Development of Best Practices for Ship Recycling Processes

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TABLE A.3.1 CONTD.. Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical Serious Skin Contact : attention. Inhalation : Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or Serious Inhalation : waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Breathing If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. Other measures are usually unnecessary. (NIOSH, 2003) Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Ingestion : Serious Ingestion Not available. Eye contact: Immediately flush the eye with water. If irritation persists, call for medical help. Skin contact: Wash off with soap and water. If inhaled: Call for medical help. Emergency Section 5: Fire & Explosion Data Fire Hazards in Presence of Not applicable. Various Substances Explosion Hazards in Risks of explosion of the product in presence of mechanical impact: Not available. Presence of Various Substances Risks of explosion of the product in presence of static discharge: Not available. Not applicable Fire Fighting Media and Instructions Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Keep run-off water out of sewers and water sources. Fire Fighting Special Remarks on Fire Not available Hazards Special Remarks on Not available Explosion Hazards Fire Hazard Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. Section 6: Accidental Release Measures Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at a concentration level above TLV. Check Large Spill TLV on the MSDS and with local authorities. Keep material out of water sources and sewers. Land spill: Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water. Dike surface flow using soil, sand bags, foamed polyurethane, or Non-fire response foamed concrete. Water spill: Use natural barriers or oil spill control booms to limit spill travel. (AAR, 2003) Section 7 Handling and Storage Keep locked up Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes Carcinogenic, teratogenic or mutagenic materials should be stored in a separate locked safety storage cabinet or room. There is nowadays almost never a need for asbestos in the laboratory; good alternatives exist for all the applications to which asbestos used to be put. If it is present at all, asbestos will probably be in the form of asbestos cement, used perhaps as an oven lining. Precautions Storage Safe handling It is essential that asbestos is not cut, drilled or machined, since these actions release fibres into the air which are then readily inhaled. 178
TABLE A.3.1 CONTD.. Section 8 Exposure Controls/Personal Protection Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below Engineering Controls recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Personal Protection Gloves. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used Personal Protection in Case to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist of a Large Spill BEFORE handling this product. Protective equipment Protective equipment should not be necessary, since you should not be in contact with asbestos! Skin: Wear appropriate personal protective clothing to prevent skin contact. Eyes: Wear appropriate eye protection to prevent eye contact. Protective Clothing Wash skin: The worker should wash daily at the end of each work shift. Remove: No recommendation is made specifying the need for removing clothing that becomes wet or contaminated. Change: Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premise. (NIOSH, 2003) Section 9 Physical and Chemical Properties Physical state and Solid. appearance pH (1% soln/water) Not applicable. Boiling Point Decomposes (NIOSH, 2003) Melting Point Melting Point: 1112.0 ° F (Decomposes) (NIOSH, 2003) Specific Gravity Weighted average: 2.62 (Water = 1), varies, depending upon form Vapor Pressure Not applicable. Vapor Pressure 0.0 mm Hg (approx) (NIOSH, 2003) Water/Oil Dist. Coeff. The product is insoluble in water and oil. Dispersion Properties Is not dispersed in cold water, hot water. Solubility Insoluble in cold water, hot water, methanol, diethyl ether, n-octanol. Form fibrous solid which may be white, grey, brown or blueish Stability Stable Molecular Weight Varies (NIOSH, 2003) AEGL data unavailable ERPG data unavailable TEEL-1 0.075 mg/m3 TEEL-2 0.5 mg/m3 TEEL-3 2.5 mg/m3 (SCAPA, 2008) IDLH A potential human carcinogen. (NIOSH, 2003) Section 10 Stability and Reactivity Data Stability The product is stable. Corrosivity: Non-corrosive in Non-corrosive in presence of glass. presence of glass. Polymerization No. Reactivity Profile ASBESTOS minerals are generally unreactive. Section 11 Toxicological Information Routes of Entry Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals Not available 179
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DEVELOPMENT OF BEST PRACTICES FOR S
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DECLARATION This is to certify that
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ACKNOWLEDGEMENTS Research work lead
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ABSTRACT Ship recycling has been co
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ase and source of expertise require
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2.5.1 Engineering Perspective……
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5.6 Ship Dismantling Processes in B
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6.7.4 Product Standardisation……
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i LIST OF TABLES Table Title Page 2
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Figure Title Page 5.18 Window Showi
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ABBREVATIONS ACGIH American Confere
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1.1 GENERAL CHAPTER 1 INTRODUCTION
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final one is nothing but decay and
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CHAPTER 2 SHIP RECYCLING PROCESS 2.
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This will enable the ship owners to
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Fig. 2.4 Dismantling of Obsolete Sh
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Oil Insulation mixture Pumped out P
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2.4 SHIP RECYCLING PROCESSES IN VAR
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mechanism to manage ship recycling
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engineering philosophy which tries
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various types of waste oil pollutan
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destined towards the dismantling ya
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holders in global maritime industri
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2.5.4.4 Market Features of Recycled
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comprehensive ship recycle plan to
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Various options regarding recycling
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environmentally sound ship recyclin
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can be considered as a well focused
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egarding ship recycling in UK. Thes
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vessels, dismantling yards and proc
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Though ship recycling has been acce
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ii) Rules and regulations regarding
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approach tries to project demand ba
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CHAPTER 5 DEVELOPMENT OF KNOWLEDGE
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The prime modules of an expert syst
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quality of knowledge representation
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okers are, just agents seen in thes
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system is not going to show remarka
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and lines of the system have been s
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Out of these types of expert system
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INPUT Fig. 5.3 Information Model of
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5.6.3 Mooring /Sliding /Securing Du
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Application of a proper marking pla
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out of the recycled products may ad
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These important operations involved
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Sl. No 1 2 3 4 5 6 7 8 Table 5.3 Ac
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Table 5.3 contd.. Sl. No Activity C
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Table 5.3 contd.. Sl. No Activity C
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Table 5.3 contd.. Sl.No Activity Cl
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Table 5.3 contd.. Sl.No 174 175 176
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Table 5.3 contd.. Sl.No 192 193 194
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5.7.3 Identification and Classifica
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ecycling report generation exercise
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Login / Member Registration Provisi
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main web interface input screen of
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The input consists mainly of two ty
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handling of onboard materials to be
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egarding editing/adding/deleting of
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Fig. 5.25 SRR Screen Showing Select
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Upload ATTACHMENTS Associated With
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2. Expenses for beaching the ship a
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Fig 5.32 Schematic Diagram of Funct
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6.1 INTRODUCTION CHAPTER 6 DESIGN F
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. Physical product features c. Life
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well beyond the new shipbuilding ac
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‘systematic ship recycling engine
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for the end of life activities of t
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These guidelines by IMO are not gen
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Table 6.3 Roles and Responsibilitie
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Page 163 and 164: stages of design. Functional and ec
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Page 167 and 168: Steel Sheet is usually found in sup
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Page 171 and 172: of their vessel and a ‘ represent
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Page 175 and 176: 6.6.6 Maintenance of Green Safety I
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Page 179 and 180: 6.8 APPLICATIONS OF DESIGN FOR SHIP
Page 181 and 182: methodology involves generation, co
Page 183 and 184: 7.1 SUMMARY CHAPTER 7 SUMMARY AND C
Page 185 and 186: CUTTING PLAN has to be made a manda
Page 187: 7.4 SCOPE OF FUTURE WORK a) Develop
Page 190 and 191: 11. Cole, R. J Emerging trends in b
Page 192 and 193: 32. MARISEC (2001) International Ch
Page 195 and 196: APPENDIX 1 DETAILS OF DISMANTLING O
Page 197 and 198: A 1.4.2 Equipment and Manning Cutti
Page 199 and 200: APPENDIX 2 SHIP RECYCLER RECOMMEDER
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Page 205 and 206: A 2.6 Linking of RULES to QUESTIONS
Page 207 and 208: APPENDIX-3 PART OF SHIP RECYCLING R
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