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elements39<br />

Quarterly Science newsletter Issue 2|2012<br />

IntervIew<br />

“there’s no success without trust in a working partnership.”<br />

PrOJeCt HOUSe SYSteMS InteGrAtIOn<br />

Product and process go hand in hand<br />

CAtALYSIS<br />

Profiling simplifies scale-up in PMPC production


2 Contents<br />

10<br />

28<br />

36<br />

elements39 Issue 2|2012<br />

CoVeR PHoto<br />

Irina Profir, doctoral candidate at LIKAT, in <strong>Evonik</strong>’s new<br />

laboratory at LIKAT<br />

neWs<br />

4 Test plant for CO 2 separation started up<br />

4 BMBF PeTrA project to simplify administration of biopharmaceuticals<br />

5 Opening of Advanced Project House in Taiwan<br />

6 New university partner in China<br />

6 <strong>Evonik</strong> and LIKAT expand research cooperation in catalysis<br />

InteRVIeW<br />

7 “There’s no success without trust in a working partnership.”<br />

PRoJeCt HoUse sYsteMs InteGRAtIon<br />

10 Product and process go hand in hand<br />

CoMMent<br />

18 Innovations make history<br />

neWs<br />

21 Honorary professorship for Dr. Klaus Engel<br />

21 Sale of the colorants business<br />

22 Groundbreaking ceremony for new organics production facility<br />

22 Biogas upgrading: New plant for hollow fiber membrane modules<br />

23 <strong>Evonik</strong> invests in High-Tech Gründerfonds II<br />

23 Groundbreaking ceremony for new H 2 O 2 plant in China<br />

CAtALYsIs<br />

24 New tool for characterizing catalysts:<br />

Profiling simplifies scale-up in PMPC production<br />

MedICAL teCHnoLoGY<br />

28 Implants made from PEEK ensure new quality in medicine<br />

neWs<br />

34 Lightweight design solutions for China automotive industry<br />

34 The first-ever electrical sports car with a weight below 1,000 kg<br />

35 VESTAMID® HTplus in mass-produced gearshift levers<br />

35 High-performance plastics: Certified bio-based<br />

InnoVAtIon MAnAGeMent<br />

36 Identifying and developing new markets<br />

desIGnInG WItH PoLYMeRs<br />

40 Protective measures for treasures<br />

neWs<br />

42 Student project presented in Marl<br />

42 More than 400 offshore pipes with VESTAMID® NRG<br />

43 Creavis starts with new BISON project<br />

43 Credits


esources<br />

In 2011, <strong>Evonik</strong> generated sales of €1.9 billion with products and applications that<br />

were developed in the last five years—and there will be more to come. Indeed, the<br />

Group’s R&D pipeline is amply filled with and balanced by 450 short-, medium-,<br />

and long-term projects. Last year, the first patent applications placed <strong>Evonik</strong> among<br />

the leaders in specialty chemistry; in 2011, we filed 300 new patents, while our<br />

total number of patents and applications exceeded 24,000.<br />

Our R&D activities are guided by our strategy of concentrating on high-growth<br />

megatrends such as health, nutrition, resource efficiency, and globalization—on<br />

forward-looking markets that create not only financial, but also social value. In other<br />

words, we keep investing in R&D a rich store of resources for the purpose of protecting<br />

our natural resources. And to ensure that this stockpile does not dwindle<br />

away, we increased our R&D expenditures in 2011 to €365 million, or eight percent<br />

more than the previous year.<br />

This is money well spent, as is demonstrated by our Project House Systems Integration,<br />

which is now wrapping up its activities. The employees of the project house<br />

found solutions for plastic glazing for cars, concentrating solar thermal energy,<br />

and for the production of thin fibers for filtration applications. As disparate as these<br />

developments are, they all share the same goals: They advance the development of<br />

sustainable products and processes, in keeping with our strategy, and they make<br />

an important contribution to energy and resource efficiency. Of the nine projects<br />

the project house worked on in its three-year run, seven have already been returned<br />

to the participating business lines, which are now bringing them to market maturity.<br />

These results are also striking for the fact that the project house began its activities<br />

in early 2009 at an ill-omened time: The height of the financial and economic crisis,<br />

when economizing was paramount. <strong>Evonik</strong> cut costs like everyone else, but not in<br />

R&D. We launched the project house as planned.<br />

Another example of our commitment to using our research to save resources can<br />

be found in our Health & Nutrition Business Unit, which is currently expanding<br />

its market activities to aquaculture. Adding our amino acids to fish feed can save<br />

valuable fish meal that would otherwise have to be mixed with the feed as a source<br />

of protein, and which often comes from natural stocks of wild marine animals.<br />

At least three kilograms of captured fish are required to produce one kilogram of<br />

edible fish. Our amino acids also allow fish and crustaceans to digest the feed better,<br />

so that more animals receive optimal nutrition with the same amount of feed. For<br />

this reason, Health & Nutrition has developed new products that are an optimized<br />

methionine source for shrimp and other crustaceans—innovative products designed<br />

to help ensure that fewer wild fish are required for aquaculture. This preserves the<br />

stocks of wild fish, and it counteracts overfishing. These new products are perhaps<br />

only a small but nevertheless effective step toward a future in which we will have<br />

to feed a constantly growing world population. In my view, this future will be worth<br />

living only if we succeed in utilizing food, as a resource, as efficiently as possible.<br />

edItoRIAL 3<br />

Patrik Wohlhauser<br />

Member of the Executive Board<br />

of <strong>Evonik</strong> <strong>Industries</strong> AG<br />

elements39 Issue 2|2012


4 neWs<br />

test plant for CO 2 separation started up<br />

At the foot of the chimney of STEAG’s cogeneration plant in Herne, a ninemeter-high<br />

test plant has been built for evaluating new absorbents. The test<br />

plant, which is supposed to allow researchers to investigate absorbents for<br />

separating CO 2 from industrial and waste gases under real conditions, is part<br />

of the Efficient CO 2 Separation (EffiCO 2 ) Project of Creavis’ Science-to-<br />

Business Center Eco².<br />

<strong>Evonik</strong>’s business units are working together with experts from industry<br />

and science to develop new absorbents that should significantly reduce energy<br />

requirements for CO 2 separation. The aim is to investigate these new<br />

substances both under real conditions and in the laboratory. Over the next<br />

few weeks, the test plant will be tested for this purpose with commercially<br />

available absorption media to obtain a reference process for the new absorbents.<br />

For the investigations which are to occur under real conditions, the power<br />

plant has been built in such a way that part of the flue gas can be taken directly<br />

from the chimney and characterized by online analytics. The entire system<br />

has been made of glass to make it easy to view the process.<br />

Before the CO 2 is separated from the flue gas, interfering flue-gas components<br />

are removed in a scrubber column. Connected to this is the absorption<br />

column, in which the CO 2 contained in the flue gas is absorbed. In a<br />

third unit, the absorption medium is regenerated and pure CO 2 obtained,<br />

which is analyzed and returned to the chimney. The regenerated absorption<br />

medium is reconveyed to the absorption column and a continuous process is<br />

made possible. The EffiCO 2 project is funded by the German Federal Ministry<br />

of Education and Research (BMBF).<br />

A greenhouse gas, CO 2 is considered to be the single-most important<br />

cause of climate change. Global CO 2 emissions in 2010 amounted to more<br />

than 33 gigatons, an increase of about 30 percent over 1990. The energy<br />

sector emits the highest proportion of CO 2 . Because of mounting global<br />

energy requirements, the energy sector will continue in the future to account<br />

for a large share of CO 2 emissions. To meet energy requirements and simultaneously<br />

reduce CO 2 emissions, various CO 2 separation technologies are<br />

being developed and tested worldwide.<br />

BMBF PetrA project<br />

to simplify<br />

administration of<br />

biopharmaceuticals<br />

The goal of the interdisciplinary research project<br />

PeTrA*, which is sponsored by the<br />

German Federal Ministry of Education and<br />

Research (BMBF), is to remove the need for<br />

injections for biopharmaceuticals used for<br />

example in cancer immunotherapy by developing<br />

spray and tablet formulations which<br />

include innovative biofunctional polymers.<br />

The project is designed to simplify the administration<br />

of biopharmaceuticals and to improve<br />

their bioavailability. PeTrA is managed by a<br />

consortium consisting of <strong>Evonik</strong> Indus tries<br />

elements39 Issue 2|2012<br />

the nine-meter-high test<br />

plant for CO 2 separation<br />

AG, Merck KGaA, EMC microcollections<br />

GmbH (a hightech company for peptide and<br />

peptidomimetics synthesis), the Helmholtz<br />

Center for Infection Research (HZI), and the<br />

Fraunhofer Institute for Interfacial Engi neering<br />

and Biotechnology (IGB).<br />

The project, which started on July 1, 2011,<br />

is scheduled to last for three years Ap prox -<br />

imately half of the €6 million budget is supported<br />

by the three industry partners. The<br />

PeTrA consortium also includes the Friedrich<br />

Schiller University in Jena, Saarland University,<br />

the University of Nij megen (Neth erlands),<br />

Bonn University Hospital, the Charité<br />

Hospital Berlin, Kiel University, and Würzburg<br />

Uni versity.<br />

Biopharmaceuticals have been on the<br />

advance for years in modern drug therapy.<br />

They include peptides, proteins and antibodies,<br />

nucleic acids, and blood components, that<br />

all represent a promising basis for new active<br />

principles and for cancer immunotherapy.<br />

Many of these highly successful drugs im -<br />

prove patient life quality and have enormous<br />

technological potential for the pharmaceutical<br />

industry.<br />

Today, biopharmaceuticals are mostly<br />

administered by injection. Indeed, there is no<br />

efficient or broadly applicable system for<br />

administering them via the mouth (oral) or<br />

through the respiratory pathways (inhalation)<br />

because they are not easily absorbed by the<br />

mucous membranes of the gastrointestinal<br />

tract and respiration system, and tend to be<br />

degraded in the stomach before they can<br />

have an effect on the body. The PeTrA project<br />

aims at overcoming these obstacles by<br />

packaging highly sensitive biopharmaceuticals<br />

into nano- and micro-sized particles that<br />

transport the active ingredients through the<br />

mucous membranes and protect them from<br />

degradation in the stomach.


“Tablets and sprays are more convenient for<br />

patients, particularly in long-term therapies<br />

which can require continuous drug intake<br />

over weeks or months,” says Dr. Rosario Lizio<br />

about the motivation of the research partners.<br />

Lizio, the PeTrA project coordinator, is also<br />

the head of the Discovery & Development<br />

department of Pharma Polymers, a product<br />

line of the Health Care Business Line of<br />

<strong>Evonik</strong> specialized in drug delivery systems.<br />

*PeTrA stands for “Platform for efficient epithelial<br />

transport of pharmaceutical applications with inno -<br />

vative particular carrier systems” (<strong>Evonik</strong>-Funding<br />

Ref. No.: 13N11454) and is part of the BMBF grant<br />

project “Efficient drug transport in biological systems—BioMatVital:<br />

Biotransporters.”<br />

Opening of Advanced Project House in taiwan<br />

<strong>Evonik</strong> has opened its Light & Electronics<br />

Advanced Project House (APH) in Taiwan.<br />

The new APH is located in Industrial Technology<br />

Research Institute (ITRI) in Hsinchu,<br />

one of Taiwan’s leading research institutes.<br />

“As the first project house <strong>Evonik</strong> established<br />

outside of Germany, it is quite literally a big<br />

step for <strong>Evonik</strong> in innovation in Greater China<br />

and Asia,” commented Dr. Dahai Yu, member<br />

of the Executive Board responsible for Asia,<br />

at the opening ceremony held in ITRI. “The<br />

opening of the Light & Electronics APH is a<br />

new stepping stone for entering into new<br />

markets and the globalization of R&D.”<br />

“The market is constantly changing. With<br />

the APH in Taiwan, we aim to generate a link<br />

to the growing light and electronics industry<br />

in Asia, and identify and realize new business<br />

opportunities through joint technical developments<br />

and close hands-on interactions with<br />

our customers,” said Patrik Wohlhauser,<br />

Mem ber of the Executive Board responsible<br />

for innovation management.<br />

<strong>Evonik</strong> evaluated the technical and market<br />

success probability of potential project topics<br />

such as lighting, displays, touch panels, photovoltaic,<br />

LEDs, and functional coatings. With<br />

its opening, several projects have been started<br />

up with the company’s business units’ and<br />

business lines’ commitment and support. In<br />

addition, a New Business Develop ment function<br />

will be built up to identify new business<br />

opportunities in the electronics industry. The<br />

start focuses on Taiwan, main land China, and<br />

Korea.<br />

“We’re really glad to see that the construction<br />

of office and labs has been completed<br />

at ITRI even faster than planned. For<br />

us, ITRI is the best place to start, as it provides<br />

good infrastructure and a condensed knowhow<br />

platform, as well as the local network.”<br />

said Dr. Michael Cölle, head of the APH,<br />

neWs<br />

during the opening ceremony. “We’ve built<br />

up a technical team made up of local talents,<br />

and the team will gradually increase according<br />

to the project needs in the future. We<br />

expect to foster customer interaction continuously<br />

and generate new business.”<br />

Located in one of the world’s most important<br />

electronics markets, the APH finds a new<br />

way for <strong>Evonik</strong> to access the market. The<br />

APH is to give rise to a new R&D competence<br />

center for the Group in Asia.<br />

From left to right: Dr. Michael Cölle (Head of<br />

the Advanced Project House Light & electronics),<br />

Dr. Peter nagler (Chief Innovation Officer evonik),<br />

Dr. Ming-Ji wu (Ministry of economic Affairs),<br />

Dr. Dahai Yu (executive Board Member evonik),<br />

Dr. Jonq-Min Liu (executive vice President ItrI),<br />

Dr. Hans-Josef ritzert (President evonik Greater<br />

China), Jia Ming Liu (General Director MCL, ItrI),<br />

Dr. Gerard Berote (President evonik taiwan)<br />

5<br />

elements39 Issue 2|2012


6 neWs<br />

new university partner in China<br />

Premiere in China: <strong>Evonik</strong> has sealed its first strategic university<br />

partnership in Asia with Shanghai Jiaotong University (SJTU). The<br />

cooperation agreement was signed by SJTU Vice President Xu Fei<br />

and Dr. Hans-Josef Ritzert, Regional President Greater China, with<br />

Dr. Dahai Yu, <strong>Evonik</strong> Executive Board Member, and Prof. Zhang<br />

Jie, SJTU President, also in attendance at the ceremony.<br />

Speaking at the event, Dr. Dahai Yu said, “I am delighted about<br />

this strategic cooperation with Jiaotong University. Our partnership<br />

will strengthen research and development cooperation in the<br />

chemicals field and beyond.” Prof. Zhang Jie likewise welcomed<br />

the new partnership, saying, “Innovation is the key to success, both<br />

for <strong>Evonik</strong> and for Jiaotong University. I am certain that our cooperation<br />

will generate genuine innovative power on both sides.”<br />

As one of Asia’s leading universities for the natural sciences<br />

and technology, SJTU offers modern resources for research and<br />

development. This cooperation deal provides <strong>Evonik</strong> access to<br />

excellent research facilities, technologies, and high-tech apparatus<br />

at the university. Awarded the title of “<strong>Evonik</strong> Professor,” three<br />

scientists at SJTU will conduct <strong>Evonik</strong>-funded R&D projects and<br />

hold scientific lectures for <strong>Evonik</strong> employees.<br />

Agreement was likewise reached on close cooperation in the<br />

area of intellectual property law. Experts from <strong>Evonik</strong> are also slotted<br />

to hold an industrial chemicals seminar at SJTU every two<br />

weeks. And <strong>Evonik</strong> will provide opportunities for students at SJTU<br />

to complete a course of practical training at the company.<br />

The Strategic Partner University Program is an important part<br />

of the strategy pursued by <strong>Evonik</strong>’s Corporate Innovation Strategy<br />

& Management to develop partnership agreements with leading<br />

universities all over the world.<br />

elements39 Issue 2|2012<br />

evonik and LIKAt<br />

expand research<br />

cooperation in catalysis<br />

<strong>Evonik</strong> and the Leibniz Institute for Catalysis (LIKAT) are<br />

planning to expand their cooperation in the area of catalysis<br />

research for the long term. The Institute has been<br />

successfully working with <strong>Evonik</strong> in the field of catalysis<br />

for more than ten years and the parties recently agreed<br />

to extend their long-term cooperation.<br />

For this purpose, the Advanced Intermediates Business<br />

Unit of <strong>Evonik</strong> has set up a new laboratory in the LIKAT<br />

facility, which will be dedicated to the development of<br />

new catalysts and the optimization of existing production<br />

processes. <strong>Evonik</strong> agreed to make a large investment<br />

available for this purpose in a framework agreement.<br />

“Our cooperation has generated a large number of<br />

innovations and patents over the past years,” says Prof.<br />

Dr. Stefan Buchholz, head of Innovation Management of<br />

the <strong>Evonik</strong> Advanced Intermediates Business Unit. “We<br />

plan to follow up on this success by bringing additional<br />

catalysis research products to commercial maturity in the<br />

years to come.”<br />

Catalysis is considered one of the most significant<br />

levers of efficient chemical production and is a key technology<br />

of the 21st century. It helps save energy and re -<br />

sources and reduces by-products and waste in chemical<br />

production. The Advanced Intermediates Business Unit<br />

uses the catalysts for the production of plasticizers in its<br />

integrated C4 technology platform in the Marl Chemical<br />

Park.<br />

LIKAT, the largest European research institute in the<br />

area of applied catalysis, is an internationally leading institute<br />

for the research and development of homogeneous<br />

and heterogeneous catalysts as well as catalytic processes<br />

and technologies. The main focus of its scientific work<br />

is on gaining new insights into basic catalysis research and<br />

studying their application to technical concepts.


“There’s no success without trust<br />

in a working partnership.”<br />

<strong>Evonik</strong> and the Leibniz Institute for<br />

Catalysis (LIKAT) in Rostock (Germany)<br />

have been working together for over a<br />

decade. The cooperation with the<br />

Performance Intermediates Business Line<br />

in particular has produced numerous patents<br />

and new catalysts. The new lab at<br />

LIKAT cements <strong>Evonik</strong>’s commitment to<br />

broadening the partnership, and Prof.<br />

Matthias Beller, in charge of LIKAT, and<br />

Prof. Stefan Buchholz, head of Innovation<br />

Management at <strong>Evonik</strong>’s Advanced<br />

Intermediates Business Unit, share their<br />

thoughts on what this entails.<br />

which areas will you be researching<br />

together in the new lab?<br />

Buchholz: The main joint research do -<br />

main at the EVA, the <strong>Evonik</strong> Advanced<br />

Catalysis Lab@LIKAT, centers on new<br />

catalysts for manufacturing processes at<br />

the Performance Intermediates Business<br />

Line. The focus is on hydroformylation,<br />

globally the most important homogenous<br />

catalytic reaction to use organometallic<br />

catalysts. More than ten million metric<br />

tons of products, mostly plasticizer alco-<br />

with it every year. With an annual production<br />

capacity of just over 400,000<br />

metric tons, <strong>Evonik</strong> is one of the leading<br />

manufacturers of isononanol (INA) and<br />

2-propylheptanol (2PH), which are used<br />

mainly in making two types of plasticizers:<br />

Diisononyl phthalate (DINP) and<br />

di(2-propyl heptyl) phtha late (DPHP).<br />

DINP and DPHP belong to the group of<br />

high-molecular-weight phthalates, which<br />

distinguish themselves through their<br />

superior application engineering profile<br />

and toxicological safety.<br />

Beller: We also look forward to putting<br />

the catalysis expertise gained over so<br />

many years to work on carbonylations<br />

and hydroformylations. One idea is to<br />

functionalize renewable resources into<br />

viable products for <strong>Evonik</strong>. We believe<br />

that renewables will become increasingly<br />

important in coming years. While this<br />

opens up many new opportunities, it is<br />

also an area that presents major challenges—and<br />

they must be met. We intend<br />

to venture into uncharted territory, too.<br />

It’s a high-risk proposition from a re -<br />

search standpoint, but it may well also<br />

InteRVIeW<br />

Prof. Matthias Beller (left), in charge of LIKAt,<br />

and Prof. Stefan Buchholz, head of Innovation<br />

Management at evonik’s Advanced Intermediates<br />

Business Unit<br />

what are the objectives?<br />

Buchholz: The goal for <strong>Evonik</strong> is to<br />

continue strengthening our leadership<br />

position, especially in hydroformylation.<br />

New catalyst systems, for instance,<br />

would enable us to achieve both higher<br />

yields as well as even higher selectivities<br />

for target molecules.<br />

Here, the key is to keep catalyst<br />

costs under control. Hydroformylation<br />

catalysts are often based on rhodium,<br />

an extremely rare precious metal that’s<br />

several times more expensive than gold.<br />

Ligands, mostly organic phosphines or<br />

phosphites, stabilize the rhodium catalysts,<br />

which in turn helps minimize precious<br />

metal loss. In addition, they also<br />

have a decisive impact on catalyst activity<br />

and selectivity. And because manufacturing<br />

ligands is often a complex and<br />

expensive process, we have to make<br />

sure that the ligands we jointly develop<br />

are also economically feasible in terms<br />

of their production cost.<br />

Another key aspect is that ligands have<br />

to remain stable under extreme reaction<br />

conditions, that is, high pressure and high<br />

hols and surfactants, are manufactured yield significant economic rewards. temperature, and deliver the end-<br />

333<br />

7<br />

elements39 Issue 2|2012


8 InteRVIeW<br />

333 product in a desired grade. Plasticizer<br />

alcohol viscosity, for instance, is a key application<br />

engineering parameter that’s essentially<br />

influenced through<br />

catalyst selectivity.<br />

What we’ve just talked about are<br />

mid-range goals. We’re also thinking<br />

more long-term. One such project involves<br />

revisiting the old dogma that only<br />

rhodium and cobalt can efficiently catalyze<br />

the hydroformylation. Our exploratory<br />

work at LIKAT shows that palladium<br />

and iridium present an heretofore<br />

untapped potential for carbonylation<br />

reactions. Together with LIKAT and the<br />

work group under Prof. Arno Behr at<br />

the Technical University of Dortmund,<br />

an additional partner in the scope of the<br />

Proforming Project funded by the BMBF<br />

(Federal Ministry of Education and Research),<br />

we intend to find out what that<br />

potential is and how to realize it.<br />

Beller: The idea is to provide the various<br />

<strong>Evonik</strong> business units with fundamental<br />

innovations in homogenous and<br />

heterogeneous catalysis. This will in<br />

turn spark concrete bilateral projects,<br />

which <strong>Evonik</strong> could then scale up industrially.<br />

who’ll be doing what? Is evonik’s role<br />

limited to providing the funding?<br />

Beller: That’s definitely not the case<br />

here. Funding is important and it can<br />

accelerate research projects, but it’s no<br />

guarantee for success. Success comes<br />

from working together and from intensive<br />

exchange with academic research.<br />

Buchholz: The sheer diversity of<br />

demands placed on the catalysts to be<br />

developed makes abundantly clear that<br />

only a broadly based, methodical approach<br />

has the greater chances of success. The<br />

compelling advantage is that <strong>Evonik</strong><br />

brings decades of accumulated experience<br />

and expertise in production to the<br />

table, while LIKAT contributes the latest<br />

findings from basic research. These two<br />

complementary perspectives are not<br />

only im portant in driving current proj-<br />

elements39 Issue 2|2012<br />

ects towards a successful outcome,<br />

but also create a steady source of new<br />

research topics.<br />

what benefits can LIKAt derive from the<br />

partnership?<br />

Beller: The Leibniz Institute for Catalysis<br />

is one of the world’s largest public<br />

research facilities in the area of applied<br />

catalysis. Complementing the research<br />

work at German universities and Max<br />

Planck Institutes, LIKAT’s declared goal<br />

is to help translate basic research findings<br />

into industrial applications. Yet this<br />

can only be achieved in cooperation<br />

with partners from industry. Or put differently:<br />

We definitely share in the success<br />

of technical solutions arrived at<br />

jointly in the lab.<br />

And what’s in it for evonik?<br />

Buchholz: The longstanding, broadly<br />

based cooperation with LIKAT has<br />

played a major role in systematically<br />

securing and expanding our technological<br />

edge in the area of hydroformylation<br />

but also in telomerization. Besides the<br />

concrete research findings, we also<br />

value the dialogue with Mr. Beller, an<br />

internationally recognized and leading<br />

catalysis researcher, and with Prof.<br />

Armin Börner as very inspiring—and that<br />

greatly stimulates our internal development<br />

work.<br />

Here, personal exchange is key—even<br />

with all the advanced communication<br />

tools and methods available today, it is<br />

still indispensable to the creative process.<br />

That’s why we not only have project<br />

leaders talking with each other, but<br />

also the people in the team—the group<br />

heads and doctoral candidates at LIKAT,<br />

and the researchers at <strong>Evonik</strong>. This pro ximity<br />

gives PhD candidates insights into<br />

industrial research, and it helps them<br />

prepare for their career. Several doc -<br />

to ral candidates appreciated this aspect<br />

to the extent that they signed on with<br />

<strong>Evonik</strong>. The ability to interact with<br />

future colleagues in a workplace set -<br />

t ing is an invaluable advantage, too.<br />

Besides, it is also the best way to spread<br />

the knowledge gained as a team effort<br />

throughout the company.<br />

what are the cons, if any, of such a<br />

research partnership?<br />

Beller: Compared to, say, a project<br />

funded by the German research community,<br />

academic freedom does have to<br />

operate within a more defined framework<br />

in this type of cooperation. As a<br />

researcher, one might view this as a constraint,<br />

but the way I see it, the benefits<br />

far outweigh any perceived disadvantages.<br />

Buchholz: The costs and the benefits—<br />

and the latter shouldn’t be construed as<br />

short-term profit optimization—have<br />

to be constantly weighed against each<br />

other. Of course, the need to be as open<br />

as possible to enable the partner to get<br />

fully involved sometimes conflicts with<br />

the need to respect the necessary obligations<br />

that come with intellectual property,<br />

and that is why it is so important<br />

to build trust. Trust, as our experience<br />

with LIKAT has shown, thrives especially<br />

well in a long-term partnership.<br />

You have been working together now for<br />

over ten years. How has the partnership<br />

evolved over time?<br />

Beller: In the beginning the cooperation<br />

between <strong>Evonik</strong> and my colleague Armin<br />

Börner in Rostock was focused on developing<br />

better hydroformylation catalysts<br />

for plasticizer alcohols. We essentially<br />

synthesized and catalytically tested new<br />

organometallic complexes and organic<br />

ligands for catalyst modification. This<br />

fell short of the goal to develop industrially<br />

viable and feasible systems, however.<br />

That’s why we expanded the scope<br />

to include mechanistic experiments,<br />

detailed catalyst studies, and structural<br />

activity tests. In 2009 our findings were<br />

implemented into practice in <strong>Evonik</strong>’s<br />

integrated C4 technology platform in<br />

Marl. Something we naturally found very<br />

gratifying.


“If you want to develop advanced<br />

chemical manufacturing processes, you<br />

need to know the catalysis cycle.”<br />

Buchholz: If you want to develop<br />

advanced chemical manufacturing processes,<br />

you need to know the catalysis<br />

cycle. And that requires deep methodological<br />

expertise in many areas: In<br />

in-situ IR and NMR spectroscopy, in<br />

theoretical chemistry, and in ligand synthesis.<br />

We’ve systematically grown our<br />

competencies in these areas and today<br />

we reap the ben efits in the new products<br />

and processes we develop as well as in<br />

our joint explor atory work.<br />

Beller: The past two years have also<br />

shown us that other chemical technologies<br />

are potentially attractive to <strong>Evonik</strong>.<br />

In this regard, we support our colleagues<br />

in Marl in establishing a strong patent<br />

basis.<br />

Looking back, I can say that, together,<br />

we’ve definitely met our share of challenges<br />

over the years. And we managed<br />

that to a large part on the basis of the<br />

trust that exists between us as partners.<br />

This is not something that can be taken<br />

for granted, and at this stage I would like<br />

to take the opportunity to thank Mr.<br />

Buchholz and Prof. Robert Franke and<br />

also Dr. Klaus-Diether Wiese as representatives<br />

of <strong>Evonik</strong>.<br />

Catalysis is a key technology for the<br />

chemical industry. How does Germany<br />

compare internationally? And what part<br />

do partnerships play?<br />

Buchholz: Germany continues to rank<br />

at the top. Here, LIKAT’s scientific<br />

excellence makes it stand out even more.<br />

What distinguishes it from other catalysis<br />

research facilities in Germany and<br />

Europe is the strong focus on practical<br />

implementation.<br />

LIKAT is only following through on<br />

a longstanding tradition. In Germany,<br />

the chemical industry and academic research<br />

institutes have always maintained<br />

close ties—much more so than in many<br />

other countries, where these two domains<br />

are almost hostile to each other,<br />

or where there’s no strong, innovationdriven<br />

chemical industry to enable this<br />

kind of partnership approach to develop<br />

in the first place. potential. 777<br />

InteRVIeW<br />

the Leibniz Institute for Catalysis (LIKAt)<br />

in rostock (Germany)<br />

There’s no doubt that the combination<br />

of openness to practical implementation<br />

and academic excellence is what makes<br />

LIKAT a preferred partner to <strong>Evonik</strong>.<br />

Beller: High-performance catalysts are<br />

instrumental in ensuring that chemical<br />

reactions don’t consume more resources<br />

than necessary, by avoiding by-products<br />

and reducing energy requirements.<br />

They are key to economic as well as ecological<br />

value creation in the spirit of<br />

decoupling technological progress from<br />

the consumption of natural resources.<br />

Germany has a preeminent position<br />

in catalysis research, both in basic and<br />

applied research. And on the academic<br />

side, with two Max Planck Institutes—<br />

the Max Planck Institute for Carbon Research<br />

in Mülheim on the Ruhr and the<br />

Fritz Haber Institute in Berlin—and the<br />

Leibniz Institute for Catalysis in Rostock<br />

as well as leading research groups at<br />

various universities such as Aachen,<br />

Berlin, Karlsruhe, and Munich, we have<br />

a very solid platform of excellence as<br />

well. However, it takes a working partnership<br />

between academia and industry<br />

to make innovations happen—to translate<br />

research findings into viable, sustainable,<br />

and feasible industrial processes.<br />

Our new joint lab has the best chances of<br />

playing a pivotal role in realizing this<br />

9<br />

elements39 Issue 2|2012


10 PRoJeCt HoUse sYsteMs InteGRAtIon<br />

elements39 Issue 2|2012<br />

Product and process<br />

go hand in hand<br />

Chemical products have to satisfy customers’ requirements and<br />

the demands of the market completely. Over the past three years,<br />

<strong>Evonik</strong>’s developers in the Project House Systems Integration<br />

of Creavis Technologies & Innovation have paved the way for<br />

new applications for innovative materials.<br />

[ text Dr. Michael Olbrich ]<br />

ReseaRch in the ivory tower—this is a beloved metaphor<br />

for describing the gap between scientific work<br />

and market reality. At <strong>Evonik</strong>, R&D has long forsaken<br />

the ivory tower in favor of efficient development<br />

work based on market requirements and megatrends.<br />

<strong>Evonik</strong>’s project houses, an element of the strategic<br />

research and development unit Creavis Technologies<br />

& Innovation, are one feature of its R&D landscape.<br />

In many of these project houses, employees from<br />

a variety of disciplines and business units of the<br />

Group have worked together to develop ideas and innovations<br />

since the year 2000. Over a period of three<br />

years, the employees combine their knowledge and<br />

their different experiences and advance their projects<br />

single-mindedly, outside day-to-day operations.<br />

This allows them to build new areas of expertise and<br />

bring products and processes to market readiness<br />

faster.<br />

While the first project houses focused primarily<br />

on the development of basic technology and products,<br />

their objective evolved over time to a greater focus<br />

on new processes and new applications—today, they<br />

work in closer proximity to the market. Project hous es<br />

work on behalf of the Group to venture further into<br />

new markets than the business units, and it is an open<br />

question whether a project can be brought to successful<br />

completion within three years—whether a<br />

technically attractive solution will be found and, ultimately,<br />

whether a marketable product is produced.<br />

The work of the project houses, therefore, complements<br />

the research done in the business units by<br />

advancing medium-risk developments. But the risk<br />

is worth it: The interdisciplinary teamwork outside<br />

normal day-to-day business often proves to be a catalyst<br />

for pathbreaking ideas. And for the individual<br />

researchers, the limited duration of the project house<br />

commitment—combined with its high visibility among<br />

top management—is a challenge that promotes personal<br />

development and extends employees’ horizons<br />

beyond their normal daily work.<br />

As the strategic research and development unit of<br />

<strong>Evonik</strong> <strong>Industries</strong>, Creavis is commissioned to build<br />

new and sustainable businesses for <strong>Evonik</strong> and develop<br />

forward-looking technology platforms. The


work of the project houses focuses on very fundamental<br />

medium-risk research topics that span multiple<br />

business units. High-risk research topics that<br />

represent completely new fields for <strong>Evonik</strong> are implemented<br />

in Creavis’ Science-to-Business (S2B)<br />

Centers.<br />

The Project House Systems Integration began its<br />

work at the Hanau site in early 2009. Unlike the seven<br />

previous project houses, the 21 employees were not<br />

tasked with developing new technologies and products<br />

but with finding new applications for existing<br />

(trial) products. They took a holistic approach to their<br />

R&D: The idea was to develop the product together<br />

with the required new processing technology so we<br />

can hand the customer not only a product but a system<br />

solution. These system solutions conquer the<br />

usual market entry barriers because they can be integrated<br />

more easily into existing production processes<br />

or offered to the customer as an entirely redesigned<br />

process.<br />

Product and process development go hand in<br />

hand: For example, a plastic may require a certain set<br />

PRoJeCt HoUse sYsteMs InteGRAtIon<br />

of processing parameters, but the technological<br />

parameters at the processing end might be defined<br />

differently. This holistic approach and the coordination<br />

of product and process were the starting point<br />

of development activities and an essential component<br />

of the work in the Project House Systems Integration.<br />

The objective was to develop economically attractive<br />

system solutions suitable for large-scale production.<br />

<strong>Evonik</strong> also develops additional competencies along<br />

the value-added chain, and creates added value<br />

through more efficient applications, resourceefficient<br />

processes, and/or more sustainable products.<br />

333<br />

Partnership of product<br />

and process<br />

For example, the developers in the<br />

Project House Systems Integration<br />

researched lightweight design in cars<br />

from a variety of angles. to this end,<br />

they adopted a holistic r&D approach:<br />

to open up new applications for<br />

evonik’s (trial) products, they developed<br />

the products, together with<br />

the required new processing technology,<br />

into a system solution<br />

11<br />

elements39 Issue 2|2012


12 PRoJeCt HoUse sYsteMs InteGRAtIon<br />

elements39 Issue 2|2012<br />

333<br />

About 300 years of professional experience in a wide<br />

variety of functions and six different disciplines: the<br />

21 employees of the Project House Systems Integration<br />

333<br />

Through close proximity to application and market,<br />

the tasks in the Project House Systems Inte -<br />

g ration beyond the actual technology were highly<br />

diverse: The employees evaluated processes for their<br />

commercial value, developed business models and<br />

plans, analyzed value-added chains in detail, prepared<br />

conceptual studies for potential production lines, and<br />

conducted life cycle assessments.<br />

Work in the project house also placed specific<br />

demands on the employees. Skills such as creativity,<br />

network building, and adaptation to changed conditions<br />

are important prerequisites for success—<br />

unexpected R&D results often mean the modification<br />

of entire project plans.<br />

In this regard, a key efficiency and creativity<br />

factor was the mixture of young and experienced<br />

employees. The employees in the Project House Systems<br />

Integration had about 300 years of combined<br />

experience at their disposal, came from six different<br />

educational disciplines, and had previously worked<br />

in a variety of functions, from classical R&D, through<br />

production, to marketing and sales. They received<br />

additional support from 18 students, who were tackling<br />

a range of issues in work ranging from internships<br />

to such projects as a diploma thesis, a Bachelor’s<br />

or Master’s thesis, or an MBA.<br />

The success of the projects closely depends, not<br />

least, on an intense exchange with the participating<br />

business units, precisely because of the market proximity<br />

of the development projects. Consequently, the<br />

“project sponsors” from the business units played a<br />

central role. They were the interface to the market<br />

and the customer, since they managed the starting<br />

products in the business unit and—if the project is<br />

successful—are in charge of further development and,<br />

ultimately, commercialization after the project house<br />

is concluded. They supported the projects, analyzed<br />

the findings, and ensured close internal communication<br />

on the activities of the project house.<br />

In the preparation stage of the project house,<br />

ideas and suggestions from various business units<br />

were collected and evaluated as part of a feasibility<br />

study. From a total of 75 proposals, nine projects were<br />

left that met the basic requirements for development<br />

in the Project House Systems Integration: The product<br />

has to be closely partnered with a specific pro-<br />

Project house anchored<br />

in the business units


cessing method for an innovative application. The<br />

application itself cannot be blocked by third-party<br />

patents and must belong to a growth market. The<br />

competition must offer sufficient leeway, and not<br />

least: The innovation must promise new commercial<br />

success for the Group.<br />

In all nine projects, the project managers each<br />

pursued several development routes at the same time,<br />

and investigated a number of potential fields of application.<br />

This increased the likelihood of success,<br />

and gave employees enough freedom to find the best<br />

solution for each, and the best possible route to it.<br />

Lightweight construction was a key focus of the<br />

work in the Project House Systems Integration. In the<br />

Automotive Glazing project, PLEXIGLAS® glazing<br />

was developed to make vehicles lighter in weight and,<br />

therefore, increase fuel efficiency and reduce emissions.<br />

The requirements for car windscreens are invariably<br />

high: High mechanical strength must be matched<br />

by high impact strength. The panes have to be UV-<br />

and weather-resistant, guarantee high light transmission,<br />

and withstand temperatures of up to 80 °C without<br />

haziness. Scratch- and abrasion-resistance also<br />

play an important role.<br />

The procedure was different, depending on the<br />

type of glazing and production quantities. For smaller,<br />

injection-molding panes installed in large piece 333<br />

PRoJeCt HoUse sYsteMs InteGRAtIon<br />

BAtteRY teCHnoLoGY<br />

Sustainable mobility<br />

PLeXIGLAS® glazing is<br />

only about half as heavy<br />

as conventional glazing<br />

The speed with which electric vehicles become<br />

operational largely depends on the performance<br />

of the battery. In cooperation with <strong>Evonik</strong> Lita rion<br />

GmbH, the experts in the Project House Systems<br />

Integration have worked on one of the most<br />

important chem ical components of the battery:<br />

The separator, which separates the electrodes in<br />

a battery cell. Based on <strong>Evonik</strong>’s existing<br />

SEPARION® separator, the project house investigated<br />

how the separator could be made thinner<br />

and lighter, for the purpose of increasing the<br />

amount of energy stored in the cell, and making<br />

the battery cells smaller and more compact. The<br />

challenge of this task is in cost-efficient mass<br />

production.<br />

13<br />

elements39 Issue 2|2012


14 PRoJeCt HoUse sYsteMs InteGRAtIon<br />

ReneWABLe eneRGIes<br />

A systematic approach<br />

to new energy<br />

The expansion plans for renewable energies are extremely<br />

ambitious in countries like Germany, Spain, and the United<br />

States, but also in North Africa and the Arab world. Con centrating<br />

solar power (CSP) will play an important role in these<br />

plans. In addition to site factors, the profitability and achievement<br />

of “grid parity” of CSP power plants depend heavily<br />

on the cost of the power plants. Collector fields, where the<br />

sun energy is converted to heat, are one cost driver. The<br />

savings potential is viewed as enormous: For example, if the<br />

parabolic or even flat collectors are no longer produced<br />

based on glass solar mirrors but on mirrored plastic, weight<br />

and transport costs drop, and the substructure in the solar<br />

field is considerably easier and more cost-effective to build.<br />

Together with the Performance Polymers Business Unit<br />

and external partners, the team developed technical solu -<br />

tions for the reflector and the surface finish. The first mirror<br />

materials based on PLEXIGLAS® from <strong>Evonik</strong> are currently<br />

undergoing approval testing. The key to their market viability<br />

is not only durability but also the optimal reflection of the<br />

direct sunlight and a surface finish that, for example, protects<br />

against abrasion through sand and dust.<br />

Collectors for solar thermal energy. If they were<br />

made of reflective plastic instead of glass, the<br />

substructure would be easier and more costeffective<br />

to build. the first mirror materials<br />

based on PLeXIGLAS® from evonik are currently<br />

undergoing approval testing<br />

elements39 Issue 2|2012<br />

Prototype of roof<br />

glazing with integrated<br />

photovoltaic cells<br />

New solutions for<br />

lighter vehicles<br />

counts, the researchers worked with the Performance<br />

Polymers Business Unit to develop a new<br />

impact-resistant molding compound. In 2011, several<br />

metric tons of the new compound were produced for<br />

the purpose of conducting injection-molding and extrusion<br />

tests under real conditions. At the same time,<br />

project house researchers developed various processing<br />

technologies and tested their suitability. One of<br />

their projects was to modify an injection-molding<br />

technology in such a way that PLEXIGLAS® can be<br />

combined with another plastic to form a multi-layer<br />

design in a single step.<br />

These developments fit seamlessly into the strategy<br />

of the automobile industry of using primarily<br />

lightweight, fuel-saving materials in the future to<br />

meet guidelines on emissions and climate protection.<br />

PLEXIGLAS® glazing saves up to 50 percent of the<br />

weight of conventional glazing. The excellent acoustic<br />

properties of the plastic system increases comfort,<br />

and the shatterproof material ensures heightened<br />

safety for passengers.<br />

Transparent car roofs were another focus of<br />

automotive glazing. Because they are used in signi-


ficantly smaller piece counts, they are produced in a<br />

heat forming process. By the end of their first development<br />

year, they had already received approval from<br />

the German Federal Motor Transport Authority that<br />

covers not only roof glazing but also rear and fixed<br />

side windows. This meant that concrete projects with<br />

customers could be started as early as the second year<br />

of the project house. Various automobile manufacturers<br />

are currently conducting street tests of the<br />

first PLEXIGLAS® glazing in prototype vehicles.<br />

In another project, the developers investigated<br />

how a photovoltaic function might be integrated into<br />

the roof glazing. The challenge for developers of<br />

these power-supplying variants is that the PV cell and<br />

polymer composite show different thermal expansion<br />

coefficients. To ensure that the solar cells do not tear,<br />

the researchers developed a sandwich structure, in<br />

which the optically active cells are embedded in an<br />

elastomer matrix that is decoupled from the exterior<br />

PLEXIGLAS® composite layers. They have developed<br />

three different processing techniques in all for manufacturing<br />

such composites.<br />

These composites, however, are flat PV semi-<br />

finished products that still have to be formed into the<br />

spherical shape of the roof glazing. The developers<br />

have successfully advanced these to prototype status:<br />

To make them operational, they produced prototypical<br />

roofs for a standard subcompact car, including<br />

A sandwich made of rOHACeLL® rigid foam and fiber composite top layers<br />

is ideally suited to lightweight construction in the vehicle: this method of construction<br />

allows a unique combination of low weight and maximum mechanical stability<br />

PRoJeCt HoUse sYsteMs InteGRAtIon<br />

roof glazing with integrated PV cells and transparent<br />

roof glazing without PV integration. <strong>Evonik</strong>’s objective<br />

is to gather practical experience with this demonstration<br />

vehicle and, at the same time, convince<br />

automobile manufacturers and potential customers<br />

of the benefits of PLEXIGLAS® glazing solutions.<br />

Transparent glazing:<br />

The first prototypes have<br />

already hit the streets<br />

<strong>Evonik</strong>’s ROHACELL® rigid foam also makes a<br />

big contribution to the lightweight construction in<br />

the vehicle: In combination with high-strength cover<br />

layers, it creates an extremely rigid composite that<br />

finds potential applications in both the interior and<br />

exterior. Concrete applications have been and are<br />

now being tried out in numerous projects with<br />

customers: From construction components with<br />

rather simple requirements, such as rear seat backs,<br />

all the way to structurally relevant components,<br />

where ROHACELL® composites are far superior to<br />

conservative construction methods when it comes to<br />

energy absorption and stiffness.<br />

333<br />

15<br />

elements39 Issue 2|2012


16 PRoJeCt HoUse sYsteMs InteGRAtIon<br />

e-sPInnInG<br />

Fine dust doesn’t stand a chance<br />

One of the technical highlights from the Project House<br />

Systems Integration is a new generation of polymer-based<br />

filter materials that can be used to separate fine dust from the<br />

waste gases of such installations as incinerators or cement<br />

plants. In cooperation with external machine manufacturers,<br />

this electrospinning process, as it is called, has been developed<br />

for the highly temperature-resistant Polyimide P84 all<br />

the way to the pilot production scale. The secret to this<br />

material is fibers with a diameter significantly below one<br />

micrometer: In purely mathematical terms, a purchase order<br />

of one gram of polymer yields a fiber length of about 5,000<br />

kilometers. This creates an extremely finely woven filter<br />

medium.<br />

In electrospinning, a P84 solution is set in an electrical<br />

field under high voltage. When a certain electrical field<br />

strength is reached, the dosing electrode forms a “fiber jet”<br />

in the direction of the counter electrode. The solvent evaporates<br />

and a fine fleece forms on a substrate in front of the<br />

counter electrode. The fibers are then stuck together and<br />

fixed on a stable support fabric. In close cooperation with<br />

the Performance Polymers Business Unit, the developers in<br />

the project house have created the basis for optimizing the<br />

filtration properties of the fiber material with an eye toward<br />

their end application. The newly acquired electrospinning<br />

plant in the project house even allows small-scale internal<br />

pilot production at <strong>Evonik</strong> <strong>Industries</strong>. This, in turn, will<br />

enable researchers to evaluate the ability of other polymers<br />

to be spun in this same way.<br />

elements39 Issue 2|2012<br />

A close-meshed<br />

filter medium for<br />

the deposition<br />

of fine particles,<br />

produced by electrospinning<br />

333 But the key to commercial success for these composites<br />

is cost-efficient mass production. This was a<br />

special focus of the project, and there was a surprising<br />

result: There is not just one economical process<br />

but a number of processes that provide the best cost<br />

efficiency, depending on the component and piece<br />

count.<br />

Micromagnets in new<br />

applications<br />

VP MAGSILICA® are highly versatile magnetic particles.<br />

The brownish powder consists of ultrafine iron<br />

oxides embedded in a dense silicon dioxide matrix.<br />

Through induction, VP MAGSILICA® can be heated<br />

to over 500 °C in a few seconds without stirring. So<br />

the push of a button, for example, can generate local<br />

heat, such as that required by chemical crosslinking<br />

reactions, which can be accelerated significantly by<br />

the heat supply. These applications were investigated<br />

in the Bonding on Demand project.<br />

Here, project house employees worked with<br />

equipment manufacturers and the Inorganic Materials<br />

Business Unit to develop new expertise in the inductive<br />

heating of plastics and adhesives, and build a<br />

complete application technology. With the help of<br />

mobile induction units, potential customers conducted<br />

pilot tests in production and addressed a number<br />

of issues: How do we work VP MAGSILICA® into<br />

an adhesive or a rubber? How should we construct<br />

and design the induction apparatus? How do we<br />

achieve the best heat input?<br />

One of the big potential applications for VP MAG-<br />

SILICA® is the crosslinking (vulcanization) of rubber<br />

profiles. In this process, the powder is added in small<br />

concentrations to the rubber formulation and heated<br />

immediately after extrusion, thereby vulcanizing the<br />

rubber. It became clear that the mechanical properties<br />

of the hardened profiles are comparable to conventionally<br />

vulcanized rubbers.<br />

Even modern insulating glass panes can be bonded<br />

faster and easier with the superparamagnetic powder.<br />

Normally, the double panes of modern windows<br />

are placed and bonded together in the edge region by<br />

an aluminum spacer. In order to fulfill the requirements<br />

of the upcoming thermal insulation regulation,<br />

the aluminum will be omitted as a thermal bridge. In<br />

cooperation with a hotmelt adhesive manufacturer,<br />

the project house has developed a mounting process<br />

by which the aluminum spacer can be replaced by<br />

plastic.<br />

Three years of work in the Project House Systems<br />

Integration have been crowned with success: At the<br />

end of the third year, all nine projects are still alive<br />

and continue to look promising. Seven of the nine<br />

projects have already been sent back to the par ti -


On the way to the market<br />

cipating business lines, while the other two will conclude<br />

by the middle of this year. The individual business<br />

units now have the task of taking the technical<br />

development results to market readiness.<br />

As different and multi-faceted as the projects are,<br />

they are quite similar in their strategic objectives:<br />

They contribute to energy and resource efficiency<br />

and advance the development of more sustainable<br />

products and processes for <strong>Evonik</strong> and its partners<br />

and customers. At the same time, the innovations increase<br />

the competitiveness of the company by opening<br />

up forward-looking markets, and by strengthening<br />

customer loyalty through practical solutions with<br />

high added value.<br />

The results of these projects are important not<br />

least because the Project House Systems Integration<br />

was planned and prepared in the midst of the economic<br />

crisis. But instead of slowing down work on<br />

the projects, it proved to be a challenge and opportunity<br />

for everyone involved. The Group’s decision<br />

to invest in interdisciplinary and demanding research,<br />

even in economically challenging times, turned out<br />

to be the right strategy. Planning the project house<br />

based on the prevailing economic conditions did<br />

nothing to detract from its success. 777<br />

PRoJeCt HoUse sYsteMs InteGRAtIon<br />

with vP MAGSILICA®, adhesives and plastics can be inductively<br />

heated to accelerate the crosslinking reaction. the Bonding<br />

on Demand project investigated the best way to coordinate the<br />

product and processing technology to achieve optimal results<br />

dr. Michael olbrich is the head of the Project House<br />

Systems Integration. After studying chemistry at the<br />

Albert Ludwig University in Freiburg and receiving<br />

his PhD from the Institute for Macromolecular<br />

Chemistry there, he started his career in 1995 in the<br />

construction chemicals industry at the Polymer<br />

Institute Dr. R. Stenner GmbH, as an assistant to the<br />

CEO. In 1999, he was hired to be head of molded foam<br />

application technology at PolymerLatex GmbH & Co.<br />

KG. In 2001, he took a job with <strong>Evonik</strong> Röhm GmbH<br />

in the Binders and Additives Business Line. His last<br />

job there was head of global sales for the Road Mar king<br />

and Casting Resins business segment. Since 2008,<br />

he has been working on the preliminary feasi bility<br />

study for the Project House Systems Integration at<br />

Creavis.<br />

+49 6181 59-4976, michael.olbrich@evonik.com<br />

17<br />

elements39 Issue 2|2012


18 CoMMent<br />

Innovations make history<br />

elements39 Issue 2|2012<br />

Innovations are, and always have been, an important cornerstone of a better future.<br />

To ensure the livelihood of future generations, then, we must continue to put good<br />

ideas into practice. But without social acceptance, even the best innovations will fail.<br />

[ text Dr. Klaus Engel ]<br />

A steady source of innovations for more than<br />

four decades: eUDrAGIt® tablet coating, which<br />

allows temporal and spatial control of the<br />

release of pharmaceutical active ingredients<br />

What comes to mind? The answer is essential to<br />

the future of our country, because inspiration, new<br />

ideas, and innovation are some of Germany’s most<br />

important resources. Without innovation, we<br />

wouldn’t be able to maintain or improve our standard<br />

of living. Without innovation, we’ll not be able to<br />

drive forward a sustainable, eco-friendly lifestyle and<br />

economy. This insight is no longer truly innovative,<br />

but it’s still not generally accepted. We must make<br />

sure that Germany, the land of industry, the land of<br />

research and production, doesn’t become the land<br />

of denial and procrastination if the public refuses to<br />

recognize the economic underpinnings of our prosperity.<br />

In today’s Germany, the triumvirate of research, innovation,<br />

and industry always inspires a great deal of<br />

skepticism, or even fear, which we have to counter<br />

with fair, fact-based arguments. If we can persuade<br />

the public and dispel its anxiety, we can achieve a<br />

great deal. It’s still worth our while to establish the<br />

facts.<br />

Innovations are, and always have been, an important<br />

cornerstone of a better future. Indeed, they are<br />

our lifeboat. The fledgling Federal Republic of Germany<br />

is a good example. Sixty years ago today, in<br />

1952, the new German constitutional state was already<br />

three years old. The murderous world war had<br />

ended only seven years before. In 1952, rubble and


sorrow were still part of everyday life in the divided<br />

Germany. In an address to the German people, Federal<br />

President Theodor Heuss complained that privation<br />

was “firmly rooted in many, many places.” And<br />

yet 1952 was also a year of new confidence, as the first<br />

fruits of the reconstruction became palpable. The<br />

German economic miracle was taking shape—through<br />

a lot of hard work, capital assistance from abroad,<br />

and, not least, inge nuity.<br />

Innovation as a lifeboat to a better future? While<br />

Heuss lamented the poverty back then, he also spoke<br />

of confidence and “highly sophisticated inventions<br />

that would set the German people back on course.”<br />

An end-of-the-year review from 1952 proudly celebrates<br />

the television: “We invented and built a number<br />

of new machines.” Journalists can point to successful<br />

export trade fairs as proof. Even back then,<br />

the focus was always on innovations, new ideas that<br />

will prevail on the market—in Germany, but also<br />

abroad.<br />

A core message from 1952 still holds true today;<br />

the economic prosperity of the people of our country<br />

is not based on the merging of simple components or<br />

by merely imitating the achievements of others. Our<br />

opportunities lie in forward thinking and improvements,<br />

in brainpower, and know-how. Sixty years<br />

later, in the Germany of the 21st century, this still applies—even<br />

if we use different vocabulary. Ingenuity<br />

and industriousness were the bywords of 1952. Today,<br />

concepts such as innovative power and competitiveness<br />

are more common.<br />

The German economy was also gaining steam internationally<br />

60 years ago. As early as 1952, customers<br />

around the globe associated “Made in Germany”<br />

on goods and products with quality. But the economic<br />

size classes have changed: Back then, it was sovereign<br />

nations, national economic systems or national economies<br />

that competed with each other. In the wake of<br />

globalization, on the other hand, we’re more likely<br />

to talk of competition between alliances and world<br />

regions.<br />

Another important difference between 1952 and<br />

2012 is the time factor: The speed of innovations has<br />

increased. More than a half century passed from the<br />

time the television was invented to the time it was<br />

widely found in households across Germany. When<br />

it came to the mobile phone, that time span was only<br />

a little over ten years.<br />

Over the last few decades, Germany has managed<br />

to maintain a healthy, powerful industrial climate—<br />

despite the crises and dramatic changes across entire<br />

industries. The capacity for self-renewal, innovation<br />

for our own sake, was a key factor in this regard. Today,<br />

the chemical industry in Germany often serves<br />

completely different markets, supplies entirely different<br />

products than in 1952.<br />

<strong>Evonik</strong> <strong>Industries</strong> itself reflects this change. The<br />

Group began operating under this name in 2007, only<br />

five years ago, thereby focusing its energies expressly<br />

on the power to create. The new company brought<br />

with it decades of experience from the chemical industry—and<br />

an appreciation of the value of innovation.<br />

<strong>Evonik</strong>’s history contains names such as Degussa,<br />

Chemische Werke Hüls, Th. Goldschmidt, and<br />

Röhm, just to mention a few. Even in the decades before<br />

the name change, these companies and groups<br />

were no strangers to innovation. Some milestones<br />

from <strong>Evonik</strong>’s history provide good illustrations.<br />

EUDRAGIT®, the protective coating for tablets,<br />

came on the market in the 1950s and made it possible,<br />

for the first time, to control the release of a medical<br />

agent in the patient’s body.<br />

In the colorful 1960s, plastic was king, and awareness<br />

of environmental protection was on the rise. In<br />

1964, the Group began producing proprietary biodegradable<br />

detergents, the active cleansing agents 333<br />

CoMMent<br />

Current research topics at evonik: A binder for<br />

corrosion protection formulations that significantly<br />

reduces, or avoids, the use of toxic heavy metals<br />

The core message is unchanged<br />

19<br />

elements39 Issue 2|2012


20 CoMMent<br />

333 for laundry detergents. Even research into catalysts<br />

for exhaust fumes from industry and traffic were<br />

gaining importance—more than 20 years before the<br />

law required cars to be fitted with catalysts.<br />

In the 1970s, the oil crisis arrived and increased<br />

the prices of raw materials and energy. The chemical<br />

industry, in turn, introduced more economical and<br />

environmentally compatible products to the market.<br />

Among other advances, the Group made a key contribution<br />

to reducing the environmental impact of<br />

cars: The first production plant for MTBE—a lead substitute<br />

important for the antiknock properties of gasoline—was<br />

built in Marl in 1976.<br />

The 1980s saw intense public debate over forest<br />

dieback, disarmament, and atomic energy. Across<br />

Germany, the Group at that time was peerless in its<br />

activities related to monosilane-gas—a starting material<br />

for the production of solar cells. The innovations<br />

of this decade also included additives for solvent-free<br />

coatings.<br />

In the 1990s, <strong>Evonik</strong> also ensured that green ideas<br />

gave birth to tangible products: Its silicas and organosilanes<br />

supplied two essential components for<br />

the production of tires that save fuel through extremely<br />

low rolling resistance and thereby also protect<br />

the environment. In addition, the Group transitioned<br />

increasingly to the production of surfactants<br />

from renewable raw materials. And about four decades<br />

after its debut, the EUDRAGIT® tablet coating<br />

experienced another surge in innovation—the market<br />

launch of a new variant for patients who depend on<br />

continuous drug delivery.<br />

Since the dawn of the 21st century, the Group has<br />

also focused its innovative power inwardly, adopting<br />

new structures in research and development—one of<br />

the most important sources for innovation. Its objective<br />

is improved knowledge transfer and completely<br />

market-oriented R&D.<br />

Currently, <strong>Evonik</strong> intends to benefit above all from<br />

the worldwide social development processes in<br />

health, nutrition, resource efficiency, and globalization.<br />

Some of the Group’s innovations include bricks<br />

for home construction that stand out for their special<br />

heat-insulating filler, and biopharmaceuticals that<br />

come as sprays or tablets and eliminate the need for<br />

injections. They also include binders for corrosion<br />

protection formulations that significantly reduce or<br />

avoid the use of toxic heavy metals.<br />

Hydrogen peroxide—an environmentally friendly<br />

bleaching agent that replaces chlorine bleach—is a<br />

great example of a changing market. Another example<br />

is PLEXIGLAS®: The plastic was introduced on<br />

the market as early as the 1930s, and a new variant<br />

now provides noise protection for a heavily traveled<br />

elements39 Issue 2|2012<br />

Dr. Klaus engel is Chairman of the<br />

executive Board of evonik <strong>Industries</strong> AG<br />

highway in southern China. And it demonstrates,<br />

once again, that the global innovation superhighway<br />

offers Germany, as an industrial nation, literally<br />

boundless opportunities.<br />

All these examples support my core thesis: We<br />

cannot abandon our efforts to put good ideas into<br />

practice, because they ensure the livelihood of future<br />

generations. As always, the key here is dialogue: In-<br />

Continuing the dialogue<br />

ner cities plagued by smog, lakes and rivers covered<br />

by foam from laundry detergents have all warned us<br />

to make changes. There can be no doubt that legislation<br />

and public pressure have helped bring about<br />

the transformation. But without innovation—in other<br />

words, without industrial practice—our progress<br />

would have been trifling.<br />

This is why we should discuss the pros and cons<br />

of innovations and new projects in a spirit of fairness<br />

and commitment—without social acceptance, even<br />

the best innovations will fail. But at the same time,<br />

we shouldn’t allow endless, irrelevant debate to slam<br />

the brakes on us and make us veer off the lane of reason.<br />

Driving on the hard shoulder is dangerous. For<br />

an industrial nation like Germany, which depends on<br />

innovation, it’s particularly hazardous. 777


Honorary professorship for Dr. Klaus engel<br />

Dr. Klaus Engel (55), the Chairman of the Executive Board of <strong>Evonik</strong><br />

<strong>Industries</strong> AG, recently received an honorary professorship from the<br />

School of Engineering at Duisburg-Essen University (UDE). Engel is<br />

the President of the Chemical Industry Association (VCI) and also<br />

chairs the Battery Technology Working Group in the National<br />

Platform for Electromobility, which was established by the German<br />

Chancellor.<br />

As an industry expert, Engel keeps in touch with UDE professors<br />

regularly, but his practical insights will now benefit the curriculum of<br />

the school, too. He will give lectures within the scope of the “Duisburg<br />

Dialogs” and will be involved in designing a lecture series that will<br />

also feature discussions with other representatives of <strong>Evonik</strong> on scientific<br />

questions from an industry perspective. The objective is to<br />

give university students a practical perspective of applying basic scientific<br />

concepts in industrial and business contexts.<br />

In his new capacity, Engel is particularly concerned about reaching<br />

out to junior scientists. “As a location for industry, Germany must<br />

continue maintaining the highest level of quality it is known for, and<br />

that goes for the future too, and the key to this lies in training and<br />

advancing talented and committed young people. I look forward to<br />

making a personal, practical contribution to this effort at Duisburg-<br />

Essen University,” he noted during the award ceremony of the honorary<br />

professorship in Duisburg, adding that Duisburg-Essen<br />

University is an example of establishing functional bridges between<br />

different sites. “Those efforts are not always successful,” Engel said.<br />

“There are always new obstacles to overcome, both in terms of space<br />

and content, which is essential for lasting success in science, research,<br />

Sale of the colorants business<br />

On April 30, 2012, <strong>Evonik</strong> <strong>Industries</strong> sold its<br />

global colorants business to the U.S. private<br />

investment firm Arsenal Capital Partners.<br />

<strong>Evonik</strong>’s colorants business develops, produces,<br />

and markets colorant systems for<br />

decorative coatings under the trademark<br />

COLORTREND®. Its CHROMA-CHEM® products<br />

are used for industrial applications including<br />

maintenance, marine, and wood coatings.<br />

In 2011 <strong>Evonik</strong>’s colorants business generated<br />

sales of around €130 million. With a global<br />

setup the colorants business employs more<br />

neWs<br />

and teaching, as well as in the industry. It is my hope to use the honorary<br />

professorship for building bridges, between science and industry,<br />

theory and practice, and between people and markets. New<br />

insights become only genuinely valuable when they are shared.”<br />

“Close contact with the industry is particularly important for engineering<br />

programs,” emphasized the university’s President, Prof.<br />

Ulrich Radtke. Dr. Engel is originally from Duisburg and holds<br />

a degree in chemistry from the University of Bochum.<br />

At the award ceremony of the honorary professorship in<br />

Duisburg: north rhine-westphalia Minister for economic Affairs<br />

Harry voigtsberger, evonik CeO Dr. Klaus engel, and university<br />

President Prof. Ulrich radtke (from left to right)<br />

than 300 people in its production sites and<br />

laboratories supported by sales and technical<br />

professionals. These facilities are located in<br />

the USA, Can ada, Brazil, Australia, China,<br />

Malaysia, and the Netherlands.<br />

“We are delighted with the opportunity<br />

to acquire a leading global business in the<br />

colorants space,” said John Televantos, Partner<br />

at Arsenal and Co-Head of the firm’s Specialty<br />

Industrials Group. “The business has a strong<br />

reputation because of its people, technology,<br />

quality, and service. It provides a great platform<br />

to build a stronger global business in a<br />

sector that we understand and believe it will<br />

perform well as an independent company<br />

benefiting from Arsenal’s resources and<br />

expertise. We look forward to supporting<br />

and building the business organically and<br />

with strategic acquisitions that will further<br />

expand its network.”<br />

21<br />

elements39 Issue 2|2012


22 neWs<br />

Groundbreaking<br />

ceremony for new organics<br />

production facility<br />

In March 2012, <strong>Evonik</strong> <strong>Industries</strong> broke ground to mark the official<br />

start of the construction of a new organics production facility in<br />

Shanghai (China), an upper-two-digit-million-euro investment. The<br />

ceremony was attended by more than 200 guests including government<br />

officials, regional and global contacts of <strong>Evonik</strong>’s key customers,<br />

elements39 Issue 2|2012<br />

strategic partners, as well as management and employees of the<br />

company.<br />

The detail engineering of the new organics production facility is<br />

already completed and the plant is expected to be operational in 2013.<br />

It will supply innovative ingredients and specialty surfactants based<br />

on renewable raw materials for the personal care, household care, and<br />

industrial specialties industry. It will primarily serve markets in China<br />

and Asia Pacific, with an annual capacity of 80 kt. The new production<br />

plant will be built on a 33,000 sqm plot of land at <strong>Evonik</strong>’s Multi-<br />

User Site China (MUSC) in Shanghai Chemical Industry Park (SCIP).<br />

It is conveniently located in the Yangtze River Delta Economic Zone.<br />

<strong>Evonik</strong>’s new organics production facility is also setting environmental<br />

standards. MUSC, a wholly-owned <strong>Evonik</strong> site, follows all<br />

Shanghai, China and <strong>Evonik</strong> standards and laws. In addition, the site<br />

is regularly audited and certified (ISO 9001, 14001 and OSHA 18001).<br />

<strong>Evonik</strong> will implement state-of-the-art environmental protection<br />

meas ures, such as sophisticated air pollution and waste treatment<br />

controls and two-step waste water treatment.<br />

Parallel to the construction of the new production plant, <strong>Evonik</strong><br />

is expanding its R&D center at its Xinzhuang site in Shanghai, with<br />

an investment of € 23 million. The expansion includes state-of-theart<br />

laboratories for research and development, application technology,<br />

and technical service, with aims to develop product applications<br />

and provide technology service for customers throughout China and<br />

Asia Pacific.<br />

Biogas upgrading: new plant for hollow fiber membrane modules<br />

<strong>Evonik</strong> <strong>Industries</strong> is investing an upper-singledigit-million-euro<br />

amount in a plant produc ing<br />

SEPURAN® hollow fiber membrane mod ules<br />

at its Schörfling (Austria) site. In particular, the<br />

novel membrane technology facilitates the<br />

energy-efficient upgrading of biogas to biomethane.<br />

Biomethane is fed into the public<br />

natural gas grid. The new hollow fibre spinning<br />

plant will come on-stream within 2012<br />

to meet the grow ing demand on the biogas<br />

market.<br />

“With this investment, we’re systematically<br />

strengthening our activities in the area<br />

of gas separation membranes, proving our<br />

commitment to renewable energies by producing<br />

biomethane that can be fed directly<br />

into the grid,” said Dr. Axel Kobus, head of the<br />

growth segment Fibers & Membranes. “In<br />

contrast to other processes, our membrane<br />

tech nology needs no auxiliary chemicals; nor<br />

does it generate any solid wastes or effluents<br />

that would need to be disposed of.” The <strong>Evonik</strong><br />

process is offered on the market by leading<br />

plant engineering and construction partners,<br />

and works cost-effectively, even in relatively<br />

small plants. It is therefore particularly suitable<br />

for the local energy supply of tomorrow.<br />

The novel technology is based on membranes<br />

produced from high-performance<br />

Hollow fiber membrane module for<br />

the upgrading of biogas to biomethane<br />

polymers that in the past have been, for<br />

example, processed into fibers and used in<br />

hot-gas filtration. At pressures of up to 25 bar,<br />

such membranes allow significantly improved<br />

separation of carbon dioxide and methane<br />

with stable selectivity, in a single process<br />

step. The method yields methane of purity<br />

higher than 99 percent. Neither energyintensive<br />

recycle streams nor costly downstream<br />

processing steps are required, which<br />

significantly distinguishes the <strong>Evonik</strong> method<br />

from the technologies currently available on<br />

the market.<br />

At present, biogas is still largely converted<br />

to electricity at its production site, with a<br />

maximum of 40 percent of its energy being<br />

utilized by the conversion to power. In such<br />

local power generation the waste heat often<br />

remains largely unused. When fed into the<br />

natural gas grid, however, the raw material<br />

can be stored much more efficiently, and<br />

more than 90 percent of its energy utilized<br />

as power and heat.


evonik invests in High-tech Gründerfonds II<br />

<strong>Evonik</strong> <strong>Industries</strong> has invested €2.5 million in<br />

High-Tech Gründerfonds II, expanding the<br />

number of industry investors to 13 corporations.<br />

In 2011 <strong>Evonik</strong> invested €365 million<br />

into research and development projects and<br />

is continuing its innovation strategy with its<br />

involvement in the fund. High-Tech Gründerfonds<br />

II began in October 2011 with a<br />

volume of €288.5 million in the first closing.<br />

It is able to provide seed financing of up to<br />

€500,000 of venture capital to innovative<br />

technology companies and reserve another<br />

€1.5 million per company for follow-up<br />

rounds.<br />

“The goal is to provide early financing for<br />

technologies, to create lasting value in the<br />

companies and to develop them in order to<br />

make them commercially viable. Overall, we<br />

have already been able to finance over 260<br />

companies since the start of Gründerfonds I<br />

in 2005. These start-ups have succeeded in<br />

arranging approx. €400 million of additional<br />

venture capital subsequent to our investments,”<br />

says Dr. Michael Brandkamp, Mana<br />

ging Director of High-Tech Gründerfonds.<br />

He adds, “With the involvement of <strong>Evonik</strong><br />

we have not only been able to increase the<br />

second fund to €291 million, but would also<br />

like to significantly increase the number of<br />

start-ups in the chemicals sector in Germany.”<br />

“<strong>Evonik</strong> <strong>Industries</strong> fosters a distinctive<br />

innovation culture. With our innovations we<br />

want to maintain our technology competence<br />

in the long-term and continue to expand it,”<br />

explains Dr. Bernhard Mohr, Head of Cor porate<br />

Venturing at <strong>Evonik</strong>. “Our involvement<br />

in High-Tech Gründerfonds II is another part<br />

of this strategy of investing in innovations and<br />

providing assistance to promising young startups<br />

in the chemicals sector and related disciplines.”<br />

Following Altana and BASF, <strong>Evonik</strong> is the<br />

third company from the chemicals sector to<br />

invest in High-Tech Gründerfonds II. This<br />

neWs<br />

should send a clear signal to universities and<br />

institutes of higher learning with a knack for<br />

spin-offs, as well as research facilities in the<br />

chemicals sector and related disciplines. “We<br />

want to motivate young scientists in the field<br />

of chemistry and related areas, which can also<br />

be engineering sciences, to start companies<br />

and to provide them with the necessary networks<br />

and contacts, in addition to starting<br />

capital,” says Michael Brandkamp, explaining<br />

the strong presence of the chemicals industry<br />

in the group of investors.<br />

Proximity to corporations has many<br />

advan tages. In addition to customer-supplier<br />

relationships opened up between small and<br />

large companies, the facilities or distribution<br />

channels of the industry may possibly also be<br />

used by start-ups. The industry benefits from<br />

trends, innovations, and completely new, cutting-edge<br />

business models.<br />

High-Tech Gründerfonds invests in<br />

young, high potential high-tech start-ups.<br />

The seed financing provided is designed to<br />

enable start-ups to take an idea through prototyping<br />

and to market launch. Investors in<br />

this public/private partnership include the<br />

Federal Ministry of Economics and Tech nology,<br />

the KfW Banking Group, as well as thirteen<br />

industrial groups. High-Tech Gründerfonds<br />

has about €563 million under management<br />

in two funds (€272 million High-Tech<br />

Gründerfonds I, €291 million High-Tech<br />

Gründerfonds II).<br />

Groundbreaking ceremony for new hydrogen peroxide plant in China<br />

An official ceremony was held at the end of<br />

April 2012 to mark the groundbreaking for<br />

<strong>Evonik</strong>’s new hydrogen peroxide plant in<br />

China. The plant is scheduled to go online,<br />

with a planned annual production capacity of<br />

230,000 metric tons, at the end of 2013, thus<br />

increasing <strong>Evonik</strong>’s current overall annual capacity<br />

of around 600,000 metric tons of<br />

H 2 O 2 production by nearly 40 percent.<br />

<strong>Evonik</strong> <strong>Industries</strong> recently founded <strong>Evonik</strong><br />

Specialty Chemicals (Jilin) Co., Ltd. (ESCJ)<br />

to run the new production facility. <strong>Evonik</strong> will<br />

supply its H 2 O 2 from Jilin directly to the adjacent<br />

propylene oxide plant run by Jishen<br />

Chemical Industry Co., Ltd. via a pipeline that<br />

will link the two facilities. A long-term supply<br />

agreement is in place between these companies.<br />

Jishen will use the so-called HPPO<br />

process to make propylene oxide from the<br />

hydrogen peroxide. Propylene oxide is used<br />

chiefly in the manufacturing of polyurethane<br />

intermediates. The polyurethanes then go<br />

into making things like upholstery for car<br />

seats or furniture. The HPPO process was<br />

developed by <strong>Evonik</strong> in collaboration with<br />

ThyssenKrupp Uhde GmbH.<br />

“Our investment in Jilin,” explains Jan Van<br />

den Bergh, the head of <strong>Evonik</strong>’s Advanced<br />

Intermediates Business Unit, “is an excellent<br />

example of our strategy to develop innovative<br />

technology to access new sales markets<br />

for hydrogen peroxide. This move is also part<br />

of a growth strategy that sees us making targeted<br />

investments in Asia and that will help<br />

us to achieve growth in that region.”<br />

The HPPO plant in China that will use the<br />

<strong>Evonik</strong>-Uhde technique will be the second<br />

of its kind. The first-ever large-scale HPPO<br />

operation anywhere in the world was jointly<br />

established by <strong>Evonik</strong>, ThyssenKrupp Uhde,<br />

and a Korean chemicals company (the licensee)<br />

in Ulsan (Korea) in 2008.<br />

Hydrogen peroxide has previously been<br />

used mostly as a bleaching agent in the textile<br />

and pulp industry. The new HPPO process<br />

now makes it possible for this environmentally<br />

friendly oxidant to also be used in the<br />

chemical direct synthesis of propylene oxide.<br />

The advantages of the HPPO process are that<br />

it requires significantly less investment, that<br />

it enables a high degree of production efficiency,<br />

and that it is an extremely eco-friendly<br />

process.<br />

23<br />

elements39 Issue 2|2012


24 CAtALYsIs<br />

elements39 Issue 2|2012<br />

New tool for characterizing catalysts<br />

Profiling simplifies scale-up<br />

in PMPC production<br />

Owing to their complex composition, heterogeneous catalysts cannot<br />

always be characterized entirely—something that can lead to unpleasant<br />

surprises when the production formulation is transferred to the commercial<br />

scale. With profiling, the experts of <strong>Evonik</strong>’s Catalysts Business<br />

Line have developed a method that visually illustrates the influence<br />

of the formulation on the catalytic properties. Profiling not only simplifies<br />

scale-up but also allows the customer to sample more efficiently.<br />

[ text Dr. Dorit Wolf ]


it Remains a challenge for catalysis experts to completely<br />

characterize a solid catalyst. Due to the complexity<br />

of these catalysts, they do not form a uniform<br />

phase, but display various polymorphic solid phases<br />

at once, which are also not defined at the molecular<br />

level. As a result, many physical and chemical properties<br />

are subject to broad distribution. Good examples<br />

include the particle sizes of the carrier materials,<br />

the size of the metal particles on the carriers, the<br />

acidity or basicity of surface centers, or even the oxidation<br />

conditions of the active transition metal components.<br />

It becomes even more complicated when the conditions<br />

on the edges of the distribution functions influence<br />

the catalytic properties. With their content<br />

being so infinitesimally small, it is difficult or impossible<br />

to use physicochemical methods to identify and<br />

quantify them.<br />

As a catalyst producer, however, <strong>Evonik</strong> must ensure<br />

the consistent quality and performance of its<br />

products. In addition to the standard methods of physicochemical<br />

characterization, such as determining<br />

particle sizes, elementary analysis, determining pore<br />

Figure 1<br />

Property profile of catalysts: Profiling<br />

illustrates the performance features “activity”<br />

and “selectivity” in various test reactions<br />

100<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

Catalyst 001 Catalyst 002 Catalyst 003<br />

MtBe cracking [%]<br />

0<br />

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(1)<br />

Selectivity<br />

(1)<br />

Activity<br />

(2)<br />

Selectivity<br />

(2)<br />

Activity<br />

(3)<br />

Selectivity<br />

(3)<br />

Characterization using catalysis<br />

volumes, and pore radius distribution, the company<br />

now has a method of evaluating the catalyst: Profiling.<br />

This tool, developed in-house, reliably indicates<br />

the extent to which changes in the manufacturing<br />

process influence the catalytic properties.<br />

The method is based on testing precious metal<br />

powder catalysts (PMPC) in different catalytic reactions<br />

that represent the key fields of application:<br />

Hydrogenation of CC double and CC triple bonds, of<br />

CO and CN groups, and of aromatic nitro groups. It<br />

also factors the hydrogenation of substrates that<br />

simultaneously display different hydrogenizable<br />

functional groups. The various reactions test the<br />

catalysts’ activity and selectivity—the actual performance<br />

features described in the property profile<br />

of each catalyst (see Fig. 1).<br />

The profiles differ greatly, depending on the composition<br />

of the catalyst— the type of precious metal, the<br />

precious metal loading, and the carrier type— 333<br />

CAtALYsIs<br />

Activity<br />

(4)<br />

Selectivity<br />

(4)<br />

25<br />

elements39 Issue 2|2012


26 CAtALYsIs<br />

Figure 2<br />

Diagrams of the production formulae to the left, catalyst performance profiles to the right. evonik’s new method shows<br />

which production parameters influence catalyst performance, and whether any still require fine-tuning<br />

Compound<br />

1<br />

Compound<br />

1<br />

Compound<br />

1<br />

Compound<br />

3<br />

Heating and<br />

stirring<br />

reduction<br />

Compound<br />

3<br />

Heating and<br />

stirring<br />

reduction<br />

Compound<br />

3<br />

Heating and<br />

stirring<br />

reduction<br />

elements39 Issue 2|2012<br />

Compound<br />

2<br />

Compound<br />

2<br />

Compound<br />

2<br />

Lab<br />

Heating and<br />

stirring<br />

Production<br />

A<br />

Heating and<br />

stirring<br />

Production<br />

B<br />

Heating and<br />

stirring<br />

Drying<br />

1<br />

Filtration<br />

rewetting<br />

Drying<br />

2<br />

Drying<br />

1<br />

Filtration<br />

rewetting<br />

Drying<br />

2<br />

Drying<br />

1<br />

Filtration<br />

Activity/selectivity indicator [%]<br />

100<br />

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Activity/selectivity indicator [%]<br />

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50<br />

40<br />

30<br />

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reaction number<br />

Activity/selectivity indicator [%]<br />

100<br />

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80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

0 1 2 3 4 5 6 7 8 9 10 11<br />

reaction number


Figure 3<br />

Performance profiles of various prepared PMPC catalysts (5 % Pd/C) from evonik. these profiles allow<br />

conclusions to be drawn regarding the preferred reactions and substrates of the particular catalyst types<br />

%<br />

100<br />

75<br />

50<br />

25<br />

0<br />

%<br />

100<br />

75<br />

50<br />

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0<br />

%<br />

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50<br />

25<br />

0<br />

%<br />

100<br />

75<br />

50<br />

25<br />

0<br />

DEG-Catalyst 1 DEG-Catalyst 2 DEG-Catalyst 3 DEG-Catalyst 4<br />

DEG-Catalyst 5 DEG-Catalyst 6 DEG-Catalyst 7 DEG-Catalyst 8<br />

DEG-Catalyst 9 DEG-Catalyst 10 DEG-Catalyst 11 DEG-Catalyst 12<br />

DEG-Catalyst 13 DEG-Catalyst 14 DEG-Catalyst 15<br />

DEG-Catalyst 16<br />

1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9<br />

Reaction Reaction Reaction Reaction<br />

333 but also on the manufacturing formula. To put it<br />

differently: The catalytic performance profiles are a<br />

type of unique fingerprint for each type of catalyst.<br />

<strong>Evonik</strong> uses profiling in the development of new<br />

catalysts when laboratory formulas have to be transferred<br />

to the commercial scale. With the new method,<br />

they can analyze whether the properties lend themselves<br />

to reproduction, and whether the catalysts produced<br />

perform as well as the laboratory models.<br />

Figure 2 demonstrates that profiling is well suited<br />

to this purpose. It not only shows whether the catalyst<br />

formula could be successfully transferred from<br />

the laboratory to the production scale but also which<br />

production parameters determine catalyst performance<br />

and whether they might still require finetuning.<br />

Profiling therefore allows selective improvement<br />

in the robustness of the catalyst production<br />

process, and it also assists quality assurance.<br />

Figure 3 shows various profiles of the catalysts of<br />

<strong>Evonik</strong>’s PMPC portfolio. All of these are five percent<br />

Pd catalysts, with activated carbon as the carrier. The<br />

only difference in these catalysts is the way they were<br />

produced. In the end, they all have the same quantitative<br />

composition. The figure shows how extremely<br />

sensitive the performance profiles are to the parameters<br />

of catalyst production. This makes profiling a<br />

useful tool not only for scaling up catalysts: The<br />

method also makes it possible to derive preferred<br />

reactions and substrates for the various catalyst types<br />

from the profiles.<br />

In other words, it allows fast identification of the<br />

types of reactions or substrates that will make a certain<br />

catalyst in the <strong>Evonik</strong> portfolio display particularly<br />

high activity and selectivity and, on the other<br />

hand, which substrates will make the catalyst less<br />

active or selective. By this method, customers can<br />

obtain a sample optimally designed for their specific<br />

application. 777<br />

CAtALYsIs<br />

More robust production processes<br />

Pd dr. dorit Wolf has been R&D group leader in<br />

<strong>Evonik</strong>’s Catalysts Business Line since 2004. She<br />

studied chemistry at the University of Leipzig, where<br />

she earned her doctorate in 1991. In 1997, Wolf qualified<br />

as a university lecturer in chemical technology at<br />

the Chair for Chemical Technology at Ruhr University<br />

in Bochum. She subsequently accepted a position as<br />

director of the Reaction Technology Working Group at<br />

the Institute for Applied Chemistry Berlin-Adlershof.<br />

In 2001 she moved to <strong>Evonik</strong> to direct the Hetero geneous<br />

Catalysis Group in the Catalysis Project House.<br />

+49 6181 59-8746, dorit.wolf@evonik.com<br />

27<br />

elements39 Issue 2|2012


28 MedICAL teCHnoLoGY<br />

elements39 Issue 2|2012<br />

Implants made from PEEK ensure<br />

new quality in medicine<br />

Whether it is spinal disc problems or certain diseases of the gastrointestinal<br />

tract, dental technology or cardiac pacemakers: For many health concerns,<br />

implants are the method of choice for restoring a patient’s quality of life.<br />

As an implant material, polyetheretherketone has established a firm position<br />

in a market defined not by large piece counts, but by custom-designed<br />

individual solutions. <strong>Evonik</strong> has met this challenge with VESTAKEEP® PEEK.<br />

[ text Marc Knebel ]<br />

Cranial-Maxillo-Facial<br />

Dental<br />

Orthopedics<br />

Cardiovascular<br />

Spine<br />

Fields of application<br />

for implants made<br />

from PeeK polymers


Patients Who suffeR from stomach or intestinal<br />

tumors can experience constriction of the digestive<br />

tract—a condition called stenosis, which prevents food<br />

from passing through. In these cases, a stent—an elastic,<br />

tube-shaped, self-expanding wire mesh that<br />

unfolds following placement in the esophagus or the<br />

affected section of the intestine—reopens the pathway<br />

for food. The stent does not cure the patient’s<br />

disease, but it does alleviate suffering and improves<br />

the patient’s quality of life.<br />

Traditionally produced from polyamide or polyester,<br />

stents can now be made from <strong>Evonik</strong>’s polyetheretherketone<br />

(PEEK) VESTAKEEP® as well. The<br />

material boasts not only excellent biocompatibility,<br />

which <strong>Evonik</strong> has verified in numerous tests by<br />

external testing institutes, but also high biostability.<br />

The latter is a direct result of the aromatic, partially<br />

crystalline properties of the PEEK polymer, which<br />

not only imparts outstanding resistance to corrosion,<br />

hydrolysis, and chemicals but also renders it inert to<br />

bodily liquids—the material retains its stability, even<br />

under aggressive conditions.<br />

The stents are one of the new medical applications<br />

<strong>Evonik</strong> has opened up with VESTAKEEP®. The fact<br />

that EPT—<strong>Evonik</strong> Polymer Technology GmbH, which<br />

manufactures PEEK semi-finished products—is certi-<br />

Synthesis of PeeK. the aromatic,<br />

partially crystalline properties<br />

of the PeeK polymer make it highly<br />

resistant to chemicals and bodily<br />

fluids<br />

fied to EN ISO 13485:2003 simplifies marketing of the<br />

material. This certification makes it easier for the<br />

producers of medical products to qualify as suppliers,<br />

and ensures specific medical standards of care and<br />

traceability are met. This completes a key hurdle in<br />

advancing new applications.<br />

In addition to its biostability and biocompatibility<br />

(see also elements34, p. 30 ff), the advantages of<br />

VESTAKEEP® include its outstanding mechanical<br />

properties, such as high dimensional stability based<br />

on low water intake, high stiffness at low weight, high<br />

resistance to heat distortion, and a long-term service<br />

temperature of 260 °C. This high-performance plastic<br />

is also easy to work into versatile shapes—an argument<br />

not only for the filigree construction of stents<br />

but also for use as an extremely thin-walled battery<br />

housing in cardiac pacemakers, in dental technology,<br />

or as an implant pump for patients who, for instance,<br />

suffer from excess fluid in the abdomen as a result of<br />

liver disease. 333<br />

Orthopedics: A growing<br />

field of applications<br />

F F<br />

+<br />

na2CO3 – naF<br />

– H2O O OH<br />

– CO2 O<br />

OH<br />

MedICAL teCHnoLoGY<br />

O<br />

O<br />

evonik produces veStAKeeP®<br />

in a Class 10000 clean room,<br />

which commenced operation<br />

in April 2011<br />

n<br />

29<br />

elements39 Issue 2|2012


30 MedICAL teCHnoLoGY<br />

elements39 Issue 2|2012<br />

333 Historical areas of application for high-performance<br />

PEEK have been spinal implants, with a growing<br />

interest in orthopedic devices and recently<br />

accepted applications such as mouth, jaw, and skull<br />

implants. For spine surgery, in the case of herniated<br />

discs it can be advisable to remove the intervertebral<br />

disc and replace it with a prosthesis called a “spine<br />

cage.” Because the cage is supposed to create a bony<br />

connection between the neighboring vertebrae, it has<br />

a central cavity that can be filled with calcium phosphate<br />

or the patient’s own bone material. Anatomically<br />

shaped, it also has a toothed surface for high<br />

“primary stability”—the stability achieved solely<br />

through the clamping effect of the implant in the<br />

bones.<br />

While cage implants are machined from a higher<br />

volume, off-the-shelf design, cranial implants have<br />

moved to a more custom design for each patient. They<br />

are used in patients with extensive skull defects to<br />

protect the delicate brain—whether it is a congenital<br />

malformation or the result of an accident or sickness.<br />

To this end, a 3D X-ray scan is used to reconstruct<br />

the exact three-dimensional anatomy of the surface<br />

of the skull on a computer. The implant is then<br />

adapted to this form and produced from a block of<br />

PEEK using CNC milling technology.<br />

A protective shield<br />

for the skull<br />

Compared to the long-established implant materials<br />

titanium and cobalt-chromium, PEEK offers a variety<br />

of advantages in orthopedics. The plastic scores<br />

points in terms of ductility, elongation at break, and<br />

fatigue resistance—blows or shocks to the implant are<br />

effectively absorbed. From a patient perspective they<br />

appreciate the extremely low thermal conductivity:<br />

Cranial plates made of titanium, which have excellent<br />

heat conductivity, can cause pain when temperatures<br />

fluctuate dramatically in the environment around<br />

them—for example, when the patient leaves a wellheated<br />

house to go outdoors in winter.<br />

VESTAKEEP® is also X-ray transparent and therefore<br />

invisible in computer tomography and magnetic<br />

resonance imaging, which allows easy monitoring of<br />

bone growth and structure during the healing process.<br />

Titanium and cobalt-chromium, on the other<br />

hand, are opaque to X-rays and generate artifacts that<br />

make it difficult to analyze the image.<br />

There are sometimes cases in which the physician<br />

wants to see the implant—he may, for example, check<br />

Spine cage made of veStAKeeP® PeeK as a placeholder<br />

for the space between the vertebrae, which recreates<br />

the natural height of the intervertebral disc segment<br />

As an added service, evonik also offers customers<br />

CAe (computer-aided engineering). these<br />

simulations provide information on how much<br />

stress an implant receives and how it should<br />

be constructed<br />

X-ray image of 2-mm-thick veStAKeeP® platelets<br />

that were layered in stacks of varying heights.<br />

the absorption of the X-ray light increases as the<br />

thickness of the layers increases (from bottom<br />

to top). At the same time, it is possible to control<br />

the absorption by varying the content of the<br />

barium sulfate


In permanent bending tests, veStAKeeP® holds up three times<br />

as long as a comparable competing PeeK product<br />

veStAKeeP® Ultimate Standard PeeK polymer<br />

Bending force [n]<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

0 100,000 200,000 300,000 400,000<br />

Cycles<br />

On the computer, 3D X-ray scans are used to<br />

reconstruct the exact three-dimensional anatomy<br />

of the skull. this is done for the purpose of<br />

manufacturing skull implants, where the implant is<br />

adapted to this form. CnC milling technology is<br />

used to make the implant from one block of PeeK<br />

Visible thanks to<br />

barium sulfate<br />

MedICAL teCHnoLoGY<br />

the primary stability of a spine cage to make sure it<br />

is properly seated, and whether the bones are actually<br />

growing through it. This is why tantalum pins are<br />

used in PEEK cages to make the implant visible. However,<br />

incorporating the pins is a pretty tedious, laborintensive<br />

post-processing step because they have to<br />

be seated perfectly flush—the cavities around the pins<br />

could cause problems during cleaning and sterilization.<br />

For such cases, <strong>Evonik</strong> has developed a new<br />

VESTAKEEP® PEEK variant that contains barium sulfate.<br />

The idea comes from diagnostic radiology: Physicians<br />

give patients a suspension made of barium<br />

sulfate to display the esophagus, stomach and small<br />

and large intestines, as well as mobility disorders of<br />

these organs, in a CT image. Decades of experience<br />

have proven the safety of using barium sulfate.<br />

Studies by <strong>Evonik</strong> have shown that a content of<br />

less than ten percent barium sulfate is enough to make<br />

the implant visible on an X-ray, without generating<br />

the kinds of disruptive artifacts caused by metals.<br />

While the quality of the X-ray depends on a number<br />

of factors—such as the strength of the X-ray radiation<br />

and geometry, and the wall thickness of the implant—<br />

a filling level of six percent barium sulfate is wellsuited<br />

to a majority of applications. For example, a<br />

spine cage can be portrayed clearly in an X-ray image,<br />

and at the same time allows the monitoring of<br />

bone growth in the cavity.<br />

Osteointegration—the healing process in the bones<br />

in which the bone cells graft to the implant and implant<br />

surface, which normally takes about six to<br />

twelve months—is essential for a stable fit for an implant<br />

in the spinal column. The factors that influence<br />

osteointegration are the individual properties of the<br />

bone, the construction of the implant, and its surface<br />

condition. With regard to the latter, titanium is<br />

superior to PEEK, because the metal surface shows<br />

improved grafting behavior, and the bone substance<br />

anchors faster to the metal. Consequently, the 333<br />

Coating should accelerate<br />

bone growth<br />

31<br />

elements39 Issue 2|2012


32 MedICAL teCHnoLoGY<br />

InteRVIeW<br />

“Material artifacts diminish the image quality”<br />

Dr. Markus Braun has two jobs: He is attending physician at<br />

the Klinikum Westfalen in Dortmund and team doctor at<br />

Borussia Dortmund football club. A specialist in sports medicine,<br />

Braun knows a great deal—about premature signs of<br />

exhaustion, fast healing processes, and the question of the<br />

right implant material.<br />

You’ll be standing on the sidelines again next weekend,<br />

Dr. Braun: As a fan or a concerned physician?<br />

Braun: All of the above! My first responsibility is as a physician,<br />

but you automatically become a fan. When you spend<br />

that much time with the players, you develop a personal<br />

relationship beyond the normal doctor-patient relationship.<br />

How much time do you actually spend with the players?<br />

Braun: In any given week I spend a couple of hours on<br />

the training ground almost every evening. And I go to<br />

every game on the weekend. This time we go to Berlin:<br />

We’ll be traveling from Friday afternoon to Saturday<br />

evening. Then, it’s right back to training Sunday morning.<br />

Editor’s note: Dr. Braun also had his work cut out for him<br />

this weekend. In the win over Hertha BSC, Lukasz Piszczek<br />

suffered a concussion and contusion of the skull when<br />

he collided with another player.<br />

everyone knows that professional athletes are especially<br />

prone to injury. what long-term impact does this kind<br />

of permanent stress have on the body?<br />

Braun: Signs of exhaustion are often the first to appear.<br />

By age 40 or 45, osteoarthritis is not unusual. Top athletes<br />

are also frequent candidates for implants.<br />

what criteria are crucial to the optimal implant?<br />

Braun: Naturally, it would be best to completely forego<br />

the use of foreign material. This is not always possible,<br />

however. When foreign material has to be used, the material<br />

properties are crucial: Biocompatibility is the first<br />

consideration. Of course, the material must be as durable<br />

as possible to prevent the need for a second operation.<br />

Wear resistance and the right amount of elasticity are<br />

crucial to stability. If these properties are not what they<br />

should be, the implant can cause problems later.<br />

elements39 Issue 2|2012<br />

what materials do you work with?<br />

Braun: There is a trend in medicine toward minimally<br />

invasive surgery and away from large-scale operations.<br />

Minimally invasive surgery makes only small incisions and<br />

is controlled by imaging methods such as CT or MRT. In<br />

the case of CT, small steel needles are used, and in MRT,<br />

amagnetic materials such as carbon fibers or titanium.<br />

Many materials are well known to generate artifacts on<br />

the screen. How do you handle that?<br />

Braun: Artifacts on the image are a disaster! For me, they<br />

are a real problem, particularly with the equipment.<br />

Braun shows a CT scan from a spinal column cementing procedure.<br />

The area around the bone punch cannula is obscured<br />

by the white of the artifacts. Without this buildup of artifacts,<br />

I could work with greater precision.<br />

the material PeeK doesn’t leave artifacts.<br />

Braun: That is, in fact, an interesting feature of my work.<br />

To get that kind of information, I usually have to do my own<br />

research or trust the claims of the implant manufacturers.<br />

Right now, there is no direct exchange between doctors and<br />

material manufacturers. And these are the experts who<br />

ultimately have to convert my requirements into concrete<br />

technical data.


dr. Markus Braun, 45, is a trained medical specialist in orthopedics, and has<br />

worked as the team doctor for first-division German soccer team Borussia Dortmund<br />

since 2003. Previously, he spent five years as the team doctor for Rot-Weiß<br />

Essen. In his full-time career, Braun has held various positions at clinics in Duisburg,<br />

Essen, and Bochum. Since mid-2011, he has worked as attending physician<br />

at the newly established sports medicine department at Klinikum Westfalen<br />

(Dortmund). His specialty is minimally invasive surgery using imaging methods.<br />

You are an expert in healing processes. It’s incredible sometimes<br />

how fast professional soccer players recover even from<br />

serious injuries: what’s the magic behind that?<br />

Braun: (laughs) No magic! Essentially, there are three simple<br />

reasons for that: First, the patients are young and in top<br />

condition. This is why the body responds well to treatments<br />

and therapies. Second, the players have access to their own<br />

physical therapists, who create an optimal environment<br />

that allows the natural healing processes to run their course<br />

without interference. And third: The players go to rehab<br />

far more for the optimal stimulation therapy under the<br />

direction of skilled rehab trainers.<br />

who decides whether a player is fit enough to play again?<br />

Braun: That’s an interdisciplinary decision between the<br />

physical therapists, rehab trainers, and the doctor. To some<br />

extent, the player is responsible. Everyone tries for the<br />

fastest possible recovery time.<br />

Do you ever just have to say “no”?<br />

Braun: That happens sometimes. The players always want<br />

to get back on the field by the next game. At that moment,<br />

they’re just highly motivated employees. We doctors have<br />

to act as a brake if the risk to their health is too great.<br />

MedICAL teCHnoLoGY<br />

333<br />

spinal segment that received the implant stabilizes<br />

more quickly and is also able to take stress faster.<br />

On the other hand, with an E-modulus of 3.3 Gigapascal<br />

the elasticity of PEEK roughly corresponds to<br />

that of a bone. This allows an optimal transmission of<br />

force between the implant material and the natural<br />

bone, which can in turn have a positive effect on bone<br />

healing.<br />

Both advantages can be combined by coating the<br />

PEEK implant, which improves the grafting behavior<br />

of bone cells on PEEK. Common coating materials are<br />

hydroxylapatite, calcium phosphate, titanium, or a<br />

special nano-coating. Depending on the material, they<br />

are applied by vacuum plasma spraying, chemical<br />

treatment, or physical vapor deposition.<br />

<strong>Evonik</strong> is currently working on a number of formulas<br />

in cooperation with various companies that<br />

specialize in coating medical products. The current<br />

results are quite promising, as tests by an independent<br />

accredited testing laboratory show: VESTA-<br />

KEEP® PEEK substrates, for example, demonstrate<br />

exceptionally high tensile and shear strength—the<br />

coatings adhere extremely well—and meet the requirements<br />

of the FDA on these points.<br />

The potential of PEEK polymers, however, is far<br />

from being exhausted. To increase the rigidity of the<br />

material even further, <strong>Evonik</strong> is working on a variant<br />

strengthened with carbon fibers (CF). Potential<br />

applications are plates and screws in the trauma<br />

segment used by surgeons to stabilize broken or<br />

fractured bones. The advantage lies in the fact that<br />

patients receive a metal-free solution, which helps<br />

those with allergic reactions to metal ions. Patients<br />

can also undergo MRI examinations later on, which<br />

is not possible with metal implants. Beyond this,<br />

<strong>Evonik</strong> has even more development plans for promoting<br />

the use of VESTAKEEP® PEEK as a metal substitute<br />

in the body and more reports will follow as<br />

VESTAKEEP® accomplishes these technologies. 777<br />

Marc Knebel is Business<br />

Manager of VESTAKEEP®<br />

Medical in <strong>Evonik</strong>’s High<br />

Performance Polymers<br />

Business Line.<br />

+49 2365 49-6783,<br />

marc.knebel@evonik.com<br />

33<br />

elements39 Issue 2|2012


34 neWs<br />

Lightweight design<br />

solutions for China<br />

automotive industry<br />

The all-new electric car prototype was in the<br />

spotlight at the Shanghai International Industry<br />

Fair on Shanghai Motor’s booth, underscoring<br />

the benefits of lightweight design solutions<br />

from <strong>Evonik</strong> <strong>Industries</strong>. The new-energy<br />

vehicle is powered by a lithium-ion bat tery.<br />

The car uses several lightweight materials<br />

from <strong>Evonik</strong> for various applications to support<br />

reduced energy consumption and lower<br />

emissions, such as PLEXIGLAS® material for<br />

the side screens, rear window, and rear lamp,<br />

as well as ROHACELL® rigid core material<br />

and an epoxy resin formulation based on<br />

VESTA MIN® hardener technology for the<br />

engine hood. “We are proud to have played<br />

a part in providing Shanghai Motor’s first<br />

electric car with our lightweight and environmentally<br />

progressive plastic solutions,” said<br />

Xu Hang, Project Head of Lightweight Design<br />

in China.<br />

elements39 Issue 2|2012<br />

The use of <strong>Evonik</strong>’s PLEXIGLAS®—a coated<br />

PMMA to replace traditional mineral glass—<br />

in the demo car reduces the weight of the<br />

fixed side screens up to 40–50 percent. It also<br />

helps to reduce energy consumption and CO 2<br />

emissions. The advantages of PLEXIGLAS®<br />

glazing include UV stability and good acoustic<br />

properties, which means added value for the<br />

vehicle as a whole. In addition, the car designer<br />

can achieve more design freedom with<br />

this material and gain sophisticated curve<br />

structure which is not feasible by using traditional<br />

mineral glass. The special grade of<br />

PLEXIGLAS® material is also applied at the<br />

rear lamps to achieve a special light diffusing<br />

effect.<br />

The engine hood uses the structural foam<br />

ROHACELL® developed by <strong>Evonik</strong>. This ma -<br />

terial is used as core in sandwich structures.<br />

Compared to a steel engine hood, the sandwich<br />

version reduces weight by up to 70 percent.<br />

Due to the outstanding heat resistance<br />

and remarkable mechanical strength of<br />

ROHACELL® material, it can shorten curing<br />

cycles at elevated temperatures above 130 °C<br />

and offers a cost-efficient production.<br />

Because of its high mechanical strength at<br />

low densities, even small thicknesses of<br />

ROHACELL® enable the construction of lightweight<br />

body parts with extreme stiffness.<br />

To support high output production of<br />

composite body parts, a new epoxy resin formulation<br />

based on VESTA MIN® hardener<br />

technology was used in the resin infusion<br />

manufacturing process. Short cycle times can<br />

be realized to allow mass production.<br />

Shanghai Motor’s first electric car<br />

the first-ever electrical sports car with a weight below 1,000 kg<br />

The performance data of the lightweight<br />

electrical sports car Elise-E that <strong>Evonik</strong><br />

<strong>Industries</strong> presented at the Car Symposium<br />

in Bochum are impressive: The vehicle<br />

weighs 950 kg, has a power of 150 kW, accelerates<br />

from 0 to 100 km/h in 4.4 seconds.<br />

The top speed is limited to 200 km/h. The<br />

purpose of exhibiting the vehicle was to show<br />

the automotive industry what can be achieved<br />

with <strong>Evonik</strong>’s expertise in chemicals.<br />

Thanks to the combined use of innovative<br />

storage technology, lightweight components,<br />

and tires with reduced rolling resistance, the<br />

sports car is the first-ever model to weigh less<br />

than 1,000 kilograms. With the exhibit,<br />

<strong>Evonik</strong> is demonstrating that electrical cars,<br />

which are currently used primarily as city vehicles,<br />

can also be part of the sports car segment.<br />

The vehicle is a combination of automotive<br />

components made with the specialty<br />

chemical components of <strong>Evonik</strong> and the<br />

sophisticated automotive technology of the<br />

British sports car manufacturer Lotus. The<br />

necessary power comes from a lithium-ion<br />

battery with the globally unique CERIO®<br />

storage technology. At the core of this battery<br />

is the ceramic high-performance separator<br />

SEPARION®, which is extremely thin and<br />

highly heat-resistant. It separates the anode<br />

reliably from the cathode and sets new standards<br />

for lithium-ion cells in terms of cycle<br />

stability, performance output, and safety by<br />

using additional components. In addition, the<br />

separator allows for the highly compact<br />

design of the battery cells, which results in<br />

high energy density at a low weight.<br />

The weight of the electrical sports car’s<br />

body has also been reduced with <strong>Evonik</strong> tech-<br />

the lightweight electrical<br />

sports car elise-e


nologies. The sandwich structure with the<br />

structural foam ROHACELL® and carbon<br />

fibers makes the body 60–70 percent lighter<br />

than a comparable steel structure. <strong>Evonik</strong><br />

applied a new resin infusion process with an<br />

innovative epoxy resin formula based on the<br />

VESTAMIN® hardener technology to manufacture<br />

it. This process allows for class-A sur-<br />

veStAMID® Htplus in mass-produced gearshift levers<br />

The high-performance polymer VESTAMID®<br />

HTplus is making gearshift levers lighter.<br />

A leading automotive OEM in Europe is now<br />

using <strong>Evonik</strong> polyphthalamides (PPA) in the<br />

serial production of a gearshift lever part. The<br />

Turkish company Eurotec AS has compounded<br />

the high-performance polymer specifically<br />

for this purpose.<br />

“Our decision in favor of VESTAMID®<br />

HTplus M1000 was based on the good processing<br />

characteristics and the outstanding<br />

mechanical properties of the material,” says<br />

Reha Gür, commercial director at Eurotec.<br />

“This allowed us to offer the OEM a customized<br />

product based on their future expectations<br />

that not only weighs less, but is also<br />

more economical than a previous solution and<br />

bringing fast production possibilities with<br />

environmentally friendly behavior.”<br />

The original gearshift lever component<br />

had been made of metal. Because of the special<br />

property profile of PPA, Eurotec<br />

switched its production to the high-performance<br />

polymer. Other arguments in favor<br />

of using PPA included high resistance to<br />

faces and reliable quality in the serial manufacture<br />

of composite automotive body parts.<br />

Side windows made of PLEXIGLAS® also<br />

contributed to the weight reduction, as they<br />

have a weight-saving potential of 40–50 percent<br />

compared to conventional mineral glass.<br />

Vehicles with less weight and high power<br />

have to be safe and sustainable on the road.<br />

lubricants and oils that are typically present<br />

in clutch systems.<br />

In addition to high chemical resistance,<br />

molded parts made from VESTAMID® HTplus<br />

offer high dimensional stability and excellent<br />

mechanical properties such as rigidity and<br />

tensile strength. The high-performance polymer<br />

is therefore ideally suited for use in conventional<br />

metal applications.<br />

High-performance plastics: Certified bio-based<br />

The VESTAMID® Terra family of polyamides<br />

from <strong>Evonik</strong> <strong>Industries</strong> has been certified as<br />

“bio-based” by independent institutes. The<br />

bio-based components have been certified<br />

according to DIN ISO 10694, 1996-08, and<br />

by the USDA’s Biopreferred® program. These<br />

official laboratories used C14 trace carbon<br />

analytics to verify that the carbon in these<br />

prod ucts originates not from petroleum, but<br />

biomass instead.<br />

The polymers are partially or entirely<br />

based on renewable feedstocks. The starting<br />

material is the castor bean (Ricinus communis)<br />

and its oil derivates, which are synthesized<br />

into monomers that form the basis of the<br />

polyamides. At present, three Terra products<br />

are available: VESTAMID® Terra HS is based<br />

on polyamide 610, which is the polycondensation<br />

product of 1,6-hexamethylene diamine<br />

(H) and 1,10-decanedoic diacid (sebacic acid<br />

– S). Sebacic acid is derived from castor oil,<br />

making Terra HS a 63 percent bio-content<br />

polymer. VESTAMID® Terra DS is based on<br />

polyamide 1010, which is the polycondensation<br />

product of 1,10-decamethylene diamine<br />

(D) and 1,10-decanedoic diacid. Both decamethylene<br />

diamine and sebacic acid are<br />

derived from castor oil, making Terra DS a 100<br />

percent bio-content polymer. The 45 percent<br />

bio-content polymer VESTAMID® Terra DD<br />

neWs<br />

In this fast-running electrical vehicle, this is<br />

ensured by special lightweight tires, which<br />

were developed with high-performance<br />

Silica ULTRASIL® and the silane Si 363® manufactured<br />

by <strong>Evonik</strong>. They reduce the rolling<br />

resistance of the tires by approx. 20 percent,<br />

leading to energy savings of about five percent.<br />

veStAMID® Htplus makes<br />

the gearshift lever component<br />

resistant to lubricants<br />

is based on polyamide 1012, which is the<br />

polycondensation product of 1,10-decamethylene<br />

diamine (D) and 1,12-dodecanedoic<br />

diacid (D).<br />

“The bio-based polyamides prove that<br />

outstanding performance and responsible<br />

sourc ing are not mutually exclusive,” says Benjamin<br />

Brehmer, business manager for biopolymers.<br />

“We impart precisely those properties<br />

to our materials which the market expects<br />

from high-performance plastics.” Thanks to<br />

their excellent chemical resistance, low water<br />

absorption, and good dimensional stability,<br />

the polyamides are suitable for a vast number<br />

of applications and processing techniques.<br />

35<br />

elements39 Issue 2|2012


36 InnoVAtIon MAnAGeMent<br />

elements39 Issue 2|2012<br />

Identifying and<br />

developing new<br />

markets<br />

In the Coatings & Additives<br />

Business Unit, the New<br />

Business Development<br />

Functional Unit generates<br />

additional, sustainable<br />

business beyond the<br />

existing business areas.


Left: One rapidly<br />

growing market that<br />

Coatings & Additives<br />

is working on in the<br />

new Business Development<br />

Functional Unit is<br />

additive manufacturing.<br />

this allows the layered<br />

construction of complex<br />

3D structures and components<br />

that are not<br />

possible or prohibitively<br />

expensive to produce<br />

by other methods<br />

right: How can we<br />

permanently protect<br />

the touch screens of<br />

tablet PCs and smartphones<br />

against unsightly<br />

scratches or fingerprints?<br />

How do we<br />

achieve a refined surface<br />

reflection that also<br />

allows the screen to<br />

be read easily? In the<br />

new Business Development<br />

Functional Unit<br />

of the Coatings & Additives<br />

Business Unit,<br />

evonik looks for innovative<br />

answers<br />

theRe Was a time when innovation was driven purely<br />

by technology. In those days, advancements in the<br />

broad R&D subject areas had a direct impact on a<br />

company’s business activities. Today, this putative<br />

causal chain from technological innovation to entrepreneurial<br />

success is not exactly broken, but it has<br />

become increasingly difficult for companies to continue<br />

growing in established markets based on individual<br />

technological innovations or an inventor’s flash<br />

of genius. “Now, innovations are often created by developers<br />

splicing together existing technologies, and<br />

thus offering new applications to satisfy market demands<br />

that have existed for a relatively short time,”<br />

says Dr. Stephan Fengler, Vice President of the New<br />

Business Development Functional Unit in the Coatings<br />

& Additives Business Unit at <strong>Evonik</strong> <strong>Industries</strong>.<br />

Such products as electronic devices with touchsensitive<br />

screens have created new needs that can be<br />

met by coatings. Before Apple’s iPhone became a<br />

smashing success, such devices existed only in certain<br />

niche markets. A growing number of users regularly<br />

use their smartphone now to send e-mail, manage<br />

appointments, shop online, and download apps,<br />

so scratches, reflections, and fingerprints on touch<br />

screens are unwelcome on an application associated<br />

in this way with design and lifestyle. Since it is a common<br />

problem, producers of smartphones and tablet<br />

PCs have suddenly become interested in finding an<br />

inexpensive, functional coating for the glossy displays.<br />

InnoVAtIon MAnAGeMent<br />

The example of the touch screen reveals how embedded<br />

future innovations can be: Innovations outside<br />

the core activities of Coatings & Additives that could<br />

mean real additional business for <strong>Evonik</strong>. Identifying<br />

and promoting this growth potential is the work of<br />

New Business Development, which is headed by Fengler<br />

and located in Darmstadt and Marl. “We explore<br />

what kinds of needs new technologies are creating<br />

on the market.”<br />

So the task of New Business Development, in association<br />

with the business unit’s Innovation Management<br />

unit, is not to figure out how to generate<br />

additional sales with individual products from the<br />

business lines, but to adopt a mindset that goes beyond<br />

business lines and is firmly rooted in innovation.<br />

New technologies<br />

generate new needs<br />

Naturally, this kind of approach succeeds only if it is<br />

designed for the intermediate to long term. “It calls<br />

for new partnerships, new partners,” says Fengler.<br />

“And this is why it’s so hard to reconcile with day-today<br />

business.”<br />

The New Business Development Functional Unit<br />

has been a part of Coatings & Additives since 2006.<br />

Over that time, its team has grown. But it has no laboratory<br />

of its own—instead, it works in close cooperation<br />

with the business lines of the business unit.<br />

The team also stays in close contact with corporate<br />

R&D, which <strong>Evonik</strong> pools in its strategic development<br />

unit Creavis, and with other business units.<br />

“New Business Development also seizes upon ideas<br />

outside the business lines and co-finances projects<br />

that, for example, are designed to run for several<br />

years and take on the kind of risk that a business line<br />

can’t assume by itself,” says Fengler. New Business<br />

Development, then, is by no means a kind of extended<br />

workbench of the business lines. Rather, it is a strategically<br />

important component of Coatings & Additives,<br />

which is investing considerable assets in the<br />

unit. The management team of the business unit manages<br />

its activities.<br />

Coatings & Additives is at home in the world of<br />

the paints, coatings, and printing inks and in the adhesives<br />

and sealing compounds industries. The business<br />

unit also develops custom-made functional polymers<br />

for lubricant applications. These product groups<br />

include crosslinkers such as expoxide resin curing<br />

agents, and crosslinkers for powdered coatings,<br />

333<br />

37<br />

elements39 Issue 2|2012


38 InnoVAtIon MAnAGeMent<br />

when barnacles, mussels, bacteria, and fungi adhere to the hulls of ships, the results<br />

are expensive. Frictional resistance and fuel consumption increase, and the hulls have to<br />

be cleaned and repainted regularly. tin-based biocidal paints are banned, and even<br />

copper-based coatings have some environmental impact. Here, substitutes are being<br />

sought that protect the environment and have an exceptionally long service life<br />

elements39 Issue 2|2012<br />

333 polymer-based coatings, and adhesive agents, as<br />

well as additives for coatings and lubricants. The<br />

employees of Coatings & Additives are active at 21<br />

production sites and technology centers worldwide.<br />

In 2011, the business unit achieved annual sales of<br />

more than €1.7 billion.<br />

For New Business Development, the most attractive<br />

applications in the field of classical coatings are<br />

those that depend on a technology for their third<br />

function, behind color and protection. These func-<br />

New functionalities sought<br />

tions can be self-cleaning or anti-fouling properties,<br />

but also heat-repelling, electrically conductive, or<br />

other properties. Often, they are based on nanostructuring<br />

that, combined with the polymer expertise of<br />

the business unit, produces thin functional layers.<br />

“With functional coatings, the innovation and the<br />

new business activity doesn’t necessarily translate<br />

into large production volumes but into the value generated<br />

by the user,” explains Fengler. This has a number<br />

of advantages that limit the risk of a project. Coatings<br />

in the range of a few nanometers require only<br />

pilot-scale production facilities, so investment costs<br />

remain manageable. “For the business unit, then, this<br />

is a new way of thinking and working,” says Fengler.<br />

In the field of crosslinking technologies, the most<br />

attractive applications are in composites for lightweight<br />

construction.<br />

whether wind turbine, sailboat, or helicopter, the importance<br />

of composites for structural components is growing, because they<br />

combine low weight with high mechanical stability. Coatings &<br />

Additives investigates how the business unit’s expertise can be<br />

used to develop high-performance composites<br />

Nine employees work in the New Business Development<br />

Functional Unit at Coatings & Additives, including<br />

project managers and those involved with<br />

conceptualizing new ideas. These are chemists, physicists,<br />

and business managers, all of whom are communicative<br />

and open to new ideas. “They are team<br />

players, who are able to establish networks across<br />

organizational boundaries,” says Fengler.<br />

Different kinds of employees are sought for a job<br />

in New Business Development, including inventors,<br />

the technically minded, entrepreneurs, project managers,<br />

developers, and marketers. The inventor embodies<br />

high creativity and scientific curiosity. The<br />

technically minded are experts in certain technologies<br />

and possess analytical skills. Willing to take risks,<br />

the entrepreneur contributes skills in networking<br />

and “selling” ideas. The “project manager” type stands<br />

out for leadership qualities and structured thought.<br />

The developer applies technical know-how and persistence.<br />

And finally, the “marketer” type contributes<br />

a broad-based understanding of the markets, as well<br />

as the ability to persuade customers.<br />

These complementary abilities are necessary for<br />

the concrete work of opening up additional business.<br />

“Because vague ideas can’t produce results,” says Fengler.<br />

Even worse, various independent studies have<br />

shown that innovation projects involve a high level<br />

of risk, and, in the end, only a small percentage of<br />

ideas actually reach their goal. But because success<br />

is easier to sell than failure, New Business Development<br />

has to know how to handle this demoralizing<br />

reality. “We acknowledge it when employees take on<br />

risky projects whose outcome is impossible to gauge,”


says Fengler. “And we don’t allow projects to die as<br />

soon as we begin to encounter problems.”<br />

Despite a culture that allows for mistakes, the<br />

projects of New Business Development are subject to<br />

strict project management. As a rule, a steering commit<br />

tee evaluates the progress and detailed plan of a<br />

project each quarter. Scenario projections, which are<br />

continuously updated, are a way to assess the potential<br />

economic benefits of a project.<br />

To generate ideas for new business, New Business<br />

Development uses the full range of tools of innovation<br />

management. “It’s really important to allow the<br />

team to come up with crazy ideas and find inspiration<br />

from outside the company,” says Fengler. External<br />

input can come from consultants, customer workshops,<br />

or student teams that receive tricky problems<br />

to solve from <strong>Evonik</strong> through its networks. Not surprisingly,<br />

this also includes market analyses.<br />

New Business Development is currently exploring<br />

crowdsourcing: The team is using Internet-based networks<br />

of experts to clarify problems that cannot be<br />

solved based on existing know-how. “Oftentimes, this<br />

is a question of how experts assess the potential of a<br />

certain technology for a specific application,” explains<br />

Fengler.<br />

For an idea in New Business Development to become<br />

a project, it must show sufficient business potential.<br />

“We then develop a vision of how to expand<br />

a market, and pour over this repeatedly as time goes<br />

on,” says Fengler. If the project steering committee<br />

approves it, employees first develop a concept and<br />

then follow up with one or more laboratory tests.<br />

New Business Development also involves colleagues<br />

Each new idea is tested<br />

from relevant business lines at this stage, wherever<br />

possible. “Later on, if a business line is interested in<br />

taking on a project in its sphere of responsibility, it<br />

can do so,” explains Fengler. “Otherwise, we manage<br />

the projects all the way to market launch.”<br />

New Business Development is currently managing<br />

about a dozen preliminary projects—projects that are<br />

in the evaluation and conception phase, and in which<br />

colleagues from the operative units of the business<br />

unit are already involved. At the same time, New<br />

Business Development is managing a few projects that<br />

already have significant development resources.<br />

“Some of these,” says Fengler, “will hopefully bear<br />

fruit over the next five to ten years.” 777<br />

InnoVAtIon MAnAGeMent<br />

dr. stephan Fengler heads the New Business<br />

Development Functional Unit in <strong>Evonik</strong>’s Coatings &<br />

Additives Business Unit. After studying chemical<br />

engineering at the Mendeleyev University of Chemical<br />

Technology of Russia and earning his doctorate at the<br />

Technical University of Berlin in the Department of<br />

Polyme ri zation Technology, he began his career at<br />

Röhm GmbH in Darmstadt in 1995. Fengler held several<br />

positions in the Research, Production, and Marketing<br />

unit before assuming his current duties in 2011.<br />

+49 6151 18-4974, stephan.fengler@evonik.com<br />

39<br />

elements39 Issue 2|2012


40 desIGnInG WItH PoLYMeRs<br />

elements39 Issue 2|2012<br />

The world’s museums house priceless works of art.<br />

New PLEXIGLAS® Optical HC put these exhibits in the<br />

best possible light, permanently protecting them from<br />

damage and depreciation.<br />

YeaR afteR YeaR, millions of people flock to museums to marvel<br />

at the artifacts of past cultures or the works of contemporary<br />

artists: Drawings and paintings, sculptures and documents,<br />

historical garments, consumer items, and weapons. Few of these<br />

visitors are aware, though, that the professional protection<br />

of the exhibits is just as vital as their presentation. Indeed,<br />

<strong>Evonik</strong> is making a major contribution here. The company’s new<br />

PLEXIGLAS® Optical HC, with its abrasion-resistant coating,<br />

protects priceless exhibits against mechanical or chemical damage,<br />

prevents them from yellowing, presents them without any<br />

color distortion, and makes it possible to individually design display<br />

cabinets, boxes, protective panels, and transport packaging.<br />

One of the greatest challenges in exhibiting paintings, documents,<br />

and art treasures is in achieving the optimal lighting. Ideally,<br />

structures, colors, and details should be seen undistorted,<br />

but the UV radiation in natural light often damages historical<br />

material. This causes sketches, watercolors, and garments to lose<br />

their original colors, pages of books to turn yellow and thin out,<br />

and canvases and other materials to become brittle.<br />

no color distortion<br />

Protective measures<br />

for treasures<br />

This is why PLEXIGLAS® contains an integrated chemical UV<br />

filter that filters out damaging high-energy radiation. At the same<br />

time the material, with a transmission of 92 percent, is highly<br />

transparent in the visible region of the spectrum, allowing<br />

a clear and sharp view of the details and the structures of the<br />

exhibits with colors remaining true: The polymer avoids color<br />

distortion such as caused by, for example, the greenish tinge of<br />

float glass.<br />

A large number of archives and museums have already discovered<br />

this amazing plastic for themselves. The U.S. National<br />

Archive transported seminal U.S. historical documents in cus-<br />

tom-made PLEXIGLAS® display cases throughout the country<br />

for a traveling exhibition. The DeBeers Diamond Museum in<br />

Johannesburg, South Africa, displays historical documents in<br />

non-reflecting PLEXIGLAS®. In the Landtag (parliament) of the<br />

German state of Hesse, sketches by the architect Georg Moller<br />

were exhibited behind PLEXIGLAS® to mark the 150th anniversary<br />

of his death. The slight curve of the glazing showed off the<br />

sketches to best advantage.<br />

But transmission and UV absorption are not the only requirements<br />

for the professional protection of museum treasures. Visitors<br />

leave behind their tracks: Fingerprints, sweat, and abrasion<br />

due to zippers or handbags.<br />

This is why the new PLEXIGLAS® Optical HC is equipped<br />

with a special surface coating, ensuring excellent resistance to<br />

mechanical impact and cleaning chemicals. This protects display<br />

cases and picture glazing against distracting chips and scratches,<br />

and the surface quality remains unchanged even with heavy<br />

wear. A comparison with uncoated acrylic shows that the coating<br />

increases abrasion resistance by a factor of ten, and more<br />

than doubles the hardness.<br />

well protected against chemical attack<br />

Fingerprints and mechanical impact are unavoidable when<br />

visitors come close to exhibits. Targeted chemical attacks on<br />

artworks are risks of an entirely different dimension—but<br />

PLEXIGLAS® Optical HC offers effective protection even against<br />

these. Thanks to its surface coating, the material is resistant not<br />

only to abrasion but also to chemicals. This makes it easier for<br />

galleries and museums to meet their generally very stringent<br />

security requirements.<br />

But protecting artworks does not begin in the museum or<br />

gallery. The art market is booming, and touring exhibitions give


At an exhibition in Darmstadt, the gallery owner opted for<br />

PLeXIGLAS® Optical HC picture glazing to allow visitors<br />

to view the pictures without color distortion (above).<br />

For an exhibition of American historical documents that was<br />

toured through the country, the U.S. national Archive<br />

chose PLeXIGLAS® display cases because they offer protection<br />

and are highly transparent and lightweight (below)<br />

art lovers access to unique treasures almost all over the world.<br />

Light, yet break-resistant packaging is needed to transport them.<br />

Conventional float glass is heavy and breaks easily. Acrylic has<br />

a break resistance that is higher by a factor of eleven, and is only<br />

half as heavy. This offers key advantages for transport, and also<br />

in the presentation of large and heavy exhibits.<br />

PLEXIGLAS® Optical HC can be produced in thicknesses<br />

of 1.5 to 16 millimeters, with variants individually adapted to<br />

customers’ wishes: Panels, for example, may be transparent or<br />

colored, and surfaces matted or antiglare. The material is<br />

desIGnInG WItH PoLYMeRs<br />

produced under clean-room conditions at a new combined<br />

extrusion and coating line at the Weiterstadt site, which came<br />

on-stream last year. Extruded PLEXIGLAS® panels are finished<br />

here with a specially developed coating that provides an<br />

abrasion- and chemical-resistant surface, with process, substrate,<br />

and coating being optimally coordinated.<br />

Great design freedom<br />

Lastly, the material offers customers and artists vast freedom of<br />

design: The material can be cut, drilled, sawed, rolled, scored<br />

and broken, laser processed, and digitally printed. This allows it<br />

to be used for shapes and artworks that cannot be realized in<br />

glass. Individual panels can be glued together. An adhesive<br />

developed especially for this purpose creates by chemical reaction<br />

a high-strength and virtually invisible bond. Moreover,<br />

PLEXIGLAS® Optical HC can be processed like standard<br />

PLEXIGLAS®. However, line bending and thermoforming are not<br />

suitable for machining abrasion-resistant coated PLEXIGLAS®<br />

Optical HC because these processes could lead to damage or detachment<br />

of the coating. The uncoated side of the panel, like<br />

extruded acrylic, forms a strong and reliable adhesive bond.<br />

Its excellent mechanical and optical properties coupled with<br />

easy processability make abrasion-resistant PLEXIGLAS®<br />

Optical HC of interest for a wide range of applications. In addition<br />

to the exhibiting and transporting of artworks, it is used in<br />

electronic displays, signage, furniture making, shopfitting, and<br />

exhibition booth construction, as well as for industrial glazing,<br />

for example to protect high-value machines and systems, and for<br />

sectional doors. To put it briefly, PLEXIGLAS® Optical HC promises<br />

the optimal solution for all applications calling for the transparency<br />

and durability of glass combined with the lightness and<br />

break resistance of a plastic. 777<br />

41<br />

elements39 Issue 2|2012


42 neWs<br />

Student project presented in Marl<br />

A group of students from the Technical University<br />

Dortmund has created plans for a production<br />

plant for highly pure 1-butene at<br />

Marl Chemical Park. The students received<br />

support for their project assignment from<br />

<strong>Evonik</strong>’s Advanced Intermediates Business<br />

Unit’s Innovation Management.<br />

Students taking the course in bio and<br />

chemical engineering at the TU Dortmund<br />

are required to take part in a group project<br />

assignment to conceptualize a specialty chemicals<br />

plant. They have only six weeks to complete<br />

their assignment, which entails composing<br />

the process-related design and defining<br />

the dimensions of a facility, with its columns,<br />

reactors, receptacles, heat exchangers, pumps,<br />

and compressors, as well as devising layouts,<br />

optimizing energy utilization at their facility,<br />

and doing the cost and economic-feasibility<br />

accounting.<br />

It has become something of a tradition for<br />

the Innovation Management team at the<br />

elements39 Issue 2|2012<br />

Jason Chan (second<br />

from left), head of the<br />

raffinate facility,<br />

detailed Performance<br />

Intermediate’s integrated<br />

C4 operations<br />

Advanced Intermediates Business Unit to put<br />

forward its proposal for the project to the<br />

university’s Technical Chemistry Chair, Prof.<br />

Arno Behr. This involvement adds to the practical<br />

character of the assignment, while it also<br />

serves as a proverbial bridge between academia<br />

and industry. What’s more, the collaboration<br />

allows the students to subsequently<br />

make the comparison between their finished<br />

theoretical concept, as devised on the<br />

basis of information available to them from<br />

literary sources, with actual facilities operating<br />

in practice at Marl Chemical Park.<br />

In 2011 the Innovation Management<br />

team’s project proposal was for the conceptualization<br />

of a facility for the manufacture of<br />

highly pure 1-butene. The Performance Intermediates<br />

Business Line runs an integrated C4<br />

facility at the Marl site. Aside from butadienes,<br />

MTBE, isononanol, and diisononyl<br />

phthalate (DINP), a plasticizer, this, the only<br />

plant of its kind anywhere in the world, also<br />

More than 400 offshore pipes with veStAMID® nrG<br />

VESTAMID® NRG 1001, a high-performance<br />

polymer, can already be found in a total of<br />

over 800 kilometers of pipeline. The polyamide<br />

12 made by <strong>Evonik</strong> <strong>Industries</strong> has gone<br />

into the making of more than 400 unbonded<br />

flexible pipes to service the oil production<br />

industry. Oil companies have been using<br />

these pipes in their offshore projects for<br />

years now.<br />

What has made the polyamide 12 molding<br />

compound so popular are its superior properties<br />

over those of other polyamides used as<br />

barrier layers in flexible pipes. Together with<br />

Wellstream International Limited, <strong>Evonik</strong><br />

conducted intensive testing to demonstrate<br />

compliance with the international norms API<br />

17J for flexible risers and ISO 13628-2. The<br />

tests praised the creep performance, ductility,<br />

thermal expansion, methanol compatibility,<br />

and hydrolysis resistance.<br />

The molding compound has since been used<br />

commercially for the manufacture of flexible<br />

pipes. Specially developed VESTAMID® NRG<br />

combines its technical advantages with<br />

extraordinarily consistent product quality,<br />

which ensures outstanding processability and<br />

thus reduces setup times, scrap, and the risk<br />

of extrusion faults.<br />

For decades now, <strong>Evonik</strong> has been a<br />

leader in the development and marketing of<br />

high-grade polyamide compounds for line<br />

systems in motor vehicles. This high degree<br />

of expertise in the development of extrusion<br />

compounds has now been carried over to<br />

molding compounds for the thick-walled piping<br />

systems which, thanks to their advantages<br />

over existing systems, are increasingly<br />

coming into use in the oil and gas industries.<br />

Flexible: Offshore pipes<br />

with veStAMID® nrG<br />

makes 1-butene. 1-butene is a key comonomer<br />

used predominantly to make high-grade<br />

polyethylene and poly-1-butene.<br />

The students executed their group assignment<br />

in the 2011/2012 winter semester. They<br />

then visited Marl Chemical Park for a guided<br />

tour by Jason Chan, head of the raffinate facility,<br />

who detailed the integrated C4 operations<br />

to them. This group of aspiring young<br />

academics proved to be particularly fascinated<br />

by the two 80- meter-high columns at the<br />

heart of 1-butene production.<br />

The group was then invited to present its<br />

own concept to an audience comprising staff<br />

members from the business unit’s Production,<br />

Engineering, and Research teams and from<br />

Process Technology and Engineering. The<br />

students impressed this audience with the<br />

sound quality of their completed work. The<br />

discussion which followed addressed the differences<br />

apparent between the students’ concept<br />

and a real facility and also brought forth<br />

a number of tips concerning practical considerations.<br />

The participants all agreed that educational<br />

elements of this kind on the student<br />

curriculum help to make studies more practice-oriented<br />

as well as providing a platform<br />

for contact between industry and students.<br />

Thus, the scheme sees the Innovation Manage<br />

ment unit making a valuable contribution<br />

to <strong>Evonik</strong>’s em ployer branding endeavors.


Creavis starts with new BISOn project<br />

The Biotechnological Synthesis of Carbo xyamines and Carboxyalcohols<br />

Project, or “BISON” for short, was launched at the end of<br />

last year. Creavis Technologies & Inno va tion’s Science-to-Business<br />

Center (S2B) Bio technology is in charge of the project, the aim of<br />

which is to use biotechnology to modify molecules that could be used<br />

for polymer building blocks or fine chemicals in the future. Creavis<br />

is the strategic research and development unit of <strong>Evonik</strong>.<br />

Both renewable and petroleum-based raw materials are used as<br />

starting materials in the BISON project. Customized microorganisms<br />

then convert and modify these materials to produce the desired end<br />

product. The actual modification of the molecules is done by selective<br />

oxidation and amination–or what is also known as biotransformation.<br />

BISON involves experts from the fields of microbiology, protein<br />

engineering, and process development. Working with the Tech nical<br />

Credits<br />

Publisher<br />

<strong>Evonik</strong> <strong>Industries</strong> AG<br />

Corporate Innovation<br />

Strategy & Management<br />

Rellinghauser Straße 1–11<br />

45128 Essen<br />

Germany<br />

scientific Advisory Board<br />

Dr. Norbert Finke<br />

Corporate Innovation<br />

Strategy & Management<br />

norbert.finke@evonik.com<br />

editor in Chief<br />

Dr. Karin Aßmann<br />

<strong>Evonik</strong> Services GmbH<br />

Editorial Department<br />

karin.assmann@evonik.com<br />

Contribution editors<br />

Christa Friedl<br />

Thomas Lange<br />

Michael Vogel<br />

neWs 43<br />

University of Munich (Germany) and the S2B Center Biotechnology,<br />

the consortium will develop the microbial cell factory for a future<br />

generation of production processes that promise to be more sustainable<br />

than the former process in the chemical in dustry. The German<br />

Federal Ministry of Edu cation and Research (BMBF) is funding the<br />

project, which will run for three years.<br />

This project owes its success to the Car boxyFun project, which did<br />

well and was also funded by the BMBF. In the future, BISON will take<br />

the findings from Car boxyFun and transfer them to other biotechnological<br />

processes so that the microbial cell factory can become reality.<br />

Biotechnological processes are gaining in popularity in the chemical<br />

industry. One of the reasons for this is that the biotech processes<br />

involve lower investment costs than chemical processes. This means,<br />

for example, that multi-level production stages can be mapped in a<br />

single bacterium cell–the microbial cell factory.<br />

Photos<br />

<strong>Evonik</strong> <strong>Industries</strong><br />

Karsten Bootmann<br />

Dirk Bannert<br />

Martin Daniels<br />

Dieter Debo<br />

Stefan Wildhirt<br />

Eurotec (p. 35)<br />

Wellstream (p. 42)<br />

Fotolia.com/Uwe Annas (p. 2, 11)<br />

Corbis/Imaginechina (p. 6)<br />

Fotolia.com/lunamarina (p. 38)<br />

Fotolia.com/mirpic (p. 38)<br />

Fotolia.com/Berni (p. 39)<br />

Fotolia.com/graham tomlin (p. 39)<br />

A glance into a<br />

laboratory of the<br />

Creavis’ Science-<br />

to-Business Center<br />

Biotechnology in<br />

Marl<br />

design<br />

Michael Stahl, Munich (Germany)<br />

Printed by<br />

Laupenmühlen Druck GmbH & Co. KG<br />

Bochum (Germany)<br />

Reproduction only with permission<br />

of the editorial office<br />

<strong>Evonik</strong> <strong>Industries</strong> is a worldwide<br />

manufacturer of PMMA products sold<br />

under the PLEXIGLAS® trademark<br />

on the European, Asian, African, and<br />

Australian continents and under the<br />

ACRYLITE® trademark in the Americas<br />

elements39 Issue 2|2012


Real problems, real answers. The only way to find<br />

quick solutions is by openly addressing uncomfortable<br />

truths. That’s why we make frank and transparent<br />

communication an integral part of cooperation with<br />

our customers. We join together in open dialog<br />

to devise sustainable, step-by-step solutions. If you’d<br />

like to know more good reasons for working with us<br />

in a spirit of trust, go to www.evonik.com/pharma.<br />

Working with us is no game of chance<br />

but transparent right from the start.<br />

We love your problems.

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