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Burrard Inlet Environmental Indicators Report - the BIEAP and ...

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<strong>Burrard</strong> <strong>Inlet</strong> <strong>Environmental</strong> <strong>Indicators</strong> <strong>Report</strong> February 2008<br />

Results <strong>and</strong> Trends<br />

Copper <strong>and</strong> PCB levels are <strong>the</strong> selected<br />

indicators; however, many o<strong>the</strong>r contaminants<br />

also enter <strong>Burrard</strong> <strong>Inlet</strong>, where <strong>the</strong>y may have a<br />

negative effect on marine life. Water <strong>and</strong><br />

sediment are also monitored for pH (acidity or<br />

alkalinity), dissolved oxygen, suspended solids,<br />

turbidity, o<strong>the</strong>r metals (arsenic, cadmium,<br />

chromium, lead, mercury, nickel <strong>and</strong> zinc)<br />

bacteria (total coliforms, enterococci), chlorineproduced<br />

oxidants, cyanide, ammonia,<br />

hydrogen sulphide, phenol, chlorophenol,<br />

styrene, tributyl tin, 1,2-dichloroethane <strong>and</strong><br />

polycyclic aromatic hydrocarbons (PAHs).<br />

Copper concentrations in water<br />

Between 1985 <strong>and</strong> 2005, 86 samples were<br />

collected from several sites in <strong>Burrard</strong> <strong>Inlet</strong>.<br />

Copper levels ranged from 0.0001 mg/L to 0.012<br />

mg/L, with 17 samples (20%) exceeding <strong>the</strong> water<br />

quality guideline maximum of 0.003 mg/L. Data<br />

were examined for change over time, but no<br />

statistically significant trends were apparent.<br />

Samples from <strong>the</strong> Central Harbour had <strong>the</strong> lowest<br />

number of exceedances. These results highlight<br />

<strong>the</strong> difficulties associated with sampling water,<br />

which can easily miss transient events. In such<br />

cases, copper levels in sediment can provide<br />

more reliable indications of changes over time.<br />

Copper concentration in sediment (mg/kg)<br />

Copper in <strong>the</strong> surface microlayer<br />

The surface microlalyer, <strong>the</strong> 50 to 100 micron<br />

thin boundary between water <strong>and</strong> air is<br />

ecologically important. This is <strong>the</strong> area where<br />

complex transport processes occur between<br />

<strong>the</strong> ocean <strong>and</strong> atmosphere <strong>and</strong> where larval<br />

forms of many fish <strong>and</strong> invertebrates live. The<br />

surface microlayer has been shown to contain<br />

contaminants at levels many times higher than<br />

in <strong>the</strong> water column, which may have an<br />

impact on marine life stages that inhabit this<br />

layer.<br />

In 2000, <strong>the</strong> Ministry of Environment collected<br />

surface microlayer samples at six locations in<br />

<strong>Burrard</strong> <strong>Inlet</strong> (Moore <strong>and</strong> Freyman 2001).<br />

Copper levels exceeded water quality<br />

guidelines, <strong>and</strong> were 3 to 30 times higher than<br />

in <strong>the</strong> underlying water. Levels were greatest<br />

in <strong>the</strong> Inner Harbour <strong>and</strong> Port Moody Arm. This<br />

suggests contamination in areas immediately<br />

surrounding point sources, or in embayed<br />

areas adjacent to developed l<strong>and</strong>s, which can<br />

supply atmospheric deposition <strong>and</strong> runoff.<br />

Based on this limited sampling, it is not<br />

expected that significant microlayer<br />

contamination extends over large areas of<br />

Georgia Strait; however, fur<strong>the</strong>r monitoring is<br />

required to characterize <strong>the</strong> environmental<br />

significance of microlayer contamination.<br />

Chart 6-1: Copper Concentrations in <strong>Burrard</strong> <strong>Inlet</strong> Sediment (1985 to 2005)<br />

400<br />

350<br />

Central Harbour<br />

False Creek East<br />

Inner Harbour<br />

Copper concentrations in<br />

sediment have decreased<br />

consistently between 1989 <strong>and</strong><br />

300<br />

250<br />

Outer Harbour North<br />

Outer Harbour South<br />

Port Moody Arm<br />

Sediment quality objective<br />

2005 as shown in Chart 6-1,<br />

although levels still exceed<br />

guidelines (108 mg/kg, probable<br />

200<br />

effects level) at <strong>the</strong> Outer Harbour<br />

North <strong>and</strong> Inner Harbour locations.<br />

150<br />

Levels higher than this guideline<br />

100<br />

put sediment-dwelling organisms<br />

at risk for toxic effects. Historically,<br />

50<br />

levels were highest within <strong>the</strong><br />

0<br />

1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 2004 2006<br />

Inner Harbour <strong>and</strong> lowest in Outer<br />

Harbour South. The amount of<br />

copper in surface sediments is<br />

decreasing, in part due to decreased levels from permitted effluents, combined sewer overflows<br />

<strong>and</strong> industrial sources <strong>and</strong> in part because Metro Vancouver has added buffering to <strong>the</strong> drinking<br />

water (less acidic drinking water results in less leaching of copper from older household pipes).<br />

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