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Gas Laws

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• What are you asked to find? the pressure of oxygen collected<br />

Items Data<br />

Total pressure, P total<br />

92.3 kPa<br />

Temperature 16°C<br />

Vapor pressure of water 1.82 kPa<br />

at 16°C, *<br />

P H2O<br />

Pressure of collected O 2, ? kPa<br />

* determined from Table 11-1<br />

P O2<br />

2. PLAN<br />

• What step is needed to Use Dalton’s law of partial prescalculate<br />

the pressure of the sures to determine the pressure of<br />

oxygen collected? the oxygen alone in the container.<br />

Use the following equation to determine the pressure of oxygen<br />

alone.<br />

3. COMPUTE<br />

PO2 Ptotal PH2O vapor 92.3 kPa 1.82 kPa 90.5 kPa<br />

4. EVALUATE<br />

• Are the units correct? Yes; the units should be kPa.<br />

• Is the number of significant Yes; the number of significant figfigures<br />

correct? ures is correct because the total<br />

pressure was given to one decimal<br />

place.<br />

• Is the answer reasonable? Yes; the pressure of the collected<br />

oxygen and the water vapor add up<br />

to the total pressure of the system.<br />

PRACTICE<br />

P O2 given<br />

P total from Table 11-1<br />

P H2O vapor<br />

1. A chemist collects a sample of H 2S(g) over water<br />

at a temperature of 27°C. The total pressure of the<br />

gas that has displaced a volume of 15 mL of<br />

water is 207.33 kPa. What is the pressure of the<br />

H 2S gas collected? ans: 203.76 kPa<br />

<strong>Gas</strong> <strong>Laws</strong> 131

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