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Gas Laws

Gas Laws

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SAMPLE PROBLEM 1<br />

A sample of nitrogen collected in the laboratory occupies a<br />

volume of 725 mL at a pressure of 0.971 atm. What volume<br />

will the gas occupy at a pressure of 1.40 atm, assuming the<br />

temperature remains constant?<br />

SOLUTION<br />

1. ANALYZE<br />

• What is given in the the original volume and pressure of<br />

problem? the nitrogen sample, and the new<br />

pressure of the sample<br />

• What are you asked to find? the volume at the new pressure<br />

Items Data<br />

Original pressure, P 1<br />

Original volume, V 1<br />

New pressure, P 2<br />

New volume, V 2<br />

0.971 atm<br />

725 mL N 2<br />

1.40 atm<br />

? mL N 2<br />

2. PLAN<br />

• What steps are needed to Rearrange the Boyle’s law equation<br />

calculate the new volume of to solve for V 2, substitute known<br />

the gas? quantities, and calculate.<br />

1<br />

P1V1 P2V2 to solve for V2 ,<br />

divide both sides of<br />

the equation by P2 to<br />

isolate V2 insert data and solve for V2 2<br />

P1V1 V2 <br />

P2 3. COMPUTE<br />

Substitute data for the terms of the equation, and compute the result.<br />

V 2 P 1V 1<br />

P 2<br />

0.971 atm 725 mL N 2<br />

1.40 atm<br />

503 mL N 2<br />

4. EVALUATE<br />

• Are the units correct? Yes; units canceled to give mL N2. • Is the number of significant Yes; the number of significant figfigures<br />

correct? ures is correct because data were<br />

given to three significant figures.<br />

• Is the answer reasonable? Yes; pressure increased by about 1/3,<br />

volume must decrease by about 1/3.<br />

<strong>Gas</strong> <strong>Laws</strong> 119

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