- Page 4: 1"'1 National Library of Canada Bib
- Page 8: y thcnnally dc
- Page 11 and 12: Gregory for his kindness and making
- Page 15: LIST OF TABLES Table 1.1 Corrosion
- Page 21 and 22: single crystals ofquartz (Nacken, 1
- Page 23 and 24: phosphate control in the 19&Os was
- Page 25: the standard Gibbs energies and ent
- Page 36: consist ofortnophospllatcs. The bou
- Page 41 and 42: 2 FcIlFc[[J204(S) + 26 Na+(aq) + 12
- Page 44 and 45: solubility and phase relations ofpr
- Page 46: where 11 equals the ionic state ofh
- Page 49: '", g :£ 30
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1.10 Project Objectives The objecti
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II - "7 /'7"7L 41 J n
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2.3.2 Single Crystal X-Ray Dif'frac
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2.4 Synthesis and Characterization
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Several solid starting materials we
- Page 75 and 76:
FeUlNTA(aq) + HPOl(aq) + NH/(aq) __
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All runs lasted up to to days at a
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0.0 l--l_-L_l-....J.._-L_l-....J..-
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dissolution orSNHP and allowed the
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(a) (b) Figure 3.1a and b: Scanning
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and the equilibrium constant for ma
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groups. Oxidizing agents were previ
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and reacted with aqueous sodium pho
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(al (b) Figure 3.5a and b: Scanning
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Figure 3.7: Scanning electron micro
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Table 3.1: Positional parameters fo
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Figure 3.10: Scanning electron micr
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pattern is listed in Table A.LI3. E
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4.0 SOLUBILITY AND REACTION KINETIC
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Table 4.1 Experimental C
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Table 4.3 Standard slale properties
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Table 4.6 HKF equation ofstate coef
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Equilibrium constants are listed in
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Table 4.9 Equilbrium constants for
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Table 4.10 Standard state propertie
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lower NalP04 mole ratio than the re
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Broadbent D., Lewis G.G., and Wetto
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Marshall W.L. (1982) Two-liquid-pha
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Welton E.A.M. (1981) Phase equilibr
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APPENDIX I: Powder X-ray Diffractio
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TABLE A.l.l: X-Ray Diffraction Resu
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TABLE A,I.3 (continued) Quinlan JCP
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TABLE A.1.4 (continued) Quinlan (19
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TABLE A.l.S (continued) JCPDS Quinl
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TABLE A.1.6 (continued) Quinlan (19
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TABLE A.L8 (continued) Boudin JCPDS
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TABLE A.I.9 (continued) Product RGH
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TABLE A.I.IO (continued) Ziemniak a
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TABLE AJ.11 (continued) Zicmniak an
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TABLE A.T.I2 (continued) Zicmniak a
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TABLE A.I.13 (continued) Ziemniak a
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Experimental A colorless irrcg.plal
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Slfuc!ure Solution Refinemenl Funct
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111
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TABLE A.1II.1: Summary of ICP ES Re
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TABLE A.lll.2: KinclicData Time m(N
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TABLE A.III.2 (continued) Time m(Na
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TABLE A.lll.2 (continued) Time m(Na
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TABLE A.lIl.l (continued) Time m(Na
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TABLE A.III.3 (continued) t "C m(p0