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Gas Laws

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SAMPLE PROBLEM 4<br />

A sample of hydrogen gas has a volume of 65.0 mL at a pressure<br />

of 0.992 atm and a temperature of 16°C. What volume<br />

will the hydrogen occupy at 0.984 atm and 25°C?<br />

SOLUTION<br />

1. ANALYZE<br />

• What is given in the the original volume, pressure, and<br />

problem? temperature of the hydrogen, and<br />

the new pressure and temperature of<br />

the hydrogen<br />

• What are you asked to find? the volume at the new temperature<br />

and pressure<br />

Items Data<br />

Original volume, V 1<br />

Original pressure, P 1<br />

Original temperature, t 1<br />

Original Kelvin temperature, T 1<br />

New volume, V 2<br />

New pressure, P 2<br />

New temperature, t 2<br />

New Kelvin temperature, T 2<br />

2. PLAN<br />

• What steps are needed to Rearrange the combined gas law<br />

calculate the new volume of equation to solve for V 2, substitute<br />

the gas? known quantities, and calculate.<br />

128 Chapter 11<br />

1<br />

P1V1 <br />

T1 P 2 V 2<br />

T 2<br />

to solve for V2 ,<br />

multiply both sides of<br />

the equation by T2 /P2 to<br />

isolate V2 insert data and solve for V2 65.0 mL<br />

0.992 atm<br />

16°C<br />

(16 273) K 289 K<br />

? mL<br />

0.984 atm<br />

25°C<br />

(25 273) K 298 K<br />

2<br />

T2P1V1 V2 P2T1 3. COMPUTE<br />

Substitute data for the terms of the equation, and compute the result.<br />

V 2 T 2P 1V 1<br />

P 2T 1<br />

298 K 0.992 atm 65.0 mL H 2<br />

0.984 atm 289 K<br />

67.6 mL H 2

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