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elements39<br />
Quarterly Science newsletter Issue 2|2012<br />
IntervIew<br />
“there’s no success without trust in a working partnership.”<br />
PrOJeCt HOUSe SYSteMS InteGrAtIOn<br />
Product and process go hand in hand<br />
CAtALYSIS<br />
Profiling simplifies scale-up in PMPC production
2 Contents<br />
10<br />
28<br />
36<br />
elements39 Issue 2|2012<br />
CoVeR PHoto<br />
Irina Profir, doctoral candidate at LIKAT, in <strong>Evonik</strong>’s new<br />
laboratory at LIKAT<br />
neWs<br />
4 Test plant for CO 2 separation started up<br />
4 BMBF PeTrA project to simplify administration of biopharmaceuticals<br />
5 Opening of Advanced Project House in Taiwan<br />
6 New university partner in China<br />
6 <strong>Evonik</strong> and LIKAT expand research cooperation in catalysis<br />
InteRVIeW<br />
7 “There’s no success without trust in a working partnership.”<br />
PRoJeCt HoUse sYsteMs InteGRAtIon<br />
10 Product and process go hand in hand<br />
CoMMent<br />
18 Innovations make history<br />
neWs<br />
21 Honorary professorship for Dr. Klaus Engel<br />
21 Sale of the colorants business<br />
22 Groundbreaking ceremony for new organics production facility<br />
22 Biogas upgrading: New plant for hollow fiber membrane modules<br />
23 <strong>Evonik</strong> invests in High-Tech Gründerfonds II<br />
23 Groundbreaking ceremony for new H 2 O 2 plant in China<br />
CAtALYsIs<br />
24 New tool for characterizing catalysts:<br />
Profiling simplifies scale-up in PMPC production<br />
MedICAL teCHnoLoGY<br />
28 Implants made from PEEK ensure new quality in medicine<br />
neWs<br />
34 Lightweight design solutions for China automotive industry<br />
34 The first-ever electrical sports car with a weight below 1,000 kg<br />
35 VESTAMID® HTplus in mass-produced gearshift levers<br />
35 High-performance plastics: Certified bio-based<br />
InnoVAtIon MAnAGeMent<br />
36 Identifying and developing new markets<br />
desIGnInG WItH PoLYMeRs<br />
40 Protective measures for treasures<br />
neWs<br />
42 Student project presented in Marl<br />
42 More than 400 offshore pipes with VESTAMID® NRG<br />
43 Creavis starts with new BISON project<br />
43 Credits
esources<br />
In 2011, <strong>Evonik</strong> generated sales of €1.9 billion with products and applications that<br />
were developed in the last five years—and there will be more to come. Indeed, the<br />
Group’s R&D pipeline is amply filled with and balanced by 450 short-, medium-,<br />
and long-term projects. Last year, the first patent applications placed <strong>Evonik</strong> among<br />
the leaders in specialty chemistry; in 2011, we filed 300 new patents, while our<br />
total number of patents and applications exceeded 24,000.<br />
Our R&D activities are guided by our strategy of concentrating on high-growth<br />
megatrends such as health, nutrition, resource efficiency, and globalization—on<br />
forward-looking markets that create not only financial, but also social value. In other<br />
words, we keep investing in R&D a rich store of resources for the purpose of protecting<br />
our natural resources. And to ensure that this stockpile does not dwindle<br />
away, we increased our R&D expenditures in 2011 to €365 million, or eight percent<br />
more than the previous year.<br />
This is money well spent, as is demonstrated by our Project House Systems Integration,<br />
which is now wrapping up its activities. The employees of the project house<br />
found solutions for plastic glazing for cars, concentrating solar thermal energy,<br />
and for the production of thin fibers for filtration applications. As disparate as these<br />
developments are, they all share the same goals: They advance the development of<br />
sustainable products and processes, in keeping with our strategy, and they make<br />
an important contribution to energy and resource efficiency. Of the nine projects<br />
the project house worked on in its three-year run, seven have already been returned<br />
to the participating business lines, which are now bringing them to market maturity.<br />
These results are also striking for the fact that the project house began its activities<br />
in early 2009 at an ill-omened time: The height of the financial and economic crisis,<br />
when economizing was paramount. <strong>Evonik</strong> cut costs like everyone else, but not in<br />
R&D. We launched the project house as planned.<br />
Another example of our commitment to using our research to save resources can<br />
be found in our Health & Nutrition Business Unit, which is currently expanding<br />
its market activities to aquaculture. Adding our amino acids to fish feed can save<br />
valuable fish meal that would otherwise have to be mixed with the feed as a source<br />
of protein, and which often comes from natural stocks of wild marine animals.<br />
At least three kilograms of captured fish are required to produce one kilogram of<br />
edible fish. Our amino acids also allow fish and crustaceans to digest the feed better,<br />
so that more animals receive optimal nutrition with the same amount of feed. For<br />
this reason, Health & Nutrition has developed new products that are an optimized<br />
methionine source for shrimp and other crustaceans—innovative products designed<br />
to help ensure that fewer wild fish are required for aquaculture. This preserves the<br />
stocks of wild fish, and it counteracts overfishing. These new products are perhaps<br />
only a small but nevertheless effective step toward a future in which we will have<br />
to feed a constantly growing world population. In my view, this future will be worth<br />
living only if we succeed in utilizing food, as a resource, as efficiently as possible.<br />
edItoRIAL 3<br />
Patrik Wohlhauser<br />
Member of the Executive Board<br />
of <strong>Evonik</strong> <strong>Industries</strong> AG<br />
elements39 Issue 2|2012
4 neWs<br />
test plant for CO 2 separation started up<br />
At the foot of the chimney of STEAG’s cogeneration plant in Herne, a ninemeter-high<br />
test plant has been built for evaluating new absorbents. The test<br />
plant, which is supposed to allow researchers to investigate absorbents for<br />
separating CO 2 from industrial and waste gases under real conditions, is part<br />
of the Efficient CO 2 Separation (EffiCO 2 ) Project of Creavis’ Science-to-<br />
Business Center Eco².<br />
<strong>Evonik</strong>’s business units are working together with experts from industry<br />
and science to develop new absorbents that should significantly reduce energy<br />
requirements for CO 2 separation. The aim is to investigate these new<br />
substances both under real conditions and in the laboratory. Over the next<br />
few weeks, the test plant will be tested for this purpose with commercially<br />
available absorption media to obtain a reference process for the new absorbents.<br />
For the investigations which are to occur under real conditions, the power<br />
plant has been built in such a way that part of the flue gas can be taken directly<br />
from the chimney and characterized by online analytics. The entire system<br />
has been made of glass to make it easy to view the process.<br />
Before the CO 2 is separated from the flue gas, interfering flue-gas components<br />
are removed in a scrubber column. Connected to this is the absorption<br />
column, in which the CO 2 contained in the flue gas is absorbed. In a<br />
third unit, the absorption medium is regenerated and pure CO 2 obtained,<br />
which is analyzed and returned to the chimney. The regenerated absorption<br />
medium is reconveyed to the absorption column and a continuous process is<br />
made possible. The EffiCO 2 project is funded by the German Federal Ministry<br />
of Education and Research (BMBF).<br />
A greenhouse gas, CO 2 is considered to be the single-most important<br />
cause of climate change. Global CO 2 emissions in 2010 amounted to more<br />
than 33 gigatons, an increase of about 30 percent over 1990. The energy<br />
sector emits the highest proportion of CO 2 . Because of mounting global<br />
energy requirements, the energy sector will continue in the future to account<br />
for a large share of CO 2 emissions. To meet energy requirements and simultaneously<br />
reduce CO 2 emissions, various CO 2 separation technologies are<br />
being developed and tested worldwide.<br />
BMBF PetrA project<br />
to simplify<br />
administration of<br />
biopharmaceuticals<br />
The goal of the interdisciplinary research project<br />
PeTrA*, which is sponsored by the<br />
German Federal Ministry of Education and<br />
Research (BMBF), is to remove the need for<br />
injections for biopharmaceuticals used for<br />
example in cancer immunotherapy by developing<br />
spray and tablet formulations which<br />
include innovative biofunctional polymers.<br />
The project is designed to simplify the administration<br />
of biopharmaceuticals and to improve<br />
their bioavailability. PeTrA is managed by a<br />
consortium consisting of <strong>Evonik</strong> Indus tries<br />
elements39 Issue 2|2012<br />
the nine-meter-high test<br />
plant for CO 2 separation<br />
AG, Merck KGaA, EMC microcollections<br />
GmbH (a hightech company for peptide and<br />
peptidomimetics synthesis), the Helmholtz<br />
Center for Infection Research (HZI), and the<br />
Fraunhofer Institute for Interfacial Engi neering<br />
and Biotechnology (IGB).<br />
The project, which started on July 1, 2011,<br />
is scheduled to last for three years Ap prox -<br />
imately half of the €6 million budget is supported<br />
by the three industry partners. The<br />
PeTrA consortium also includes the Friedrich<br />
Schiller University in Jena, Saarland University,<br />
the University of Nij megen (Neth erlands),<br />
Bonn University Hospital, the Charité<br />
Hospital Berlin, Kiel University, and Würzburg<br />
Uni versity.<br />
Biopharmaceuticals have been on the<br />
advance for years in modern drug therapy.<br />
They include peptides, proteins and antibodies,<br />
nucleic acids, and blood components, that<br />
all represent a promising basis for new active<br />
principles and for cancer immunotherapy.<br />
Many of these highly successful drugs im -<br />
prove patient life quality and have enormous<br />
technological potential for the pharmaceutical<br />
industry.<br />
Today, biopharmaceuticals are mostly<br />
administered by injection. Indeed, there is no<br />
efficient or broadly applicable system for<br />
administering them via the mouth (oral) or<br />
through the respiratory pathways (inhalation)<br />
because they are not easily absorbed by the<br />
mucous membranes of the gastrointestinal<br />
tract and respiration system, and tend to be<br />
degraded in the stomach before they can<br />
have an effect on the body. The PeTrA project<br />
aims at overcoming these obstacles by<br />
packaging highly sensitive biopharmaceuticals<br />
into nano- and micro-sized particles that<br />
transport the active ingredients through the<br />
mucous membranes and protect them from<br />
degradation in the stomach.
“Tablets and sprays are more convenient for<br />
patients, particularly in long-term therapies<br />
which can require continuous drug intake<br />
over weeks or months,” says Dr. Rosario Lizio<br />
about the motivation of the research partners.<br />
Lizio, the PeTrA project coordinator, is also<br />
the head of the Discovery & Development<br />
department of Pharma Polymers, a product<br />
line of the Health Care Business Line of<br />
<strong>Evonik</strong> specialized in drug delivery systems.<br />
*PeTrA stands for “Platform for efficient epithelial<br />
transport of pharmaceutical applications with inno -<br />
vative particular carrier systems” (<strong>Evonik</strong>-Funding<br />
Ref. No.: 13N11454) and is part of the BMBF grant<br />
project “Efficient drug transport in biological systems—BioMatVital:<br />
Biotransporters.”<br />
Opening of Advanced Project House in taiwan<br />
<strong>Evonik</strong> has opened its Light & Electronics<br />
Advanced Project House (APH) in Taiwan.<br />
The new APH is located in Industrial Technology<br />
Research Institute (ITRI) in Hsinchu,<br />
one of Taiwan’s leading research institutes.<br />
“As the first project house <strong>Evonik</strong> established<br />
outside of Germany, it is quite literally a big<br />
step for <strong>Evonik</strong> in innovation in Greater China<br />
and Asia,” commented Dr. Dahai Yu, member<br />
of the Executive Board responsible for Asia,<br />
at the opening ceremony held in ITRI. “The<br />
opening of the Light & Electronics APH is a<br />
new stepping stone for entering into new<br />
markets and the globalization of R&D.”<br />
“The market is constantly changing. With<br />
the APH in Taiwan, we aim to generate a link<br />
to the growing light and electronics industry<br />
in Asia, and identify and realize new business<br />
opportunities through joint technical developments<br />
and close hands-on interactions with<br />
our customers,” said Patrik Wohlhauser,<br />
Mem ber of the Executive Board responsible<br />
for innovation management.<br />
<strong>Evonik</strong> evaluated the technical and market<br />
success probability of potential project topics<br />
such as lighting, displays, touch panels, photovoltaic,<br />
LEDs, and functional coatings. With<br />
its opening, several projects have been started<br />
up with the company’s business units’ and<br />
business lines’ commitment and support. In<br />
addition, a New Business Develop ment function<br />
will be built up to identify new business<br />
opportunities in the electronics industry. The<br />
start focuses on Taiwan, main land China, and<br />
Korea.<br />
“We’re really glad to see that the construction<br />
of office and labs has been completed<br />
at ITRI even faster than planned. For<br />
us, ITRI is the best place to start, as it provides<br />
good infrastructure and a condensed knowhow<br />
platform, as well as the local network.”<br />
said Dr. Michael Cölle, head of the APH,<br />
neWs<br />
during the opening ceremony. “We’ve built<br />
up a technical team made up of local talents,<br />
and the team will gradually increase according<br />
to the project needs in the future. We<br />
expect to foster customer interaction continuously<br />
and generate new business.”<br />
Located in one of the world’s most important<br />
electronics markets, the APH finds a new<br />
way for <strong>Evonik</strong> to access the market. The<br />
APH is to give rise to a new R&D competence<br />
center for the Group in Asia.<br />
From left to right: Dr. Michael Cölle (Head of<br />
the Advanced Project House Light & electronics),<br />
Dr. Peter nagler (Chief Innovation Officer evonik),<br />
Dr. Ming-Ji wu (Ministry of economic Affairs),<br />
Dr. Dahai Yu (executive Board Member evonik),<br />
Dr. Jonq-Min Liu (executive vice President ItrI),<br />
Dr. Hans-Josef ritzert (President evonik Greater<br />
China), Jia Ming Liu (General Director MCL, ItrI),<br />
Dr. Gerard Berote (President evonik taiwan)<br />
5<br />
elements39 Issue 2|2012
6 neWs<br />
new university partner in China<br />
Premiere in China: <strong>Evonik</strong> has sealed its first strategic university<br />
partnership in Asia with Shanghai Jiaotong University (SJTU). The<br />
cooperation agreement was signed by SJTU Vice President Xu Fei<br />
and Dr. Hans-Josef Ritzert, Regional President Greater China, with<br />
Dr. Dahai Yu, <strong>Evonik</strong> Executive Board Member, and Prof. Zhang<br />
Jie, SJTU President, also in attendance at the ceremony.<br />
Speaking at the event, Dr. Dahai Yu said, “I am delighted about<br />
this strategic cooperation with Jiaotong University. Our partnership<br />
will strengthen research and development cooperation in the<br />
chemicals field and beyond.” Prof. Zhang Jie likewise welcomed<br />
the new partnership, saying, “Innovation is the key to success, both<br />
for <strong>Evonik</strong> and for Jiaotong University. I am certain that our cooperation<br />
will generate genuine innovative power on both sides.”<br />
As one of Asia’s leading universities for the natural sciences<br />
and technology, SJTU offers modern resources for research and<br />
development. This cooperation deal provides <strong>Evonik</strong> access to<br />
excellent research facilities, technologies, and high-tech apparatus<br />
at the university. Awarded the title of “<strong>Evonik</strong> Professor,” three<br />
scientists at SJTU will conduct <strong>Evonik</strong>-funded R&D projects and<br />
hold scientific lectures for <strong>Evonik</strong> employees.<br />
Agreement was likewise reached on close cooperation in the<br />
area of intellectual property law. Experts from <strong>Evonik</strong> are also slotted<br />
to hold an industrial chemicals seminar at SJTU every two<br />
weeks. And <strong>Evonik</strong> will provide opportunities for students at SJTU<br />
to complete a course of practical training at the company.<br />
The Strategic Partner University Program is an important part<br />
of the strategy pursued by <strong>Evonik</strong>’s Corporate Innovation Strategy<br />
& Management to develop partnership agreements with leading<br />
universities all over the world.<br />
elements39 Issue 2|2012<br />
evonik and LIKAt<br />
expand research<br />
cooperation in catalysis<br />
<strong>Evonik</strong> and the Leibniz Institute for Catalysis (LIKAT) are<br />
planning to expand their cooperation in the area of catalysis<br />
research for the long term. The Institute has been<br />
successfully working with <strong>Evonik</strong> in the field of catalysis<br />
for more than ten years and the parties recently agreed<br />
to extend their long-term cooperation.<br />
For this purpose, the Advanced Intermediates Business<br />
Unit of <strong>Evonik</strong> has set up a new laboratory in the LIKAT<br />
facility, which will be dedicated to the development of<br />
new catalysts and the optimization of existing production<br />
processes. <strong>Evonik</strong> agreed to make a large investment<br />
available for this purpose in a framework agreement.<br />
“Our cooperation has generated a large number of<br />
innovations and patents over the past years,” says Prof.<br />
Dr. Stefan Buchholz, head of Innovation Management of<br />
the <strong>Evonik</strong> Advanced Intermediates Business Unit. “We<br />
plan to follow up on this success by bringing additional<br />
catalysis research products to commercial maturity in the<br />
years to come.”<br />
Catalysis is considered one of the most significant<br />
levers of efficient chemical production and is a key technology<br />
of the 21st century. It helps save energy and re -<br />
sources and reduces by-products and waste in chemical<br />
production. The Advanced Intermediates Business Unit<br />
uses the catalysts for the production of plasticizers in its<br />
integrated C4 technology platform in the Marl Chemical<br />
Park.<br />
LIKAT, the largest European research institute in the<br />
area of applied catalysis, is an internationally leading institute<br />
for the research and development of homogeneous<br />
and heterogeneous catalysts as well as catalytic processes<br />
and technologies. The main focus of its scientific work<br />
is on gaining new insights into basic catalysis research and<br />
studying their application to technical concepts.
“There’s no success without trust<br />
in a working partnership.”<br />
<strong>Evonik</strong> and the Leibniz Institute for<br />
Catalysis (LIKAT) in Rostock (Germany)<br />
have been working together for over a<br />
decade. The cooperation with the<br />
Performance Intermediates Business Line<br />
in particular has produced numerous patents<br />
and new catalysts. The new lab at<br />
LIKAT cements <strong>Evonik</strong>’s commitment to<br />
broadening the partnership, and Prof.<br />
Matthias Beller, in charge of LIKAT, and<br />
Prof. Stefan Buchholz, head of Innovation<br />
Management at <strong>Evonik</strong>’s Advanced<br />
Intermediates Business Unit, share their<br />
thoughts on what this entails.<br />
which areas will you be researching<br />
together in the new lab?<br />
Buchholz: The main joint research do -<br />
main at the EVA, the <strong>Evonik</strong> Advanced<br />
Catalysis Lab@LIKAT, centers on new<br />
catalysts for manufacturing processes at<br />
the Performance Intermediates Business<br />
Line. The focus is on hydroformylation,<br />
globally the most important homogenous<br />
catalytic reaction to use organometallic<br />
catalysts. More than ten million metric<br />
tons of products, mostly plasticizer alco-<br />
with it every year. With an annual production<br />
capacity of just over 400,000<br />
metric tons, <strong>Evonik</strong> is one of the leading<br />
manufacturers of isononanol (INA) and<br />
2-propylheptanol (2PH), which are used<br />
mainly in making two types of plasticizers:<br />
Diisononyl phthalate (DINP) and<br />
di(2-propyl heptyl) phtha late (DPHP).<br />
DINP and DPHP belong to the group of<br />
high-molecular-weight phthalates, which<br />
distinguish themselves through their<br />
superior application engineering profile<br />
and toxicological safety.<br />
Beller: We also look forward to putting<br />
the catalysis expertise gained over so<br />
many years to work on carbonylations<br />
and hydroformylations. One idea is to<br />
functionalize renewable resources into<br />
viable products for <strong>Evonik</strong>. We believe<br />
that renewables will become increasingly<br />
important in coming years. While this<br />
opens up many new opportunities, it is<br />
also an area that presents major challenges—and<br />
they must be met. We intend<br />
to venture into uncharted territory, too.<br />
It’s a high-risk proposition from a re -<br />
search standpoint, but it may well also<br />
InteRVIeW<br />
Prof. Matthias Beller (left), in charge of LIKAt,<br />
and Prof. Stefan Buchholz, head of Innovation<br />
Management at evonik’s Advanced Intermediates<br />
Business Unit<br />
what are the objectives?<br />
Buchholz: The goal for <strong>Evonik</strong> is to<br />
continue strengthening our leadership<br />
position, especially in hydroformylation.<br />
New catalyst systems, for instance,<br />
would enable us to achieve both higher<br />
yields as well as even higher selectivities<br />
for target molecules.<br />
Here, the key is to keep catalyst<br />
costs under control. Hydroformylation<br />
catalysts are often based on rhodium,<br />
an extremely rare precious metal that’s<br />
several times more expensive than gold.<br />
Ligands, mostly organic phosphines or<br />
phosphites, stabilize the rhodium catalysts,<br />
which in turn helps minimize precious<br />
metal loss. In addition, they also<br />
have a decisive impact on catalyst activity<br />
and selectivity. And because manufacturing<br />
ligands is often a complex and<br />
expensive process, we have to make<br />
sure that the ligands we jointly develop<br />
are also economically feasible in terms<br />
of their production cost.<br />
Another key aspect is that ligands have<br />
to remain stable under extreme reaction<br />
conditions, that is, high pressure and high<br />
hols and surfactants, are manufactured yield significant economic rewards. temperature, and deliver the end-<br />
333<br />
7<br />
elements39 Issue 2|2012
8 InteRVIeW<br />
333 product in a desired grade. Plasticizer<br />
alcohol viscosity, for instance, is a key application<br />
engineering parameter that’s essentially<br />
influenced through<br />
catalyst selectivity.<br />
What we’ve just talked about are<br />
mid-range goals. We’re also thinking<br />
more long-term. One such project involves<br />
revisiting the old dogma that only<br />
rhodium and cobalt can efficiently catalyze<br />
the hydroformylation. Our exploratory<br />
work at LIKAT shows that palladium<br />
and iridium present an heretofore<br />
untapped potential for carbonylation<br />
reactions. Together with LIKAT and the<br />
work group under Prof. Arno Behr at<br />
the Technical University of Dortmund,<br />
an additional partner in the scope of the<br />
Proforming Project funded by the BMBF<br />
(Federal Ministry of Education and Research),<br />
we intend to find out what that<br />
potential is and how to realize it.<br />
Beller: The idea is to provide the various<br />
<strong>Evonik</strong> business units with fundamental<br />
innovations in homogenous and<br />
heterogeneous catalysis. This will in<br />
turn spark concrete bilateral projects,<br />
which <strong>Evonik</strong> could then scale up industrially.<br />
who’ll be doing what? Is evonik’s role<br />
limited to providing the funding?<br />
Beller: That’s definitely not the case<br />
here. Funding is important and it can<br />
accelerate research projects, but it’s no<br />
guarantee for success. Success comes<br />
from working together and from intensive<br />
exchange with academic research.<br />
Buchholz: The sheer diversity of<br />
demands placed on the catalysts to be<br />
developed makes abundantly clear that<br />
only a broadly based, methodical approach<br />
has the greater chances of success. The<br />
compelling advantage is that <strong>Evonik</strong><br />
brings decades of accumulated experience<br />
and expertise in production to the<br />
table, while LIKAT contributes the latest<br />
findings from basic research. These two<br />
complementary perspectives are not<br />
only im portant in driving current proj-<br />
elements39 Issue 2|2012<br />
ects towards a successful outcome,<br />
but also create a steady source of new<br />
research topics.<br />
what benefits can LIKAt derive from the<br />
partnership?<br />
Beller: The Leibniz Institute for Catalysis<br />
is one of the world’s largest public<br />
research facilities in the area of applied<br />
catalysis. Complementing the research<br />
work at German universities and Max<br />
Planck Institutes, LIKAT’s declared goal<br />
is to help translate basic research findings<br />
into industrial applications. Yet this<br />
can only be achieved in cooperation<br />
with partners from industry. Or put differently:<br />
We definitely share in the success<br />
of technical solutions arrived at<br />
jointly in the lab.<br />
And what’s in it for evonik?<br />
Buchholz: The longstanding, broadly<br />
based cooperation with LIKAT has<br />
played a major role in systematically<br />
securing and expanding our technological<br />
edge in the area of hydroformylation<br />
but also in telomerization. Besides the<br />
concrete research findings, we also<br />
value the dialogue with Mr. Beller, an<br />
internationally recognized and leading<br />
catalysis researcher, and with Prof.<br />
Armin Börner as very inspiring—and that<br />
greatly stimulates our internal development<br />
work.<br />
Here, personal exchange is key—even<br />
with all the advanced communication<br />
tools and methods available today, it is<br />
still indispensable to the creative process.<br />
That’s why we not only have project<br />
leaders talking with each other, but<br />
also the people in the team—the group<br />
heads and doctoral candidates at LIKAT,<br />
and the researchers at <strong>Evonik</strong>. This pro ximity<br />
gives PhD candidates insights into<br />
industrial research, and it helps them<br />
prepare for their career. Several doc -<br />
to ral candidates appreciated this aspect<br />
to the extent that they signed on with<br />
<strong>Evonik</strong>. The ability to interact with<br />
future colleagues in a workplace set -<br />
t ing is an invaluable advantage, too.<br />
Besides, it is also the best way to spread<br />
the knowledge gained as a team effort<br />
throughout the company.<br />
what are the cons, if any, of such a<br />
research partnership?<br />
Beller: Compared to, say, a project<br />
funded by the German research community,<br />
academic freedom does have to<br />
operate within a more defined framework<br />
in this type of cooperation. As a<br />
researcher, one might view this as a constraint,<br />
but the way I see it, the benefits<br />
far outweigh any perceived disadvantages.<br />
Buchholz: The costs and the benefits—<br />
and the latter shouldn’t be construed as<br />
short-term profit optimization—have<br />
to be constantly weighed against each<br />
other. Of course, the need to be as open<br />
as possible to enable the partner to get<br />
fully involved sometimes conflicts with<br />
the need to respect the necessary obligations<br />
that come with intellectual property,<br />
and that is why it is so important<br />
to build trust. Trust, as our experience<br />
with LIKAT has shown, thrives especially<br />
well in a long-term partnership.<br />
You have been working together now for<br />
over ten years. How has the partnership<br />
evolved over time?<br />
Beller: In the beginning the cooperation<br />
between <strong>Evonik</strong> and my colleague Armin<br />
Börner in Rostock was focused on developing<br />
better hydroformylation catalysts<br />
for plasticizer alcohols. We essentially<br />
synthesized and catalytically tested new<br />
organometallic complexes and organic<br />
ligands for catalyst modification. This<br />
fell short of the goal to develop industrially<br />
viable and feasible systems, however.<br />
That’s why we expanded the scope<br />
to include mechanistic experiments,<br />
detailed catalyst studies, and structural<br />
activity tests. In 2009 our findings were<br />
implemented into practice in <strong>Evonik</strong>’s<br />
integrated C4 technology platform in<br />
Marl. Something we naturally found very<br />
gratifying.
“If you want to develop advanced<br />
chemical manufacturing processes, you<br />
need to know the catalysis cycle.”<br />
Buchholz: If you want to develop<br />
advanced chemical manufacturing processes,<br />
you need to know the catalysis<br />
cycle. And that requires deep methodological<br />
expertise in many areas: In<br />
in-situ IR and NMR spectroscopy, in<br />
theoretical chemistry, and in ligand synthesis.<br />
We’ve systematically grown our<br />
competencies in these areas and today<br />
we reap the ben efits in the new products<br />
and processes we develop as well as in<br />
our joint explor atory work.<br />
Beller: The past two years have also<br />
shown us that other chemical technologies<br />
are potentially attractive to <strong>Evonik</strong>.<br />
In this regard, we support our colleagues<br />
in Marl in establishing a strong patent<br />
basis.<br />
Looking back, I can say that, together,<br />
we’ve definitely met our share of challenges<br />
over the years. And we managed<br />
that to a large part on the basis of the<br />
trust that exists between us as partners.<br />
This is not something that can be taken<br />
for granted, and at this stage I would like<br />
to take the opportunity to thank Mr.<br />
Buchholz and Prof. Robert Franke and<br />
also Dr. Klaus-Diether Wiese as representatives<br />
of <strong>Evonik</strong>.<br />
Catalysis is a key technology for the<br />
chemical industry. How does Germany<br />
compare internationally? And what part<br />
do partnerships play?<br />
Buchholz: Germany continues to rank<br />
at the top. Here, LIKAT’s scientific<br />
excellence makes it stand out even more.<br />
What distinguishes it from other catalysis<br />
research facilities in Germany and<br />
Europe is the strong focus on practical<br />
implementation.<br />
LIKAT is only following through on<br />
a longstanding tradition. In Germany,<br />
the chemical industry and academic research<br />
institutes have always maintained<br />
close ties—much more so than in many<br />
other countries, where these two domains<br />
are almost hostile to each other,<br />
or where there’s no strong, innovationdriven<br />
chemical industry to enable this<br />
kind of partnership approach to develop<br />
in the first place. potential. 777<br />
InteRVIeW<br />
the Leibniz Institute for Catalysis (LIKAt)<br />
in rostock (Germany)<br />
There’s no doubt that the combination<br />
of openness to practical implementation<br />
and academic excellence is what makes<br />
LIKAT a preferred partner to <strong>Evonik</strong>.<br />
Beller: High-performance catalysts are<br />
instrumental in ensuring that chemical<br />
reactions don’t consume more resources<br />
than necessary, by avoiding by-products<br />
and reducing energy requirements.<br />
They are key to economic as well as ecological<br />
value creation in the spirit of<br />
decoupling technological progress from<br />
the consumption of natural resources.<br />
Germany has a preeminent position<br />
in catalysis research, both in basic and<br />
applied research. And on the academic<br />
side, with two Max Planck Institutes—<br />
the Max Planck Institute for Carbon Research<br />
in Mülheim on the Ruhr and the<br />
Fritz Haber Institute in Berlin—and the<br />
Leibniz Institute for Catalysis in Rostock<br />
as well as leading research groups at<br />
various universities such as Aachen,<br />
Berlin, Karlsruhe, and Munich, we have<br />
a very solid platform of excellence as<br />
well. However, it takes a working partnership<br />
between academia and industry<br />
to make innovations happen—to translate<br />
research findings into viable, sustainable,<br />
and feasible industrial processes.<br />
Our new joint lab has the best chances of<br />
playing a pivotal role in realizing this<br />
9<br />
elements39 Issue 2|2012
10 PRoJeCt HoUse sYsteMs InteGRAtIon<br />
elements39 Issue 2|2012<br />
Product and process<br />
go hand in hand<br />
Chemical products have to satisfy customers’ requirements and<br />
the demands of the market completely. Over the past three years,<br />
<strong>Evonik</strong>’s developers in the Project House Systems Integration<br />
of Creavis Technologies & Innovation have paved the way for<br />
new applications for innovative materials.<br />
[ text Dr. Michael Olbrich ]<br />
ReseaRch in the ivory tower—this is a beloved metaphor<br />
for describing the gap between scientific work<br />
and market reality. At <strong>Evonik</strong>, R&D has long forsaken<br />
the ivory tower in favor of efficient development<br />
work based on market requirements and megatrends.<br />
<strong>Evonik</strong>’s project houses, an element of the strategic<br />
research and development unit Creavis Technologies<br />
& Innovation, are one feature of its R&D landscape.<br />
In many of these project houses, employees from<br />
a variety of disciplines and business units of the<br />
Group have worked together to develop ideas and innovations<br />
since the year 2000. Over a period of three<br />
years, the employees combine their knowledge and<br />
their different experiences and advance their projects<br />
single-mindedly, outside day-to-day operations.<br />
This allows them to build new areas of expertise and<br />
bring products and processes to market readiness<br />
faster.<br />
While the first project houses focused primarily<br />
on the development of basic technology and products,<br />
their objective evolved over time to a greater focus<br />
on new processes and new applications—today, they<br />
work in closer proximity to the market. Project hous es<br />
work on behalf of the Group to venture further into<br />
new markets than the business units, and it is an open<br />
question whether a project can be brought to successful<br />
completion within three years—whether a<br />
technically attractive solution will be found and, ultimately,<br />
whether a marketable product is produced.<br />
The work of the project houses, therefore, complements<br />
the research done in the business units by<br />
advancing medium-risk developments. But the risk<br />
is worth it: The interdisciplinary teamwork outside<br />
normal day-to-day business often proves to be a catalyst<br />
for pathbreaking ideas. And for the individual<br />
researchers, the limited duration of the project house<br />
commitment—combined with its high visibility among<br />
top management—is a challenge that promotes personal<br />
development and extends employees’ horizons<br />
beyond their normal daily work.<br />
As the strategic research and development unit of<br />
<strong>Evonik</strong> <strong>Industries</strong>, Creavis is commissioned to build<br />
new and sustainable businesses for <strong>Evonik</strong> and develop<br />
forward-looking technology platforms. The
work of the project houses focuses on very fundamental<br />
medium-risk research topics that span multiple<br />
business units. High-risk research topics that<br />
represent completely new fields for <strong>Evonik</strong> are implemented<br />
in Creavis’ Science-to-Business (S2B)<br />
Centers.<br />
The Project House Systems Integration began its<br />
work at the Hanau site in early 2009. Unlike the seven<br />
previous project houses, the 21 employees were not<br />
tasked with developing new technologies and products<br />
but with finding new applications for existing<br />
(trial) products. They took a holistic approach to their<br />
R&D: The idea was to develop the product together<br />
with the required new processing technology so we<br />
can hand the customer not only a product but a system<br />
solution. These system solutions conquer the<br />
usual market entry barriers because they can be integrated<br />
more easily into existing production processes<br />
or offered to the customer as an entirely redesigned<br />
process.<br />
Product and process development go hand in<br />
hand: For example, a plastic may require a certain set<br />
PRoJeCt HoUse sYsteMs InteGRAtIon<br />
of processing parameters, but the technological<br />
parameters at the processing end might be defined<br />
differently. This holistic approach and the coordination<br />
of product and process were the starting point<br />
of development activities and an essential component<br />
of the work in the Project House Systems Integration.<br />
The objective was to develop economically attractive<br />
system solutions suitable for large-scale production.<br />
<strong>Evonik</strong> also develops additional competencies along<br />
the value-added chain, and creates added value<br />
through more efficient applications, resourceefficient<br />
processes, and/or more sustainable products.<br />
333<br />
Partnership of product<br />
and process<br />
For example, the developers in the<br />
Project House Systems Integration<br />
researched lightweight design in cars<br />
from a variety of angles. to this end,<br />
they adopted a holistic r&D approach:<br />
to open up new applications for<br />
evonik’s (trial) products, they developed<br />
the products, together with<br />
the required new processing technology,<br />
into a system solution<br />
11<br />
elements39 Issue 2|2012
12 PRoJeCt HoUse sYsteMs InteGRAtIon<br />
elements39 Issue 2|2012<br />
333<br />
About 300 years of professional experience in a wide<br />
variety of functions and six different disciplines: the<br />
21 employees of the Project House Systems Integration<br />
333<br />
Through close proximity to application and market,<br />
the tasks in the Project House Systems Inte -<br />
g ration beyond the actual technology were highly<br />
diverse: The employees evaluated processes for their<br />
commercial value, developed business models and<br />
plans, analyzed value-added chains in detail, prepared<br />
conceptual studies for potential production lines, and<br />
conducted life cycle assessments.<br />
Work in the project house also placed specific<br />
demands on the employees. Skills such as creativity,<br />
network building, and adaptation to changed conditions<br />
are important prerequisites for success—<br />
unexpected R&D results often mean the modification<br />
of entire project plans.<br />
In this regard, a key efficiency and creativity<br />
factor was the mixture of young and experienced<br />
employees. The employees in the Project House Systems<br />
Integration had about 300 years of combined<br />
experience at their disposal, came from six different<br />
educational disciplines, and had previously worked<br />
in a variety of functions, from classical R&D, through<br />
production, to marketing and sales. They received<br />
additional support from 18 students, who were tackling<br />
a range of issues in work ranging from internships<br />
to such projects as a diploma thesis, a Bachelor’s<br />
or Master’s thesis, or an MBA.<br />
The success of the projects closely depends, not<br />
least, on an intense exchange with the participating<br />
business units, precisely because of the market proximity<br />
of the development projects. Consequently, the<br />
“project sponsors” from the business units played a<br />
central role. They were the interface to the market<br />
and the customer, since they managed the starting<br />
products in the business unit and—if the project is<br />
successful—are in charge of further development and,<br />
ultimately, commercialization after the project house<br />
is concluded. They supported the projects, analyzed<br />
the findings, and ensured close internal communication<br />
on the activities of the project house.<br />
In the preparation stage of the project house,<br />
ideas and suggestions from various business units<br />
were collected and evaluated as part of a feasibility<br />
study. From a total of 75 proposals, nine projects were<br />
left that met the basic requirements for development<br />
in the Project House Systems Integration: The product<br />
has to be closely partnered with a specific pro-<br />
Project house anchored<br />
in the business units
cessing method for an innovative application. The<br />
application itself cannot be blocked by third-party<br />
patents and must belong to a growth market. The<br />
competition must offer sufficient leeway, and not<br />
least: The innovation must promise new commercial<br />
success for the Group.<br />
In all nine projects, the project managers each<br />
pursued several development routes at the same time,<br />
and investigated a number of potential fields of application.<br />
This increased the likelihood of success,<br />
and gave employees enough freedom to find the best<br />
solution for each, and the best possible route to it.<br />
Lightweight construction was a key focus of the<br />
work in the Project House Systems Integration. In the<br />
Automotive Glazing project, PLEXIGLAS® glazing<br />
was developed to make vehicles lighter in weight and,<br />
therefore, increase fuel efficiency and reduce emissions.<br />
The requirements for car windscreens are invariably<br />
high: High mechanical strength must be matched<br />
by high impact strength. The panes have to be UV-<br />
and weather-resistant, guarantee high light transmission,<br />
and withstand temperatures of up to 80 °C without<br />
haziness. Scratch- and abrasion-resistance also<br />
play an important role.<br />
The procedure was different, depending on the<br />
type of glazing and production quantities. For smaller,<br />
injection-molding panes installed in large piece 333<br />
PRoJeCt HoUse sYsteMs InteGRAtIon<br />
BAtteRY teCHnoLoGY<br />
Sustainable mobility<br />
PLeXIGLAS® glazing is<br />
only about half as heavy<br />
as conventional glazing<br />
The speed with which electric vehicles become<br />
operational largely depends on the performance<br />
of the battery. In cooperation with <strong>Evonik</strong> Lita rion<br />
GmbH, the experts in the Project House Systems<br />
Integration have worked on one of the most<br />
important chem ical components of the battery:<br />
The separator, which separates the electrodes in<br />
a battery cell. Based on <strong>Evonik</strong>’s existing<br />
SEPARION® separator, the project house investigated<br />
how the separator could be made thinner<br />
and lighter, for the purpose of increasing the<br />
amount of energy stored in the cell, and making<br />
the battery cells smaller and more compact. The<br />
challenge of this task is in cost-efficient mass<br />
production.<br />
13<br />
elements39 Issue 2|2012
14 PRoJeCt HoUse sYsteMs InteGRAtIon<br />
ReneWABLe eneRGIes<br />
A systematic approach<br />
to new energy<br />
The expansion plans for renewable energies are extremely<br />
ambitious in countries like Germany, Spain, and the United<br />
States, but also in North Africa and the Arab world. Con centrating<br />
solar power (CSP) will play an important role in these<br />
plans. In addition to site factors, the profitability and achievement<br />
of “grid parity” of CSP power plants depend heavily<br />
on the cost of the power plants. Collector fields, where the<br />
sun energy is converted to heat, are one cost driver. The<br />
savings potential is viewed as enormous: For example, if the<br />
parabolic or even flat collectors are no longer produced<br />
based on glass solar mirrors but on mirrored plastic, weight<br />
and transport costs drop, and the substructure in the solar<br />
field is considerably easier and more cost-effective to build.<br />
Together with the Performance Polymers Business Unit<br />
and external partners, the team developed technical solu -<br />
tions for the reflector and the surface finish. The first mirror<br />
materials based on PLEXIGLAS® from <strong>Evonik</strong> are currently<br />
undergoing approval testing. The key to their market viability<br />
is not only durability but also the optimal reflection of the<br />
direct sunlight and a surface finish that, for example, protects<br />
against abrasion through sand and dust.<br />
Collectors for solar thermal energy. If they were<br />
made of reflective plastic instead of glass, the<br />
substructure would be easier and more costeffective<br />
to build. the first mirror materials<br />
based on PLeXIGLAS® from evonik are currently<br />
undergoing approval testing<br />
elements39 Issue 2|2012<br />
Prototype of roof<br />
glazing with integrated<br />
photovoltaic cells<br />
New solutions for<br />
lighter vehicles<br />
counts, the researchers worked with the Performance<br />
Polymers Business Unit to develop a new<br />
impact-resistant molding compound. In 2011, several<br />
metric tons of the new compound were produced for<br />
the purpose of conducting injection-molding and extrusion<br />
tests under real conditions. At the same time,<br />
project house researchers developed various processing<br />
technologies and tested their suitability. One of<br />
their projects was to modify an injection-molding<br />
technology in such a way that PLEXIGLAS® can be<br />
combined with another plastic to form a multi-layer<br />
design in a single step.<br />
These developments fit seamlessly into the strategy<br />
of the automobile industry of using primarily<br />
lightweight, fuel-saving materials in the future to<br />
meet guidelines on emissions and climate protection.<br />
PLEXIGLAS® glazing saves up to 50 percent of the<br />
weight of conventional glazing. The excellent acoustic<br />
properties of the plastic system increases comfort,<br />
and the shatterproof material ensures heightened<br />
safety for passengers.<br />
Transparent car roofs were another focus of<br />
automotive glazing. Because they are used in signi-
ficantly smaller piece counts, they are produced in a<br />
heat forming process. By the end of their first development<br />
year, they had already received approval from<br />
the German Federal Motor Transport Authority that<br />
covers not only roof glazing but also rear and fixed<br />
side windows. This meant that concrete projects with<br />
customers could be started as early as the second year<br />
of the project house. Various automobile manufacturers<br />
are currently conducting street tests of the<br />
first PLEXIGLAS® glazing in prototype vehicles.<br />
In another project, the developers investigated<br />
how a photovoltaic function might be integrated into<br />
the roof glazing. The challenge for developers of<br />
these power-supplying variants is that the PV cell and<br />
polymer composite show different thermal expansion<br />
coefficients. To ensure that the solar cells do not tear,<br />
the researchers developed a sandwich structure, in<br />
which the optically active cells are embedded in an<br />
elastomer matrix that is decoupled from the exterior<br />
PLEXIGLAS® composite layers. They have developed<br />
three different processing techniques in all for manufacturing<br />
such composites.<br />
These composites, however, are flat PV semi-<br />
finished products that still have to be formed into the<br />
spherical shape of the roof glazing. The developers<br />
have successfully advanced these to prototype status:<br />
To make them operational, they produced prototypical<br />
roofs for a standard subcompact car, including<br />
A sandwich made of rOHACeLL® rigid foam and fiber composite top layers<br />
is ideally suited to lightweight construction in the vehicle: this method of construction<br />
allows a unique combination of low weight and maximum mechanical stability<br />
PRoJeCt HoUse sYsteMs InteGRAtIon<br />
roof glazing with integrated PV cells and transparent<br />
roof glazing without PV integration. <strong>Evonik</strong>’s objective<br />
is to gather practical experience with this demonstration<br />
vehicle and, at the same time, convince<br />
automobile manufacturers and potential customers<br />
of the benefits of PLEXIGLAS® glazing solutions.<br />
Transparent glazing:<br />
The first prototypes have<br />
already hit the streets<br />
<strong>Evonik</strong>’s ROHACELL® rigid foam also makes a<br />
big contribution to the lightweight construction in<br />
the vehicle: In combination with high-strength cover<br />
layers, it creates an extremely rigid composite that<br />
finds potential applications in both the interior and<br />
exterior. Concrete applications have been and are<br />
now being tried out in numerous projects with<br />
customers: From construction components with<br />
rather simple requirements, such as rear seat backs,<br />
all the way to structurally relevant components,<br />
where ROHACELL® composites are far superior to<br />
conservative construction methods when it comes to<br />
energy absorption and stiffness.<br />
333<br />
15<br />
elements39 Issue 2|2012
16 PRoJeCt HoUse sYsteMs InteGRAtIon<br />
e-sPInnInG<br />
Fine dust doesn’t stand a chance<br />
One of the technical highlights from the Project House<br />
Systems Integration is a new generation of polymer-based<br />
filter materials that can be used to separate fine dust from the<br />
waste gases of such installations as incinerators or cement<br />
plants. In cooperation with external machine manufacturers,<br />
this electrospinning process, as it is called, has been developed<br />
for the highly temperature-resistant Polyimide P84 all<br />
the way to the pilot production scale. The secret to this<br />
material is fibers with a diameter significantly below one<br />
micrometer: In purely mathematical terms, a purchase order<br />
of one gram of polymer yields a fiber length of about 5,000<br />
kilometers. This creates an extremely finely woven filter<br />
medium.<br />
In electrospinning, a P84 solution is set in an electrical<br />
field under high voltage. When a certain electrical field<br />
strength is reached, the dosing electrode forms a “fiber jet”<br />
in the direction of the counter electrode. The solvent evaporates<br />
and a fine fleece forms on a substrate in front of the<br />
counter electrode. The fibers are then stuck together and<br />
fixed on a stable support fabric. In close cooperation with<br />
the Performance Polymers Business Unit, the developers in<br />
the project house have created the basis for optimizing the<br />
filtration properties of the fiber material with an eye toward<br />
their end application. The newly acquired electrospinning<br />
plant in the project house even allows small-scale internal<br />
pilot production at <strong>Evonik</strong> <strong>Industries</strong>. This, in turn, will<br />
enable researchers to evaluate the ability of other polymers<br />
to be spun in this same way.<br />
elements39 Issue 2|2012<br />
A close-meshed<br />
filter medium for<br />
the deposition<br />
of fine particles,<br />
produced by electrospinning<br />
333 But the key to commercial success for these composites<br />
is cost-efficient mass production. This was a<br />
special focus of the project, and there was a surprising<br />
result: There is not just one economical process<br />
but a number of processes that provide the best cost<br />
efficiency, depending on the component and piece<br />
count.<br />
Micromagnets in new<br />
applications<br />
VP MAGSILICA® are highly versatile magnetic particles.<br />
The brownish powder consists of ultrafine iron<br />
oxides embedded in a dense silicon dioxide matrix.<br />
Through induction, VP MAGSILICA® can be heated<br />
to over 500 °C in a few seconds without stirring. So<br />
the push of a button, for example, can generate local<br />
heat, such as that required by chemical crosslinking<br />
reactions, which can be accelerated significantly by<br />
the heat supply. These applications were investigated<br />
in the Bonding on Demand project.<br />
Here, project house employees worked with<br />
equipment manufacturers and the Inorganic Materials<br />
Business Unit to develop new expertise in the inductive<br />
heating of plastics and adhesives, and build a<br />
complete application technology. With the help of<br />
mobile induction units, potential customers conducted<br />
pilot tests in production and addressed a number<br />
of issues: How do we work VP MAGSILICA® into<br />
an adhesive or a rubber? How should we construct<br />
and design the induction apparatus? How do we<br />
achieve the best heat input?<br />
One of the big potential applications for VP MAG-<br />
SILICA® is the crosslinking (vulcanization) of rubber<br />
profiles. In this process, the powder is added in small<br />
concentrations to the rubber formulation and heated<br />
immediately after extrusion, thereby vulcanizing the<br />
rubber. It became clear that the mechanical properties<br />
of the hardened profiles are comparable to conventionally<br />
vulcanized rubbers.<br />
Even modern insulating glass panes can be bonded<br />
faster and easier with the superparamagnetic powder.<br />
Normally, the double panes of modern windows<br />
are placed and bonded together in the edge region by<br />
an aluminum spacer. In order to fulfill the requirements<br />
of the upcoming thermal insulation regulation,<br />
the aluminum will be omitted as a thermal bridge. In<br />
cooperation with a hotmelt adhesive manufacturer,<br />
the project house has developed a mounting process<br />
by which the aluminum spacer can be replaced by<br />
plastic.<br />
Three years of work in the Project House Systems<br />
Integration have been crowned with success: At the<br />
end of the third year, all nine projects are still alive<br />
and continue to look promising. Seven of the nine<br />
projects have already been sent back to the par ti -
On the way to the market<br />
cipating business lines, while the other two will conclude<br />
by the middle of this year. The individual business<br />
units now have the task of taking the technical<br />
development results to market readiness.<br />
As different and multi-faceted as the projects are,<br />
they are quite similar in their strategic objectives:<br />
They contribute to energy and resource efficiency<br />
and advance the development of more sustainable<br />
products and processes for <strong>Evonik</strong> and its partners<br />
and customers. At the same time, the innovations increase<br />
the competitiveness of the company by opening<br />
up forward-looking markets, and by strengthening<br />
customer loyalty through practical solutions with<br />
high added value.<br />
The results of these projects are important not<br />
least because the Project House Systems Integration<br />
was planned and prepared in the midst of the economic<br />
crisis. But instead of slowing down work on<br />
the projects, it proved to be a challenge and opportunity<br />
for everyone involved. The Group’s decision<br />
to invest in interdisciplinary and demanding research,<br />
even in economically challenging times, turned out<br />
to be the right strategy. Planning the project house<br />
based on the prevailing economic conditions did<br />
nothing to detract from its success. 777<br />
PRoJeCt HoUse sYsteMs InteGRAtIon<br />
with vP MAGSILICA®, adhesives and plastics can be inductively<br />
heated to accelerate the crosslinking reaction. the Bonding<br />
on Demand project investigated the best way to coordinate the<br />
product and processing technology to achieve optimal results<br />
dr. Michael olbrich is the head of the Project House<br />
Systems Integration. After studying chemistry at the<br />
Albert Ludwig University in Freiburg and receiving<br />
his PhD from the Institute for Macromolecular<br />
Chemistry there, he started his career in 1995 in the<br />
construction chemicals industry at the Polymer<br />
Institute Dr. R. Stenner GmbH, as an assistant to the<br />
CEO. In 1999, he was hired to be head of molded foam<br />
application technology at PolymerLatex GmbH & Co.<br />
KG. In 2001, he took a job with <strong>Evonik</strong> Röhm GmbH<br />
in the Binders and Additives Business Line. His last<br />
job there was head of global sales for the Road Mar king<br />
and Casting Resins business segment. Since 2008,<br />
he has been working on the preliminary feasi bility<br />
study for the Project House Systems Integration at<br />
Creavis.<br />
+49 6181 59-4976, michael.olbrich@evonik.com<br />
17<br />
elements39 Issue 2|2012
18 CoMMent<br />
Innovations make history<br />
elements39 Issue 2|2012<br />
Innovations are, and always have been, an important cornerstone of a better future.<br />
To ensure the livelihood of future generations, then, we must continue to put good<br />
ideas into practice. But without social acceptance, even the best innovations will fail.<br />
[ text Dr. Klaus Engel ]<br />
A steady source of innovations for more than<br />
four decades: eUDrAGIt® tablet coating, which<br />
allows temporal and spatial control of the<br />
release of pharmaceutical active ingredients<br />
What comes to mind? The answer is essential to<br />
the future of our country, because inspiration, new<br />
ideas, and innovation are some of Germany’s most<br />
important resources. Without innovation, we<br />
wouldn’t be able to maintain or improve our standard<br />
of living. Without innovation, we’ll not be able to<br />
drive forward a sustainable, eco-friendly lifestyle and<br />
economy. This insight is no longer truly innovative,<br />
but it’s still not generally accepted. We must make<br />
sure that Germany, the land of industry, the land of<br />
research and production, doesn’t become the land<br />
of denial and procrastination if the public refuses to<br />
recognize the economic underpinnings of our prosperity.<br />
In today’s Germany, the triumvirate of research, innovation,<br />
and industry always inspires a great deal of<br />
skepticism, or even fear, which we have to counter<br />
with fair, fact-based arguments. If we can persuade<br />
the public and dispel its anxiety, we can achieve a<br />
great deal. It’s still worth our while to establish the<br />
facts.<br />
Innovations are, and always have been, an important<br />
cornerstone of a better future. Indeed, they are<br />
our lifeboat. The fledgling Federal Republic of Germany<br />
is a good example. Sixty years ago today, in<br />
1952, the new German constitutional state was already<br />
three years old. The murderous world war had<br />
ended only seven years before. In 1952, rubble and
sorrow were still part of everyday life in the divided<br />
Germany. In an address to the German people, Federal<br />
President Theodor Heuss complained that privation<br />
was “firmly rooted in many, many places.” And<br />
yet 1952 was also a year of new confidence, as the first<br />
fruits of the reconstruction became palpable. The<br />
German economic miracle was taking shape—through<br />
a lot of hard work, capital assistance from abroad,<br />
and, not least, inge nuity.<br />
Innovation as a lifeboat to a better future? While<br />
Heuss lamented the poverty back then, he also spoke<br />
of confidence and “highly sophisticated inventions<br />
that would set the German people back on course.”<br />
An end-of-the-year review from 1952 proudly celebrates<br />
the television: “We invented and built a number<br />
of new machines.” Journalists can point to successful<br />
export trade fairs as proof. Even back then,<br />
the focus was always on innovations, new ideas that<br />
will prevail on the market—in Germany, but also<br />
abroad.<br />
A core message from 1952 still holds true today;<br />
the economic prosperity of the people of our country<br />
is not based on the merging of simple components or<br />
by merely imitating the achievements of others. Our<br />
opportunities lie in forward thinking and improvements,<br />
in brainpower, and know-how. Sixty years<br />
later, in the Germany of the 21st century, this still applies—even<br />
if we use different vocabulary. Ingenuity<br />
and industriousness were the bywords of 1952. Today,<br />
concepts such as innovative power and competitiveness<br />
are more common.<br />
The German economy was also gaining steam internationally<br />
60 years ago. As early as 1952, customers<br />
around the globe associated “Made in Germany”<br />
on goods and products with quality. But the economic<br />
size classes have changed: Back then, it was sovereign<br />
nations, national economic systems or national economies<br />
that competed with each other. In the wake of<br />
globalization, on the other hand, we’re more likely<br />
to talk of competition between alliances and world<br />
regions.<br />
Another important difference between 1952 and<br />
2012 is the time factor: The speed of innovations has<br />
increased. More than a half century passed from the<br />
time the television was invented to the time it was<br />
widely found in households across Germany. When<br />
it came to the mobile phone, that time span was only<br />
a little over ten years.<br />
Over the last few decades, Germany has managed<br />
to maintain a healthy, powerful industrial climate—<br />
despite the crises and dramatic changes across entire<br />
industries. The capacity for self-renewal, innovation<br />
for our own sake, was a key factor in this regard. Today,<br />
the chemical industry in Germany often serves<br />
completely different markets, supplies entirely different<br />
products than in 1952.<br />
<strong>Evonik</strong> <strong>Industries</strong> itself reflects this change. The<br />
Group began operating under this name in 2007, only<br />
five years ago, thereby focusing its energies expressly<br />
on the power to create. The new company brought<br />
with it decades of experience from the chemical industry—and<br />
an appreciation of the value of innovation.<br />
<strong>Evonik</strong>’s history contains names such as Degussa,<br />
Chemische Werke Hüls, Th. Goldschmidt, and<br />
Röhm, just to mention a few. Even in the decades before<br />
the name change, these companies and groups<br />
were no strangers to innovation. Some milestones<br />
from <strong>Evonik</strong>’s history provide good illustrations.<br />
EUDRAGIT®, the protective coating for tablets,<br />
came on the market in the 1950s and made it possible,<br />
for the first time, to control the release of a medical<br />
agent in the patient’s body.<br />
In the colorful 1960s, plastic was king, and awareness<br />
of environmental protection was on the rise. In<br />
1964, the Group began producing proprietary biodegradable<br />
detergents, the active cleansing agents 333<br />
CoMMent<br />
Current research topics at evonik: A binder for<br />
corrosion protection formulations that significantly<br />
reduces, or avoids, the use of toxic heavy metals<br />
The core message is unchanged<br />
19<br />
elements39 Issue 2|2012
20 CoMMent<br />
333 for laundry detergents. Even research into catalysts<br />
for exhaust fumes from industry and traffic were<br />
gaining importance—more than 20 years before the<br />
law required cars to be fitted with catalysts.<br />
In the 1970s, the oil crisis arrived and increased<br />
the prices of raw materials and energy. The chemical<br />
industry, in turn, introduced more economical and<br />
environmentally compatible products to the market.<br />
Among other advances, the Group made a key contribution<br />
to reducing the environmental impact of<br />
cars: The first production plant for MTBE—a lead substitute<br />
important for the antiknock properties of gasoline—was<br />
built in Marl in 1976.<br />
The 1980s saw intense public debate over forest<br />
dieback, disarmament, and atomic energy. Across<br />
Germany, the Group at that time was peerless in its<br />
activities related to monosilane-gas—a starting material<br />
for the production of solar cells. The innovations<br />
of this decade also included additives for solvent-free<br />
coatings.<br />
In the 1990s, <strong>Evonik</strong> also ensured that green ideas<br />
gave birth to tangible products: Its silicas and organosilanes<br />
supplied two essential components for<br />
the production of tires that save fuel through extremely<br />
low rolling resistance and thereby also protect<br />
the environment. In addition, the Group transitioned<br />
increasingly to the production of surfactants<br />
from renewable raw materials. And about four decades<br />
after its debut, the EUDRAGIT® tablet coating<br />
experienced another surge in innovation—the market<br />
launch of a new variant for patients who depend on<br />
continuous drug delivery.<br />
Since the dawn of the 21st century, the Group has<br />
also focused its innovative power inwardly, adopting<br />
new structures in research and development—one of<br />
the most important sources for innovation. Its objective<br />
is improved knowledge transfer and completely<br />
market-oriented R&D.<br />
Currently, <strong>Evonik</strong> intends to benefit above all from<br />
the worldwide social development processes in<br />
health, nutrition, resource efficiency, and globalization.<br />
Some of the Group’s innovations include bricks<br />
for home construction that stand out for their special<br />
heat-insulating filler, and biopharmaceuticals that<br />
come as sprays or tablets and eliminate the need for<br />
injections. They also include binders for corrosion<br />
protection formulations that significantly reduce or<br />
avoid the use of toxic heavy metals.<br />
Hydrogen peroxide—an environmentally friendly<br />
bleaching agent that replaces chlorine bleach—is a<br />
great example of a changing market. Another example<br />
is PLEXIGLAS®: The plastic was introduced on<br />
the market as early as the 1930s, and a new variant<br />
now provides noise protection for a heavily traveled<br />
elements39 Issue 2|2012<br />
Dr. Klaus engel is Chairman of the<br />
executive Board of evonik <strong>Industries</strong> AG<br />
highway in southern China. And it demonstrates,<br />
once again, that the global innovation superhighway<br />
offers Germany, as an industrial nation, literally<br />
boundless opportunities.<br />
All these examples support my core thesis: We<br />
cannot abandon our efforts to put good ideas into<br />
practice, because they ensure the livelihood of future<br />
generations. As always, the key here is dialogue: In-<br />
Continuing the dialogue<br />
ner cities plagued by smog, lakes and rivers covered<br />
by foam from laundry detergents have all warned us<br />
to make changes. There can be no doubt that legislation<br />
and public pressure have helped bring about<br />
the transformation. But without innovation—in other<br />
words, without industrial practice—our progress<br />
would have been trifling.<br />
This is why we should discuss the pros and cons<br />
of innovations and new projects in a spirit of fairness<br />
and commitment—without social acceptance, even<br />
the best innovations will fail. But at the same time,<br />
we shouldn’t allow endless, irrelevant debate to slam<br />
the brakes on us and make us veer off the lane of reason.<br />
Driving on the hard shoulder is dangerous. For<br />
an industrial nation like Germany, which depends on<br />
innovation, it’s particularly hazardous. 777
Honorary professorship for Dr. Klaus engel<br />
Dr. Klaus Engel (55), the Chairman of the Executive Board of <strong>Evonik</strong><br />
<strong>Industries</strong> AG, recently received an honorary professorship from the<br />
School of Engineering at Duisburg-Essen University (UDE). Engel is<br />
the President of the Chemical Industry Association (VCI) and also<br />
chairs the Battery Technology Working Group in the National<br />
Platform for Electromobility, which was established by the German<br />
Chancellor.<br />
As an industry expert, Engel keeps in touch with UDE professors<br />
regularly, but his practical insights will now benefit the curriculum of<br />
the school, too. He will give lectures within the scope of the “Duisburg<br />
Dialogs” and will be involved in designing a lecture series that will<br />
also feature discussions with other representatives of <strong>Evonik</strong> on scientific<br />
questions from an industry perspective. The objective is to<br />
give university students a practical perspective of applying basic scientific<br />
concepts in industrial and business contexts.<br />
In his new capacity, Engel is particularly concerned about reaching<br />
out to junior scientists. “As a location for industry, Germany must<br />
continue maintaining the highest level of quality it is known for, and<br />
that goes for the future too, and the key to this lies in training and<br />
advancing talented and committed young people. I look forward to<br />
making a personal, practical contribution to this effort at Duisburg-<br />
Essen University,” he noted during the award ceremony of the honorary<br />
professorship in Duisburg, adding that Duisburg-Essen<br />
University is an example of establishing functional bridges between<br />
different sites. “Those efforts are not always successful,” Engel said.<br />
“There are always new obstacles to overcome, both in terms of space<br />
and content, which is essential for lasting success in science, research,<br />
Sale of the colorants business<br />
On April 30, 2012, <strong>Evonik</strong> <strong>Industries</strong> sold its<br />
global colorants business to the U.S. private<br />
investment firm Arsenal Capital Partners.<br />
<strong>Evonik</strong>’s colorants business develops, produces,<br />
and markets colorant systems for<br />
decorative coatings under the trademark<br />
COLORTREND®. Its CHROMA-CHEM® products<br />
are used for industrial applications including<br />
maintenance, marine, and wood coatings.<br />
In 2011 <strong>Evonik</strong>’s colorants business generated<br />
sales of around €130 million. With a global<br />
setup the colorants business employs more<br />
neWs<br />
and teaching, as well as in the industry. It is my hope to use the honorary<br />
professorship for building bridges, between science and industry,<br />
theory and practice, and between people and markets. New<br />
insights become only genuinely valuable when they are shared.”<br />
“Close contact with the industry is particularly important for engineering<br />
programs,” emphasized the university’s President, Prof.<br />
Ulrich Radtke. Dr. Engel is originally from Duisburg and holds<br />
a degree in chemistry from the University of Bochum.<br />
At the award ceremony of the honorary professorship in<br />
Duisburg: north rhine-westphalia Minister for economic Affairs<br />
Harry voigtsberger, evonik CeO Dr. Klaus engel, and university<br />
President Prof. Ulrich radtke (from left to right)<br />
than 300 people in its production sites and<br />
laboratories supported by sales and technical<br />
professionals. These facilities are located in<br />
the USA, Can ada, Brazil, Australia, China,<br />
Malaysia, and the Netherlands.<br />
“We are delighted with the opportunity<br />
to acquire a leading global business in the<br />
colorants space,” said John Televantos, Partner<br />
at Arsenal and Co-Head of the firm’s Specialty<br />
Industrials Group. “The business has a strong<br />
reputation because of its people, technology,<br />
quality, and service. It provides a great platform<br />
to build a stronger global business in a<br />
sector that we understand and believe it will<br />
perform well as an independent company<br />
benefiting from Arsenal’s resources and<br />
expertise. We look forward to supporting<br />
and building the business organically and<br />
with strategic acquisitions that will further<br />
expand its network.”<br />
21<br />
elements39 Issue 2|2012
22 neWs<br />
Groundbreaking<br />
ceremony for new organics<br />
production facility<br />
In March 2012, <strong>Evonik</strong> <strong>Industries</strong> broke ground to mark the official<br />
start of the construction of a new organics production facility in<br />
Shanghai (China), an upper-two-digit-million-euro investment. The<br />
ceremony was attended by more than 200 guests including government<br />
officials, regional and global contacts of <strong>Evonik</strong>’s key customers,<br />
elements39 Issue 2|2012<br />
strategic partners, as well as management and employees of the<br />
company.<br />
The detail engineering of the new organics production facility is<br />
already completed and the plant is expected to be operational in 2013.<br />
It will supply innovative ingredients and specialty surfactants based<br />
on renewable raw materials for the personal care, household care, and<br />
industrial specialties industry. It will primarily serve markets in China<br />
and Asia Pacific, with an annual capacity of 80 kt. The new production<br />
plant will be built on a 33,000 sqm plot of land at <strong>Evonik</strong>’s Multi-<br />
User Site China (MUSC) in Shanghai Chemical Industry Park (SCIP).<br />
It is conveniently located in the Yangtze River Delta Economic Zone.<br />
<strong>Evonik</strong>’s new organics production facility is also setting environmental<br />
standards. MUSC, a wholly-owned <strong>Evonik</strong> site, follows all<br />
Shanghai, China and <strong>Evonik</strong> standards and laws. In addition, the site<br />
is regularly audited and certified (ISO 9001, 14001 and OSHA 18001).<br />
<strong>Evonik</strong> will implement state-of-the-art environmental protection<br />
meas ures, such as sophisticated air pollution and waste treatment<br />
controls and two-step waste water treatment.<br />
Parallel to the construction of the new production plant, <strong>Evonik</strong><br />
is expanding its R&D center at its Xinzhuang site in Shanghai, with<br />
an investment of € 23 million. The expansion includes state-of-theart<br />
laboratories for research and development, application technology,<br />
and technical service, with aims to develop product applications<br />
and provide technology service for customers throughout China and<br />
Asia Pacific.<br />
Biogas upgrading: new plant for hollow fiber membrane modules<br />
<strong>Evonik</strong> <strong>Industries</strong> is investing an upper-singledigit-million-euro<br />
amount in a plant produc ing<br />
SEPURAN® hollow fiber membrane mod ules<br />
at its Schörfling (Austria) site. In particular, the<br />
novel membrane technology facilitates the<br />
energy-efficient upgrading of biogas to biomethane.<br />
Biomethane is fed into the public<br />
natural gas grid. The new hollow fibre spinning<br />
plant will come on-stream within 2012<br />
to meet the grow ing demand on the biogas<br />
market.<br />
“With this investment, we’re systematically<br />
strengthening our activities in the area<br />
of gas separation membranes, proving our<br />
commitment to renewable energies by producing<br />
biomethane that can be fed directly<br />
into the grid,” said Dr. Axel Kobus, head of the<br />
growth segment Fibers & Membranes. “In<br />
contrast to other processes, our membrane<br />
tech nology needs no auxiliary chemicals; nor<br />
does it generate any solid wastes or effluents<br />
that would need to be disposed of.” The <strong>Evonik</strong><br />
process is offered on the market by leading<br />
plant engineering and construction partners,<br />
and works cost-effectively, even in relatively<br />
small plants. It is therefore particularly suitable<br />
for the local energy supply of tomorrow.<br />
The novel technology is based on membranes<br />
produced from high-performance<br />
Hollow fiber membrane module for<br />
the upgrading of biogas to biomethane<br />
polymers that in the past have been, for<br />
example, processed into fibers and used in<br />
hot-gas filtration. At pressures of up to 25 bar,<br />
such membranes allow significantly improved<br />
separation of carbon dioxide and methane<br />
with stable selectivity, in a single process<br />
step. The method yields methane of purity<br />
higher than 99 percent. Neither energyintensive<br />
recycle streams nor costly downstream<br />
processing steps are required, which<br />
significantly distinguishes the <strong>Evonik</strong> method<br />
from the technologies currently available on<br />
the market.<br />
At present, biogas is still largely converted<br />
to electricity at its production site, with a<br />
maximum of 40 percent of its energy being<br />
utilized by the conversion to power. In such<br />
local power generation the waste heat often<br />
remains largely unused. When fed into the<br />
natural gas grid, however, the raw material<br />
can be stored much more efficiently, and<br />
more than 90 percent of its energy utilized<br />
as power and heat.
evonik invests in High-tech Gründerfonds II<br />
<strong>Evonik</strong> <strong>Industries</strong> has invested €2.5 million in<br />
High-Tech Gründerfonds II, expanding the<br />
number of industry investors to 13 corporations.<br />
In 2011 <strong>Evonik</strong> invested €365 million<br />
into research and development projects and<br />
is continuing its innovation strategy with its<br />
involvement in the fund. High-Tech Gründerfonds<br />
II began in October 2011 with a<br />
volume of €288.5 million in the first closing.<br />
It is able to provide seed financing of up to<br />
€500,000 of venture capital to innovative<br />
technology companies and reserve another<br />
€1.5 million per company for follow-up<br />
rounds.<br />
“The goal is to provide early financing for<br />
technologies, to create lasting value in the<br />
companies and to develop them in order to<br />
make them commercially viable. Overall, we<br />
have already been able to finance over 260<br />
companies since the start of Gründerfonds I<br />
in 2005. These start-ups have succeeded in<br />
arranging approx. €400 million of additional<br />
venture capital subsequent to our investments,”<br />
says Dr. Michael Brandkamp, Mana<br />
ging Director of High-Tech Gründerfonds.<br />
He adds, “With the involvement of <strong>Evonik</strong><br />
we have not only been able to increase the<br />
second fund to €291 million, but would also<br />
like to significantly increase the number of<br />
start-ups in the chemicals sector in Germany.”<br />
“<strong>Evonik</strong> <strong>Industries</strong> fosters a distinctive<br />
innovation culture. With our innovations we<br />
want to maintain our technology competence<br />
in the long-term and continue to expand it,”<br />
explains Dr. Bernhard Mohr, Head of Cor porate<br />
Venturing at <strong>Evonik</strong>. “Our involvement<br />
in High-Tech Gründerfonds II is another part<br />
of this strategy of investing in innovations and<br />
providing assistance to promising young startups<br />
in the chemicals sector and related disciplines.”<br />
Following Altana and BASF, <strong>Evonik</strong> is the<br />
third company from the chemicals sector to<br />
invest in High-Tech Gründerfonds II. This<br />
neWs<br />
should send a clear signal to universities and<br />
institutes of higher learning with a knack for<br />
spin-offs, as well as research facilities in the<br />
chemicals sector and related disciplines. “We<br />
want to motivate young scientists in the field<br />
of chemistry and related areas, which can also<br />
be engineering sciences, to start companies<br />
and to provide them with the necessary networks<br />
and contacts, in addition to starting<br />
capital,” says Michael Brandkamp, explaining<br />
the strong presence of the chemicals industry<br />
in the group of investors.<br />
Proximity to corporations has many<br />
advan tages. In addition to customer-supplier<br />
relationships opened up between small and<br />
large companies, the facilities or distribution<br />
channels of the industry may possibly also be<br />
used by start-ups. The industry benefits from<br />
trends, innovations, and completely new, cutting-edge<br />
business models.<br />
High-Tech Gründerfonds invests in<br />
young, high potential high-tech start-ups.<br />
The seed financing provided is designed to<br />
enable start-ups to take an idea through prototyping<br />
and to market launch. Investors in<br />
this public/private partnership include the<br />
Federal Ministry of Economics and Tech nology,<br />
the KfW Banking Group, as well as thirteen<br />
industrial groups. High-Tech Gründerfonds<br />
has about €563 million under management<br />
in two funds (€272 million High-Tech<br />
Gründerfonds I, €291 million High-Tech<br />
Gründerfonds II).<br />
Groundbreaking ceremony for new hydrogen peroxide plant in China<br />
An official ceremony was held at the end of<br />
April 2012 to mark the groundbreaking for<br />
<strong>Evonik</strong>’s new hydrogen peroxide plant in<br />
China. The plant is scheduled to go online,<br />
with a planned annual production capacity of<br />
230,000 metric tons, at the end of 2013, thus<br />
increasing <strong>Evonik</strong>’s current overall annual capacity<br />
of around 600,000 metric tons of<br />
H 2 O 2 production by nearly 40 percent.<br />
<strong>Evonik</strong> <strong>Industries</strong> recently founded <strong>Evonik</strong><br />
Specialty Chemicals (Jilin) Co., Ltd. (ESCJ)<br />
to run the new production facility. <strong>Evonik</strong> will<br />
supply its H 2 O 2 from Jilin directly to the adjacent<br />
propylene oxide plant run by Jishen<br />
Chemical Industry Co., Ltd. via a pipeline that<br />
will link the two facilities. A long-term supply<br />
agreement is in place between these companies.<br />
Jishen will use the so-called HPPO<br />
process to make propylene oxide from the<br />
hydrogen peroxide. Propylene oxide is used<br />
chiefly in the manufacturing of polyurethane<br />
intermediates. The polyurethanes then go<br />
into making things like upholstery for car<br />
seats or furniture. The HPPO process was<br />
developed by <strong>Evonik</strong> in collaboration with<br />
ThyssenKrupp Uhde GmbH.<br />
“Our investment in Jilin,” explains Jan Van<br />
den Bergh, the head of <strong>Evonik</strong>’s Advanced<br />
Intermediates Business Unit, “is an excellent<br />
example of our strategy to develop innovative<br />
technology to access new sales markets<br />
for hydrogen peroxide. This move is also part<br />
of a growth strategy that sees us making targeted<br />
investments in Asia and that will help<br />
us to achieve growth in that region.”<br />
The HPPO plant in China that will use the<br />
<strong>Evonik</strong>-Uhde technique will be the second<br />
of its kind. The first-ever large-scale HPPO<br />
operation anywhere in the world was jointly<br />
established by <strong>Evonik</strong>, ThyssenKrupp Uhde,<br />
and a Korean chemicals company (the licensee)<br />
in Ulsan (Korea) in 2008.<br />
Hydrogen peroxide has previously been<br />
used mostly as a bleaching agent in the textile<br />
and pulp industry. The new HPPO process<br />
now makes it possible for this environmentally<br />
friendly oxidant to also be used in the<br />
chemical direct synthesis of propylene oxide.<br />
The advantages of the HPPO process are that<br />
it requires significantly less investment, that<br />
it enables a high degree of production efficiency,<br />
and that it is an extremely eco-friendly<br />
process.<br />
23<br />
elements39 Issue 2|2012
24 CAtALYsIs<br />
elements39 Issue 2|2012<br />
New tool for characterizing catalysts<br />
Profiling simplifies scale-up<br />
in PMPC production<br />
Owing to their complex composition, heterogeneous catalysts cannot<br />
always be characterized entirely—something that can lead to unpleasant<br />
surprises when the production formulation is transferred to the commercial<br />
scale. With profiling, the experts of <strong>Evonik</strong>’s Catalysts Business<br />
Line have developed a method that visually illustrates the influence<br />
of the formulation on the catalytic properties. Profiling not only simplifies<br />
scale-up but also allows the customer to sample more efficiently.<br />
[ text Dr. Dorit Wolf ]
it Remains a challenge for catalysis experts to completely<br />
characterize a solid catalyst. Due to the complexity<br />
of these catalysts, they do not form a uniform<br />
phase, but display various polymorphic solid phases<br />
at once, which are also not defined at the molecular<br />
level. As a result, many physical and chemical properties<br />
are subject to broad distribution. Good examples<br />
include the particle sizes of the carrier materials,<br />
the size of the metal particles on the carriers, the<br />
acidity or basicity of surface centers, or even the oxidation<br />
conditions of the active transition metal components.<br />
It becomes even more complicated when the conditions<br />
on the edges of the distribution functions influence<br />
the catalytic properties. With their content<br />
being so infinitesimally small, it is difficult or impossible<br />
to use physicochemical methods to identify and<br />
quantify them.<br />
As a catalyst producer, however, <strong>Evonik</strong> must ensure<br />
the consistent quality and performance of its<br />
products. In addition to the standard methods of physicochemical<br />
characterization, such as determining<br />
particle sizes, elementary analysis, determining pore<br />
Figure 1<br />
Property profile of catalysts: Profiling<br />
illustrates the performance features “activity”<br />
and “selectivity” in various test reactions<br />
100<br />
90<br />
80<br />
70<br />
60<br />
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MtBe cracking [%]<br />
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(3)<br />
Selectivity<br />
(3)<br />
Characterization using catalysis<br />
volumes, and pore radius distribution, the company<br />
now has a method of evaluating the catalyst: Profiling.<br />
This tool, developed in-house, reliably indicates<br />
the extent to which changes in the manufacturing<br />
process influence the catalytic properties.<br />
The method is based on testing precious metal<br />
powder catalysts (PMPC) in different catalytic reactions<br />
that represent the key fields of application:<br />
Hydrogenation of CC double and CC triple bonds, of<br />
CO and CN groups, and of aromatic nitro groups. It<br />
also factors the hydrogenation of substrates that<br />
simultaneously display different hydrogenizable<br />
functional groups. The various reactions test the<br />
catalysts’ activity and selectivity—the actual performance<br />
features described in the property profile<br />
of each catalyst (see Fig. 1).<br />
The profiles differ greatly, depending on the composition<br />
of the catalyst— the type of precious metal, the<br />
precious metal loading, and the carrier type— 333<br />
CAtALYsIs<br />
Activity<br />
(4)<br />
Selectivity<br />
(4)<br />
25<br />
elements39 Issue 2|2012
26 CAtALYsIs<br />
Figure 2<br />
Diagrams of the production formulae to the left, catalyst performance profiles to the right. evonik’s new method shows<br />
which production parameters influence catalyst performance, and whether any still require fine-tuning<br />
Compound<br />
1<br />
Compound<br />
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reduction<br />
elements39 Issue 2|2012<br />
Compound<br />
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Compound<br />
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Compound<br />
2<br />
Lab<br />
Heating and<br />
stirring<br />
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Heating and<br />
stirring<br />
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Heating and<br />
stirring<br />
Drying<br />
1<br />
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rewetting<br />
Drying<br />
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Drying<br />
1<br />
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rewetting<br />
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Activity/selectivity indicator [%]<br />
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40<br />
30<br />
20<br />
10<br />
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reaction number
Figure 3<br />
Performance profiles of various prepared PMPC catalysts (5 % Pd/C) from evonik. these profiles allow<br />
conclusions to be drawn regarding the preferred reactions and substrates of the particular catalyst types<br />
%<br />
100<br />
75<br />
50<br />
25<br />
0<br />
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DEG-Catalyst 1 DEG-Catalyst 2 DEG-Catalyst 3 DEG-Catalyst 4<br />
DEG-Catalyst 5 DEG-Catalyst 6 DEG-Catalyst 7 DEG-Catalyst 8<br />
DEG-Catalyst 9 DEG-Catalyst 10 DEG-Catalyst 11 DEG-Catalyst 12<br />
DEG-Catalyst 13 DEG-Catalyst 14 DEG-Catalyst 15<br />
DEG-Catalyst 16<br />
1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9<br />
Reaction Reaction Reaction Reaction<br />
333 but also on the manufacturing formula. To put it<br />
differently: The catalytic performance profiles are a<br />
type of unique fingerprint for each type of catalyst.<br />
<strong>Evonik</strong> uses profiling in the development of new<br />
catalysts when laboratory formulas have to be transferred<br />
to the commercial scale. With the new method,<br />
they can analyze whether the properties lend themselves<br />
to reproduction, and whether the catalysts produced<br />
perform as well as the laboratory models.<br />
Figure 2 demonstrates that profiling is well suited<br />
to this purpose. It not only shows whether the catalyst<br />
formula could be successfully transferred from<br />
the laboratory to the production scale but also which<br />
production parameters determine catalyst performance<br />
and whether they might still require finetuning.<br />
Profiling therefore allows selective improvement<br />
in the robustness of the catalyst production<br />
process, and it also assists quality assurance.<br />
Figure 3 shows various profiles of the catalysts of<br />
<strong>Evonik</strong>’s PMPC portfolio. All of these are five percent<br />
Pd catalysts, with activated carbon as the carrier. The<br />
only difference in these catalysts is the way they were<br />
produced. In the end, they all have the same quantitative<br />
composition. The figure shows how extremely<br />
sensitive the performance profiles are to the parameters<br />
of catalyst production. This makes profiling a<br />
useful tool not only for scaling up catalysts: The<br />
method also makes it possible to derive preferred<br />
reactions and substrates for the various catalyst types<br />
from the profiles.<br />
In other words, it allows fast identification of the<br />
types of reactions or substrates that will make a certain<br />
catalyst in the <strong>Evonik</strong> portfolio display particularly<br />
high activity and selectivity and, on the other<br />
hand, which substrates will make the catalyst less<br />
active or selective. By this method, customers can<br />
obtain a sample optimally designed for their specific<br />
application. 777<br />
CAtALYsIs<br />
More robust production processes<br />
Pd dr. dorit Wolf has been R&D group leader in<br />
<strong>Evonik</strong>’s Catalysts Business Line since 2004. She<br />
studied chemistry at the University of Leipzig, where<br />
she earned her doctorate in 1991. In 1997, Wolf qualified<br />
as a university lecturer in chemical technology at<br />
the Chair for Chemical Technology at Ruhr University<br />
in Bochum. She subsequently accepted a position as<br />
director of the Reaction Technology Working Group at<br />
the Institute for Applied Chemistry Berlin-Adlershof.<br />
In 2001 she moved to <strong>Evonik</strong> to direct the Hetero geneous<br />
Catalysis Group in the Catalysis Project House.<br />
+49 6181 59-8746, dorit.wolf@evonik.com<br />
27<br />
elements39 Issue 2|2012
28 MedICAL teCHnoLoGY<br />
elements39 Issue 2|2012<br />
Implants made from PEEK ensure<br />
new quality in medicine<br />
Whether it is spinal disc problems or certain diseases of the gastrointestinal<br />
tract, dental technology or cardiac pacemakers: For many health concerns,<br />
implants are the method of choice for restoring a patient’s quality of life.<br />
As an implant material, polyetheretherketone has established a firm position<br />
in a market defined not by large piece counts, but by custom-designed<br />
individual solutions. <strong>Evonik</strong> has met this challenge with VESTAKEEP® PEEK.<br />
[ text Marc Knebel ]<br />
Cranial-Maxillo-Facial<br />
Dental<br />
Orthopedics<br />
Cardiovascular<br />
Spine<br />
Fields of application<br />
for implants made<br />
from PeeK polymers
Patients Who suffeR from stomach or intestinal<br />
tumors can experience constriction of the digestive<br />
tract—a condition called stenosis, which prevents food<br />
from passing through. In these cases, a stent—an elastic,<br />
tube-shaped, self-expanding wire mesh that<br />
unfolds following placement in the esophagus or the<br />
affected section of the intestine—reopens the pathway<br />
for food. The stent does not cure the patient’s<br />
disease, but it does alleviate suffering and improves<br />
the patient’s quality of life.<br />
Traditionally produced from polyamide or polyester,<br />
stents can now be made from <strong>Evonik</strong>’s polyetheretherketone<br />
(PEEK) VESTAKEEP® as well. The<br />
material boasts not only excellent biocompatibility,<br />
which <strong>Evonik</strong> has verified in numerous tests by<br />
external testing institutes, but also high biostability.<br />
The latter is a direct result of the aromatic, partially<br />
crystalline properties of the PEEK polymer, which<br />
not only imparts outstanding resistance to corrosion,<br />
hydrolysis, and chemicals but also renders it inert to<br />
bodily liquids—the material retains its stability, even<br />
under aggressive conditions.<br />
The stents are one of the new medical applications<br />
<strong>Evonik</strong> has opened up with VESTAKEEP®. The fact<br />
that EPT—<strong>Evonik</strong> Polymer Technology GmbH, which<br />
manufactures PEEK semi-finished products—is certi-<br />
Synthesis of PeeK. the aromatic,<br />
partially crystalline properties<br />
of the PeeK polymer make it highly<br />
resistant to chemicals and bodily<br />
fluids<br />
fied to EN ISO 13485:2003 simplifies marketing of the<br />
material. This certification makes it easier for the<br />
producers of medical products to qualify as suppliers,<br />
and ensures specific medical standards of care and<br />
traceability are met. This completes a key hurdle in<br />
advancing new applications.<br />
In addition to its biostability and biocompatibility<br />
(see also elements34, p. 30 ff), the advantages of<br />
VESTAKEEP® include its outstanding mechanical<br />
properties, such as high dimensional stability based<br />
on low water intake, high stiffness at low weight, high<br />
resistance to heat distortion, and a long-term service<br />
temperature of 260 °C. This high-performance plastic<br />
is also easy to work into versatile shapes—an argument<br />
not only for the filigree construction of stents<br />
but also for use as an extremely thin-walled battery<br />
housing in cardiac pacemakers, in dental technology,<br />
or as an implant pump for patients who, for instance,<br />
suffer from excess fluid in the abdomen as a result of<br />
liver disease. 333<br />
Orthopedics: A growing<br />
field of applications<br />
F F<br />
+<br />
na2CO3 – naF<br />
– H2O O OH<br />
– CO2 O<br />
OH<br />
MedICAL teCHnoLoGY<br />
O<br />
O<br />
evonik produces veStAKeeP®<br />
in a Class 10000 clean room,<br />
which commenced operation<br />
in April 2011<br />
n<br />
29<br />
elements39 Issue 2|2012
30 MedICAL teCHnoLoGY<br />
elements39 Issue 2|2012<br />
333 Historical areas of application for high-performance<br />
PEEK have been spinal implants, with a growing<br />
interest in orthopedic devices and recently<br />
accepted applications such as mouth, jaw, and skull<br />
implants. For spine surgery, in the case of herniated<br />
discs it can be advisable to remove the intervertebral<br />
disc and replace it with a prosthesis called a “spine<br />
cage.” Because the cage is supposed to create a bony<br />
connection between the neighboring vertebrae, it has<br />
a central cavity that can be filled with calcium phosphate<br />
or the patient’s own bone material. Anatomically<br />
shaped, it also has a toothed surface for high<br />
“primary stability”—the stability achieved solely<br />
through the clamping effect of the implant in the<br />
bones.<br />
While cage implants are machined from a higher<br />
volume, off-the-shelf design, cranial implants have<br />
moved to a more custom design for each patient. They<br />
are used in patients with extensive skull defects to<br />
protect the delicate brain—whether it is a congenital<br />
malformation or the result of an accident or sickness.<br />
To this end, a 3D X-ray scan is used to reconstruct<br />
the exact three-dimensional anatomy of the surface<br />
of the skull on a computer. The implant is then<br />
adapted to this form and produced from a block of<br />
PEEK using CNC milling technology.<br />
A protective shield<br />
for the skull<br />
Compared to the long-established implant materials<br />
titanium and cobalt-chromium, PEEK offers a variety<br />
of advantages in orthopedics. The plastic scores<br />
points in terms of ductility, elongation at break, and<br />
fatigue resistance—blows or shocks to the implant are<br />
effectively absorbed. From a patient perspective they<br />
appreciate the extremely low thermal conductivity:<br />
Cranial plates made of titanium, which have excellent<br />
heat conductivity, can cause pain when temperatures<br />
fluctuate dramatically in the environment around<br />
them—for example, when the patient leaves a wellheated<br />
house to go outdoors in winter.<br />
VESTAKEEP® is also X-ray transparent and therefore<br />
invisible in computer tomography and magnetic<br />
resonance imaging, which allows easy monitoring of<br />
bone growth and structure during the healing process.<br />
Titanium and cobalt-chromium, on the other<br />
hand, are opaque to X-rays and generate artifacts that<br />
make it difficult to analyze the image.<br />
There are sometimes cases in which the physician<br />
wants to see the implant—he may, for example, check<br />
Spine cage made of veStAKeeP® PeeK as a placeholder<br />
for the space between the vertebrae, which recreates<br />
the natural height of the intervertebral disc segment<br />
As an added service, evonik also offers customers<br />
CAe (computer-aided engineering). these<br />
simulations provide information on how much<br />
stress an implant receives and how it should<br />
be constructed<br />
X-ray image of 2-mm-thick veStAKeeP® platelets<br />
that were layered in stacks of varying heights.<br />
the absorption of the X-ray light increases as the<br />
thickness of the layers increases (from bottom<br />
to top). At the same time, it is possible to control<br />
the absorption by varying the content of the<br />
barium sulfate
In permanent bending tests, veStAKeeP® holds up three times<br />
as long as a comparable competing PeeK product<br />
veStAKeeP® Ultimate Standard PeeK polymer<br />
Bending force [n]<br />
30<br />
25<br />
20<br />
15<br />
10<br />
5<br />
0<br />
0 100,000 200,000 300,000 400,000<br />
Cycles<br />
On the computer, 3D X-ray scans are used to<br />
reconstruct the exact three-dimensional anatomy<br />
of the skull. this is done for the purpose of<br />
manufacturing skull implants, where the implant is<br />
adapted to this form. CnC milling technology is<br />
used to make the implant from one block of PeeK<br />
Visible thanks to<br />
barium sulfate<br />
MedICAL teCHnoLoGY<br />
the primary stability of a spine cage to make sure it<br />
is properly seated, and whether the bones are actually<br />
growing through it. This is why tantalum pins are<br />
used in PEEK cages to make the implant visible. However,<br />
incorporating the pins is a pretty tedious, laborintensive<br />
post-processing step because they have to<br />
be seated perfectly flush—the cavities around the pins<br />
could cause problems during cleaning and sterilization.<br />
For such cases, <strong>Evonik</strong> has developed a new<br />
VESTAKEEP® PEEK variant that contains barium sulfate.<br />
The idea comes from diagnostic radiology: Physicians<br />
give patients a suspension made of barium<br />
sulfate to display the esophagus, stomach and small<br />
and large intestines, as well as mobility disorders of<br />
these organs, in a CT image. Decades of experience<br />
have proven the safety of using barium sulfate.<br />
Studies by <strong>Evonik</strong> have shown that a content of<br />
less than ten percent barium sulfate is enough to make<br />
the implant visible on an X-ray, without generating<br />
the kinds of disruptive artifacts caused by metals.<br />
While the quality of the X-ray depends on a number<br />
of factors—such as the strength of the X-ray radiation<br />
and geometry, and the wall thickness of the implant—<br />
a filling level of six percent barium sulfate is wellsuited<br />
to a majority of applications. For example, a<br />
spine cage can be portrayed clearly in an X-ray image,<br />
and at the same time allows the monitoring of<br />
bone growth in the cavity.<br />
Osteointegration—the healing process in the bones<br />
in which the bone cells graft to the implant and implant<br />
surface, which normally takes about six to<br />
twelve months—is essential for a stable fit for an implant<br />
in the spinal column. The factors that influence<br />
osteointegration are the individual properties of the<br />
bone, the construction of the implant, and its surface<br />
condition. With regard to the latter, titanium is<br />
superior to PEEK, because the metal surface shows<br />
improved grafting behavior, and the bone substance<br />
anchors faster to the metal. Consequently, the 333<br />
Coating should accelerate<br />
bone growth<br />
31<br />
elements39 Issue 2|2012
32 MedICAL teCHnoLoGY<br />
InteRVIeW<br />
“Material artifacts diminish the image quality”<br />
Dr. Markus Braun has two jobs: He is attending physician at<br />
the Klinikum Westfalen in Dortmund and team doctor at<br />
Borussia Dortmund football club. A specialist in sports medicine,<br />
Braun knows a great deal—about premature signs of<br />
exhaustion, fast healing processes, and the question of the<br />
right implant material.<br />
You’ll be standing on the sidelines again next weekend,<br />
Dr. Braun: As a fan or a concerned physician?<br />
Braun: All of the above! My first responsibility is as a physician,<br />
but you automatically become a fan. When you spend<br />
that much time with the players, you develop a personal<br />
relationship beyond the normal doctor-patient relationship.<br />
How much time do you actually spend with the players?<br />
Braun: In any given week I spend a couple of hours on<br />
the training ground almost every evening. And I go to<br />
every game on the weekend. This time we go to Berlin:<br />
We’ll be traveling from Friday afternoon to Saturday<br />
evening. Then, it’s right back to training Sunday morning.<br />
Editor’s note: Dr. Braun also had his work cut out for him<br />
this weekend. In the win over Hertha BSC, Lukasz Piszczek<br />
suffered a concussion and contusion of the skull when<br />
he collided with another player.<br />
everyone knows that professional athletes are especially<br />
prone to injury. what long-term impact does this kind<br />
of permanent stress have on the body?<br />
Braun: Signs of exhaustion are often the first to appear.<br />
By age 40 or 45, osteoarthritis is not unusual. Top athletes<br />
are also frequent candidates for implants.<br />
what criteria are crucial to the optimal implant?<br />
Braun: Naturally, it would be best to completely forego<br />
the use of foreign material. This is not always possible,<br />
however. When foreign material has to be used, the material<br />
properties are crucial: Biocompatibility is the first<br />
consideration. Of course, the material must be as durable<br />
as possible to prevent the need for a second operation.<br />
Wear resistance and the right amount of elasticity are<br />
crucial to stability. If these properties are not what they<br />
should be, the implant can cause problems later.<br />
elements39 Issue 2|2012<br />
what materials do you work with?<br />
Braun: There is a trend in medicine toward minimally<br />
invasive surgery and away from large-scale operations.<br />
Minimally invasive surgery makes only small incisions and<br />
is controlled by imaging methods such as CT or MRT. In<br />
the case of CT, small steel needles are used, and in MRT,<br />
amagnetic materials such as carbon fibers or titanium.<br />
Many materials are well known to generate artifacts on<br />
the screen. How do you handle that?<br />
Braun: Artifacts on the image are a disaster! For me, they<br />
are a real problem, particularly with the equipment.<br />
Braun shows a CT scan from a spinal column cementing procedure.<br />
The area around the bone punch cannula is obscured<br />
by the white of the artifacts. Without this buildup of artifacts,<br />
I could work with greater precision.<br />
the material PeeK doesn’t leave artifacts.<br />
Braun: That is, in fact, an interesting feature of my work.<br />
To get that kind of information, I usually have to do my own<br />
research or trust the claims of the implant manufacturers.<br />
Right now, there is no direct exchange between doctors and<br />
material manufacturers. And these are the experts who<br />
ultimately have to convert my requirements into concrete<br />
technical data.
dr. Markus Braun, 45, is a trained medical specialist in orthopedics, and has<br />
worked as the team doctor for first-division German soccer team Borussia Dortmund<br />
since 2003. Previously, he spent five years as the team doctor for Rot-Weiß<br />
Essen. In his full-time career, Braun has held various positions at clinics in Duisburg,<br />
Essen, and Bochum. Since mid-2011, he has worked as attending physician<br />
at the newly established sports medicine department at Klinikum Westfalen<br />
(Dortmund). His specialty is minimally invasive surgery using imaging methods.<br />
You are an expert in healing processes. It’s incredible sometimes<br />
how fast professional soccer players recover even from<br />
serious injuries: what’s the magic behind that?<br />
Braun: (laughs) No magic! Essentially, there are three simple<br />
reasons for that: First, the patients are young and in top<br />
condition. This is why the body responds well to treatments<br />
and therapies. Second, the players have access to their own<br />
physical therapists, who create an optimal environment<br />
that allows the natural healing processes to run their course<br />
without interference. And third: The players go to rehab<br />
far more for the optimal stimulation therapy under the<br />
direction of skilled rehab trainers.<br />
who decides whether a player is fit enough to play again?<br />
Braun: That’s an interdisciplinary decision between the<br />
physical therapists, rehab trainers, and the doctor. To some<br />
extent, the player is responsible. Everyone tries for the<br />
fastest possible recovery time.<br />
Do you ever just have to say “no”?<br />
Braun: That happens sometimes. The players always want<br />
to get back on the field by the next game. At that moment,<br />
they’re just highly motivated employees. We doctors have<br />
to act as a brake if the risk to their health is too great.<br />
MedICAL teCHnoLoGY<br />
333<br />
spinal segment that received the implant stabilizes<br />
more quickly and is also able to take stress faster.<br />
On the other hand, with an E-modulus of 3.3 Gigapascal<br />
the elasticity of PEEK roughly corresponds to<br />
that of a bone. This allows an optimal transmission of<br />
force between the implant material and the natural<br />
bone, which can in turn have a positive effect on bone<br />
healing.<br />
Both advantages can be combined by coating the<br />
PEEK implant, which improves the grafting behavior<br />
of bone cells on PEEK. Common coating materials are<br />
hydroxylapatite, calcium phosphate, titanium, or a<br />
special nano-coating. Depending on the material, they<br />
are applied by vacuum plasma spraying, chemical<br />
treatment, or physical vapor deposition.<br />
<strong>Evonik</strong> is currently working on a number of formulas<br />
in cooperation with various companies that<br />
specialize in coating medical products. The current<br />
results are quite promising, as tests by an independent<br />
accredited testing laboratory show: VESTA-<br />
KEEP® PEEK substrates, for example, demonstrate<br />
exceptionally high tensile and shear strength—the<br />
coatings adhere extremely well—and meet the requirements<br />
of the FDA on these points.<br />
The potential of PEEK polymers, however, is far<br />
from being exhausted. To increase the rigidity of the<br />
material even further, <strong>Evonik</strong> is working on a variant<br />
strengthened with carbon fibers (CF). Potential<br />
applications are plates and screws in the trauma<br />
segment used by surgeons to stabilize broken or<br />
fractured bones. The advantage lies in the fact that<br />
patients receive a metal-free solution, which helps<br />
those with allergic reactions to metal ions. Patients<br />
can also undergo MRI examinations later on, which<br />
is not possible with metal implants. Beyond this,<br />
<strong>Evonik</strong> has even more development plans for promoting<br />
the use of VESTAKEEP® PEEK as a metal substitute<br />
in the body and more reports will follow as<br />
VESTAKEEP® accomplishes these technologies. 777<br />
Marc Knebel is Business<br />
Manager of VESTAKEEP®<br />
Medical in <strong>Evonik</strong>’s High<br />
Performance Polymers<br />
Business Line.<br />
+49 2365 49-6783,<br />
marc.knebel@evonik.com<br />
33<br />
elements39 Issue 2|2012
34 neWs<br />
Lightweight design<br />
solutions for China<br />
automotive industry<br />
The all-new electric car prototype was in the<br />
spotlight at the Shanghai International Industry<br />
Fair on Shanghai Motor’s booth, underscoring<br />
the benefits of lightweight design solutions<br />
from <strong>Evonik</strong> <strong>Industries</strong>. The new-energy<br />
vehicle is powered by a lithium-ion bat tery.<br />
The car uses several lightweight materials<br />
from <strong>Evonik</strong> for various applications to support<br />
reduced energy consumption and lower<br />
emissions, such as PLEXIGLAS® material for<br />
the side screens, rear window, and rear lamp,<br />
as well as ROHACELL® rigid core material<br />
and an epoxy resin formulation based on<br />
VESTA MIN® hardener technology for the<br />
engine hood. “We are proud to have played<br />
a part in providing Shanghai Motor’s first<br />
electric car with our lightweight and environmentally<br />
progressive plastic solutions,” said<br />
Xu Hang, Project Head of Lightweight Design<br />
in China.<br />
elements39 Issue 2|2012<br />
The use of <strong>Evonik</strong>’s PLEXIGLAS®—a coated<br />
PMMA to replace traditional mineral glass—<br />
in the demo car reduces the weight of the<br />
fixed side screens up to 40–50 percent. It also<br />
helps to reduce energy consumption and CO 2<br />
emissions. The advantages of PLEXIGLAS®<br />
glazing include UV stability and good acoustic<br />
properties, which means added value for the<br />
vehicle as a whole. In addition, the car designer<br />
can achieve more design freedom with<br />
this material and gain sophisticated curve<br />
structure which is not feasible by using traditional<br />
mineral glass. The special grade of<br />
PLEXIGLAS® material is also applied at the<br />
rear lamps to achieve a special light diffusing<br />
effect.<br />
The engine hood uses the structural foam<br />
ROHACELL® developed by <strong>Evonik</strong>. This ma -<br />
terial is used as core in sandwich structures.<br />
Compared to a steel engine hood, the sandwich<br />
version reduces weight by up to 70 percent.<br />
Due to the outstanding heat resistance<br />
and remarkable mechanical strength of<br />
ROHACELL® material, it can shorten curing<br />
cycles at elevated temperatures above 130 °C<br />
and offers a cost-efficient production.<br />
Because of its high mechanical strength at<br />
low densities, even small thicknesses of<br />
ROHACELL® enable the construction of lightweight<br />
body parts with extreme stiffness.<br />
To support high output production of<br />
composite body parts, a new epoxy resin formulation<br />
based on VESTA MIN® hardener<br />
technology was used in the resin infusion<br />
manufacturing process. Short cycle times can<br />
be realized to allow mass production.<br />
Shanghai Motor’s first electric car<br />
the first-ever electrical sports car with a weight below 1,000 kg<br />
The performance data of the lightweight<br />
electrical sports car Elise-E that <strong>Evonik</strong><br />
<strong>Industries</strong> presented at the Car Symposium<br />
in Bochum are impressive: The vehicle<br />
weighs 950 kg, has a power of 150 kW, accelerates<br />
from 0 to 100 km/h in 4.4 seconds.<br />
The top speed is limited to 200 km/h. The<br />
purpose of exhibiting the vehicle was to show<br />
the automotive industry what can be achieved<br />
with <strong>Evonik</strong>’s expertise in chemicals.<br />
Thanks to the combined use of innovative<br />
storage technology, lightweight components,<br />
and tires with reduced rolling resistance, the<br />
sports car is the first-ever model to weigh less<br />
than 1,000 kilograms. With the exhibit,<br />
<strong>Evonik</strong> is demonstrating that electrical cars,<br />
which are currently used primarily as city vehicles,<br />
can also be part of the sports car segment.<br />
The vehicle is a combination of automotive<br />
components made with the specialty<br />
chemical components of <strong>Evonik</strong> and the<br />
sophisticated automotive technology of the<br />
British sports car manufacturer Lotus. The<br />
necessary power comes from a lithium-ion<br />
battery with the globally unique CERIO®<br />
storage technology. At the core of this battery<br />
is the ceramic high-performance separator<br />
SEPARION®, which is extremely thin and<br />
highly heat-resistant. It separates the anode<br />
reliably from the cathode and sets new standards<br />
for lithium-ion cells in terms of cycle<br />
stability, performance output, and safety by<br />
using additional components. In addition, the<br />
separator allows for the highly compact<br />
design of the battery cells, which results in<br />
high energy density at a low weight.<br />
The weight of the electrical sports car’s<br />
body has also been reduced with <strong>Evonik</strong> tech-<br />
the lightweight electrical<br />
sports car elise-e
nologies. The sandwich structure with the<br />
structural foam ROHACELL® and carbon<br />
fibers makes the body 60–70 percent lighter<br />
than a comparable steel structure. <strong>Evonik</strong><br />
applied a new resin infusion process with an<br />
innovative epoxy resin formula based on the<br />
VESTAMIN® hardener technology to manufacture<br />
it. This process allows for class-A sur-<br />
veStAMID® Htplus in mass-produced gearshift levers<br />
The high-performance polymer VESTAMID®<br />
HTplus is making gearshift levers lighter.<br />
A leading automotive OEM in Europe is now<br />
using <strong>Evonik</strong> polyphthalamides (PPA) in the<br />
serial production of a gearshift lever part. The<br />
Turkish company Eurotec AS has compounded<br />
the high-performance polymer specifically<br />
for this purpose.<br />
“Our decision in favor of VESTAMID®<br />
HTplus M1000 was based on the good processing<br />
characteristics and the outstanding<br />
mechanical properties of the material,” says<br />
Reha Gür, commercial director at Eurotec.<br />
“This allowed us to offer the OEM a customized<br />
product based on their future expectations<br />
that not only weighs less, but is also<br />
more economical than a previous solution and<br />
bringing fast production possibilities with<br />
environmentally friendly behavior.”<br />
The original gearshift lever component<br />
had been made of metal. Because of the special<br />
property profile of PPA, Eurotec<br />
switched its production to the high-performance<br />
polymer. Other arguments in favor<br />
of using PPA included high resistance to<br />
faces and reliable quality in the serial manufacture<br />
of composite automotive body parts.<br />
Side windows made of PLEXIGLAS® also<br />
contributed to the weight reduction, as they<br />
have a weight-saving potential of 40–50 percent<br />
compared to conventional mineral glass.<br />
Vehicles with less weight and high power<br />
have to be safe and sustainable on the road.<br />
lubricants and oils that are typically present<br />
in clutch systems.<br />
In addition to high chemical resistance,<br />
molded parts made from VESTAMID® HTplus<br />
offer high dimensional stability and excellent<br />
mechanical properties such as rigidity and<br />
tensile strength. The high-performance polymer<br />
is therefore ideally suited for use in conventional<br />
metal applications.<br />
High-performance plastics: Certified bio-based<br />
The VESTAMID® Terra family of polyamides<br />
from <strong>Evonik</strong> <strong>Industries</strong> has been certified as<br />
“bio-based” by independent institutes. The<br />
bio-based components have been certified<br />
according to DIN ISO 10694, 1996-08, and<br />
by the USDA’s Biopreferred® program. These<br />
official laboratories used C14 trace carbon<br />
analytics to verify that the carbon in these<br />
prod ucts originates not from petroleum, but<br />
biomass instead.<br />
The polymers are partially or entirely<br />
based on renewable feedstocks. The starting<br />
material is the castor bean (Ricinus communis)<br />
and its oil derivates, which are synthesized<br />
into monomers that form the basis of the<br />
polyamides. At present, three Terra products<br />
are available: VESTAMID® Terra HS is based<br />
on polyamide 610, which is the polycondensation<br />
product of 1,6-hexamethylene diamine<br />
(H) and 1,10-decanedoic diacid (sebacic acid<br />
– S). Sebacic acid is derived from castor oil,<br />
making Terra HS a 63 percent bio-content<br />
polymer. VESTAMID® Terra DS is based on<br />
polyamide 1010, which is the polycondensation<br />
product of 1,10-decamethylene diamine<br />
(D) and 1,10-decanedoic diacid. Both decamethylene<br />
diamine and sebacic acid are<br />
derived from castor oil, making Terra DS a 100<br />
percent bio-content polymer. The 45 percent<br />
bio-content polymer VESTAMID® Terra DD<br />
neWs<br />
In this fast-running electrical vehicle, this is<br />
ensured by special lightweight tires, which<br />
were developed with high-performance<br />
Silica ULTRASIL® and the silane Si 363® manufactured<br />
by <strong>Evonik</strong>. They reduce the rolling<br />
resistance of the tires by approx. 20 percent,<br />
leading to energy savings of about five percent.<br />
veStAMID® Htplus makes<br />
the gearshift lever component<br />
resistant to lubricants<br />
is based on polyamide 1012, which is the<br />
polycondensation product of 1,10-decamethylene<br />
diamine (D) and 1,12-dodecanedoic<br />
diacid (D).<br />
“The bio-based polyamides prove that<br />
outstanding performance and responsible<br />
sourc ing are not mutually exclusive,” says Benjamin<br />
Brehmer, business manager for biopolymers.<br />
“We impart precisely those properties<br />
to our materials which the market expects<br />
from high-performance plastics.” Thanks to<br />
their excellent chemical resistance, low water<br />
absorption, and good dimensional stability,<br />
the polyamides are suitable for a vast number<br />
of applications and processing techniques.<br />
35<br />
elements39 Issue 2|2012
36 InnoVAtIon MAnAGeMent<br />
elements39 Issue 2|2012<br />
Identifying and<br />
developing new<br />
markets<br />
In the Coatings & Additives<br />
Business Unit, the New<br />
Business Development<br />
Functional Unit generates<br />
additional, sustainable<br />
business beyond the<br />
existing business areas.
Left: One rapidly<br />
growing market that<br />
Coatings & Additives<br />
is working on in the<br />
new Business Development<br />
Functional Unit is<br />
additive manufacturing.<br />
this allows the layered<br />
construction of complex<br />
3D structures and components<br />
that are not<br />
possible or prohibitively<br />
expensive to produce<br />
by other methods<br />
right: How can we<br />
permanently protect<br />
the touch screens of<br />
tablet PCs and smartphones<br />
against unsightly<br />
scratches or fingerprints?<br />
How do we<br />
achieve a refined surface<br />
reflection that also<br />
allows the screen to<br />
be read easily? In the<br />
new Business Development<br />
Functional Unit<br />
of the Coatings & Additives<br />
Business Unit,<br />
evonik looks for innovative<br />
answers<br />
theRe Was a time when innovation was driven purely<br />
by technology. In those days, advancements in the<br />
broad R&D subject areas had a direct impact on a<br />
company’s business activities. Today, this putative<br />
causal chain from technological innovation to entrepreneurial<br />
success is not exactly broken, but it has<br />
become increasingly difficult for companies to continue<br />
growing in established markets based on individual<br />
technological innovations or an inventor’s flash<br />
of genius. “Now, innovations are often created by developers<br />
splicing together existing technologies, and<br />
thus offering new applications to satisfy market demands<br />
that have existed for a relatively short time,”<br />
says Dr. Stephan Fengler, Vice President of the New<br />
Business Development Functional Unit in the Coatings<br />
& Additives Business Unit at <strong>Evonik</strong> <strong>Industries</strong>.<br />
Such products as electronic devices with touchsensitive<br />
screens have created new needs that can be<br />
met by coatings. Before Apple’s iPhone became a<br />
smashing success, such devices existed only in certain<br />
niche markets. A growing number of users regularly<br />
use their smartphone now to send e-mail, manage<br />
appointments, shop online, and download apps,<br />
so scratches, reflections, and fingerprints on touch<br />
screens are unwelcome on an application associated<br />
in this way with design and lifestyle. Since it is a common<br />
problem, producers of smartphones and tablet<br />
PCs have suddenly become interested in finding an<br />
inexpensive, functional coating for the glossy displays.<br />
InnoVAtIon MAnAGeMent<br />
The example of the touch screen reveals how embedded<br />
future innovations can be: Innovations outside<br />
the core activities of Coatings & Additives that could<br />
mean real additional business for <strong>Evonik</strong>. Identifying<br />
and promoting this growth potential is the work of<br />
New Business Development, which is headed by Fengler<br />
and located in Darmstadt and Marl. “We explore<br />
what kinds of needs new technologies are creating<br />
on the market.”<br />
So the task of New Business Development, in association<br />
with the business unit’s Innovation Management<br />
unit, is not to figure out how to generate<br />
additional sales with individual products from the<br />
business lines, but to adopt a mindset that goes beyond<br />
business lines and is firmly rooted in innovation.<br />
New technologies<br />
generate new needs<br />
Naturally, this kind of approach succeeds only if it is<br />
designed for the intermediate to long term. “It calls<br />
for new partnerships, new partners,” says Fengler.<br />
“And this is why it’s so hard to reconcile with day-today<br />
business.”<br />
The New Business Development Functional Unit<br />
has been a part of Coatings & Additives since 2006.<br />
Over that time, its team has grown. But it has no laboratory<br />
of its own—instead, it works in close cooperation<br />
with the business lines of the business unit.<br />
The team also stays in close contact with corporate<br />
R&D, which <strong>Evonik</strong> pools in its strategic development<br />
unit Creavis, and with other business units.<br />
“New Business Development also seizes upon ideas<br />
outside the business lines and co-finances projects<br />
that, for example, are designed to run for several<br />
years and take on the kind of risk that a business line<br />
can’t assume by itself,” says Fengler. New Business<br />
Development, then, is by no means a kind of extended<br />
workbench of the business lines. Rather, it is a strategically<br />
important component of Coatings & Additives,<br />
which is investing considerable assets in the<br />
unit. The management team of the business unit manages<br />
its activities.<br />
Coatings & Additives is at home in the world of<br />
the paints, coatings, and printing inks and in the adhesives<br />
and sealing compounds industries. The business<br />
unit also develops custom-made functional polymers<br />
for lubricant applications. These product groups<br />
include crosslinkers such as expoxide resin curing<br />
agents, and crosslinkers for powdered coatings,<br />
333<br />
37<br />
elements39 Issue 2|2012
38 InnoVAtIon MAnAGeMent<br />
when barnacles, mussels, bacteria, and fungi adhere to the hulls of ships, the results<br />
are expensive. Frictional resistance and fuel consumption increase, and the hulls have to<br />
be cleaned and repainted regularly. tin-based biocidal paints are banned, and even<br />
copper-based coatings have some environmental impact. Here, substitutes are being<br />
sought that protect the environment and have an exceptionally long service life<br />
elements39 Issue 2|2012<br />
333 polymer-based coatings, and adhesive agents, as<br />
well as additives for coatings and lubricants. The<br />
employees of Coatings & Additives are active at 21<br />
production sites and technology centers worldwide.<br />
In 2011, the business unit achieved annual sales of<br />
more than €1.7 billion.<br />
For New Business Development, the most attractive<br />
applications in the field of classical coatings are<br />
those that depend on a technology for their third<br />
function, behind color and protection. These func-<br />
New functionalities sought<br />
tions can be self-cleaning or anti-fouling properties,<br />
but also heat-repelling, electrically conductive, or<br />
other properties. Often, they are based on nanostructuring<br />
that, combined with the polymer expertise of<br />
the business unit, produces thin functional layers.<br />
“With functional coatings, the innovation and the<br />
new business activity doesn’t necessarily translate<br />
into large production volumes but into the value generated<br />
by the user,” explains Fengler. This has a number<br />
of advantages that limit the risk of a project. Coatings<br />
in the range of a few nanometers require only<br />
pilot-scale production facilities, so investment costs<br />
remain manageable. “For the business unit, then, this<br />
is a new way of thinking and working,” says Fengler.<br />
In the field of crosslinking technologies, the most<br />
attractive applications are in composites for lightweight<br />
construction.<br />
whether wind turbine, sailboat, or helicopter, the importance<br />
of composites for structural components is growing, because they<br />
combine low weight with high mechanical stability. Coatings &<br />
Additives investigates how the business unit’s expertise can be<br />
used to develop high-performance composites<br />
Nine employees work in the New Business Development<br />
Functional Unit at Coatings & Additives, including<br />
project managers and those involved with<br />
conceptualizing new ideas. These are chemists, physicists,<br />
and business managers, all of whom are communicative<br />
and open to new ideas. “They are team<br />
players, who are able to establish networks across<br />
organizational boundaries,” says Fengler.<br />
Different kinds of employees are sought for a job<br />
in New Business Development, including inventors,<br />
the technically minded, entrepreneurs, project managers,<br />
developers, and marketers. The inventor embodies<br />
high creativity and scientific curiosity. The<br />
technically minded are experts in certain technologies<br />
and possess analytical skills. Willing to take risks,<br />
the entrepreneur contributes skills in networking<br />
and “selling” ideas. The “project manager” type stands<br />
out for leadership qualities and structured thought.<br />
The developer applies technical know-how and persistence.<br />
And finally, the “marketer” type contributes<br />
a broad-based understanding of the markets, as well<br />
as the ability to persuade customers.<br />
These complementary abilities are necessary for<br />
the concrete work of opening up additional business.<br />
“Because vague ideas can’t produce results,” says Fengler.<br />
Even worse, various independent studies have<br />
shown that innovation projects involve a high level<br />
of risk, and, in the end, only a small percentage of<br />
ideas actually reach their goal. But because success<br />
is easier to sell than failure, New Business Development<br />
has to know how to handle this demoralizing<br />
reality. “We acknowledge it when employees take on<br />
risky projects whose outcome is impossible to gauge,”
says Fengler. “And we don’t allow projects to die as<br />
soon as we begin to encounter problems.”<br />
Despite a culture that allows for mistakes, the<br />
projects of New Business Development are subject to<br />
strict project management. As a rule, a steering commit<br />
tee evaluates the progress and detailed plan of a<br />
project each quarter. Scenario projections, which are<br />
continuously updated, are a way to assess the potential<br />
economic benefits of a project.<br />
To generate ideas for new business, New Business<br />
Development uses the full range of tools of innovation<br />
management. “It’s really important to allow the<br />
team to come up with crazy ideas and find inspiration<br />
from outside the company,” says Fengler. External<br />
input can come from consultants, customer workshops,<br />
or student teams that receive tricky problems<br />
to solve from <strong>Evonik</strong> through its networks. Not surprisingly,<br />
this also includes market analyses.<br />
New Business Development is currently exploring<br />
crowdsourcing: The team is using Internet-based networks<br />
of experts to clarify problems that cannot be<br />
solved based on existing know-how. “Oftentimes, this<br />
is a question of how experts assess the potential of a<br />
certain technology for a specific application,” explains<br />
Fengler.<br />
For an idea in New Business Development to become<br />
a project, it must show sufficient business potential.<br />
“We then develop a vision of how to expand<br />
a market, and pour over this repeatedly as time goes<br />
on,” says Fengler. If the project steering committee<br />
approves it, employees first develop a concept and<br />
then follow up with one or more laboratory tests.<br />
New Business Development also involves colleagues<br />
Each new idea is tested<br />
from relevant business lines at this stage, wherever<br />
possible. “Later on, if a business line is interested in<br />
taking on a project in its sphere of responsibility, it<br />
can do so,” explains Fengler. “Otherwise, we manage<br />
the projects all the way to market launch.”<br />
New Business Development is currently managing<br />
about a dozen preliminary projects—projects that are<br />
in the evaluation and conception phase, and in which<br />
colleagues from the operative units of the business<br />
unit are already involved. At the same time, New<br />
Business Development is managing a few projects that<br />
already have significant development resources.<br />
“Some of these,” says Fengler, “will hopefully bear<br />
fruit over the next five to ten years.” 777<br />
InnoVAtIon MAnAGeMent<br />
dr. stephan Fengler heads the New Business<br />
Development Functional Unit in <strong>Evonik</strong>’s Coatings &<br />
Additives Business Unit. After studying chemical<br />
engineering at the Mendeleyev University of Chemical<br />
Technology of Russia and earning his doctorate at the<br />
Technical University of Berlin in the Department of<br />
Polyme ri zation Technology, he began his career at<br />
Röhm GmbH in Darmstadt in 1995. Fengler held several<br />
positions in the Research, Production, and Marketing<br />
unit before assuming his current duties in 2011.<br />
+49 6151 18-4974, stephan.fengler@evonik.com<br />
39<br />
elements39 Issue 2|2012
40 desIGnInG WItH PoLYMeRs<br />
elements39 Issue 2|2012<br />
The world’s museums house priceless works of art.<br />
New PLEXIGLAS® Optical HC put these exhibits in the<br />
best possible light, permanently protecting them from<br />
damage and depreciation.<br />
YeaR afteR YeaR, millions of people flock to museums to marvel<br />
at the artifacts of past cultures or the works of contemporary<br />
artists: Drawings and paintings, sculptures and documents,<br />
historical garments, consumer items, and weapons. Few of these<br />
visitors are aware, though, that the professional protection<br />
of the exhibits is just as vital as their presentation. Indeed,<br />
<strong>Evonik</strong> is making a major contribution here. The company’s new<br />
PLEXIGLAS® Optical HC, with its abrasion-resistant coating,<br />
protects priceless exhibits against mechanical or chemical damage,<br />
prevents them from yellowing, presents them without any<br />
color distortion, and makes it possible to individually design display<br />
cabinets, boxes, protective panels, and transport packaging.<br />
One of the greatest challenges in exhibiting paintings, documents,<br />
and art treasures is in achieving the optimal lighting. Ideally,<br />
structures, colors, and details should be seen undistorted,<br />
but the UV radiation in natural light often damages historical<br />
material. This causes sketches, watercolors, and garments to lose<br />
their original colors, pages of books to turn yellow and thin out,<br />
and canvases and other materials to become brittle.<br />
no color distortion<br />
Protective measures<br />
for treasures<br />
This is why PLEXIGLAS® contains an integrated chemical UV<br />
filter that filters out damaging high-energy radiation. At the same<br />
time the material, with a transmission of 92 percent, is highly<br />
transparent in the visible region of the spectrum, allowing<br />
a clear and sharp view of the details and the structures of the<br />
exhibits with colors remaining true: The polymer avoids color<br />
distortion such as caused by, for example, the greenish tinge of<br />
float glass.<br />
A large number of archives and museums have already discovered<br />
this amazing plastic for themselves. The U.S. National<br />
Archive transported seminal U.S. historical documents in cus-<br />
tom-made PLEXIGLAS® display cases throughout the country<br />
for a traveling exhibition. The DeBeers Diamond Museum in<br />
Johannesburg, South Africa, displays historical documents in<br />
non-reflecting PLEXIGLAS®. In the Landtag (parliament) of the<br />
German state of Hesse, sketches by the architect Georg Moller<br />
were exhibited behind PLEXIGLAS® to mark the 150th anniversary<br />
of his death. The slight curve of the glazing showed off the<br />
sketches to best advantage.<br />
But transmission and UV absorption are not the only requirements<br />
for the professional protection of museum treasures. Visitors<br />
leave behind their tracks: Fingerprints, sweat, and abrasion<br />
due to zippers or handbags.<br />
This is why the new PLEXIGLAS® Optical HC is equipped<br />
with a special surface coating, ensuring excellent resistance to<br />
mechanical impact and cleaning chemicals. This protects display<br />
cases and picture glazing against distracting chips and scratches,<br />
and the surface quality remains unchanged even with heavy<br />
wear. A comparison with uncoated acrylic shows that the coating<br />
increases abrasion resistance by a factor of ten, and more<br />
than doubles the hardness.<br />
well protected against chemical attack<br />
Fingerprints and mechanical impact are unavoidable when<br />
visitors come close to exhibits. Targeted chemical attacks on<br />
artworks are risks of an entirely different dimension—but<br />
PLEXIGLAS® Optical HC offers effective protection even against<br />
these. Thanks to its surface coating, the material is resistant not<br />
only to abrasion but also to chemicals. This makes it easier for<br />
galleries and museums to meet their generally very stringent<br />
security requirements.<br />
But protecting artworks does not begin in the museum or<br />
gallery. The art market is booming, and touring exhibitions give
At an exhibition in Darmstadt, the gallery owner opted for<br />
PLeXIGLAS® Optical HC picture glazing to allow visitors<br />
to view the pictures without color distortion (above).<br />
For an exhibition of American historical documents that was<br />
toured through the country, the U.S. national Archive<br />
chose PLeXIGLAS® display cases because they offer protection<br />
and are highly transparent and lightweight (below)<br />
art lovers access to unique treasures almost all over the world.<br />
Light, yet break-resistant packaging is needed to transport them.<br />
Conventional float glass is heavy and breaks easily. Acrylic has<br />
a break resistance that is higher by a factor of eleven, and is only<br />
half as heavy. This offers key advantages for transport, and also<br />
in the presentation of large and heavy exhibits.<br />
PLEXIGLAS® Optical HC can be produced in thicknesses<br />
of 1.5 to 16 millimeters, with variants individually adapted to<br />
customers’ wishes: Panels, for example, may be transparent or<br />
colored, and surfaces matted or antiglare. The material is<br />
desIGnInG WItH PoLYMeRs<br />
produced under clean-room conditions at a new combined<br />
extrusion and coating line at the Weiterstadt site, which came<br />
on-stream last year. Extruded PLEXIGLAS® panels are finished<br />
here with a specially developed coating that provides an<br />
abrasion- and chemical-resistant surface, with process, substrate,<br />
and coating being optimally coordinated.<br />
Great design freedom<br />
Lastly, the material offers customers and artists vast freedom of<br />
design: The material can be cut, drilled, sawed, rolled, scored<br />
and broken, laser processed, and digitally printed. This allows it<br />
to be used for shapes and artworks that cannot be realized in<br />
glass. Individual panels can be glued together. An adhesive<br />
developed especially for this purpose creates by chemical reaction<br />
a high-strength and virtually invisible bond. Moreover,<br />
PLEXIGLAS® Optical HC can be processed like standard<br />
PLEXIGLAS®. However, line bending and thermoforming are not<br />
suitable for machining abrasion-resistant coated PLEXIGLAS®<br />
Optical HC because these processes could lead to damage or detachment<br />
of the coating. The uncoated side of the panel, like<br />
extruded acrylic, forms a strong and reliable adhesive bond.<br />
Its excellent mechanical and optical properties coupled with<br />
easy processability make abrasion-resistant PLEXIGLAS®<br />
Optical HC of interest for a wide range of applications. In addition<br />
to the exhibiting and transporting of artworks, it is used in<br />
electronic displays, signage, furniture making, shopfitting, and<br />
exhibition booth construction, as well as for industrial glazing,<br />
for example to protect high-value machines and systems, and for<br />
sectional doors. To put it briefly, PLEXIGLAS® Optical HC promises<br />
the optimal solution for all applications calling for the transparency<br />
and durability of glass combined with the lightness and<br />
break resistance of a plastic. 777<br />
41<br />
elements39 Issue 2|2012
42 neWs<br />
Student project presented in Marl<br />
A group of students from the Technical University<br />
Dortmund has created plans for a production<br />
plant for highly pure 1-butene at<br />
Marl Chemical Park. The students received<br />
support for their project assignment from<br />
<strong>Evonik</strong>’s Advanced Intermediates Business<br />
Unit’s Innovation Management.<br />
Students taking the course in bio and<br />
chemical engineering at the TU Dortmund<br />
are required to take part in a group project<br />
assignment to conceptualize a specialty chemicals<br />
plant. They have only six weeks to complete<br />
their assignment, which entails composing<br />
the process-related design and defining<br />
the dimensions of a facility, with its columns,<br />
reactors, receptacles, heat exchangers, pumps,<br />
and compressors, as well as devising layouts,<br />
optimizing energy utilization at their facility,<br />
and doing the cost and economic-feasibility<br />
accounting.<br />
It has become something of a tradition for<br />
the Innovation Management team at the<br />
elements39 Issue 2|2012<br />
Jason Chan (second<br />
from left), head of the<br />
raffinate facility,<br />
detailed Performance<br />
Intermediate’s integrated<br />
C4 operations<br />
Advanced Intermediates Business Unit to put<br />
forward its proposal for the project to the<br />
university’s Technical Chemistry Chair, Prof.<br />
Arno Behr. This involvement adds to the practical<br />
character of the assignment, while it also<br />
serves as a proverbial bridge between academia<br />
and industry. What’s more, the collaboration<br />
allows the students to subsequently<br />
make the comparison between their finished<br />
theoretical concept, as devised on the<br />
basis of information available to them from<br />
literary sources, with actual facilities operating<br />
in practice at Marl Chemical Park.<br />
In 2011 the Innovation Management<br />
team’s project proposal was for the conceptualization<br />
of a facility for the manufacture of<br />
highly pure 1-butene. The Performance Intermediates<br />
Business Line runs an integrated C4<br />
facility at the Marl site. Aside from butadienes,<br />
MTBE, isononanol, and diisononyl<br />
phthalate (DINP), a plasticizer, this, the only<br />
plant of its kind anywhere in the world, also<br />
More than 400 offshore pipes with veStAMID® nrG<br />
VESTAMID® NRG 1001, a high-performance<br />
polymer, can already be found in a total of<br />
over 800 kilometers of pipeline. The polyamide<br />
12 made by <strong>Evonik</strong> <strong>Industries</strong> has gone<br />
into the making of more than 400 unbonded<br />
flexible pipes to service the oil production<br />
industry. Oil companies have been using<br />
these pipes in their offshore projects for<br />
years now.<br />
What has made the polyamide 12 molding<br />
compound so popular are its superior properties<br />
over those of other polyamides used as<br />
barrier layers in flexible pipes. Together with<br />
Wellstream International Limited, <strong>Evonik</strong><br />
conducted intensive testing to demonstrate<br />
compliance with the international norms API<br />
17J for flexible risers and ISO 13628-2. The<br />
tests praised the creep performance, ductility,<br />
thermal expansion, methanol compatibility,<br />
and hydrolysis resistance.<br />
The molding compound has since been used<br />
commercially for the manufacture of flexible<br />
pipes. Specially developed VESTAMID® NRG<br />
combines its technical advantages with<br />
extraordinarily consistent product quality,<br />
which ensures outstanding processability and<br />
thus reduces setup times, scrap, and the risk<br />
of extrusion faults.<br />
For decades now, <strong>Evonik</strong> has been a<br />
leader in the development and marketing of<br />
high-grade polyamide compounds for line<br />
systems in motor vehicles. This high degree<br />
of expertise in the development of extrusion<br />
compounds has now been carried over to<br />
molding compounds for the thick-walled piping<br />
systems which, thanks to their advantages<br />
over existing systems, are increasingly<br />
coming into use in the oil and gas industries.<br />
Flexible: Offshore pipes<br />
with veStAMID® nrG<br />
makes 1-butene. 1-butene is a key comonomer<br />
used predominantly to make high-grade<br />
polyethylene and poly-1-butene.<br />
The students executed their group assignment<br />
in the 2011/2012 winter semester. They<br />
then visited Marl Chemical Park for a guided<br />
tour by Jason Chan, head of the raffinate facility,<br />
who detailed the integrated C4 operations<br />
to them. This group of aspiring young<br />
academics proved to be particularly fascinated<br />
by the two 80- meter-high columns at the<br />
heart of 1-butene production.<br />
The group was then invited to present its<br />
own concept to an audience comprising staff<br />
members from the business unit’s Production,<br />
Engineering, and Research teams and from<br />
Process Technology and Engineering. The<br />
students impressed this audience with the<br />
sound quality of their completed work. The<br />
discussion which followed addressed the differences<br />
apparent between the students’ concept<br />
and a real facility and also brought forth<br />
a number of tips concerning practical considerations.<br />
The participants all agreed that educational<br />
elements of this kind on the student<br />
curriculum help to make studies more practice-oriented<br />
as well as providing a platform<br />
for contact between industry and students.<br />
Thus, the scheme sees the Innovation Manage<br />
ment unit making a valuable contribution<br />
to <strong>Evonik</strong>’s em ployer branding endeavors.
Creavis starts with new BISOn project<br />
The Biotechnological Synthesis of Carbo xyamines and Carboxyalcohols<br />
Project, or “BISON” for short, was launched at the end of<br />
last year. Creavis Technologies & Inno va tion’s Science-to-Business<br />
Center (S2B) Bio technology is in charge of the project, the aim of<br />
which is to use biotechnology to modify molecules that could be used<br />
for polymer building blocks or fine chemicals in the future. Creavis<br />
is the strategic research and development unit of <strong>Evonik</strong>.<br />
Both renewable and petroleum-based raw materials are used as<br />
starting materials in the BISON project. Customized microorganisms<br />
then convert and modify these materials to produce the desired end<br />
product. The actual modification of the molecules is done by selective<br />
oxidation and amination–or what is also known as biotransformation.<br />
BISON involves experts from the fields of microbiology, protein<br />
engineering, and process development. Working with the Tech nical<br />
Credits<br />
Publisher<br />
<strong>Evonik</strong> <strong>Industries</strong> AG<br />
Corporate Innovation<br />
Strategy & Management<br />
Rellinghauser Straße 1–11<br />
45128 Essen<br />
Germany<br />
scientific Advisory Board<br />
Dr. Norbert Finke<br />
Corporate Innovation<br />
Strategy & Management<br />
norbert.finke@evonik.com<br />
editor in Chief<br />
Dr. Karin Aßmann<br />
<strong>Evonik</strong> Services GmbH<br />
Editorial Department<br />
karin.assmann@evonik.com<br />
Contribution editors<br />
Christa Friedl<br />
Thomas Lange<br />
Michael Vogel<br />
neWs 43<br />
University of Munich (Germany) and the S2B Center Biotechnology,<br />
the consortium will develop the microbial cell factory for a future<br />
generation of production processes that promise to be more sustainable<br />
than the former process in the chemical in dustry. The German<br />
Federal Ministry of Edu cation and Research (BMBF) is funding the<br />
project, which will run for three years.<br />
This project owes its success to the Car boxyFun project, which did<br />
well and was also funded by the BMBF. In the future, BISON will take<br />
the findings from Car boxyFun and transfer them to other biotechnological<br />
processes so that the microbial cell factory can become reality.<br />
Biotechnological processes are gaining in popularity in the chemical<br />
industry. One of the reasons for this is that the biotech processes<br />
involve lower investment costs than chemical processes. This means,<br />
for example, that multi-level production stages can be mapped in a<br />
single bacterium cell–the microbial cell factory.<br />
Photos<br />
<strong>Evonik</strong> <strong>Industries</strong><br />
Karsten Bootmann<br />
Dirk Bannert<br />
Martin Daniels<br />
Dieter Debo<br />
Stefan Wildhirt<br />
Eurotec (p. 35)<br />
Wellstream (p. 42)<br />
Fotolia.com/Uwe Annas (p. 2, 11)<br />
Corbis/Imaginechina (p. 6)<br />
Fotolia.com/lunamarina (p. 38)<br />
Fotolia.com/mirpic (p. 38)<br />
Fotolia.com/Berni (p. 39)<br />
Fotolia.com/graham tomlin (p. 39)<br />
A glance into a<br />
laboratory of the<br />
Creavis’ Science-<br />
to-Business Center<br />
Biotechnology in<br />
Marl<br />
design<br />
Michael Stahl, Munich (Germany)<br />
Printed by<br />
Laupenmühlen Druck GmbH & Co. KG<br />
Bochum (Germany)<br />
Reproduction only with permission<br />
of the editorial office<br />
<strong>Evonik</strong> <strong>Industries</strong> is a worldwide<br />
manufacturer of PMMA products sold<br />
under the PLEXIGLAS® trademark<br />
on the European, Asian, African, and<br />
Australian continents and under the<br />
ACRYLITE® trademark in the Americas<br />
elements39 Issue 2|2012
Real problems, real answers. The only way to find<br />
quick solutions is by openly addressing uncomfortable<br />
truths. That’s why we make frank and transparent<br />
communication an integral part of cooperation with<br />
our customers. We join together in open dialog<br />
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in a spirit of trust, go to www.evonik.com/pharma.<br />
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but transparent right from the start.<br />
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