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Gas Laws

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space; add the partial pressures of<br />

both gases when they occupy the<br />

whole space.<br />

16. 285 mL<br />

17. 89 cm3 The pressure in the bottle on<br />

top of the mountain is the sum of<br />

at the temperature of the<br />

P O2 dry<br />

P H2O vapor<br />

mountaintop and at the<br />

temperature on top of the mountain.<br />

18. 59 cm 3<br />

Solve the equation:<br />

V total/293 K <br />

(V total 0.20 cm 3 )/294 K<br />

19. 118 kPa<br />

20. 935 mL<br />

21. 26.4 kL<br />

22. 3.76 atm<br />

23. 115 mL<br />

24. 10.9 atm<br />

12 Ideal <strong>Gas</strong> Law<br />

1. a. 34.2 mol<br />

b. 6.68 10 3 kPa<br />

c. 148°C<br />

d. 1.1 10 5 L<br />

2. a. 55.9 g/mol<br />

b. 0.111 g<br />

c. 4.46 10 2 L<br />

d. 0.846 atm<br />

e. 391 g/mol<br />

3. 2.71 10 3 L<br />

4. a. 48.4 g/mol<br />

b. 9.38 g/L<br />

c. 6°C<br />

d. 2.24 atm or 227 kPa<br />

5. 33.7 atm<br />

6. 3.06 g/L<br />

7. 663 g/mol<br />

8. 204 L<br />

9. 0.0101 mol ethane<br />

10. 5.16 g NO<br />

11. 77.0% yield<br />

12. 10.5 g/mol<br />

13. 171 g/mol<br />

14. 6.55 atm<br />

15. 326 kPa<br />

16. 479 K or 206°C<br />

17. 1210 L at 75°C; 1620 L at 8°C<br />

18. 1.11 10 4 kPa<br />

19. 168 mL<br />

20. 3.85 10 3 L<br />

21. 4.05 10 3 L<br />

22. 29.0 g/mol<br />

292 ChemFile Mini-Guide to Problem Solving<br />

13 Stoichiometry<br />

of <strong>Gas</strong>es<br />

1. a. 19.0 mL N 2<br />

b. 4.26 10 4 L NH 3<br />

c. 896 L NH 3<br />

d. 899 L H 2<br />

2. a. 23 L H 2O<br />

b. 1070 L O 2<br />

c. 326 mL CO 2<br />

d. 25.2 L total products<br />

3. 1550 L O 2 at STP<br />

4. 0.894 L SiF 4<br />

5. a. 3.36 L H 2<br />

b. 488 g Fe<br />

c. 112 L H 2<br />

6. 0.013 L H 2 or 13 mL H 2<br />

7. 7.50 L O 2 at STP; 4.14 g diethyl<br />

ether<br />

8. a. 3.36 L N 2; 6.72 L CO 2; 5.60 L<br />

H 2O; 0.560 L O 2<br />

b. 15.0 L total volume all gases<br />

9. 0.894 g NH 4NO 3<br />

10. 2.19 L PH 3<br />

11. 1.2 10 3 kg Al; 7.4 10 5 L HCl<br />

12. 7.08 10 7 L NH 3<br />

13. 3.77 g BaO 2<br />

14. 5.85 L Cl 2<br />

15. 28.0 kL NH 3; 28.0 kL NO 2 overall<br />

reaction is: 4NH 3 7O 2 :<br />

4NO 2 6H 2O<br />

16. 18.2 g KClO 3<br />

17. a. 38 000 L NH 3<br />

b. 1.30 10 5 g NaHCO 3<br />

c. 12.3 L NH 3<br />

d. 5.60 10 3 L<br />

18. a. 9.93 L CO 2<br />

b. 1.63 L O 2<br />

c. 26.0 L CO 2<br />

d. 3.29 10 3 g H 2O<br />

14 Concentration<br />

of Solutions<br />

1. a. 60.0 g KMnO 4; 440.0 g H 2O<br />

b. 220 g BaCl 2<br />

c. 457 g glycerol<br />

d. 0.0642 M K 2Cr 2O 7<br />

e. 1.27 m CaCl 2<br />

f. 0.234 g NaCl<br />

g. 541 g glucose; 2040 g total<br />

2. 10.6 mol H 2SO 4<br />

3. 0.486 m linoleic acid

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