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Gas Laws

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Solve for V 2 as in Sample Problem 4.<br />

3. COMPUTE<br />

Determine the pressure of chlorine alone.<br />

Calculate the volume of Cl 2 at STP.<br />

4. EVALUATE<br />

• Are the units correct? Yes; the units canceled leaving the<br />

correct units, L.<br />

• Is the number of significant Yes; the number of significant figfigures<br />

correct? ures is correct because the data were<br />

given to a minimum of three significant<br />

figures.<br />

• Is the answer reasonable? Yes; the pressure decreased, so the<br />

volume had to increase.<br />

PRACTICE<br />

V 2 <br />

calculated<br />

above given<br />

P1 T2V1 P 2 T 1<br />

given<br />

P 1 P total P H2O vapor 156.5 kPa 2.19 kPa 154.3 kPa<br />

154.3 kPa 273 K 1.45 L<br />

101.3 kPa 292 K<br />

2.06 L<br />

In each of the following problems, assume that the molar quantity of gas<br />

does not change.<br />

1. Some hydrogen is collected over water<br />

at 10°C and 105.5 kPa pressure. The<br />

total volume of the sample was 1.93 L.<br />

Calculate the volume of the hydrogen<br />

corrected to STP. ans: 1.92 L<br />

2. One student carries out a reaction that<br />

gives off methane gas and obtains a total<br />

volume by water displacement of 338 mL<br />

at a temperature of 19°C and a pressure<br />

of 0.9566 atm. Another student does the<br />

identical experiment on another day at<br />

a temperature of 26°C and a pressure ans: The second student<br />

of 0.989 atm. Which student collected collected more<br />

more CH4? CH4. <br />

V 2<br />

<strong>Gas</strong> <strong>Laws</strong> 133

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