<br />

...<br />

...<br />

Not soluble in water.<br />

The native minerals corresponding to some of these salts or to<br />

some other of the salts of thio-antimonious acids, are :—<br />

i Boulangerite, (SbS3)2Pb3 /f .<br />

Ortho-thioantimonites < Pyrargyrite, (SbS3)Ag3.<br />

( Bournonite, (SbS^^Pb^'Cu''.<br />

(<br />

Zinkenite, (SbS2)2Pb".<br />

Miargyrite, (SbS2)Ag.<br />

Wolfsbergite, (SbS2)7Cu".<br />

Berthierite, (SbS2)2Fe".<br />

r> 4X>' *• -4. f Plumosite, Sb2SePb2.<br />

Pyro.thioantimomtes { Panabas6j Sb2s6(CuFe)2.<br />

Antimony Sulph-haloids.—When the trisulphide is dissolved in<br />

a solution of chloride of <strong>antimony</strong>, the sulphochloride is formed;<br />

but it has not been possible to isolate it (Schneider). The brown masB<br />

is crystalline and is strongly hygroscopic. The important sulphachlorides<br />

are :—<br />

SbSCl, SbSCl + 7SbCl3, Sb4SeCl2,"SbSCl3, Sb8SnCl2, SbCl5.SbCl4.<br />

The sulphiodide, SbSI, is obtained by fusing the trisulphide and<br />

the tri-iodide together. SbaS3l6 may also be mentioned, SbSBr<br />

oxemplifies the sulphobromides.<br />

,,<br />

)5<br />

3)<br />

fJ<br />

27

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